CN105218007A - A kind of corrosion-resistant mortar and preparation method thereof - Google Patents

A kind of corrosion-resistant mortar and preparation method thereof Download PDF

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Publication number
CN105218007A
CN105218007A CN201510640521.8A CN201510640521A CN105218007A CN 105218007 A CN105218007 A CN 105218007A CN 201510640521 A CN201510640521 A CN 201510640521A CN 105218007 A CN105218007 A CN 105218007A
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China
Prior art keywords
mortar
corrosion
sand
cement
resistant mortar
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CN201510640521.8A
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Chinese (zh)
Inventor
沈圣祥
李凤必
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Anhui Kunlong Building Materials Co Ltd
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Anhui Kunlong Building Materials Co Ltd
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Priority to CN201510640521.8A priority Critical patent/CN105218007A/en
Publication of CN105218007A publication Critical patent/CN105218007A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of corrosion-resistant mortar, comprise following raw material: cement, blast furnace slag, potter's clay mine tailing, sand, emulsifying agent, defoamer, calcium formiate, Vltra tears, Ying Zhi Suan Magnesium, hydroxypropyl starch ether, Gluconolactone.The present invention has the following advantages compared to existing technology: the proportioning raw materials optimizing mortar, under given conditions modified-reaction is carried out to mixtures such as the cement in mortar, add sand after reaction again and prepare mortar under given conditions, cement body and aggregate is made to form strong bonding, mortar product has stronger resistance to corrosion, energy acid-and base-resisting, salt and the corrosion of other chemical, resistance to high humidity, ageing-resistant, except for except concrete reinforcing and repairing, the building that chemical industry groove, chemical industry warehouse, refuse landfill etc. need chemically to corrode can also be used for.

