CN105200852B - A kind of cigarette paper additive and its cigarette paper of preparation - Google Patents
A kind of cigarette paper additive and its cigarette paper of preparation Download PDFInfo
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- CN105200852B CN105200852B CN201510561948.9A CN201510561948A CN105200852B CN 105200852 B CN105200852 B CN 105200852B CN 201510561948 A CN201510561948 A CN 201510561948A CN 105200852 B CN105200852 B CN 105200852B
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Abstract
The invention provides a kind of cigarette paper additive and its cigarette paper of preparation.The cigarette paper additive, the component calculated by following mass percent form：80% ~ 90% combustionregulator and 10% ~ 20% suction taste improver composition；The combustionregulator is two or more combination in magnesium lactate, potassium lactate, magnesium acetate, potassium acetate, described to inhale two or more combination that taste improver is 11 L alanyls fructose of deoxidation, 11 L prolyls fructose of deoxidation, galactosamine and gucosamine.The cigarette paper additive, by reasonably combined combustionregulator and taste improver is inhaled, is added on cigarette paper, and applied on cigarette, the CO contents in main flume can be effectively reduced, reducing flue gas stimulates, abundant smoke perfume, effectively lift the aesthetic quality of cigarette.
Description
Technical field
The present invention relates to Field of Tobacco, can effectively reduce content of CO in smoke more particularly, to one kind, lift cigarette sense organ
The cigarette paper additive of quality and its cigarette paper of preparation.
Background technology
Cigarette paper is the important materials in production of cigarettes, is one of effective way for realizing Harm reduction techniques tar reduction target.Volume
Being mainly characterized by of cigarette paper directly participates in cigarette burning, its smolderability, burning velocity, cigarette main flume and effluent to cigarette
Burst size, harmful ingredients in flue gas burst size, cigarette odor-absorbing and presentation quality of flue gas etc. have a major impact.The combustion of cigarette paper
The combustibility of performance impact cigarette is burnt, and to be matched with the combustibility of cigarette.The good cigarette paper of flammability can be accelerated
The Static burning rate of cigarette, reduce puff number.Additive in the combustibility and cigarette paper of cigarette paper has much relations,
The species and dosage of additive particularly combustionregulator in cigarette paper directly affect the burning velocity of cigarette, puff number,
The burst size of smoke delivery and harmful substances in flue gas.The use of combustionregulator do not require nothing more than the burn rate of cigarette paper with
The burn rate of cigarette matches, and also to ensure that its suction taste to cigarette does not have a negative impact, or even to cigarette sensory quality
There is castering action.Currently, more researcher adds different combustionregulators in cigarette paper, to reduce the nuisance in flue gas
Matter content, but the addition of combustionregulator so that tarry matters in smoke amount is reduced, and fragrance flavor component is reduced, Sensory Quality of Cigarette drop
It is low.The present invention is exactly the deficiency for combustionregulator is used alone, and taste improver is inhaled in increase, makes up cigarette flavor, lifting volume
Cigarette aesthetic quality.
The content of the invention
It is an object of the invention to provide one kind to reduce content of CO in smoke, lifts the cigarette paper addition of Sensory Quality of Cigarette
Agent.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
A kind of cigarette paper additive, the component calculated by following mass percent form：80% ~ 90% combustionregulator
Taste improver composition is inhaled with 10% ~ 20%；The combustionregulator is two in magnesium lactate, potassium lactate, magnesium acetate, potassium acetate
Kind or two or more combinations, the suction taste improver is 1- deoxidations -1-L- alanyls-fructose, 1- deoxidation -1-L- prolyls
Two or more combination of base-fructose, galactosamine and gucosamine.
