CN105153840A - Automotive interior energy-storage fluorescent paint and preparation method thereof - Google Patents
Automotive interior energy-storage fluorescent paint and preparation method thereof Download PDFInfo
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Abstract
The invention relates to an automotive interior energy-storage fluorescent paint and a preparation method thereof. The fluorescent paint comprises, by weight, 40-50 parts of thermoplastic acrylic resin, 5-15 parts of chlorinated polypropylene resin, 10-20 parts of fluorescent powder, 1-5 parts of abrasive powder, 0.1-0.5 parts of anti-sediment agent, 0.2-0.5 part of flatting agent, 0.5-1.5 parts of antioxidant and 15-25 parts of mixed solvent. The preparation method includes sequentially adding mixed solvent, thermoplastic acrylic resin, chlorinated polypropylene resin, anti-sediment agent and abrasive powder to an agitator vessel, agitating and mixing fully to obtain a mixture, transferring the mixture to a horizontal type grinder, grinding the mixture fully until fineness thereof is not larger than 20 micrometers, and then transferring the ground mixture to the agitator vessel, adding flatting agent, antioxidant and florescent powder according to part by weight and stirring and then mixing completely so as to obtain the automotive interior energy-storage fluorescent paint. Compared with the prior art, the fluorescent paint has the advantages of high adhesion, high light intensity, long lighting time, high stability, wear resistance and the like, can emit light at night when applied to automotive interiors, and is energy-saving, environmental friendly, convenient and practical.
Description
Technical field
The invention belongs to technical field of coatings, relate to a kind of fluorescent coating and preparation method thereof, especially relate to a kind of automotive trim accumulation of energy fluorescent coating and preparation method thereof.
Background technology
Along with popularizing of automobile, trip of driving now has become the first-selection of more and more people.Along with people are to the development of automobile individual demand, also more and more higher to the ornamental requirement of automotive upholstery, at present, the plastics that automotive upholstery extensively adopts are mainly based on thermoplastic resin, such as, Acrylonitrile Butadiene—Styrene copolymer, polypropylene, polyurethane(s), poly vinyl cyanide, polyethylene etc.And these inside gadget product moldings add defects such as can producing irregular colour, color and luster dullness, piebald fault man-hour, and easily produce agingly to become fragile, cut, contamination, the problem such as electrostatic, so coating plastic parts is essential.But prior art is mainly devoted to the improvement of the sticking power to automotive trim coating, the research in fluorescence is then few.Therefore, under existence conditions, the limitation due to automotive trim coating originally in fluorescence aspect, this just causes trip of driving night to there is inconvenience part.Such as, when driving a vehicle night, if do not open vehicle interior roof light, be just difficult to find keyhole, meanwhile, if adjustment seat, then on seat, the socket of securing band is also often difficult to find; For another example, being placed on the object in central water tumbler box, when not opening vehicle interior roof light, being difficult to accurate searching especially; If when running into the situations such as anxious acceleration, zig zag, the passenger of back row seats needs the safety handle held rapidly in compartment, but this is not when opening vehicle interior roof light night, being difficult to the very first time especially looks for, and this also can cause potential safety hazard undoubtedly.
For the problems referred to above, also the associated components adopting fluorescent adhesive paper to come in mark vehicle is had now, but because the shape of fluorescent adhesive paper is with to be pasted parts often inconsistent, this is just difficult to be attached to some details parts, and often after a period of time, the fluorescent adhesive paper adopted can drop, tears or be scratched, directly affect its result of use, meanwhile, because fluorescent adhesive paper itself is not wear-resisting, finger touch repeatedly after, fluorescent material on fluorescent adhesive paper can come off in a large number, this not only can pick up fluorescence indicative function, also can pollute environment inside car, not environmentally.
