Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of preparation method with the high voltage suspended electric power ceramic wiring terminal of alumina base of high compressive strength.
A preparation method for high voltage suspended electric power ceramic wiring terminal,
The preparation method of described ceramic wiring terminal comprises following preparation process:
(1) get the raw materials ready: with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive;
The weight part of each raw material is:
Nano aluminium oxide 10-50 part;
Barium titanate 10-50 part;
Sericite 10-50 part;
Methyl vinyl silicone rubber 5-15 part;
Mullite 5-15 part;
Talcum 5-15 part;
Clay 5-15 part;
Lazurite 5-15 part;
Zirconium white 5-15 part that yttrium is stable;
Zinc oxide 5-15 part;
Titanium oxide 5-15 part;
Ferric oxide 1-4 part;
Niobium oxides 1-4 part;
Manganse Dioxide 1-4 part;
Explosion-proof fiber 1-4 part;
Chromic oxide 1-4 part;
Nickel oxide 1-4 part;
(2) pre-burning: mixed by each raw material, at 200-300 degree Celsius of lower pre-burning 1-3 hour, obtains Preburning material;
(3) ball milling: Preburning material is mixed, then adds appropriate water, according to Preburning material: ball: water=1:2:1, ball milling 24-48 hour;
(4) granulating and forming: by the granulation of ball milling material, and cold isostatic compaction;
(5) burn till: at 600-650 DEG C, burn till 1-2 hour, and then calcine 1-2 hour at 1500-1600 DEG C.
As preferably: described pre-burning, 250 degrees Celsius of lower pre-burnings 2 hours, obtains Preburning material.
As preferably: the weight part of each raw material is:
Nano aluminium oxide 30 parts;
Barium titanate 30 parts;
Sericite 30 parts;
Methyl vinyl silicone rubber 9 parts;
Mullite 9 parts;
9 parts, talcum;
Clay 9 parts;
Lazurite 7 parts;
The zirconium white 7 parts that yttrium is stable;
7 parts, zinc oxide;
Titanium oxide 7 parts;
Ferric oxide 2 parts;
Niobium oxides 2 parts;
Manganse Dioxide 2 parts;
Explosion-proof fiber 2 parts;
1 part, chromic oxide;
Nickel oxide 1 part.
As preferably: the particle diameter of described nano aluminium oxide is 30-70nm.
As preferably: the time of described ball milling step is 36 hours.
As preferably: described in burn till burn till 1.5 hours at 620 DEG C, and then to calcine 1.5 hours at 1550 DEG C.
Beneficial effect of the present invention:
By reasonable preparation raw material, adopt the method for solid state sintering, with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive, have prepared the high voltage suspended electric power ceramic wiring terminal with high compressive strength.
The present invention is in the selection of main raw material, the nano aluminium oxide adopting physical and chemical performance more superior is as main material, by selecting the aluminum oxide of Nano grade, it has larger specific surface area and more superior tap density and more excellent mechanical property and anti-pressure ability.Simultaneously, the three kinds of materials that employ of the invention are main material, barium titanate and sericite, not only from the main material cost reducing nano aluminium oxide, meanwhile, also by the supplement effect of laminate structure, create supplement effect, meanwhile, heat-resisting, the resistance to compression of sericite and barium titanate and whippy physics and chemistry function, will produce synergistic effect and devotion effect to nano aluminium oxide.Meanwhile, also containing a lot of trace element in sericite, certain sintering aid effect will be played in sintering process.And in the selection of auxiliary material, methyl vinyl silicone rubber is modified rubber, by the compound with inorganic materials, the mechanical property of stupalith can be improved; And the stable zirconium white of mullite, talcum, clay, lazurite, yttrium plays enhancement for the performance such as anti-pressure and abrasion-proof strengthening stupalith.And the introducing of zinc oxide and titanium oxide, the self-cleaning ability of terminal stud can be improved; In the selection of additive, the present invention introduces multiple additives metal oxide, by the doping of metallic element, the performances such as the surface resistivity of pottery can be made to be optimized, then improve the voltage endurance capability of pottery.This ceramsite preparation process is simple, is applicable to suitability for industrialized production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
A preparation method for high voltage suspended electric power ceramic wiring terminal,
The preparation method of described ceramic wiring terminal comprises following preparation process:
(1) get the raw materials ready: with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive;
The weight part of each raw material is:
Nano aluminium oxide 30 parts;
Barium titanate 30 parts;
Sericite 30 parts;
Methyl vinyl silicone rubber 9 parts;
Mullite 9 parts;
9 parts, talcum;
Clay 9 parts;
Lazurite 7 parts;
The zirconium white 7 parts that yttrium is stable;
7 parts, zinc oxide;
Titanium oxide 7 parts;
Ferric oxide 2 parts;
Niobium oxides 2 parts;
Manganse Dioxide 2 parts;
Explosion-proof fiber 2 parts;
1 part, chromic oxide;
Nickel oxide 1 part;
(2) pre-burning: mixed by each raw material, 250 degrees Celsius of lower pre-burnings 2 hours, obtains Preburning material;
(3) ball milling: Preburning material is mixed, then adds appropriate water, according to Preburning material: ball: water=1:2:1, ball milling 36 hours;
(4) granulating and forming: by the granulation of ball milling material, and cold isostatic compaction;
(5) burn till: at 650 DEG C, burn till 1.5 hours, and then calcine 1.5 hours at 1550 DEG C.
