CN105177542A - Steel surface self-cleaning treating fluid for marine equipment, preparation method thereof and use thereof - Google Patents
Steel surface self-cleaning treating fluid for marine equipment, preparation method thereof and use thereof Download PDFInfo
- Publication number
- CN105177542A CN105177542A CN201510569001.2A CN201510569001A CN105177542A CN 105177542 A CN105177542 A CN 105177542A CN 201510569001 A CN201510569001 A CN 201510569001A CN 105177542 A CN105177542 A CN 105177542A
- Authority
- CN
- China
- Prior art keywords
- concentration
- steel surface
- treatment solution
- steel
- cleaning treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a steel surface self-cleaning treating fluid for marine equipment. The steel surface self-cleaning treating fluid is characterized by comprising the following components in concentration: by taking a mixture of N-isopropylacrylamide and ethylene glycol as a solvent, concentration of nano silicon carbide is 3.0-4.5g/L, concentration of nano titanium dioxide is 1.5-2.5g/L and concentration of cabon nano tube is 0.5-1.5g/L. According to a steel surface self-cleaning treatment method in seawater, action of micro arc plasmas in a solution is utilized, so that a random-distribution bionic surface is formed on the steel surface, and a sol-gel method is carried out on the surface to carry out self-cleaning treatment on the steel surface so as to form the bionic surface with a composite structure; and after being treated, a steel part is not deformed, and treatment on steel parts for the marine equipment can be directly carried out, so that a treatment process is simplified, and cost is reduced very well.
Description
Technical field
The present invention relates to the steel surface automatically cleaning treatment process of the self-cleaning treatment process of steel surface, particularly a kind of sea water resistance and marine microorganism corrosion in a kind of seawater, belong to field of metal surface treatment technology.
Background technology
In the seawater steel surface because of chloride ion corrosion and marine microorganism corrosion and corrosion prevention problem.In order to reduce chloride ion corrosion and alleviate marine microorganism corrosion, in production and practical application, employ diverse ways, the automatically cleaning treatment process of steel surface can reach above-mentioned effect.Patent (thunder thunder, Li Lingjie, Xu Wenting, Hopkinson, John Edmund, Zou Maohua, Pan Fusheng, the preparation method of a kind of metallic surface automatically cleaning, high protection rete, CN201410455019.5) (Huang is strong, Ye Yuansong, Wang Xiaolin with patent, a kind of preparation method of surface self-cleaning polymer porous membrane, CN201010163744.7) describe steel part surface independent inorganic coating and organic coating treatment process respectively, but its existence processes rete and substrate combinating strength and problem of aging, the easy so in use solidity to corrosion of steel part that causes declines.
Summary of the invention
In order to overcome the deficiencies in the prior art, the self-cleaning treatment process of steel surface in seawater provided by the invention, utilize the effect of micro arc plasma body in solution, stochastic distribution bionic surface is formed at steel surface, carry out the process of sol-gel method automatically cleaning on surface again, form the bionic surface with composite structure; Without distortion after steel part process, directly can carry out the process of marine settings iron and steel parts, simplify treatment process, reduce cost well.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of marine settings steel surface automatically cleaning treatment solution, it is characterized in that, the concentration comprising following component and each component is: with the mixture of NIPA and ethylene glycol for solvent, the concentration of nanometer silicon carbide is 3.0 ~ 4.5g/L, the concentration of nano titanium oxide is 1.5 ~ 2.5g/L, and the concentration of carbon nanotube is 0.5 ~ 1.5g/L.Nanometer silicon carbide, nano titanium oxide, even carbon nanotube are dispersed in N-polyvinylpyrrolidone and ethylene glycol solvent and form even fluid, form the surface film of nano bionic texture characteristic at steel surface with sol-gel method, utilize wear-resisting, the conduction of carbon nano tube and the preventing microorganism of nano titanium oxide of nanometer silicon carbide, play seawater and the self-cleaning effect of marine microorganism.
Preferably, the volume ratio of NIPA and ethylene glycol is 1:0.1 ~ 20.
Preferably, the volume ratio of NIPA and ethylene glycol is 3:7.
Preferably, the concentration of nanometer silicon carbide is 3.0g/L, and the concentration of nano titanium oxide is 1.5g/L, and the concentration of carbon nanotube is 0.5g/L.
Preferably, the concentration of nanometer silicon carbide is 3.5g/L, and the concentration of nano titanium oxide is 2.0g/L, and the concentration of carbon nanotube is 1.0g/L.
