CN105132070A - Aeration separation type biomass briquette - Google Patents

Aeration separation type biomass briquette Download PDF

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Publication number
CN105132070A
CN105132070A CN201510609417.2A CN201510609417A CN105132070A CN 105132070 A CN105132070 A CN 105132070A CN 201510609417 A CN201510609417 A CN 201510609417A CN 105132070 A CN105132070 A CN 105132070A
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aeration
biomass
fuel
mixture
substrate
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CN201510609417.2A
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高坤方
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Individual
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses an aeration separation type biomass briquette. The aeration separation type biomass briquette comprises a plurality of biomass fuel substrates which are molded in a laminated manner; an aeration bonding layer is arranged between every two adjacent biomass fuel substrates, and made of a mixture of a fiber bonding agent and potassium bicarbonate; the mass percent of potassium bicarbonate in the mixture of the fiber bonding agent and potassium bicarbonate is 4-9%. The aeration separation type biomass briquette has the characteristics of being high in combustion performance and universality, low in cost, and convenient to produce in large scale.

Description

A kind of aeration divergence type biomass molding fuel
Technical field
The present invention relates to Biomass Briquette Technologies field, be specially a kind of aeration divergence type biomass molding fuel.
Background technology
Along with expanding economy.The energy and environmental problem have become the focus of global concern, and the pollution problem that traditional fossil energy such as such as coal, oil and natural gas etc. produces due to the day by day exhausted energy dilemma brought and its burning becomes increasingly conspicuous, and the clean renewable energy source of exploitation is extremely urgent.Biomass are a kind of multifarious Energy resources, wide material sources, and application is simple, has a good application prospect as the effective substitute energy of one.In the last few years, utilize forest processing waste, the investigation and application making biomass granule fuel after the grinding and processing such as straw also increases gradually, current biomass energy directly forms strip, particulate state or bulk mainly through direct extrusion molding, in the course of processing, moisture problem for the course of processing of biomass fuel and the impact of performance inevitable, if moisture content is too high, biomass fuel can be caused to form slaking and rot in the process stored, also can cause the performance of combustionproperty due to moisture content problem in combustion processes; If moisture content is on the low side, lamination process difficulty is large, has a strong impact on the lifting of biomass fuel compacted density.
Summary of the invention
The object of this invention is to provide a kind of aeration divergence type biomass molding fuel; take into full account the impact of biomass fuel moisture content; make full use of the moisture of biomass fuel inside, have that combustionproperty is high, highly versatile, with low cost and be convenient to the feature of large-scale production.
The present invention can be achieved through the following technical solutions:
The invention discloses a kind of aeration divergence type biomass molding fuel, comprise some biomass fuel substrates laminated into type, aeration tack coat is provided with between described biomass fuel substrate adjacent between two, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 4 ~ 9% of the mixture of described fiber-like tackiness agent and saleratus.By being provided with aeration tack coat at biomass fuel substrate, the saleratus that heating can produce carbonic acid gas is included in aeration tack coat, ten hydrated potassium bicarbonate are become after dry saleratus crystal can absorb water, more than 50 DEG C start to decompose generation salt of wormwood, carbonic acid gas and water gradually, decompose completely when 440 DEG C.Both the moisture of the water-absorbent of saleratus organism-absorbing matter fuel internal residual in the process stored can have been utilized, effectively avoid the loss that biomass fuel slaking in storage process causes, the separation accelerated in the process that saleratus can also be utilized to decompose between different layers increases the surface-area of burning contacts, thus use the burning of biomass fuel more abundant, effectively improve the combustionproperty of biomass molding fuel; And, in the process that saleratus decomposes, moisture becomes water vapour along with carbonic acid gas and overflows, water vapour can be formed with the biomass fuel surface of calcination and fully contact, the red-hot coke of water vapour and biomass fuel surface can produce water-gas, and the main component of water-gas is carbon monoxide and hydrogen, and carbon monoxide and hydrogen are inflammable gas, can burn in combustion, promote the combustionproperty of biomass fuel further.Simultaneously, saleratus is selected to be blended in inside cellulose binder, and the mass ratio of saleratus is between 4 ~ 9%, saleratus is made to be dispersed in inside cellulose binder, what produce when effectively ensure that saleratus decomposes makes the separating force between biomass fuel substrate relatively more even, and the carbonic acid gas of generation also can utilize carbonic acid gas to drive water vapour fully to contact formation water-gas with biomass fuel when realizing biomass fuel substrate interlaminar separation.If saleratus the content of aeration tack coat higher more than 9% time, because carbonic acid gas is in the nature flame retardant resistance gas, can cause because the too high burning to biomass fuel of carbon dioxide content affects; If saleratus is when comparatively low pressure is less than 4% to the content of aeration tack coat, the water-retaining capacity of saleratus is limited, the amount of the carbonic acid gas produced is also on the low side, affect soaking effect and combustion efficacy simultaneously, the abundant degree of biomass molding fuel burning can be badly influenced, the raising of restriction biomass molding fuel combustionproperty when particularly thicker the and number of plies of biomass molding fuel thickness is more.In addition, by arranging aeration tack coat, the biomass fuel substrate that both can arrange multilayer as required meets the requirement of thickness, also the moisture controlled for biomass fuel need not be too strict, reduce difficulty of processing, promote the compacted density of biomass fuel, there is stronger versatility.In addition, the raw material selected is convenient source conservation cost, and the considerably less course of processing of aeration agent saleratus consumption of employing is very simple, and the course of processing, without the need to mating special fabrication design, effectively reduces manufacturing cost, is convenient to large-scale promotion and uses.
