CN105178116A - Waterproof corrugated paperboard - Google Patents
Waterproof corrugated paperboard Download PDFInfo
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- CN105178116A CN105178116A CN201510546453.9A CN201510546453A CN105178116A CN 105178116 A CN105178116 A CN 105178116A CN 201510546453 A CN201510546453 A CN 201510546453A CN 105178116 A CN105178116 A CN 105178116A
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Abstract
The invention relates to the technical field of corrugated paperboards and provides a waterproof corrugated paperboard with good waterproof and dampproof effects, high strength and insusceptibility to deformation. The waterproof corrugated paperboard comprises a corrugated paperboard body, wherein the corrugated paperboard body is prepared from a plurality of layers of single-layer corrugated paperboards sprayed or dipped with a waterproof and dampproof agent by binding through an waterproof adhesive; the upper and lower surfaces of the corrugated paperboard body are provided with buffer layers; and the waterproof and dampproof agent is composed of the following raw materials by weight: 20 to 35 parts of dodecyl dimethyl benzyl ammonium chloride, 30 to 40 parts of octamethylcyclotetrasiloxane, 18 to 25 parts of sodium acrylate, 30 to 40 parts of N-isopropylacrylamide, 10 to 15 parts of butadiene, 10 to 15 parts phenyl diene, 5 to 10 parts of isproportionated potassium rosinate, 30 to 40 parts of trimethylol propane triacrylate, 20 to 30 parts of stearin, 3 to 10 parts of a pH regulator and 50 to 80 parts of water.
Description
Technical field
The present invention relates to corrugated board technical field, particularly relate to a kind of waterproof corrugated board.
Background technology
Corrugated board started from for 18 beginnings of the century in the end of the century 19, because its amount is light, low price, of many uses, make simple and easy and can reclaim and even reuse, its application is had significant growth.To 20 beginnings of the century, obtain and packed and comprehensively universal, promotion and application into various commodity make.The packing container made owing to using corrugated board is to beautifying and protecting in-built commodity to have performance and the advantage of its uniqueness; therefore; with the competition of various packaging materials in obtain great success, become long with not waning and presenting one of main material of the making packing container of fast development up to now.Corrugated paper is the plate object be bonded by sheet lining and the corrugated paper of waveform being processed by corrugated roller and formed, can have the structures such as three layers, four layers, five layers.Corrugated board in use often can run into the situations such as extruding; when corrugated board is squeezed, the anti-extrusion performance of bursting strength to cardboard of corrugated board has a great impact, when being subject to the proof pressure exceeding corrugated board; obvious deformation will be there is, affect the use of corrugated paper.In conventional product, triplex board intensity is low, easily deformation occurs in use procedure, conventional five layer paperboard intensity a little more than triplex board, but inadequate owing to manufacturing compactedness, intensity is not high yet, and consumed cost is high, occupies space and volume is large.In addition, corrugated board in use also may be drenched by rainwater, seawater, affects it and uses; conventional triplex board and five layer paperboards do not possess waterproof, moistureproof effect; generally all permeated in 5 minutes, what applying glue was best is also no more than 10 minutes, can not good protective package product.
Summary of the invention
Therefore, for above content, the invention provides that a kind of waterproof moisture-proof effect is good, intensity is high, on-deformable waterproof corrugated board.
For achieving the above object, the present invention is achieved by the following technical solutions: a kind of waterproof corrugated board, comprise corrugated board body, described corrugated board body is bonded by water-resistant adhesives by the individual layer corrugated paper of plural layer through spraying or dipping waterproof moisture proof agent, the upper and lower surface of described corrugated board body is provided with cushion, described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 20 ~ 35 weight portion, octamethylcy-clotetrasiloxane 30 ~ 40 weight portion, sodium acrylate 18 ~ 25 weight portion, NIPA 30 ~ 40 weight portion, butadiene 10 ~ 15 weight portion, benzene diene 10 ~ 15 weight portion, disproportionated rosin acid potassium 5 ~ 10 weight portion, trimethyol propane triacrylate 30 ~ 40 weight portion, tristerin 20 ~ 30 weight portion, pH adjusting agent 3 ~ 10 weight portion, water 50 ~ 80 weight portion, described water-resistant adhesives is made up of the raw material of following weight portion: starch 20 ~ 30 weight portion, NaOH 2 ~ 3 weight portion, water 65 ~ 70 weight portion, sodium cellulose glycolate 0.1 ~ 0.2 weight portion, Sodium Polyacrylate 0.1 ~ 0.2 weight portion, benzophenone 0.5 ~ 1 weight portion, trimethyol propane triacrylate 0.5 ~ 1 weight portion, borax 0.1 ~ 0.2 weight portion, Lauxite 2 ~ 5 weight portion, keto-aldehyde polyvinyl alcohol compound 3 ~ 7 weight portion.