The combustionregulator can effectively adjust the combustibility of cigarette, and cigarette burn rate has significant change, burning temperature
Degree is obvious to be reduced, and the releasing content of coke tar in flue gas reduces, and the harmful substance contents such as CO substantially reduce；In the suction taste improver,
1- deoxidations -1-L- alanyls-fructose also known as 1-L- alanine -1- deoxidations-D-Fructose, 1- deoxidations -1-L- prolyls-fructose
Also known as-L-PROLINE -1- deoxidations-D-Fructose, be all with galactosamine and gucosamine Maillard reaction intermediate product, its by
The compounds such as pyrroles, pyrazine, furans are produced in thermal process, cigarette flavor can be enriched.By reasonable coordination inhale taste improver with
The ratio of combustionregulator, Sensory Quality of Cigarette can be effectively lifted, reduce flue gas harmful substance contents.
Preferably, the suction taste improver is following one of which：1- deoxidations -1-L- prolyls-fructose and galactolipin
The combination of amine, the combination of 1- deoxidations -1-L- prolyls-fructose and gucosamine, 1- deoxidations -1-L- prolyls-fructose and
The combination of 1- deoxidations -1-L- alanyls-fructose, the combination of 1- deoxidations -1-L- alanyls-fructose and galactosamine, 1- are gone
The combination of oxygen -1-L- alanyls-fructose and gucosamine, 1- deoxidations -1-L- prolyls-fructose, galactosamine and grape
The combination of osamine, the combination of 1- deoxidations -1-L- prolyls-fructose, 1- deoxidations -1-L- alanyls-fructose and galactosamine,
1- deoxidations -1-L- prolyls-fructose, the combination of 1- deoxidations -1-L- alanyls-fructose and gucosamine, 1- deoxidations -1-L-
The combination of alanyl-fructose, 1- deoxidations -1-L- prolyls-fructose, galactosamine and gucosamine..
Preferably, the component that the suction taste improver is calculated by following mass percent forms：50% ~ 90% 1- deoxidations -1-
L- prolyls-fructose and 10% ~ 50% galactosamine.
Preferably, the component calculated by following mass percent forms：90% combustionregulator and 10% suction taste improve
Agent.
It is highly preferred that the component that the suction taste improver is calculated by following mass percent forms：60% ~ 80% 1- deoxidations-
1-L- prolyls-fructose and 20% ~ 40% galactosamine.Further, by 80% 1- deoxidations -1-L- prolyls-fructose and
The composition of 20% galactosamine.
Preferably, in the combustionregulator, the component calculated by following mass percent forms：50% ~ 80% potassium
Salt and 20% ~ 50% magnesium salts.
It is highly preferred that the combustionregulator is the combination of magnesium lactate and potassium lactate.
It is highly preferred that the combustionregulator, the component calculated by following mass percent forms：60% potassium lactate and
40% magnesium lactate.
Another object of the present invention is to provide application of the above-mentioned cigarette paper additive in cigarette paper is prepared.
As an embodiment, the application comprises the following steps：
S1. the cigarette paper additive is configured to the aqueous solution that mass percentage concentration is 10 ~ 30%；
S2. prepared to step S1 in the obtained aqueous solution, add lactic acid, regulation pH value is 6.0 ~ 8.0；
S3. the step S2 aqueous solution for preparing to obtain is added on cigarette paper, cigarette paper product is made.
More particularly, according to the existing production equipment of cigarette paper, production technology carries out with slurry, copy paper, applying glue.In cigarette
In paper Process of Applying Glue, the aqueous solution containing the cigarette paper additive is coated on cigarette paper, addition manner is according to product type
Choose the mode being coated or impregnated with and carry out single or double applying glue, then require that cutting is after drying according still further to papermaking common process
Cigarette paper.
Another object of the present invention is to provide a kind of cigarette paper containing above-mentioned additive, and the additive is in cigarette
Ratio in paper is the 0.5% ~ 3.5% of cigarette paper dry weight.
It is highly preferred that ratio of the cigarette paper additive in cigarette paper is the 2.0% of cigarette paper dry weight.