Application number be 201210485968.9 Chinese invention patent disclose a kind of fluorescent coating, comprise following component and weight part content: water-soluble polymer emulsion 20-30 part, alkaline earth sulfide 20-30 part, activate promoter 10-15 part, energy-accumulating luminous matrix material 30-35 part, defoamer 15-20 part, Ricinate 10-15 part, luminescent powder 10-50 part and film coalescence aid 3-5 part.During preparation, first alkaline earth sulfide and water-soluble polymer emulsion are injected in container, start to carry out stirring at low speed, stirring velocity is 150-200 rev/min, joins in container while stirring by activate promoter, carries out mix and blend 150 minutes, and add defoamer in right amount according to the denseness situation of mixed slurry, add energy-accumulating luminous matrix material Ricinate, luminescent powder and film coalescence aid afterwards, carry out 150-200 rev/min of low speed mixing and stir 150 minutes.In the technical scheme of above-mentioned patent disclosure, the compositions such as the alkaline earth sulfide adopted, be mainly used in the field such as building decoration, security against fire, this patent coating products has better sticking power at concrete and steel framed structure, but when it is applied to plastic material, sticking power is not good enough, and adopt the powder that the grain diameters such as alkaline earth are larger in formula, after this can make coating brush, outward appearance is more coarse, and is not suitable for automotive trim field.
Summary of the invention
Object of the present invention be exactly in order to overcome above-mentioned prior art exist defect and provide a kind of sticking power high, fluorescence is good, stablizes wear-resisting automotive trim accumulation of energy fluorescent coating and preparation method thereof.
Object of the present invention can be achieved through the following technical solutions:
A kind of automotive trim accumulation of energy fluorescent coating, this fluorescent coating comprises following component and weight part content:
The acid value of described thermoplastic acrylic resin is 7-8mgKOH/g, and solid content is 35-47%, and the cl content of described chlorinated polypropylene is 26-27%.
The beautiful positive thermoplastic resin LR-7697 of the preferred Mitsubishi of described thermoplastic acrylic resin or the beautiful positive thermoplastic resin LR-7651 of Mitsubishi.Wherein, the second-order transition temperature (TG) of LR-7697 is higher, be about 85 DEG C, can at room temperature have good hardness like this, and good resistance to general chemistry moral character is (as alcohol, clean-out system, hand lotion etc.), available gasoline repeatedly wiping lacquer painting repeatedly, macerates paint film, and remove coating, can eye strain be solved.And the second-order transition temperature of LR-7651 is lower, be about 50 DEG C, after forming paint film, surface can not be really up to the mark, and easy-to-use alcohol washes wiping repeatedly, can macerate paint film, and remove coating, can solve eye strain, and resin can be certainly dry, without the need to baking.
The preferred Japanese Japan DX-526P chlorinated polypropylene of described chlorinated polypropylene.Because the consistency of acrylic resin itself is poor, and the cohesive energy ratio is higher, so polyacrylic surface tension is very low, therefore be difficult to there is good wettability to base material, and be polymerized with chlorion by polypropylene, its solvability can be strengthened, and effectively can reduce the surface tension of resin.Cl content is lower, and the sticking power for plastic basis material is better, and cl content is higher, then better with the consistency of other resins.And the preferred Japanese Japan DX-526P chlorinated polypropylene of chlorinated polypropylene in the present invention, its cl content is moderate, and through test, with thermoplastic acrylic resin, all there is good consistency, can promote that coating is to the sticking power of vehicle inside decoration plastic basis material, and resin can be certainly dry, without the need to baking.
The median size of described fluorescent material is 3.5-4.5 μm, softening temperature >=130 DEG C.
The preferred Japanese fine chemistry SinloihiFA-41 fluorescent material of described fluorescent material, this fluorescent material is again photic smooth overlength afterglow light-accumulating powder, initiatively can inhale visible ray 5-30min such as storing daylight, light, UV-light, just can at automotive interior more than continuous illumination 8h.In the atomic structure of fluorescent material, peripheral electronics, by after outside energy (as light) rays excite, from ground state transition to excited state, is in unsteady state.When the external world stops exciting, electronics returns ground state, borrows amount of heat release bright dipping this moment.
The acid number < 1mgKOH/g of described wear-resisting powder, under the standard of ASTMD1321, hardness is 2.
Described wear-resisting powder is the polyethylene wax of classification micronized Teflon modification.
The polyethylene wax of described classification micronized Teflon modification is the polyethylene wax of U.S. Lu Borun TF1778 classification micronized Teflon modification, and its hardness is higher, can effectively improve resistance to marring and wear resistance, reduces coating and is scratched the risk with scratch.
Described anti-settling agent comprises aerosil.
The preferred DegussaAEROSIL200 aerosil of described aerosil.
Described flow agent comprise in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane or terminal groups modification organosilicon one or more.
The preferred BYK306 of described flow agent.
Described protective agent comprises hindered amine light stabilizer.
The preferred BASFTinuvin770 of described hindered amine light stabilizer.