Preferably, the concentration of nanometer silicon carbide is 4.0g/L, and the concentration of nano titanium oxide is 2.5g/L, and the concentration of carbon nanotube is 1.5g/L.
A kind of preparation method of marine settings steel surface automatically cleaning treatment solution, it is characterized in that, with the mixture of NIPA and ethylene glycol for solvent, ultrasonic with under magnetic field agitation acting in conjunction, add a certain amount of nano titanium oxide, nanometer silicon carbide, carbon nanotube successively, stir obtained.
A purposes for marine settings steel surface automatically cleaning treatment solution, is characterized in that, comprise the following steps:
Step one: steel part is through the process of micro arc plasma body, and steel part surface forms the bionical texture of stochastic distribution.
Step 2: the steel part after process inserted in treatment solution and repeatedly lift, treat its surface uniform film forming, propose, make its spontaneous curing and drying, namely forms steel part self-cleaning surface rete, the standby or marine settings for oceanic climate apoplexy Denso.
The beneficial effect that the present invention reaches: the self-cleaning treatment process of steel surface in seawater provided by the invention, utilize the effect of micro arc plasma body in solution, stochastic distribution bionic surface is formed at steel surface, carry out the process of sol-gel method automatically cleaning on surface again, form the bionic surface with composite structure; Without distortion after steel part process, directly can carry out the process of marine settings iron and steel parts, simplify treatment process, reduce cost well; Nanometer silicon carbide, nano titanium oxide, even carbon nanotube are dispersed in N-polyvinylpyrrolidone and ethylene glycol solvent and form even fluid, form the surface film of nano bionic texture characteristic at steel surface with sol-gel method, utilize wear-resisting, the conduction of carbon nano tube and the preventing microorganism of nano titanium oxide of nanometer silicon carbide, play seawater and the self-cleaning effect of marine microorganism.
Embodiment
The invention will be further described below.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
Embodiment 1: a kind of marine settings steel surface automatically cleaning treatment solution, the concentration comprising following component and each component is: the mixture being 3:7 with the volume ratio of NIPA and ethylene glycol is for solvent, the concentration of nanometer silicon carbide is 3.0g/L, the concentration of nano titanium oxide is 1.5g/L, and the concentration of carbon nanotube is 0.5g/L.
A kind of preparation method of marine settings steel surface automatically cleaning treatment solution, it is characterized in that, with the mixture of NIPA and ethylene glycol for solvent, ultrasonic with under magnetic field agitation acting in conjunction, add a certain amount of nano titanium oxide, nanometer silicon carbide, carbon nanotube successively, stir obtained treatment solution; Afterwards, steel part is carried out the process of micro arc plasma body, steel part surface forms the bionical texture of stochastic distribution, steel part after process is inserted in treatment solution and repeatedly lifts, treat its surface uniform film forming, propose, make its spontaneous curing and drying, namely steel part self-cleaning surface rete is formed, the standby or marine settings for oceanic climate apoplexy Denso.
Embodiment 2: a kind of marine settings steel surface automatically cleaning treatment solution, the concentration comprising following component and each component is: the mixture being 3:7 with the volume ratio of NIPA and ethylene glycol is for solvent, the concentration of nanometer silicon carbide is 3.5g/L, the concentration of nano titanium oxide is 2.0g/L, and the concentration of carbon nanotube is 1.0g/L.
A kind of preparation method of marine settings steel surface automatically cleaning treatment solution, it is characterized in that, with the mixture of NIPA and ethylene glycol for solvent, ultrasonic with under magnetic field agitation acting in conjunction, add a certain amount of nano titanium oxide, nanometer silicon carbide, carbon nanotube successively, stir obtained treatment solution; Afterwards, steel part is carried out the process of micro arc plasma body, steel part surface forms the bionical texture of stochastic distribution, steel part after process is inserted in treatment solution and repeatedly lifts, treat its surface uniform film forming, propose, make its spontaneous curing and drying, namely steel part self-cleaning surface rete is formed, the standby or marine settings for oceanic climate apoplexy Denso.
Embodiment 3: a kind of marine settings steel surface automatically cleaning treatment solution, the concentration comprising following component and each component is: the mixture being 3:7 with the volume ratio of NIPA and ethylene glycol is for solvent, the concentration of nanometer silicon carbide is 4.0g/L, the concentration of nano titanium oxide is 2.5g/L, and the concentration of carbon nanotube is 1.5g/L.
