CN105191931B - A kind of composition of agricultural synergist and anabasine insecticide - Google Patents
A kind of composition of agricultural synergist and anabasine insecticide Download PDFInfo
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- CN105191931B CN105191931B CN201510505847.XA CN201510505847A CN105191931B CN 105191931 B CN105191931 B CN 105191931B CN 201510505847 A CN201510505847 A CN 201510505847A CN 105191931 B CN105191931 B CN 105191931B
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Abstract
The present invention relates to a kind of agricultural synergist and the composition of anabasine insecticide, includes agricultural synergist and one or more anabasine insecticides.Wherein, the agricultural synergist is NF 100, one or more of the anabasine insecticide in imidacloprid, Acetamiprid, Nitenpyram, thiacloprid, Diacloden, MTI-446, and the weight of the agricultural synergist and anabasine insecticide ratio is 1: 5 200.
Description
Technical field
The present invention relates to agriculture field, and in particular to the composition of a kind of agricultural synergist and anabasine insecticide and its
Using.
Background technology
China is a large agricultural country, the use of agricultural chemicals is be unable to do without in actual agricultural production, still, with agricultural pests
The influence of the extension of chemical prevention medication history, the agricultural chemicals not factor such as scientifical use, it follows that agricultural pests resistance day
Beneficial serious, the pest species for producing resistance are persistently increasing, and are one of current agricultural problems for being badly in need of solving.
Anabasine compound is a kind of efficient, novel pesticide of safety, high selectivity, and market development at home and abroad is very
It hurry up, China has begun to the research and development to anabasine insecticide from the end of the eighties in last century, has obtained many progress at present.
Anabasine insecticide be the rule-activator effect as post-synapse nAChR in insect CNS, due to
Its mode of action is unique, and it shows excellent preventive effect and relatively low to mammalian toxicity to current multiple resistance insect,
Such as homoptera pest can be effectively prevented and treated, and coleoptera, Diptera and lepidoptera pest etc..But with anabasine desinsection
The long-term large area of agent is applied, it has now been found that many insects generate resistance to anabasine insecticide.
NF-100 is the organic silicon surfactant that a kind of commercially available glycosyl is modified, it is known that there is preferably wetting to open up energy for it
Power, improve diffusion and infiltration of the drop in crop surface.At present in actual applications, insecticides adjuvant use is mainly used as,
To improve the physical property of pesticidal preparations.On its as synergist to increase pesticide activity in terms of, prior art does not have any
Report.
Because above-mentioned problems be present in prior art, thus exist searching can increase anabasine insecticide work
Property, extend the current demand of its service life.
The content of the invention
To solve the problems, such as that prior art is present, the present inventor have passed through long-term research, and discovery agricultural synergist is NF-
100 can be effectively increased the insecticidal effect of anabasine insecticide, alleviate development of drug resistance.Based on the discovery, inventor completes
The present invention.
It is an object of the invention to provide the composition and its application of a kind of agricultural synergist and anabasine insecticide.This
Invention is achieved through the following technical solutions：
One aspect of the present invention is related to a kind of composition of agricultural synergist and anabasine insecticide, includes agricultural synergist
With one or more anabasine insecticides, wherein, the agricultural synergist is NF-100.
Preferably, in the present compositions, the weight ratio of the agricultural synergist and anabasine insecticide is 1:
5-200, preferably 1: 10-100, more preferably 1: 20-60, most preferably 1: 25.
Preferably, in the present compositions, the anabasine insecticide is selected from imidacloprid, Acetamiprid, alkene pyridine worm
One or more in amine, thiacloprid, Diacloden, MTI-446.It is highly preferred that the anabasine insecticide be selected from imidacloprid,
One or more in Acetamiprid, Nitenpyram, thiacloprid.Most preferably, the anabasine insecticide is selected from Nitenpyram.
Another aspect of the present invention is related to a kind of insecticide, wherein, the insecticide contains 1-65 weight % above-mentioned hair
Bright composition, surplus are acceptable carrier and auxiliary agent on agricultural chemicals.
Preferably, the insecticide contains 10-50 weight % the invention described above composition, and surplus is to be subjected on agricultural chemicals
Carrier and auxiliary agent.
Insecticide of the present invention can be prepared into agriculturally acceptable any formulation.It is preferably prepared to wettable powder
Agent, water dispersible granules, aqueous emulsion or suspending agent.