The cigarette paper additive is applied to the combustibility that cigarette is can effectively improve on cigarette paper, with control sample condition
Burst size of the releasing content of coke tar without harmful substances such as significant change, CO substantially reduces reduction, cigarette in flue gas during than, cigarette burning
It is unchanged to aspirate style, flue gas excitant reduces, and flue gas concentration improves, more full and sweet, can effectively lift the sense of cigarette
Official's mass.
Another object of the present invention is to provide the application in cigarette containing above-mentioned additive cigarette paper.
Compared with prior art, the beneficial effects of the invention are as follows：
Cigarette paper additive of the present invention, by reasonably combined combustionregulator and taste conditioning agent is inhaled, can effectively be adjusted
Cigarette burning performance is saved, will be applied containing the additive cigarette paper on cigarette, the combustibility of cigarette can be effectively improved,
The burst size of the pernicious gas such as CO in cigarette smoke is reduced, cigarette flavor is enriched, increasing smoke concentration, reduces the stimulation of flue gas
Property, effective aesthetic quality for lifting cigarette.
Embodiment
The present invention is further described by specific examples below, it will be appreciated that specific implementation described herein
Example is only used for explaining the present invention, is not intended to limit the present invention, and can carry out various change in the range of right of the present invention restriction
Become.
In embodiment and comparative example, pipe tobacco used is all homogeneously double happiness（It is classical）Pipe tobacco, the limited duty of cigarette industry in Guangdong
Ren companies carry out cigarette sample experiment.
Embodiment 1
700kg paper pulp is taken, 280kg fillers, after stirring, with slurry, copy paper is carried out according to common process.Applied in cigarette paper
In the glue stage, extracting lactic acid magnesium 7.2kg, potassium lactate 10.8kg, it is dissolved in 100kg water, is mixing uniformly to form settled solution；Above-mentioned
1- deoxidations -1-L- prolyls-fructose 1.6kg is added in solution, galactosamine 0.4kg, is stirred after forming settled solution,
Lactic acid is slowly added to, gradually the pH value of regulation solution to 6.5.The above-mentioned additive solution prepared is added in applying glue bucket, used
Double spread mode is glued, and additive is uniformly coated on cigarette paper, is glued speed by controlling, is added cigarette paper
Content of the agent in cigarette paper is 2.0%（In terms of cigarette paper dry weight）.Dried at being 100 DEG C in temperature after cigarette paper applying glue,
So that moisture is about 5.0% in cigarette paper, cigarette paper product is made after cutting, the technical parameter of cigarette paper is as shown in table 1.
Embodiment 2
700kg paper pulp is taken, 290kg fillers, after stirring, with slurry, copy paper is carried out according to common process.Applied in cigarette paper
In the glue stage, extracting lactic acid magnesium 3.6kg, potassium lactate 5.4kg, it is dissolved in 100kg water, is mixing uniformly to form settled solution；Above-mentioned
1- deoxidations -1-L- prolyls-fructose 0.8kg is added in solution, galactosamine 0.2kg, is stirred after forming settled solution,
Lactic acid is slowly added to, gradually the pH value of regulation solution to 6.5.The above-mentioned additive solution prepared is added in applying glue bucket, used
Double spread mode is glued, and additive is uniformly coated on cigarette paper, is glued speed by controlling, is added cigarette paper
Content of the agent in cigarette paper is 1.0%（In terms of cigarette paper dry weight）.Dried at being 100 DEG C in temperature after cigarette paper applying glue,
So that moisture is about 5.0% in cigarette paper, cigarette paper product is made after cutting, the technical parameter of cigarette paper is as shown in table 1.