Description

A kind of corrosion-resistant mortar and preparation method thereof
Technical field
The invention belongs to architectural chemistry Material Field, be specifically related to a kind of corrosion-resistant mortar and preparation method thereof.
Background technology
Mortar is one of most widely used in current world wide, that consumption is maximum material of construction, adopt ordinary Portland cement, dry hydrate, quartz sand, Paris white, talcum powder etc. to add methyl or Vltra tears etc. more, add redisperable polymer powder in addition again and be made into mortar or become polymer mortar with polymer emulsion co-formulation.
By constantly studying and improving, existing mortar has excellent bonding, cracking resistance, freeze proof, antiseepage, chloride-penetration resistance, ageing-resistant performance, the scope of application increases greatly, is applicable to steel construction and the antiseepage of skeleton construction, anticorrosion mask and the repairing works such as ocean, sluice, waterfall, port engineering, highway, bridge, metallurgy, chemical industry, industry ground slab and covil construction.At special occasions, need to use the mortar with erosion resistance, current existing corrosion-resistant mortar mainly contains following four kinds: acid resisting mortar, sulphur acid resisting mortar, the mortar of resistance to ammonium and alkaline-resisting mortar, but its function is relatively single, cause the shortcoming that Application Areas is little, therefore the research of corrosion-resistant mortar and processing technology need further to improve.
Summary of the invention
The object of the invention is for existing problem, provide a kind of corrosion-resistant mortar and preparation method thereof.
The present invention is achieved by the following technical solutions: a kind of corrosion-resistant mortar, include the raw material of following weight part: cement 20-25 part, blast furnace slag 5-8 part, potter's clay mine tailing 6-10 part, sand 55-65 part, emulsifying agent 2-4 part, defoamer 0.5-1 part, calcium formiate 0.2-0.4 part, Vltra tears 0.3-0.6 part, Ying Zhi Suan Magnesium 0.1-0.3 part, hydroxypropyl starch ether 0.02-0.06 part, Gluconolactone 0.04-0.08 part.
As further improvement of these options, described cement to be strength grade be 42.5 silicate cement and strength grade be the mixture of the sulfate resisting Portland cement of 37.5, blending ratio is 4:1.
As further improvement of these options, described sand is selected from mountain sand, light sand sea sand or Machine-made Sand, and its fineness modulus is 1.6-2.0.
As further improvement of these options, described emulsifying agent is sorbitan fatty acid ester, sylvic acid polyoxyethylene, fatty alcohol-polyoxyethylene ether, the one in lauric acid Soxylat A 25-7 or hydroxylated alkyl groups Soxylat A 25-7.
As further improvement of these options, described defoamer is the mixture of in polyethers, phosphoric acid ester, silicone oil, higher alcohols, vegetables oil, mineral oil at least two kinds.
A preparation method for corrosion-resistant mortar, comprises the following steps:
(1) cement, blast furnace slag, potter's clay mine tailing being finely ground to granularity is 180-200 order, puts into stirrer and stirs;
(2) in powder mix, add the water suitable with its total mass and hydrochloric acid, controlling its pH value is 5.5, and adds the calcium formiate of corresponding deal, Ying Zhi Suan Magnesium, hydroxypropyl starch ether and Gluconolactone, leaves standstill 6-8 hour after stirring;
(3) in step (2) gained mud, add sand, the water of sand weight 10%, lactic acid agent, defoamer and hydroxy-methyl cellulose, control temperature, at 35-45 DEG C, stirs 2-4 hour, obtains mortar finished product.
The present invention has the following advantages compared to existing technology: the proportioning raw materials optimizing mortar, under given conditions modified-reaction is carried out to mixtures such as the cement in mortar, add sand after reaction again and prepare mortar under given conditions, cement body and aggregate is made to form strong bonding, mortar product has stronger resistance to corrosion, energy acid-and base-resisting, salt and the corrosion of other chemical, resistance to high humidity, ageing-resistant, except for except concrete reinforcing and repairing, the building that chemical industry groove, chemical industry warehouse, refuse landfill etc. need chemically to corrode can also be used for.
Embodiment
Embodiment
A kind of corrosion-resistant mortar, include the raw material of following weight part: cement 20-25 part, blast furnace slag 5-8 part, potter's clay mine tailing 6-10 part, sand 55-65 part, emulsifying agent 2-4 part, defoamer 0.5-1 part, calcium formiate 0.2-0.4 part, Vltra tears 0.3-0.6 part, Ying Zhi Suan Magnesium 0.1-0.3 part, hydroxypropyl starch ether 0.02-0.06 part, Gluconolactone 0.04-0.08 part.
Preferably, described cement to be strength grade be 42.5 silicate cement and strength grade be the mixture of the sulfate resisting Portland cement of 37.5, blending ratio is 4:1.
Preferably, described sand Machine-made Sand, its fineness modulus is 1.8.
Preferably, described emulsifying agent is fatty alcohol-polyoxyethylene ether.
Preferably, described defoamer is the mixture of polyoxyethylene polyoxypropylene tetramethylolmethane ether, silicone emulsion and the fatty acid ester compounded thing of higher alcohols, and mixing quality is than being 2:1:1.
A preparation method for corrosion-resistant mortar, comprises the following steps:
(1) cement, blast furnace slag, potter's clay mine tailing being finely ground to granularity is 180-200 order, puts into stirrer and stirs;
(2) in powder mix, add the water suitable with its total mass and hydrochloric acid, controlling its pH value is 5.5, and adds the calcium formiate of corresponding deal, Ying Zhi Suan Magnesium, hydroxypropyl starch ether and Gluconolactone, leaves standstill 6-8 hour after stirring;
(3) in step (2) gained mud, add sand, the water of sand weight 10%, lactic acid agent, defoamer and hydroxy-methyl cellulose, control temperature, at 35-45 DEG C, stirs 2-4 hour, obtains mortar finished product.
In the present invention, mortar can smear use after adding water, after tested, the salient features of mortar is: mortar finished product make after in 1-7 days pH value remain between 6-8, time of coagulation is 3.2 hours, ultimate compression strength (28 days) 0.55MPa, linear shrinkage is 0.28%, water-intake rate is 6.4%, adopt 20% sodium chloride solution, 15% hydrochloric acid soln, 20% sodium hydroxide solution and sample contacts after 48 hours respectively, observe smear layer, there is not the vestige be corroded, illustrate that in the present invention, mortar has stronger resistance to corrosion, can extensively promote the use of.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from spirit of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.