Above-mentioned formulation is this area regular dosage form, what its preparation method was well known to those skilled in the art, is prepared into
Auxiliary agent and/or carrier and its dosage used in above-mentioned various formulations are similarly well-known to those skilled in the art, such as join
According to《Formulations of pesticide process technology》.Acceptable carrier and auxiliary agent include but is not limited on agricultural chemicals used：Solvent, emulsifying agent, divide
Powder, wetting agent, adhesive, disintegrant, thickener, antifreezing agent, stabilizer, filler and/or carrier etc..People in the art
Member can select one or more auxiliary agents therein and/or carrier.
In one embodiment of the invention, the insecticide of the present invention is prepared into wettable powder, it is formulated composition
For：Anabasine insecticide 1-60%, NF-100 0.05-5%, dispersant 1-20%, wetting agent 1-20%, solid carrier are mended
Enough to 100%.Its preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
In one embodiment of the invention, the insecticide of the present invention is prepared into water dispersible granules, it is formulated composition
For：Anabasine insecticide 1-60%, NF-100 0.05-5%, dispersant 1-20%, wetting agent 1-20%, disintegrant 1-
10%, binding agent 0.1-10%, solid carrier complements to 100%.Its preparation method is：Each component is well mixed, through crushing,
It is granulated, water dispersible granules is made.
In one embodiment of the invention, the insecticide of the present invention is prepared into aqueous emulsion, its formula composition is：Newly
Nicotinic insecticide 1-60%, NF-100 0.05-5%, solvent 1-40%, emulsifying agent 1-25%, dispersant 1-25%, thickening
Agent 1-10%, defoamer 0.1-5%, antifreezing agent 0.5-10%, stabilizer 0-5%, water complement to 100%.Its preparation method is：
The dissolving of active ingredient solvent is prepared into oil phase, other each components are added to the water to stir are prepared into aqueous phase, Ran Houbian
Oil phase is added aqueous phase by stirring side, is stirred, and aqueous emulsion is made.
In one embodiment of the invention, the insecticide of the present invention is prepared into suspending agent, its formula composition is：Newly
Nicotinic insecticide 1-60%, NF-100 0.05-5%, dispersant 1-20%, wetting agent 1-20%, thickener 0.1-10%,
Antifreezing agent 0.1-5%, defoamer 0.1-5%, water complement to 100%.Its preparation method is：By active ingredient and various auxiliary agents
Mixed with water, after high speed shear is scattered, sand mill is sanded, forms high dispersive, stable suspension system, suspending agent is made.
Wherein, in above-mentioned formula, the solvent can be selected：Methanol, ethanol, isopropanol, benzene,toluene,xylene, third
Ketone, dimethylformamide, dimethyl sulfoxide (DMSO), dichloromethane, hexamethylene, cyclohexanone, 1-METHYLPYRROLIDONE, petroleum ether, acetic acid
One or more in ethyl ester；
The emulsifying agent can be selected：Sodium lignin sulfonate, lauryl sodium sulfate, neopelex, 12
Alkyl benzene calcium sulfonate, styryl phenyl APEO, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, fatty alcohol polyoxy second
Alkene ether, thermally coupled distillation columns, castor oil polyoxyethylene ether phosphate, phenyl phenol polyoxyethanyl ether phosphate, naphthalene
Sulfonate and formaldehyde condensation product, benzyl dimethyl phenol polyoxyethyl ether, sorbitan monostearate APEO, dehydration mountain
One or more in pears polyol fatty acid ester APEO；
The dispersant can be selected：Naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkyl phenol polyoxy
Vinethene formaldehyde condensation products, glycerine fatty acid APEO, polyoxyethylene alkylaryl ether, sodium lignin sulfonate, fatty alcohol
It is polyoxyethylene ether sulfate, AEO, aliphatic alcohol polyoxyvinethene phosphate, NPE, poly-
One or more in oxygen ethene lanolin alcohol, Polyoxyethylene Sorbitan acid esters；
The wetting agent can be selected：N- sodium lauroyl glutamates, trisiloxanes APEO, dodecyl sulphate
Sodium, triphenoethyl benzene phenol polyethenoxy ether, calcium dodecyl benzene sulfonate, isooctanol Disodium sulfosuccinate, lauroyl flesh ammonia
One or more in sour sodium, castor oil polyoxyethylene ether, AEO；
Described adhesive can be selected：Gelatin, Arabic gum, xanthans, starch, carboxymethyl cellulose, carboxyethylcellulose
One or more in element；
The disintegrant can be selected：One kind or more in sodium sulphate, calcium sulfate, sodium acid carbonate, ammonium sulfate, magnesium chloride
Kind；
The thickener can be selected：Polyvinyl acetate, aluminium-magnesium silicate, Arabic gum, xanthans, gelatin, polyethylene
One or more in alcohol；
The defoamer can be selected：One or more in butylphosphoric acid ester, phosphoric acid isobutyl ester, n- octanol, silicone etc.；
The antifreezing agent can be selected：One or more in ethylene glycol, propane diols, glycerine etc.；
The stabilizer can be selected：Triphenyl phosphite, N- soybean oleyl trimethylene diamine, dialkyl group succinate
One or more in sulfonate, epoxychloropropane, butyl glycidyl ether etc.；
The filler and/or carrier include solid packing and/or carrier and liquid filler and/or carrier.Wherein, solid is filled out
Material and/or carrier can be selected：One in diatomite, kaolin, attapulgite, white carbon, bentonite, montmorillonite, calcium carbonate
Kind is a variety of.The one or more that liquid filler and/or carrier can be selected in water, castor oil, soybean oil, mineral oil.