Embodiment 2:
A preparation method for high voltage suspended electric power ceramic wiring terminal,
The preparation method of described ceramic wiring terminal comprises following preparation process:
(1) get the raw materials ready: with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive;
The weight part of each raw material is:
Nano aluminium oxide 35 parts;
Barium titanate 35 parts;
Sericite 35 parts;
Methyl vinyl silicone rubber 11 parts;
Mullite 11 parts;
11 parts, talcum;
Clay 11 parts;
Lazurite 7 parts;
The zirconium white 7 parts that yttrium is stable;
7 parts, zinc oxide;
Titanium oxide 7 parts;
Ferric oxide 1 part;
Niobium oxides 2 parts;
Manganse Dioxide 1 part;
Explosion-proof fiber 2 parts;
2 parts, chromic oxide;
Nickel oxide 1 part;
(2) pre-burning: each raw material is mixed, pre-burning 3 hours, obtains Preburning material at 300 degrees Celsius;
(3) ball milling: Preburning material is mixed, then adds appropriate water, according to Preburning material: ball: water=1:2:1, ball milling 48 hours;
(4) granulating and forming: by the granulation of ball milling material, and cold isostatic compaction;
(5) burn till: at 650 DEG C, burn till 2 hours, and then calcine 2 hours at 1600 DEG C.
Embodiment 3:
A preparation method for high voltage suspended electric power ceramic wiring terminal,
The preparation method of described ceramic wiring terminal comprises following preparation process:
(1) get the raw materials ready: with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive;
The weight part of each raw material is:
Nano aluminium oxide 50 parts;
Barium titanate 50 parts;
Sericite 50 parts;
Methyl vinyl silicone rubber 15 parts;
Mullite 15 parts;
15 parts, talcum;
Clay 15 parts;
Lazurite 7 parts;
The zirconium white 7 parts that yttrium is stable;
7 parts, zinc oxide;
Titanium oxide 7 parts;
Ferric oxide 2 parts;
Niobium oxides 2 parts;
Manganse Dioxide 2 parts;
Explosion-proof fiber 2 parts;
1 part, chromic oxide;
Nickel oxide 1 part;
(2) pre-burning: each raw material is mixed, pre-burning 1 hour, obtains Preburning material at 200 degrees celsius;
(3) ball milling: Preburning material is mixed, then adds appropriate water, according to Preburning material: ball: water=1:2:1, ball milling 24 hours;
(4) granulating and forming: by the granulation of ball milling material, and cold isostatic compaction;
(5) burn till: at 600 DEG C, burn till 1 hour, and then calcine 1 hour at 1500 DEG C.
Embodiment 4:
A preparation method for high voltage suspended electric power ceramic wiring terminal,
The preparation method of described ceramic wiring terminal comprises following preparation process:
(1) get the raw materials ready: with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive;
The weight part of each raw material is:
Nano aluminium oxide 10 parts;
Barium titanate 10 parts;
Sericite 10 parts;
Methyl vinyl silicone rubber 5 parts;
Mullite 5 parts;
5 parts, talcum;
Clay 5 parts;
Lazurite 5 parts;
The zirconium white 5 parts that yttrium is stable;
5 parts, zinc oxide;
Titanium oxide 5 parts;
Ferric oxide 1 part;
Niobium oxides 1 part;
Manganse Dioxide 1 part;
Explosion-proof fiber 1 part;
1 part, chromic oxide;
Nickel oxide 1 part;
(2) pre-burning: each raw material is mixed, pre-burning 1 hour, obtains Preburning material at 200 degrees celsius;
(3) ball milling: Preburning material is mixed, then adds appropriate water, according to Preburning material: ball: water=1:2:1, ball milling 24 hours;
(4) granulating and forming: by the granulation of ball milling material, and cold isostatic compaction;
(5) burn till: at 600 DEG C, burn till 1 hour, and then calcine 1 hour at 1500 DEG C.
Embodiment 5:
A preparation method for high voltage suspended electric power ceramic wiring terminal,
The preparation method of described ceramic wiring terminal comprises following preparation process:
(1) get the raw materials ready: with nano aluminium oxide, barium titanate and sericite for main raw material, with stable zirconium white, zinc oxide and the titanium oxide of methyl vinyl silicone rubber, mullite, talcum, clay, lazurite, yttrium for ancillary component, with ferric oxide, niobium oxides, Manganse Dioxide, explosion-proof fiber, chromic oxide and nickel oxide are additive;
The weight part of each raw material is:
Nano aluminium oxide 50 parts;
Barium titanate 50 parts;
Sericite 35 parts;
Methyl vinyl silicone rubber 10 parts;
Mullite 10 parts;
10 parts, talcum;
Clay 10 parts;
Lazurite 10 parts;
The zirconium white 10 parts that yttrium is stable;
10 parts, zinc oxide;
Titanium oxide 10 parts;
Ferric oxide 3 parts;
Niobium oxides 3 parts;
Manganse Dioxide 3 parts;
Explosion-proof fiber 3 parts;
3 parts, chromic oxide;
Nickel oxide 3 parts;
(2) pre-burning: mixed by each raw material, 250 degrees Celsius of lower pre-burnings 2 hours, obtains Preburning material;
(3) ball milling: Preburning material is mixed, then adds appropriate water, according to Preburning material: ball: water=1:2:1, ball milling 36 hours;
(4) granulating and forming: by the granulation of ball milling material, and cold isostatic compaction;
(5) burn till: at 625 DEG C, burn till 1 hour, and then calcine 1 hour at 1550 DEG C.
The physical measurement data of the embodiment of the present invention are as follows:
|
Vickers' hardness/Gpa |
Ultimate compression strength/Mpa |
Specific inductivity |
Embodiment 1 |
66 |
790 |
9.08 |
Embodiment 2 |
69 |
800 |
8.99 |
Embodiment 3 |
68 |
795 |
9.12 |
Embodiment 4 |
65 |
815 |
9.15 |
Embodiment 5 |
70 |
810 |
9.20 |
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.