Further improvement is: described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 27 ~ 35 weight portion, octamethylcy-clotetrasiloxane 35 ~ 40 weight portion, sodium acrylate 22 ~ 25 weight portion, NIPA 35 ~ 40 weight portion, butadiene 12 ~ 15 weight portion, benzene diene 13 ~ 15 weight portion, disproportionated rosin acid potassium 7 ~ 10 weight portion, trimethyol propane triacrylate 35 ~ 40 weight portion, tristerin 25 ~ 30 weight portion, pH adjusting agent 5 ~ 10 weight portion, water 60 ~ 80 weight portion.
Further improvement is: described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 30 weight portion, octamethylcy-clotetrasiloxane 30 weight portion, sodium acrylate 20 weight portion, NIPA 35 weight portion, butadiene 13 weight portion, benzene diene 12 weight portion, disproportionated rosin acid potassium 7 weight portion, trimethyol propane triacrylate 35 weight portion, tristerin 25 weight portion, pH adjusting agent 5 weight portion, water 70 weight portion.
Further improvement is: described water-resistant adhesives is made up of the raw material of following weight portion: starch 25 weight portion, NaOH 2 weight portion, water 64.15 weight portion, sodium cellulose glycolate 0.2 weight portion, Sodium Polyacrylate 0.1 weight portion, benzophenone 0.7 weight portion, trimethyol propane triacrylate 0.75 weight portion, borax 0.1 weight portion, Lauxite 4 weight portion, keto-aldehyde polyvinyl alcohol compound 3 weight portion.
Further improvement is: described corrugated board body by 3 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives.
Further improvement is: described corrugated board body by 5 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives.
Further improvement is: described cushion is foamed layers.
By adopting preceding solution, the invention has the beneficial effects as follows: waterproof corrugated board of the present invention, comprise corrugated board body, described corrugated board body is bonded by water-resistant adhesives by the individual layer corrugated paper of plural layer through spraying or dipping waterproof moisture proof agent, corrugated board body has good water-proof function after spraying or dipping waterproof moisture proof agent, not easily there is the situations such as volume sticks up in wet environment, can not absorb water in rainy day transportation, keep good physical property, cushion is provided with in the upper and lower surface of described corrugated board body, make in transportation, corrugated board body is not easy to be extruded distortion.Described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 20 ~ 35 weight portion, octamethylcy-clotetrasiloxane 30 ~ 40 weight portion, sodium acrylate 18 ~ 25 weight portion, NIPA 30 ~ 40 weight portion, butadiene 10 ~ 15 weight portion, benzene diene 10 ~ 15 weight portion, disproportionated rosin acid potassium 5 ~ 10 weight portion, trimethyol propane triacrylate 30 ~ 40 weight portion, tristerin 20 ~ 30 weight portion, pH adjusting agent 3 ~ 10 weight portion, water 50 ~ 80 weight portion; Adopt new material chemical constituent mutually to arrange in pairs or groups reaction, this waterproof moisture proof agent is sprayed on corrugated paper or by corrugated paper and is immersed in this waterproof moisture proof agent, corrugated paper is fully absorbed, and then acquisition water resistance.Described water-resistant adhesives is made up of the raw material of following weight portion: starch 20 ~ 30 weight portion, NaOH 2 ~ 3 weight portion, water 65 ~ 70 weight portion, sodium cellulose glycolate 0.1 ~ 0.2 weight portion, Sodium Polyacrylate 0.1 ~ 0.2 weight portion, benzophenone 0.5 ~ 1 weight portion, trimethyol propane triacrylate 0.5 ~ 1 weight portion, borax 0.1 ~ 0.2 weight portion, Lauxite 2 ~ 5 weight portion, keto-aldehyde polyvinyl alcohol compound 3 ~ 7 weight portion; Adopt the water-resistant adhesives of above-mentioned collocation between each individual layer corrugated paper, make corrugated board water resistance on the whole all better, wherein, starch and cross-linked reaction of keto-aldehyde polyvinyl alcohol compound form membrane waterproofing, enhance overall water resistance.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how application technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technological means adopted in embodiment is well known to those skilled in the art, the reagent adopted and product be also can business obtain.Source, the trade name of agents useful for same and be necessary to list its constituent person, all indicate when occurring first.