In very particularly preferred embodiment of the invention, the anabasine compound is Nitenpyram, and by the combination
Thing is prepared into water dispersible granules, and it is (weight %) that it, which is formulated composition,：
Nitenpyram 25%,
NF-100 1%,
NPE 8%,
N- sodium lauroyl glutamates 6%,
Sodium sulphate 6%,
Arabic gum 4%,
Attapulgite complements to 100%.
Another aspect of the present invention is related to the invention described above composition or the invention described above insecticide is used to prevent and treat agricultural pests
Purposes.
Wherein described agricultural pests include but is not limited to Lepidoptera, Diptera, coleoptera, Homoptera, Orthoptera, film wing
The agricultural pests such as mesh, Isoptera, Siphonaptera, Blattaria, Thysanoptera.
The composition or insecticide of the present invention is preferred for preventing and treating planthopper (Nilaparvata lugens), brown plant-hopper
(Nilaparvata lugens), eriosoma lanigerum (Eriosoma lanigerum), black peach aphid (Myzuspersicae Sulzer),
Bemisia tabaci (Bemisia tabaci Gennadius), leafhopper (Empoasca spp.), grain aphid (Sitobion avenae
Fabricius), green bugs (Schizaphis graminum), it is most preferably for preventing and treating planthopper (Nilaparvata
lugens)。
The composition of the present invention or the amount of application of insecticide are such as 0.1-1000g ai./ha, preferably 1-200g ai./
ha。
Another aspect of the present invention is related to insecticidal effects of the agricultural synergist NF-100 for increasing anabasine insecticide
Purposes.
The weight ratio of the agricultural synergist NF-100 and anabasine insecticide be 1: 5-200, preferably 1: 10-100, more
It is preferred that 1: 20-60, most preferably 1: 25.
The anabasine insecticide is in imidacloprid, Acetamiprid, Nitenpyram, thiacloprid, Diacloden, MTI-446
It is one or more.It is highly preferred that the anabasine insecticide in imidacloprid, Acetamiprid, Nitenpyram, thiacloprid one
Kind is a variety of.Most preferably, the anabasine insecticide is selected from Nitenpyram.
Various raw materials and/or reagent used herein are commercially available.Such as the anabasine insecticide and each
Kind auxiliary agent, carrier can easily commercially.The synergist NF-10 is also commercially available, such as can be purchased from
Promise agriculture Beijing International Biotechnology Co., Ltd etc..
Unless otherwise indicated, " % " involved in the present invention is " percentage by weight ".
The synergist of the present invention significantly increases the insecticidal effect of anabasine insecticide, reduces pesticide activity component
Usage amount, has delayed the development of pesticide resistance, while is advantageous to environmental protection, promotes agricultural sustainable development.
Embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these tools
Body embodiment.One skilled in the art would recognize that present invention encompasses may include in Claims scope
All alternatives, improvement project and equivalents.
NF-100 used in following embodiments is purchased from promise agriculture Beijing International Biotechnology Co., Ltd.Unless otherwise indicated,
Involved " % " is " percentage by weight ".
(1) Biological Test Example
Test example 1
Subjects：Rice hoppers (Nilaparvata lugens), choose healthy growth, nymph of the same size.
Test method：With reference to《NY/T 1154.11-2008 farm-chemical indoor determination test rules》The 11st, insecticide
Divide " rice-stem dipping method ", determine indoor biological activity of each processing to planthopper.