Embodiment 3
700kg paper pulp is taken, 270kg fillers, after stirring, with slurry, copy paper is carried out according to common process.Applied in cigarette paper
In the glue stage, the kg of extracting lactic acid magnesium 10.8, the kg of potassium lactate 16.2, it is dissolved in 100 kg water, is mixing uniformly to form settled solution；
1- deoxidations -1-L- prolyls-kg of fructose 2.4 is added in above-mentioned solution, the kg of galactosamine 0.6, stirs to form clarification
After solution, lactic acid is slowly added to, gradually the pH value of regulation solution to 6.5.The above-mentioned additive solution prepared is added into applying glue bucket
In, it is glued using double spread mode, additive is uniformly coated on cigarette paper, is glued speed by controlling, makes volume
Content of the cigarette paper additive in cigarette paper is 3.0%（In terms of cigarette paper dry weight）.After cigarette paper applying glue in the case where temperature is 100 DEG C
Dried so that moisture is about 5.0% in cigarette paper, cigarette paper product is made after cutting, the technical parameter of cigarette paper is such as
Shown in table 1.
Embodiment 4
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 9.0
Kg, potassium lactate 9.0 kg, 1- deoxidation -1-L- prolyls-fructose 1.6kg, galactosamine 0.4kg, the technology of cigarette paper is made
Parameter is as shown in table 1.
Embodiment 5
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 6.0
Kg, potassium lactate 12.0 kg, 1- deoxidation -1-L- prolyls-fructose 1.6kg, galactosamine 0.4kg, the skill of cigarette paper is made
Art parameter is as shown in table 1.
Embodiment 6
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium acetate 7.2
Kg, potassium acetate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 1.6kg, galactosamine 0.4kg, the skill of cigarette paper is made
Art parameter is as shown in table 1.
Embodiment 7
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, 1- deoxidation -1-L- prolyls-kg of fructose 1.0, the kg of galactosamine 1.0, cigarette paper is made
Technical parameter is as shown in table 1.
Embodiment 8
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 1.8kg, the kg of galactosamine 0.2, the skill of cigarette paper is made
Art parameter is as shown in table 1.
Embodiment 9
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 1.2kg, galactosamine 0.8kg, the skill of cigarette paper is made
Art parameter is as shown in table 1.
Embodiment 10
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium acetate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 1.6kg, galactosamine 0.4kg, the technology of cigarette paper is made
Parameter is as shown in table 1.
Embodiment 11
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium acetate 7.2
Kg, potassium lactate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 1.6kg, galactosamine 0.4kg, the technology of cigarette paper is made
Parameter is as shown in table 1.
Embodiment 12
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate
7.2kg, potassium lactate 10.8kg, gucosamine 1.6kg, galactosamine 0.4kg, the technical parameter that cigarette paper is made are as shown in table 1.
Embodiment 13
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 0.9 kg, 1- deoxidation -1-L- alanyls-fructose 0.9
Kg, the kg of galactosamine 0.2, the technical parameter that cigarette paper is made are as shown in table 1.
Embodiment 14
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, 1- deoxidation -1-L- prolyls-fructose 0.9 kg, 1- deoxidation -1-L- alanyls-fructose 0.9
Kg, the kg of galactosamine 0.1, the kg of gucosamine 0.1, the technical parameter that cigarette paper is made are as shown in table 1.
Embodiment 15
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 1.8
Kg, potassium lactate 16.2 kg, 1- deoxidation -1-L- prolyls-fructose 1.8kg, the kg of galactosamine 0.2, the skill of cigarette paper is made
Art parameter is as shown in table 1.
Embodiment 16
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate
16.2 kg, potassium lactate 1.8 kg, 1- deoxidation -1-L- prolyls-fructose 1.8kg, the kg of galactosamine 0.2, cigarette paper is made
Technical parameter it is as shown in table 1.
Embodiment 17
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 1.8
Kg, potassium lactate 16.2 kg, 1- deoxidation -1-L- prolyls-kg of fructose 0.4, the kg of galactosamine 1.6, cigarette paper is made
Technical parameter is as shown in table 1.
Comparative example 1
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, the 1- deoxidation -1-L- prolyls-kg of fructose 2.0, the technical parameter such as institute of table 1 of cigarette paper is made
Show.
Comparative example 2
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, the kg of potassium lactate 10.8, the kg of galactosamine 2.0, the technical parameter that cigarette paper is made are as shown in table 1.