Described mixed solvent is n-butyl acetate and methylcyclohexane is (1-5) in mass ratio: the mixed solvent of 1.
A preparation method for automotive trim accumulation of energy fluorescent coating, the method specifically comprises the following steps:
(1) get the raw materials ready by following component and weight part:
(2) mixed solvent, thermoplastic acrylic resin, chlorinated polypropylene, anti-settling agent and wear-resisting powder are joined successively in stirred vessel by weight, control stirring velocity is 100-300r/min, is uniformly mixed 10-20min;
(3) transfer in horizontal mill, fully be ground to fineness≤20 μm, transfer in stirred vessel, add flow agent, protective agent and fluorescent material by weight, control stirring velocity is 100-300r/min, be uniformly mixed 10-20min, i.e. obtained described automotive trim accumulation of energy fluorescent coating.
The present invention mainly for plastics, as ABS, PP, nylon, glass fibre etc., and for the general all more difficult realization of sticking power of plastics, particularly all can keep better sticking power on different sorts plastics, extremely difficult especially.Automotive trim accumulation of energy fluorescent coating of the present invention is mainly used in automobile interior part field, other performances for coating products have more requirements, as resistance to sweat, resistance to sunscreen, acidproof alkali lye, rub resistance etc., simultaneously, outward appearance for product also has higher requirements, as fineness (affecting feel and visual impression).
In the present invention, coating products not only has excellent sticking power on ABS to adopt chlorinated polypropylene to ensure, and all has good sticking power at PP, PA (two kinds of plastics internal cohesive energys are high, and sticking power difficulty is done).Adopt the polyethylene wax of classification micronized Teflon modification as wear-resisting powder, effectively can improve the crocking resistance of coating.
At present, in automobile market, with the present invention, there is similar fluorescent effect, only have the product that this kind of plasticity-of fluorescent adhesive paper is poor.And fluorescent effect is made into automotive trim paint, still to belong to rare.The present invention takes into full account the practicality of product coating, provides the mark of glimmer night, exempts from driving ceiling light, and have good aesthetic property in car, utilizes the strong feature of the plasticity-of liquid coating just, can accomplish exhaustive.
The difficult point that the present invention solves is mainly in the sticking power matching of coating for base material and the stability problem of fluorescent material in resin.The box of polypropylene material, internal cohesive energy is higher, and common coating prod is more difficult good sticking power in the above, by adding chlorinated polypropylene, can improve sticking power forcefully.Secondly, thermoplastic acrylic resin, because its acid value is between 7-8mgKOH/g, fluorescent material not easily can by resin decomposition, thus resin can by fluorescent material parcel and with its stable existence.Wear-resisting powder is along with the increase of weight part in formula, and abrasion resistant effect can strengthen thereupon, but can not be excessive, because can reduce luminous intensity and the time of fluorescent material.And the weight part of fluorescent material in formula is 10-20 part, along with consumption increment, luminous intensity and time are strengthened all to some extent, but can not be excessive, because the excessive resin that easily causes of fluorescent material is poor to its parcel property, and easy dry linting.
Compared with prior art, the present invention has following characteristics:
1) owing to adopting chlorinated polypropylene, itself and thermoplastic acrylic resin have good consistency, can strengthen solvability, and effectively can reduce the surface tension of resin, effectively can promote that coating is to the sticking power of base material;
2) owing to introducing the polyethylene wax of classification micronized Teflon modification as wear-resisting powder, can effectively improve resistance to marring and wear resistance, reduce coating and be scratched the risk with scratch;
3) owing to adding appropriate fluorescent material in component, fluorescent material and interlaminar resin, by suitable weight proportion, make resin fully can wrap fluorescent material, under guarantee luminous intensity and the condition of time, effectively can eliminate parcel property poor, the problem of easy dry linting;
4) preparation method is simple, mild condition, and raw material sources are wide, and cost is low, it is high that obtained fluorescent coating has sticking power, and luminous intensity is high, and fluorescent lifetime is long, stablizes the advantages such as wear-resisting, for automotive upholstery, can at self-luminescence at night, energy-conserving and environment-protective, convenient and practical.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1:
A kind of automotive trim accumulation of energy fluorescent coating preparation method, the method comprises following processing step:
By butyl ester, methylcyclohexane, LR-7697, DX-526P, AEROSIL200, TF1778, add successively in order in container, according to 100 ~ 300r/pm low rate mixing 10min, upper horizontal mill, by fineness grinding≤20um, add BYK306 again, Tinuvin770, SinloihiFA-41, according to 100 ~ 300r/pm low rate mixing 20min.Namely automotive trim accumulation of energy fluorescent coating is obtained
Said components is constructed in ABS, on polypropylene and nylon material.