Embodiment one
A kind of waterproof corrugated board, comprise corrugated board body, described corrugated board body by 3 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives, the upper and lower surface of described corrugated board body is provided with plastic foam cushion, described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 20 weight portion, octamethylcy-clotetrasiloxane 30 weight portion, sodium acrylate 18 weight portion, NIPA 30 weight portion, butadiene 10 weight portion, benzene diene 10 weight portion, disproportionated rosin acid potassium 5 weight portion, trimethyol propane triacrylate 30 weight portion, tristerin 20 weight portion, pH adjusting agent 3 weight portion, water 50 weight portion, described water-resistant adhesives is made up of the raw material of following weight portion: starch 20 weight portion, NaOH 2 weight portion, water 65 weight portion, sodium cellulose glycolate 0.1 weight portion, Sodium Polyacrylate 0.1 weight portion, benzophenone 0.5 weight portion, trimethyol propane triacrylate 0.5 weight portion, borax 0.1 weight portion, Lauxite 2 weight portion, keto-aldehyde polyvinyl alcohol compound 3 weight portion.
Embodiment two
A kind of waterproof corrugated board, comprise corrugated board body, described corrugated board body by 5 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives, the upper and lower surface of described corrugated board body is provided with plastic foam cushion, described waterproof moisture proof agent is made up of each raw material of following weight portion: described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 275 weight portion, octamethylcy-clotetrasiloxane 35 weight portion, sodium acrylate 22 weight portion, NIPA 35 weight portion, butadiene 12 weight portion, benzene diene 13 weight portion, disproportionated rosin acid potassium 7 weight portion, trimethyol propane triacrylate 35 weight portion, tristerin 25 weight portion, pH adjusting agent 5 weight portion, water 60 weight portion, described water-resistant adhesives is made up of the raw material of following weight portion: starch 25 weight portion, NaOH 2 weight portion, water 64.15 weight portion, sodium cellulose glycolate 0.2 weight portion, Sodium Polyacrylate 0.1 weight portion, benzophenone 0.7 weight portion, trimethyol propane triacrylate 0.75 weight portion, borax 0.1 weight portion, Lauxite 4 weight portion, keto-aldehyde polyvinyl alcohol compound 3 weight portion.
Embodiment three
A kind of waterproof corrugated board, comprise corrugated board body, described corrugated board body by 5 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives, the upper and lower surface of described corrugated board body is provided with plastic foam cushion, described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 30 weight portion, octamethylcy-clotetrasiloxane 30 weight portion, sodium acrylate 20 weight portion, NIPA 35 weight portion, butadiene 13 weight portion, benzene diene 12 weight portion, disproportionated rosin acid potassium 7 weight portion, trimethyol propane triacrylate 35 weight portion, tristerin 25 weight portion, pH adjusting agent 5 weight portion, water 70 weight portion, described water-resistant adhesives is made up of the raw material of following weight portion: starch 30 weight portion, NaOH 3 weight portion, water 70 weight portion, sodium cellulose glycolate 0.2 weight portion, Sodium Polyacrylate 0.2 weight portion, benzophenone 1 weight portion, trimethyol propane triacrylate 1 weight portion, borax 0.2 weight portion, Lauxite 5 weight portion, keto-aldehyde polyvinyl alcohol compound 7 weight portion.
Embodiment four
A kind of waterproof corrugated board, comprise corrugated board body, described corrugated board body by 5 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives, the upper and lower surface of described corrugated board body is provided with plastic foam cushion, described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 35 weight portion, octamethylcy-clotetrasiloxane 40 weight portion, sodium acrylate 25 weight portion, NIPA 40 weight portion, butadiene 15 weight portion, benzene diene 15 weight portion, disproportionated rosin acid potassium 10 weight portion, trimethyol propane triacrylate 40 weight portion, tristerin 30 weight portion, pH adjusting agent 10 weight portion, water 80 weight portion, described water-resistant adhesives is made up of the raw material of following weight portion: starch 30 weight portion, NaOH 3 weight portion, water 70 weight portion, sodium cellulose glycolate 0.2 weight portion, Sodium Polyacrylate 0.2 weight portion, benzophenone 1 weight portion, trimethyol propane triacrylate 1 weight portion, borax 0.2 weight portion, Lauxite 5 weight portion, keto-aldehyde polyvinyl alcohol compound 7 weight portion.