Comparative example 3
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, potassium lactate 10.8 kg, the 1- deoxidation -1-L- alanyls-kg of fructose 2.0, the technical parameter such as institute of table 1 of cigarette paper is made
Show.
Comparative example 4
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 7.2
Kg, the kg of potassium lactate 10.8, the kg of gucosamine 2.0, the technical parameter that cigarette paper is made are as shown in table 1.
Comparative example 5
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Magnesium lactate 18
Kg, 1- deoxidation -1-L- prolyls-fructose 1.8kg, the kg of galactosamine 0.2, the technical parameter such as institute of table 1 of obtained cigarette paper
Show.
Comparative example 6
Preparation method is same as Example 1, and the component of cigarette paper additive is as different from Example 1：Potassium lactate
18.0 kg, 1- deoxidation -1-L- prolyls-fructose 1.8kg, the kg of galactosamine 0.2, the technical parameter such as table of obtained cigarette paper
Shown in 1.
Control sample
Preparation method is same as Example 1, as different from Example 1 in cigarette paper production process, does not add cigarette
Paper additive, the technical parameter that cigarette paper is made are as shown in table 1.
Take above-described embodiment and cigarette paper prepared by comparative example and be not added with the cigarette paper of cigarette paper additive of the present invention
For control sample, the technical parameter of each cigarette paper is shown in Table 1.It is in the case of pipe tobacco and other cigarette material identicals, cigarette is made of paper
Into the cigarette finished product of same size.
The cigarette paper technical parameter of table 1
Smoke chemistry constituent analysis is carried out to above-mentioned cigarette sample, Jiao in flue gas is determined using GB/T 19609-2004
Oil content；Smoking nicotine content is determined using GB/T 23355-2009；Carbon monoxide in flue gas is determined using GB/T23356-2009
Content, analysis result are as shown in table 2.
The cigarette sample smoke chemistry composition analysis result of table 2
As known from Table 2, compared with control sample, tar, nicotine and the CO burst sizes of embodiment and comparative example have significantly
Reduce, the reduction amplitude of wherein CO burst sizes is maximum, and maximum reduction amount is 2.3 mg/cig, the range of decrease 17.97%.This shows, adopts
With the additive application of the present invention on cigarette paper, can reduce has harmful substance contents in flue gas, the reduction width especially to CO
Degree is the most obvious.
Sensory evaluating smoking is carried out to above-mentioned cigarette, method of smokeing panel test is with reference to tobacco business standard YC/T138-1998《Tobacco and cigarette
Straw-made articles sensory evaluation method》Evaluation method, it the results are shown in Table 3.As known from Table 3, it is of the present invention compared with control sample
Embodiment cigarette style characteristic it is unchanged, fragrance vector is more sufficient, and miscellaneous gas diminishes, stimulate degree relative reduction, cigarette
Sense organ comprehensive score significantly improves compared with control sample, and this illustrates that cigarette paper additive of the present invention is reducing flue gas CO etc.
While harmful components, there is castering action to Sensory Quality of Cigarette, there is upgrading harm reduction.
Due to cigarette sensory evaluating smoking, pipe tobacco is main contributor, and paper substrate is secondary cause.Generally change the species of pipe tobacco
The larger difference of score generation of smokeing panel test can be caused.From comparative example 1 to 6 it is recognised that being carried out using to paper substrate compared with control sample
Optimization, in general it is only capable of lifting 0.5 ~ 2 point of sensory evaluation scores；And after rational allocation of the inventor to inhaling taste improver, energy
Lift 1.5 ~ 6.5 points again on the basis of original lifting, reach significant effect.
The cigarette sensory evaluating smoking's score of table 3
Cigarette smoke Studies on Analysis of Flavor Constituents
Gather the cigarette smoke of embodiment 1 and control sample, by gas chromatography/mass spectrometry (GC/MS) carry out smoke perfume into
Analysis, its result is as shown in table 4, and numerical value is the relative value that standard sample dosage is added in GC/MS in table（%）.