Each treatment agent in following table is configured to series concentration (in terms of pesticide activity component with the 1% Tween 80 aqueous solution
Calculate).Then, ready rice stem is impregnated into 30s in decoction, taking-up is dried, and is placed in diameter 3cm test tube, per test tube 3
Strain, often handle 4 repetitions, and set the 1% Tween 80 aqueous solution and the 1%NF-100 aqueous solution processing do blank control.Then, often
Test tube accesses 15 nymphs, normal condition raising test worm, inspection result after 48h, calculates the death rate, and calculate the LC of each processing50；
And then calculate synergy ratio.
The computational methods of wherein synergy ratio are：Synergy ratio=LC50A agricultural chemicals/LC50A agricultural chemicals+NF-100
As a result it is as follows：
| Sequence number | Treatment agent | LC50(mg/L) | Synergy ratio |
| 1-0 | Nitenpyram | 5.08 | - |
| 1-1 | Nitenpyram: NF-100=100: 1 | 3.75 | 1.35 |
| 1-2 | Nitenpyram: NF-100=50: 1 | 3.62 | 1.40 |
| 1-3 | Nitenpyram: NF-100=25: 1 | 2.84 | 1.79 |
| 1-4 | Nitenpyram: NF-100=12.5: 1 | 3.56 | 1.43 |
| 2-0 | Thiacloprid | 7.65 | - |
| 2-1 | Thiacloprid: NF-100=100: 1 | 6.17 | 1.24 |
| 2-2 | Thiacloprid: NF-100=50: 1 | 5.82 | 1.31 |
| 2-3 | Thiacloprid: NF-100=25: 1 | 4.98 | 1.54 |
| 2-4 | Thiacloprid: NF-100=12.5: 1 | 5.35 | 1.43 |
| 3-0 | AVM | 8.24 | - |
| 3-1 | AVM: NF-100=100: 1 | 8.19 | 1.01 |
| 3-2 | AVM: NF-100=50: 1 | 8.25 | 1.00 |
| 3-3 | AVM: NF-100=25: 1 | 8.11 | 1.02 |
| 3-4 | AVM: NF-100=12.5: 1 | 8.31 | 0.99 |
| Blank control | 1%NF-100 | - | - |
| Blank control | 1% Tween 80 | - | - |
Above-mentioned data are not difficult to find out, NF-100 can substantially increase killing for anabasine insecticide Nitenpyram and thiacloprid
Worm effect, reduce its LC50Value, synergy ratio are all higher than 1.2；Particularly with Nitenpyram, its synergy ratio is all higher than 1.35, most
It is high by reachable 1.79, it is preferable, i.e. NF-100 can increase the insecticidal effect of anabasine insecticide, be synergy.It is but right
For AVM, NF-100 addition is on insecticidal effect almost without influence, that is to say, that NF-100 is for AVM
It is hardly synergy.
Test example 2
Subjects：Grain aphid (Sitobion avenae Fabricius), choose healthy growth, of the same size
Test worm.
Test method：Each treatment agent in following table is configured to series concentration (with pesticide activity with the 1% Tween 80 aqueous solution
Composition calculates).Then, ready wheat leaf blade is impregnated into 30s in decoction, taking-up is dried, and is placed in diameter 3cm test tube
In, per 5, test tube, 4 repetitions are often handled, and set the 1% Tween 80 aqueous solution and blank pair is done in the processing of the 1%NF-100 aqueous solution
According to.Then, 20 aphids are accessed per test tube, normal condition raising test worm, inspection result after 48h, calculate the death rate, and calculate each
The LC of processing50, and then calculate synergy ratio.