The results of property of fluorescent coating is as shown in table 1.
The results of property of table 1 fluorescent coating
Embodiment 2:
A kind of automotive trim accumulation of energy fluorescent coating preparation method, the method comprises following processing step:
By butyl ester, methylcyclohexane, LR-7651, DX-526P, AEROSIL200, TF1778, add successively in order in container, according to 100 ~ 300r/pm low rate mixing 10min, upper horizontal mill, by fineness grinding≤20um, add BYK306 again, Tinuvin770, SinloihiFA-41, according to 100 ~ 300r/pm low rate mixing 20min.Namely automotive trim accumulation of energy fluorescent coating is obtained
Said components is constructed in ABS, on polypropylene and nylon material.
The results of property of fluorescent coating is as shown in table 2.
The results of property of table 2 fluorescent coating
Embodiment 3:
The present embodiment automotive trim accumulation of energy fluorescent coating, comprises following component and weight part content:
Wherein, the acid value of thermoplastic acrylic resin is 7-8mgKOH/g, and solid content is 35-47%, and the cl content of chlorinated polypropylene is 26-27%.
The median size of fluorescent material is 3.5-4.5 μm, softening temperature >=130 DEG C.The acid number < 1mgKOH/g of wear-resisting powder, under the standard of ASTMD1321, hardness is 2.Wear-resisting powder is the polyethylene wax of classification micronized Teflon modification.Anti-settling agent comprises aerosil.Flow agent comprise in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane or terminal groups modification organosilicon one or more.Protective agent comprises hindered amine light stabilizer.Mixed solvent is n-butyl acetate and methylcyclohexane is the mixed solvent of 5:1 in mass ratio.
The method specifically comprises the following steps:
(1) get the raw materials ready by following component and weight part:
(2) mixed solvent, thermoplastic acrylic resin, chlorinated polypropylene, anti-settling agent and wear-resisting powder are joined successively in stirred vessel by weight, control stirring velocity is 300r/min, is uniformly mixed 10min;
(3) transfer in horizontal mill, be fully ground to fineness≤20 μm, transfer in stirred vessel, add flow agent, protective agent and fluorescent material by weight, control stirring velocity is 300r/min, is uniformly mixed 20min, i.e. obtained described automotive trim accumulation of energy fluorescent coating.
Embodiment 4:
The present embodiment automotive trim accumulation of energy fluorescent coating, comprises following component and weight part content:
Wherein, the acid value of thermoplastic acrylic resin is 7-8mgKOH/g, and solid content is 35-47%, and the cl content of chlorinated polypropylene is 26-27%.
The median size of fluorescent material is 3.5-4.5 μm, softening temperature >=130 DEG C.The acid number < 1mgKOH/g of wear-resisting powder, under the standard of ASTMD1321, hardness is 2.Wear-resisting powder is the polyethylene wax of classification micronized Teflon modification.Anti-settling agent comprises aerosil.Flow agent comprise in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane or terminal groups modification organosilicon one or more.Protective agent comprises hindered amine light stabilizer.Mixed solvent is n-butyl acetate and methylcyclohexane is the mixed solvent of 1:1 in mass ratio.
The method specifically comprises the following steps:
(1) get the raw materials ready by following component and weight part:
(2) mixed solvent, thermoplastic acrylic resin, chlorinated polypropylene, anti-settling agent and wear-resisting powder are joined successively in stirred vessel by weight, control stirring velocity is 100r/min, is uniformly mixed 20min;
(3) transfer in horizontal mill, be fully ground to fineness≤20 μm, transfer in stirred vessel, add flow agent, protective agent and fluorescent material by weight, control stirring velocity is 100r/min, is uniformly mixed 20min, i.e. obtained described automotive trim accumulation of energy fluorescent coating.
Embodiment 5:
The present embodiment automotive trim accumulation of energy fluorescent coating, comprises following component and weight part content:
Wherein, the acid value of thermoplastic acrylic resin is 7-8mgKOH/g, and solid content is 35-47%, and the cl content of chlorinated polypropylene is 26-27%.