Waterproof corrugated board of the present invention, comprise corrugated board body, described corrugated board body is bonded by water-resistant adhesives by the individual layer corrugated paper of plural layer through spraying or dipping waterproof moisture proof agent, corrugated board body has good water-proof function after spraying or dipping waterproof moisture proof agent, not easily there is the situations such as volume sticks up in wet environment, can not absorb water in rainy day transportation, keep good physical property, cushion is provided with in the upper and lower surface of described corrugated board body, make in transportation, corrugated board body is not easy to be extruded distortion.Described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 20 ~ 35 weight portion, octamethylcy-clotetrasiloxane 30 ~ 40 weight portion, sodium acrylate 18 ~ 25 weight portion, NIPA 30 ~ 40 weight portion, butadiene 10 ~ 15 weight portion, benzene diene 10 ~ 15 weight portion, disproportionated rosin acid potassium 5 ~ 10 weight portion, trimethyol propane triacrylate 30 ~ 40 weight portion, tristerin 20 ~ 30 weight portion, pH adjusting agent 3 ~ 10 weight portion, water 50 ~ 80 weight portion; Adopt new material chemical constituent mutually to arrange in pairs or groups reaction, this waterproof moisture proof agent is sprayed on corrugated paper or by corrugated paper and is immersed in this waterproof moisture proof agent, corrugated paper is fully absorbed, and then acquisition water resistance.Described water-resistant adhesives is made up of the raw material of following weight portion: starch 20 ~ 30 weight portion, NaOH 2 ~ 3 weight portion, water 65 ~ 70 weight portion, sodium cellulose glycolate 0.1 ~ 0.2 weight portion, Sodium Polyacrylate 0.1 ~ 0.2 weight portion, benzophenone 0.5 ~ 1 weight portion, trimethyol propane triacrylate 0.5 ~ 1 weight portion, borax 0.1 ~ 0.2 weight portion, Lauxite 2 ~ 5 weight portion, keto-aldehyde polyvinyl alcohol compound 3 ~ 7 weight portion; Adopt the water-resistant adhesives of above-mentioned collocation between each individual layer corrugated paper, make corrugated board water resistance on the whole all better, wherein, starch and cross-linked reaction of keto-aldehyde polyvinyl alcohol compound form membrane waterproofing, enhance overall water resistance.
Above, be only the embodiment utilizing this origination techniques content, the modification that any those skilled in the art use this creation to do, change, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (7)
1. a waterproof corrugated board, it is characterized in that, comprise corrugated board body, described corrugated board body is bonded by water-resistant adhesives by the individual layer corrugated paper of plural layer through spraying or dipping waterproof moisture proof agent, the upper and lower surface of described corrugated board body is provided with cushion, described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 20 ~ 35 weight portion, octamethylcy-clotetrasiloxane 30 ~ 40 weight portion, sodium acrylate 18 ~ 25 weight portion, NIPA 30 ~ 40 weight portion, butadiene 10 ~ 15 weight portion, benzene diene 10 ~ 15 weight portion, disproportionated rosin acid potassium 5 ~ 10 weight portion, trimethyol propane triacrylate 30 ~ 40 weight portion, tristerin 20 ~ 30 weight portion, pH adjusting agent 3 ~ 10 weight portion, water 50 ~ 80 weight portion, described water-resistant adhesives is made up of the raw material of following weight portion: starch 20 ~ 30 weight portion, NaOH 2 ~ 3 weight portion, water 65 ~ 70 weight portion, sodium cellulose glycolate 0.1 ~ 0.2 weight portion, Sodium Polyacrylate 0.1 ~ 0.2 weight portion, benzophenone 0.5 ~ 1 weight portion, trimethyol propane triacrylate 0.5 ~ 1 weight portion, borax 0.1 ~ 0.2 weight portion, Lauxite 2 ~ 5 weight portion, keto-aldehyde polyvinyl alcohol compound 3 ~ 7 weight portion.
2. waterproof corrugated board according to claim 1, it is characterized in that: described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 27 ~ 35 weight portion, octamethylcy-clotetrasiloxane 35 ~ 40 weight portion, sodium acrylate 22 ~ 25 weight portion, NIPA 35 ~ 40 weight portion, butadiene 12 ~ 15 weight portion, benzene diene 13 ~ 15 weight portion, disproportionated rosin acid potassium 7 ~ 10 weight portion, trimethyol propane triacrylate 35 ~ 40 weight portion, tristerin 25 ~ 30 weight portion, pH adjusting agent 5 ~ 10 weight portion, water 60 ~ 80 weight portion.