The computational methods of wherein synergy ratio are：Synergy ratio=LC50A agricultural chemicals/LC50A agricultural chemicals+NF-100
As a result it is as follows：
| Sequence number | Treatment agent | LC50(mg/L) | Synergy ratio |
| 1-0 | Nitenpyram | 3.25 | - |
| 1-1 | Nitenpyram: NF-100=100: 1 | 2.55 | 1.27 |
| 1-2 | Nitenpyram: NF-100=50: 1 | 2.38 | 1.37 |
| 1-3 | Nitenpyram: NF-100=25: 1 | 2.02 | 1.61 |
| 1-4 | Nitenpyram: NF-100=12.5: 1 | 2.24 | 1.45 |
| 2-0 | Thiacloprid | 6.87 | - |
| 2-1 | Thiacloprid: NF-100=100: 1 | 5.81 | 1.18 |
| 2-2 | Thiacloprid: NF-100=50: 1 | 5.44 | 1.26 |
| 2-3 | Thiacloprid: NF-100=25: 1 | 4.94 | 1.39 |
| 2-4 | Thiacloprid: NF-100=12.5: 1 | 5.17 | 1.33 |
| 3-0 | Pymetrozine | 5.37 | - |
| 3-1 | Pymetrozine: NF-100=100: 1 | 5.28 | 1.02 |
| 3-2 | Pymetrozine: NF-100=50: 1 | 5.31 | 1.01 |
| 3-3 | Pymetrozine: NF-100=25: 1 | 5.35 | 1.00 |
| 3-4 | Pymetrozine: NF-100=12.5: 1 | 5.34 | 1.01 |
| Blank control | 1%NF-100 | - | - |
| Blank control | 1% Tween 80 | - | - |
Above-mentioned data are not difficult to find out, NF-100 can substantially increase killing for anabasine insecticide Nitenpyram and thiacloprid
Worm effect, reduce its LC50Value, synergy ratio are all higher than 1.2 substantially；Particularly with Nitenpyram, its synergy ratio is all higher than
1.27,1.61 are reached as high as, is preferable, i.e. NF-100 can increase the insecticidal effect of anabasine insecticide, be synergy
's.But for pymetrozine, NF-100 addition is on insecticidal effect almost without influence, that is to say, that NF-100 is to pyrrole aphid
It is hardly synergy for ketone.
(2) preparation prepares embodiment
The wettable powder of preparation example 1
Nitenpyram 50%, NF-100 1%, naphthalenesulfonate formaldehyde condensation compound sodium salt 12%, AEO
10%, kaolin complements to 100%.
Its preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
The wettable powder of preparation example 2
Thiacloprid 30%, NF-100 1%, glycerine fatty acid APEO 7%, castor oil polyoxyethylene ether 7%, silicon
Diatomaceous earth complements to 100%.
Its preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
The water dispersible granules of preparation example 3
Nitenpyram 25%, NF-100 1%, NPE 8%, N- sodium lauroyl glutamates 6%, sulphur
Sour sodium 6%, Arabic gum 4%, attapulgite complements to 100%.
Its preparation method is：Each component is well mixed, through crushing, being granulated, water dispersible granules are made.
The water dispersible granules of preparation example 4
Thiacloprid 40%, NF-100 0.5%, aliphatic alcohol polyoxyvinethene phosphate 10%, castor oil polyoxyethylene ether
10%, ammonium sulfate 5%, xanthans 5%, attapulgite complements to 100%.
Its preparation method is：Each component is well mixed, through crushing, being granulated, water dispersible granules are made.
The aqueous emulsion of preparation example 5
Thiacloprid 15%, NF-100 0.15%, dimethyl sulfoxide (DMSO) 10%, sodium lignin sulfonate 5%, polyoxyethylene wool
Lipidol 4%, polyvinyl alcohol 5%, silicone 0.5%, ethylene glycol 5%, water complements to 100%.
Its preparation method is：The dissolving of Acetamiprid solvent is prepared into oil phase, it is equal that other each components are added to the water into stirring
It is even to be prepared into aqueous phase, oil phase is then added into aqueous phase while stirring, stirred, aqueous emulsion is made.
The suspending agent of preparation example 6
Nitenpyram 30%, NF-100 0.2%, naphthalenesulfonate formaldehyde condensation compound 6%, N- sodium lauroyl glutamates
4%, aluminium-magnesium silicate 1%, ethylene glycol 3%, n- octanol 0.5%, water complements to 100%.
Its preparation method is：Each component is mixed with water, after high speed shear is scattered, sand mill is sanded, formation high dispersive,
Stable suspension system, suspending agent is made.
Comparative example 1
It is formulated relative to embodiment 2, NF-100 is replaced with the organosilicon auxiliary agent Silwet408 of equivalent, remaining composition is same, tool
Body is：
Thiacloprid 30%, Silwet408 1%, glycerine fatty acid APEO 7%, castor oil polyoxyethylene ether 7%,
Diatomite complements to 100%.
Its preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
Comparative example 2
It is formulated relative to embodiment 3, NF-100 is replaced with the organosilicon auxiliary agent Silwet408 of equivalent, remaining composition is same, tool
Body is：
Nitenpyram 25%, Silwet408 1%, NPE 8%, N- sodium lauroyl glutamates 6%,
Sodium sulphate 6%, Arabic gum 4%, attapulgite complements to 100%.