The median size of fluorescent material is 3.5-4.5 μm, softening temperature >=130 DEG C.The acid number < 1mgKOH/g of wear-resisting powder, under the standard of ASTMD1321, hardness is 2.Wear-resisting powder is the polyethylene wax of classification micronized Teflon modification.Anti-settling agent comprises aerosil.Flow agent comprise in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane or terminal groups modification organosilicon one or more.Protective agent comprises hindered amine light stabilizer.Mixed solvent is n-butyl acetate and methylcyclohexane is the mixed solvent of 1:1 in mass ratio.
The method specifically comprises the following steps:
(1) get the raw materials ready by following component and weight part:
(2) mixed solvent, thermoplastic acrylic resin, chlorinated polypropylene, anti-settling agent and wear-resisting powder are joined successively in stirred vessel by weight, control stirring velocity is 250r/min, is uniformly mixed 10min;
(3) transfer in horizontal mill, be fully ground to fineness≤20 μm, transfer in stirred vessel, add flow agent, protective agent and fluorescent material by weight, control stirring velocity is 250r/min, is uniformly mixed 10min, i.e. obtained described automotive trim accumulation of energy fluorescent coating.
Claims (10)
1. an automotive trim accumulation of energy fluorescent coating, is characterized in that, this fluorescent coating comprises following component and weight part content:
2. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, is characterized in that, the acid value of described thermoplastic acrylic resin is 7-8mgKOH/g, and solid content is 35-47%, and the cl content of described chlorinated polypropylene is 26-27%.
3. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, is characterized in that, the median size of described fluorescent material is 3.5-4.5 μm, softening temperature >=130 DEG C.
4. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, is characterized in that, the acid number < 1mgKOH/g of described wear-resisting powder, under the standard of ASTMD1321, hardness is 2.
5. a kind of automotive trim accumulation of energy fluorescent coating according to claim 4, is characterized in that, described wear-resisting powder is the polyethylene wax of classification micronized Teflon modification.
6. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, it is characterized in that, described anti-settling agent comprises aerosil.
7. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, it is characterized in that, described flow agent comprise in polydimethylsiloxane, polyether polyester modified organic silicon oxygen alkane, alkyl-modified organo-siloxane or terminal groups modification organosilicon one or more.
8. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, it is characterized in that, described protective agent comprises hindered amine light stabilizer.
9. a kind of automotive trim accumulation of energy fluorescent coating according to claim 1, is characterized in that, described mixed solvent is n-butyl acetate and methylcyclohexane is (1-5) in mass ratio: the mixed solvent of 1.
10. a preparation method for automotive trim accumulation of energy fluorescent coating as claimed in claim 1, it is characterized in that, the method specifically comprises the following steps:
(1) get the raw materials ready by following component and weight part:
(2) mixed solvent, thermoplastic acrylic resin, chlorinated polypropylene, anti-settling agent and wear-resisting powder are joined successively in stirred vessel by weight, control stirring velocity is 100-300r/min, is uniformly mixed 10-20min;
(3) transfer in horizontal mill, fully be ground to fineness≤20 μm, transfer in stirred vessel, add flow agent, protective agent and fluorescent material by weight, control stirring velocity is 100-300r/min, be uniformly mixed 10-20min, i.e. obtained described automotive trim accumulation of energy fluorescent coating.
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| CN106675380A (en) * | 2016-12-20 | 2017-05-17 | 东来涂料技术（上海）有限公司 | Safe and environment-friendly water-based leather paint for automobile TPU (Thermoplastic Polyurethane) interior and preparation method of water-based leather paint |
| CN108329775A (en) * | 2018-01-26 | 2018-07-27 | 温州大学 | A kind of fluorescent paint and preparation method thereof of resistance to environmental attack |
| CN112745735A (en) * | 2020-12-17 | 2021-05-04 | 马鞍山悠思电子科技有限公司 | Coated fluorescent paint and preparation method thereof |
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| CN105153840B (en) | 2017-11-03 |
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Address after: 201807 No. 1221 Xin He Lu, Jiading Industrial Zone, Jiading District, Shanghai. Patentee after: Dong Lai coating technology (Shanghai) Limited by Share Ltd Address before: 201807 No. 1221 Xin He Lu, North Jiading Industrial Zone, Jiading District, Shanghai. Patentee before: Eastern paint technology (Shanghai) Co., Ltd. |
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