3. waterproof corrugated board according to claim 1, it is characterized in that: described waterproof moisture proof agent is made up of each raw material of following weight portion: dodecyl benzyl dimethyl ammonium chloride 30 weight portion, octamethylcy-clotetrasiloxane 30 weight portion, sodium acrylate 20 weight portion, NIPA 35 weight portion, butadiene 13 weight portion, benzene diene 12 weight portion, disproportionated rosin acid potassium 7 weight portion, trimethyol propane triacrylate 35 weight portion, tristerin 25 weight portion, pH adjusting agent 5 weight portion, water 70 weight portion.
4. waterproof corrugated board according to claim 1, is characterized in that: described water-resistant adhesives is made up of the raw material of following weight portion: starch 25 weight portion, NaOH 2 weight portion, water 64.15 weight portion, sodium cellulose glycolate 0.2 weight portion, Sodium Polyacrylate 0.1 weight portion, benzophenone 0.7 weight portion, trimethyol propane triacrylate 0.75 weight portion, borax 0.1 weight portion, Lauxite 4 weight portion, keto-aldehyde polyvinyl alcohol compound 3 weight portion.
5. waterproof corrugated board according to claim 1, is characterized in that: described corrugated board body by 3 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives.
6. waterproof corrugated board according to claim 1, is characterized in that: described corrugated board body by 5 layers through spraying or dipping waterproof moisture proof agent individual layer corrugated paper be bonded by water-resistant adhesives.
7. waterproof corrugated board according to claim 1, is characterized in that: described cushion is foamed layers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510546453.9A CN105178116A (en) | 2015-08-31 | 2015-08-31 | Waterproof corrugated paperboard |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510546453.9A CN105178116A (en) | 2015-08-31 | 2015-08-31 | Waterproof corrugated paperboard |
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| Publication Number | Publication Date |
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| CN105178116A true CN105178116A (en) | 2015-12-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510546453.9A Pending CN105178116A (en) | 2015-08-31 | 2015-08-31 | Waterproof corrugated paperboard |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542677A (en) * | 2016-01-27 | 2016-05-04 | 枣庄市天合化工有限公司 | Starch adhesive dry powder special for paperboard and preparing method thereof |
| CN106351054A (en) * | 2016-08-29 | 2017-01-25 | 苏州市炫之彩包装有限公司 | Energy-saving environment-friendly carton material formulation |
| CN109016638A (en) * | 2018-08-27 | 2018-12-18 | 扬中市惠丰包装有限公司 | A kind of manufacture craft of high-strength waterproof corrugated case |
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| CN1220293A (en) * | 1997-12-16 | 1999-06-23 | 费天帆 | Complexing agent for preparing starch adhesive and adhesive-preparing technology |
| EP1010807A1 (en) * | 1998-11-16 | 2000-06-21 | Rohm And Haas Company | Polymers for use as barrier coatings |
| CN102086614A (en) * | 2010-08-25 | 2011-06-08 | 永港伟方（北京）科技股份有限公司 | Surface sizing agent as well as preparation method and application thereof |
| CN103628346A (en) * | 2013-11-08 | 2014-03-12 | 浙江花园包装有限公司 | Production technology of waterproof type high-bonding-strength corrugated board |
-
2015
- 2015-08-31 CN CN201510546453.9A patent/CN105178116A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220293A (en) * | 1997-12-16 | 1999-06-23 | 费天帆 | Complexing agent for preparing starch adhesive and adhesive-preparing technology |
| EP1010807A1 (en) * | 1998-11-16 | 2000-06-21 | Rohm And Haas Company | Polymers for use as barrier coatings |
| CN102086614A (en) * | 2010-08-25 | 2011-06-08 | 永港伟方（北京）科技股份有限公司 | Surface sizing agent as well as preparation method and application thereof |
| CN103628346A (en) * | 2013-11-08 | 2014-03-12 | 浙江花园包装有限公司 | Production technology of waterproof type high-bonding-strength corrugated board |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542677A (en) * | 2016-01-27 | 2016-05-04 | 枣庄市天合化工有限公司 | Starch adhesive dry powder special for paperboard and preparing method thereof |
| CN106351054A (en) * | 2016-08-29 | 2017-01-25 | 苏州市炫之彩包装有限公司 | Energy-saving environment-friendly carton material formulation |
| CN109016638A (en) * | 2018-08-27 | 2018-12-18 | 扬中市惠丰包装有限公司 | A kind of manufacture craft of high-strength waterproof corrugated case |
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Application publication date: 20151223 |