The cigarette smoke Studies on Analysis of Flavor Constituents result of table 4
| Gas componant/species | 1/% of embodiment | Control sample/% |
| Pyrazine | 17 | 9 |
| Pyroles | 15 | 10 |
| Furans | 19 | 12 |
| Organic acid | 22 | 19 |
| Phenols | 11 | 8 |
| It is accumulative | 84 | 58 |
From table 4, it can be seen that compared with control sample, in flue gas caused by cigarette prepared by embodiment 1, Pyrazine, pyrrole
Class and furfuran compound showed increased are coughed up, smoke perfume composition more horn of plenty, this explanation is using cigarette paper application of the invention
On cigarette, flavor component species in flue gas can be increased, enrich flavor component, lift aesthetic quality.
Obviously, the above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not pair
The restriction of embodiments of the present invention.For those of ordinary skill in the field, may be used also on the basis of the above description
To make other changes in different forms.There is no necessity and possibility to exhaust all the enbodiments.It is all this
All any modification, equivalent and improvement made within the spirit and principle of invention etc., should be included in the claims in the present invention
Protection domain within.
Claims (7)
1. a kind of cigarette paper additive, it is characterised in that the component calculated by following mass percent forms：80% ~ 90% combustion
Burn conditioning agent and 10% ~ 20% and inhale taste improver composition；The combustionregulator is magnesium lactate, potassium lactate, magnesium acetate, acetic acid
Two or more combinations in potassium；The component that the suction taste improver is calculated by following mass percent forms：50% ~ 90% 1- is gone
Oxygen -1-L- prolyls-fructose and 10% ~ 50% galactosamine；In the combustionregulator, by following mass percent meter
The component composition of calculation：50% ~ 80% sylvite and 20% ~ 50% magnesium salts.
2. cigarette paper additive according to claim 1, it is characterised in that the component group calculated by following mass percent
Into：90% combustionregulator and 10% suction taste improver.
3. cigarette paper additive according to claim 1, it is characterised in that the combustionregulator is magnesium lactate and lactic acid
The combination of potassium.
4. cigarette paper additive according to claim 3, it is characterised in that the combustionregulator, by following quality hundred
Divide the component composition than calculating：60% potassium lactate and 40% magnesium lactate.
5. application of the cigarette paper additive described in any one of Claims 1-4 in cigarette paper is prepared.
6. application according to claim 5, it is characterised in that comprise the following steps：
S1. the cigarette paper additive is configured to the aqueous solution that mass percentage concentration is 10 ~ 30%；
S2. prepared to step S1 in the obtained aqueous solution, add lactic acid, regulation pH value is 6.0 ~ 8.0；
S3. the step S2 aqueous solution for preparing to obtain is added on cigarette paper, cigarette paper product is made.
A kind of 7. cigarette paper, it is characterised in that containing the cigarette paper additive described in any one of claim 1 ~ 4, the cigarette
Ratio of the Paper additive in cigarette paper is the 0.5% ~ 3.5% of cigarette paper dry weight.
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| CN110846937B (en) * | 2019-11-04 | 2021-11-26 | 湖北中烟工业有限责任公司 | Heating non-combustion cigarette paper containing thermoplastic expansion microspheres and cigarette |
| CN113445367A (en) * | 2021-07-12 | 2021-09-28 | 云南中烟工业有限责任公司 | Colored cigarette paper containing Maillard reaction intermediate and preparation method thereof |
| CN113445366B (en) * | 2021-07-12 | 2023-04-25 | 云南中烟工业有限责任公司 | Black cigarette paper and preparation method thereof |
| CN115197780B (en) * | 2022-06-30 | 2023-09-15 | 河南中烟工业有限责任公司 | Method for preparing heterocyclic compound from sugar-amino acid condensate and application of heterocyclic compound |
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| CN102038284A (en) * | 2010-12-07 | 2011-05-04 | 广东中烟工业有限责任公司 | Tobacco addition and application thereof |
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