Its preparation method is：Each component is well mixed, through crushing, being granulated, water dispersible granules are made.
(3) field test
Controlling object：Planthopper
Test medicine：Preparation example 1-6 and comparative example 1-2；
The basically identical rice field of insect pest situation is selected, carries out small Division, plot area 50m2.Then apply invention formulation and
Comparative formulation, 3 repetitions are often handled, respectively repeatedly random alignment, and set clear water processing as blank control.Before dispenser, respectively
Insect population is investigated before medicine is carried out to each cell, then conventional spray pesticide, every mu of spouting liquid 25kg.Investigation in 7 days is residual after medicine
Worm amount, per 5 points of samplings of cell, every is looked into 5 plants, and calculates Rectifying efficacies by following formula, as a result see the table below：
Table of field test results is bright, and the field efficacy of the present composition is substantially better than contrast agents, after adding NF-100,
Preventive effect of the present composition significantly increased to planthopper.
Examples detailed above is only that the present invention is explained further, and is not limitation of the invention, by by above-mentioned side
Case carries out simply adjusting the scheme obtained from, equally within the protection domain of the application.
Claims (5)
1. the composition of a kind of agricultural synergist and anabasine insecticide, include agricultural synergist and one or more anabasines
Insecticides, wherein,
The agricultural synergist is NF-100；
The anabasine insecticide is Nitenpyram or thiacloprid；
The weight ratio of the agricultural synergist and anabasine insecticide is 1: 10-100.
A kind of 2. insecticide, it is characterised in that the insecticide contains the composition described in 1-65 weight % claim 1,
Surplus is acceptable carrier and auxiliary agent on agricultural chemicals.
3. insecticide according to claim 2, it is characterised in that the right that the insecticide contains 10-50 weight % will
Seek the composition described in 1.
4. the insecticide according to Claims 2 or 3, it is characterised in that the insecticide is configured to wettable powder, moisture
Shot agent, aqueous emulsion or suspending agent.
5. the insecticide described in composition or claim any one of 2-4 described in claim 1 is used to prevent and treat agricultural pests
Purposes.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105085075A (en) * | 2015-09-12 | 2015-11-25 | 顾伟 | Agricultural composition containing propamidine and foliage fertilizer |
| EP3175714B1 (en) * | 2015-12-04 | 2019-01-16 | Universite D'angers | Synegistic insecticidal composition comprising thiamethoxam and n-butyl-n-acetyl-3-ethylamine propionate |
| CN107011081B (en) * | 2017-03-08 | 2021-04-27 | 叶长东 | Slow-release pesticide-fertilizer composition |
| CN108835126A (en) * | 2018-06-27 | 2018-11-20 | 四川福思达生物技术开发有限责任公司 | A kind of agricultural insecticidal composite and its application containing nicotine compound and mineral oil |
| CN113349200B (en) * | 2021-06-08 | 2022-05-24 | 中国水稻研究所 | Application of magnolol and honokiol as pesticide synergist |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063015C (en) * | 1997-04-17 | 2001-03-14 | 山东农业大学 | Imidacloprid synergistic pesticide composition |
| CN104719325A (en) * | 2013-12-20 | 2015-06-24 | 陕西美邦农药有限公司 | Sedaxane and neonicotine-containing composition for killing pests and preventing diseases |
-
2015
- 2015-08-18 CN CN201510505847.XA patent/CN105191931B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063015C (en) * | 1997-04-17 | 2001-03-14 | 山东农业大学 | Imidacloprid synergistic pesticide composition |
| CN104719325A (en) * | 2013-12-20 | 2015-06-24 | 陕西美邦农药有限公司 | Sedaxane and neonicotine-containing composition for killing pests and preventing diseases |
Non-Patent Citations (1)
| Title |
|---|
| 剂型及表面活性剂对农药药液在植物叶片上铺展行为的影响;王波等;《农药学学报》;20120813;第14卷(第3期);1-9 * |
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Effective date of registration: 20180920 Address after: 541000 55 Yucai Road, Guilin, Guangxi Patentee after: Guilin Jiqi Biochemical Co., Ltd. Address before: 100193 303A, Beijing, Haidian District, No. 158, No. Co-patentee before: Guo Zheng Patentee before: NUMEN (BEIJING) INTERNATIONAL BIOTECH CO., LTD. Co-patentee before: Yang Yuhuai |