Claims (6)

1. a corrosion-resistant mortar, is characterized in that, includes the raw material of following weight part: cement 20-25 part, blast furnace slag 5-8 part, potter's clay mine tailing 6-10 part, sand 55-65 part, emulsifying agent 2-4 part, defoamer 0.5-1 part, calcium formiate 0.2-0.4 part, Vltra tears 0.3-0.6 part, Ying Zhi Suan Magnesium 0.1-0.3 part, hydroxypropyl starch ether 0.02-0.06 part, Gluconolactone 0.04-0.08 part.
2. a kind of corrosion-resistant mortar as claimed in claim 1, is characterized in that, described cement to be strength grade be 42.5 silicate cement and strength grade be the mixture of the sulfate resisting Portland cement of 37.5, blending ratio is 4:1.
3. a kind of corrosion-resistant mortar as claimed in claim 1, is characterized in that, described sand is selected from mountain sand, light sand sea sand or Machine-made Sand, and its fineness modulus is 1.6-2.0.
4. a kind of corrosion-resistant mortar as claimed in claim 1, it is characterized in that, described emulsifying agent is sorbitan fatty acid ester, sylvic acid polyoxyethylene, fatty alcohol-polyoxyethylene ether, the one in lauric acid Soxylat A 25-7 or hydroxylated alkyl groups Soxylat A 25-7.
5. a kind of corrosion-resistant mortar as claimed in claim 1, it is characterized in that, described defoamer is the mixture of in polyethers, phosphoric acid ester, silicone oil, higher alcohols, vegetables oil, mineral oil at least two kinds.
6. a preparation method for corrosion-resistant mortar, is characterized in that, comprises the following steps:
(1) cement, blast furnace slag, potter's clay mine tailing being finely ground to granularity is 180-200 order, puts into stirrer and stirs;
(2) in powder mix, add the water suitable with its total mass and hydrochloric acid, controlling its pH value is 5.5, and adds the calcium formiate of corresponding deal, Ying Zhi Suan Magnesium, hydroxypropyl starch ether and Gluconolactone, leaves standstill 6-8 hour after stirring;
(3) in step (2) gained mud, add sand, the water of sand weight 10%, lactic acid agent, defoamer and hydroxy-methyl cellulose, control temperature, at 35-45 DEG C, stirs 2-4 hour, obtains mortar finished product.
CN201510640521.8A 2015-09-30 2015-09-30 A kind of corrosion-resistant mortar and preparation method thereof Pending CN105218007A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106116242A (en) * 2016-06-27 2016-11-16 江苏中铁奥莱特新材料股份有限公司 A kind of special defoamer of PHC tubular pile concrete
CN108298900A (en) * 2018-01-29 2018-07-20 中国电力科学研究院有限公司 A kind of transmission pole
CN110409903A (en) * 2018-04-28 2019-11-05 中国电力科学研究院有限公司 A kind of power transmission tower and power transmission tower support column
CN115521121A (en) * 2022-10-14 2022-12-27 江西锦业实业有限公司 Corrosion-resistant cement mortar and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103723966A (en) * 2013-12-07 2014-04-16 马鞍山市金韩防水保温工程有限责任公司 Cement-based modified inorganic insulation mortar
CN104829170A (en) * 2015-01-05 2015-08-12 潍坊德霖建材科技有限公司 Preparation method of high-performance anti-corrosion repairing mortar

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103723966A (en) * 2013-12-07 2014-04-16 马鞍山市金韩防水保温工程有限责任公司 Cement-based modified inorganic insulation mortar
CN104829170A (en) * 2015-01-05 2015-08-12 潍坊德霖建材科技有限公司 Preparation method of high-performance anti-corrosion repairing mortar

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴天宝等: "《固体废物的环境管理》", 31 August 1987 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106116242A (en) * 2016-06-27 2016-11-16 江苏中铁奥莱特新材料股份有限公司 A kind of special defoamer of PHC tubular pile concrete
CN108298900A (en) * 2018-01-29 2018-07-20 中国电力科学研究院有限公司 A kind of transmission pole
CN110409903A (en) * 2018-04-28 2019-11-05 中国电力科学研究院有限公司 A kind of power transmission tower and power transmission tower support column
CN115521121A (en) * 2022-10-14 2022-12-27 江西锦业实业有限公司 Corrosion-resistant cement mortar and preparation method thereof
CN115521121B (en) * 2022-10-14 2023-11-10 中桔(广东)建材科技有限公司 Corrosion-resistant cement mortar and preparation method thereof

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Application publication date: 20160106