A kind of preparation method of marine settings steel surface automatically cleaning treatment solution, it is characterized in that, with the mixture of NIPA and ethylene glycol for solvent, ultrasonic with under magnetic field agitation acting in conjunction, add a certain amount of nano titanium oxide, nanometer silicon carbide, carbon nanotube successively, stir obtained treatment solution; Afterwards, steel part is carried out the process of micro arc plasma body, steel part surface forms the bionical texture of stochastic distribution, steel part after process is inserted in treatment solution and repeatedly lifts, treat its surface uniform film forming, propose, make its spontaneous curing and drying, namely steel part self-cleaning surface rete is formed, the standby or marine settings for oceanic climate apoplexy Denso.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and distortion, these improve and distortion also should be considered as protection scope of the present invention.
Claims (8)
1. a marine settings steel surface automatically cleaning treatment solution, it is characterized in that, the concentration comprising following component and each component is: with the mixture of NIPA and ethylene glycol for solvent, the concentration of nanometer silicon carbide is 3.0 ~ 4.5g/L, the concentration of nano titanium oxide is 1.5 ~ 2.5g/L, and the concentration of carbon nanotube is 0.5 ~ 1.5g/L.
2. marine settings steel surface automatically cleaning treatment solution according to claim 1, is characterized in that, the volume ratio of NIPA and ethylene glycol is 1:0.1 ~ 20.
3. marine settings steel surface automatically cleaning treatment solution according to claim 1, is characterized in that, the volume ratio of NIPA and ethylene glycol is 3:7.
4. marine settings steel surface automatically cleaning treatment solution according to claim 2, is characterized in that, the concentration of nanometer silicon carbide is 3.0g/L, and the concentration of nano titanium oxide is 1.5g/L, and the concentration of carbon nanotube is 0.5g/L.
5. marine settings steel surface automatically cleaning treatment solution according to claim 2, is characterized in that, the concentration of nanometer silicon carbide is 3.5g/L, and the concentration of nano titanium oxide is 2.0g/L, and the concentration of carbon nanotube is 1.0g/L.
6. marine settings steel surface automatically cleaning treatment solution according to claim 2, is characterized in that, the concentration of nanometer silicon carbide is 4.0g/L, and the concentration of nano titanium oxide is 2.5g/L, and the concentration of carbon nanotube is 1.5g/L.
7. the marine settings preparation method of steel surface automatically cleaning treatment solution, it is characterized in that, with the mixture of NIPA and ethylene glycol for solvent, ultrasonic with under magnetic field agitation acting in conjunction, add a certain amount of nano titanium oxide, nanometer silicon carbide, carbon nanotube successively, stir obtained.
8. a marine settings purposes for steel surface automatically cleaning treatment solution, is characterized in that, comprise the following steps:
Step one: steel part is through the process of micro arc plasma body, and steel part surface forms the bionical texture of stochastic distribution;
Step 2: the steel part after process inserted in treatment solution and repeatedly lift, treat its surface uniform film forming, propose, make its spontaneous curing and drying, namely forms steel part self-cleaning surface rete, the standby or marine settings for oceanic climate apoplexy Denso.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510569001.2A CN105177542B (en) | 2015-09-09 | 2015-09-09 | Marine settings steel surface automatically cleaning treatment fluid, preparation method and the usage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510569001.2A CN105177542B (en) | 2015-09-09 | 2015-09-09 | Marine settings steel surface automatically cleaning treatment fluid, preparation method and the usage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105177542A true CN105177542A (en) | 2015-12-23 |
| CN105177542B CN105177542B (en) | 2018-02-02 |
Family
ID=54899951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510569001.2A Expired - Fee Related CN105177542B (en) | 2015-09-09 | 2015-09-09 | Marine settings steel surface automatically cleaning treatment fluid, preparation method and the usage |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105177542B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108754460A (en) * | 2018-05-18 | 2018-11-06 | 蚌埠心里程电子科技有限公司 | A kind of Metal surface anti-corrosion automatically cleaning processing method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070104859A1 (en) * | 2005-05-10 | 2007-05-10 | Michael Featherby | Coating for environmental protection and indication |
| CN101423678A (en) * | 2008-10-29 | 2009-05-06 | 国家纳米科学中心 | Light curing nano composite coating |
| CN102061121A (en) * | 2010-12-06 | 2011-05-18 | 老虎粉末涂料制造（太仓）有限公司 | Environmental-protection anti-corrosive heat-dissipation powder paint, and preparation method and application thereof |
| CN103740247A (en) * | 2014-01-07 | 2014-04-23 | 海洋化工研究院有限公司 | Spray polyurea elastomer applied to marine drilling platform corrosion prevention as well as preparation method and construction method thereof |
| EP2733181A2 (en) * | 2011-07-13 | 2014-05-21 | Posco | Resin composition for a surface treatment, and steel sheet coated with same |
| CN104277664A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Marine anticorrosive coatings |
-
2015
- 2015-09-09 CN CN201510569001.2A patent/CN105177542B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070104859A1 (en) * | 2005-05-10 | 2007-05-10 | Michael Featherby | Coating for environmental protection and indication |
| CN101423678A (en) * | 2008-10-29 | 2009-05-06 | 国家纳米科学中心 | Light curing nano composite coating |
| CN102061121A (en) * | 2010-12-06 | 2011-05-18 | 老虎粉末涂料制造（太仓）有限公司 | Environmental-protection anti-corrosive heat-dissipation powder paint, and preparation method and application thereof |
| EP2733181A2 (en) * | 2011-07-13 | 2014-05-21 | Posco | Resin composition for a surface treatment, and steel sheet coated with same |
| CN103740247A (en) * | 2014-01-07 | 2014-04-23 | 海洋化工研究院有限公司 | Spray polyurea elastomer applied to marine drilling platform corrosion prevention as well as preparation method and construction method thereof |
| CN104277664A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Marine anticorrosive coatings |
Non-Patent Citations (3)
| Title |
|---|
| 严瑞瑄等: "《水溶性高分子产品手册》", 31 October 2003, 化学工业出版社 * |
| 杨成德: "《涂料开发与试验》", 28 February 2015, 科学技术文献出版社 * |
| 王敏等: "Q235钢溶液微等离子体渗硼层的研究", 《热加工工艺》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108754460A (en) * | 2018-05-18 | 2018-11-06 | 蚌埠心里程电子科技有限公司 | A kind of Metal surface anti-corrosion automatically cleaning processing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105177542B (en) | 2018-02-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104388923B (en) | A kind of preparation method of Graphene modified titanium oxide anti-corrosion of metal erosion resisting coating | |
| CN105400373B (en) | A kind of anticorrosive paint and preparation method containing graphene/removing impurities polyaniline | |
| CN106835099B (en) | A method of improving stainless steel surface quality | |
| CN104275164B (en) | A kind of use in waste water treatment graphene oxide is composite porous and preparation method thereof | |
| CN108754474A (en) | A kind of stabilized treatment fluid of acceleration weathering steel rusty scale | |
| CN103602967B (en) | A kind of high catalytic activity Ti/TiO 2/ Ce-PbO 2the preparation method of electrode | |
| CN109456677A (en) | The preparation and the application in coating of a kind of hydrotalcite/graphene oxide hybrid material | |
| CN106086996B (en) | A kind of composite surface treatment method for repairing passivation for stainless steel state of having got rusty | |
| CN103924231B (en) | Naked steel rusty scale surface of stability treatment agent | |
| CN102212864A (en) | Method for modifying electrolysis phosphorization membrane | |
| CN105086663B (en) | The marine settings anti-corrosion hydrophobic treatment liquid of steel surface, preparation method and the usage | |
| CN103409785B (en) | A kind of titanium alloy surface reduces the nano coating preparation method of sea organism attachment | |
| CN110002546B (en) | Activated (Cu-Fe-Ce)/Al2O3Preparation and application of nanoparticle electrode | |
| CN105177542A (en) | Steel surface self-cleaning treating fluid for marine equipment, preparation method thereof and use thereof | |
| CN105174773B (en) | A kind of preparation method of corrosion inhibitors for reinforced concrete | |
| CN106521404A (en) | Process for manufacturing titanium anode by once oxidation | |
| Kim et al. | Photocatalytic activity of TiO2 nanotubes doped with Ag nanoparticles | |
| CN108239778A (en) | A kind of preparation method of titanium alloy substrate surface high emissivity ceramic coating | |
| CN102074379A (en) | Production process of high-voltage anode foil for aluminum electrolytic capacitor | |
| CN111254476A (en) | Preparation method of pure copper surface corrosion-resistant black micro-arc oxidation film | |
| CN105086664A (en) | Steel surface corrosion-resistant visbreaking treatment fluid in marine climate, and preparation method and application thereof | |
| CN103060877A (en) | Electrolyte for aluminum alloy micro-plasma electrolytic oxidation and treating process thereof | |
| CN107460517A (en) | A kind of preparation method of high corrosion-resistant cast aluminium Micro-Arc Oxidized Ceramic Coating | |
| CN105297099B (en) | A kind of method of electrolyzing organic in Copper substrate surface construction bionic super-hydrophobic film | |
| RU2013155426A (en) | METAL COPPER LEACHING METHOD |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180202 Termination date: 20200909 |