The moisture content of described biomass fuel substrate is 8% to 15%.By the moisture content of conservative control biomass fuel, both effectively reduce the difficulty of biomass fuel compaction process, effectively avoid again because the too high storage for biomass molding fuel of moisture content impacts.
Described biomass fuel substrate comprises biomass crumb feedstock, described biomass crumb feedstock comprises agricultural wastes, xylogen and/or oil crops waste, according to actual needs, can select dissimilar material flexibly, fully reduce costs, expand the use of biomass molding fuel.
Described agricultural wastes comprise one or more the mixture in stalk, corn cob, bagasse, algae and Herba Eichhorniae, and source widely, effectively reduces manufacturing cost.
Described xylogen comprises one or more the mixture in wooden unit, wood chip and bark, and source widely, effectively reduces manufacturing cost.
Described oil crops waste comprises one or more the mixture in cottonseed, numb seed and tung oil tree, and source widely, effectively reduces manufacturing cost.
Described fiber-like tackiness agent is paper waste and/hydrolysis fiber, and source widely, effectively reduces manufacturing cost, can play cohesive action, and effectively dispersed carbon potassium hydrogen phthalate ensures the safe effect of aeration agent again.
The Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:30 ~ 1:70, different Thickness Ratios can be selected according to actual needs, the thickness requirement of further lifting biomass molding fuel, the high compacted density of biomass molding fuel does not provide potential room for promotion.
Described biomass fuel substrate is Puffer-type biomass fuel substrate, and described Puffer-type biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, and inflation mixes.Select Puffer-type biomass fuel substrate, the contact gear ratio surface-area of biomass molding fuel can be increased further in combustion, promote the performance of biomass molding fuel combustionproperty.
The number of plies of described biomass fuel substrate be two-layer and more than, satisfactory thickness can be selected flexibly according to actual needs, expand the thickness of biomass molding fuel further.
A kind of aeration divergence type of the present invention biomass molding fuel, has following beneficial effect:
The first, combustionproperty is high, by being provided with aeration tack coat at biomass fuel substrate, the saleratus that heating can produce carbonic acid gas is included in aeration tack coat, the separation accelerated in the process that saleratus both can have been utilized to decompose between different layers increases the surface-area of burning contacts, can be taken again out of water vapour by the carbonic acid gas produced and form water-gas lifting combustionproperty, thus use the burning of biomass fuel more abundant, effectively improve the combustionproperty of biomass molding fuel;
The second, highly versatile, by arranging aeration tack coat, the biomass fuel substrate that both can arrange multilayer as required meets the requirement of thickness, also effectively ensures the performance of the combustionproperty of high-density biology matter shaped fuel, has stronger versatility;
Three, with low cost, the raw material selected is convenient source conservation cost, and the equipment of employing is conventional equipment and saves equipment investment cost without the need to larger facility investment, reduces manufacturing cost further;
Four, be convenient to large-scale production, aeration divergence type biomass molding fuel structure is simple, and effectively simplify manufacturing procedure, and be the operation that routinizes, continuity of operation is high, effectively reduces the difficulty of large-scale production.
Accompanying drawing explanation
Accompanying drawing 1 is the diagrammatic cross-section of a kind of aeration divergence type of the present invention biomass molding fuel embodiment 1.
Embodiment
In order to make those skilled in the art person understand technical scheme of the present invention better, below in conjunction with embodiment and accompanying drawing, product of the present invention is described in further detail.
Embodiment 1
As shown in Figure 1, embodiment 1 is for having the aeration divergence type biomass molding fuel of five-layer structure, comprise three biomass fuel substrates 1 laminated into type, aeration tack coat 2 is provided with between described biomass fuel substrate 1 adjacent between two, described aeration tack coat 2 is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 4% of the mixture of described fiber-like tackiness agent and saleratus.The material of described biomass fuel substrate 1 is agricultural wastes, and described agricultural wastes comprise one or more the mixture in stalk, corn cob, bagasse, algae and Herba Eichhorniae.Described aeration tack coat 2 is 1:50 with the Thickness Ratio of described biomass fuel substrate 1.Described biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, mixes.
Embodiment 2
Embodiment 2 is for having the aeration divergence type biomass molding fuel of double-layer structure, comprise two biomass fuel substrates laminated into type, aeration tack coat is provided with between described two adjacent biomass fuel substrates, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 9% of the mixture of described fiber-like tackiness agent and saleratus.The moisture content of described biomass fuel substrate is 8%.Described biomass fuel substrate comprises biomass crumb feedstock, and described biomass crumb feedstock comprises xylogen, and described xylogen comprises one or more the mixture in wooden unit, wood chip and bark.Described fiber-like tackiness agent is paper waste and/hydrolysis fiber.The Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:30.The described biomass fuel substrate that fills adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, mixes.
Embodiment 3
Embodiment 3 is for having the aeration divergence type biomass molding fuel of five-layer structure, comprise three biomass fuel substrates laminated into type, aeration tack coat is provided with between described biomass fuel substrate adjacent between two, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 7% of the mixture of described fiber-like tackiness agent and saleratus.The moisture content of described biomass fuel substrate is 15%.Described biomass fuel substrate comprises biomass crumb feedstock, and described biomass crumb feedstock is oil crops waste.Described oil crops waste comprises one or more the mixture in cottonseed, numb seed and tung oil tree.Described fiber-like tackiness agent is paper waste and/hydrolysis fiber.The Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:70.Described Puffer-type biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, mixes.
Embodiment 4
Embodiment 4 is for having the aeration divergence type biomass molding fuel of five-layer structure, comprise three biomass fuel substrates laminated into type, aeration tack coat is provided with between described biomass fuel substrate adjacent between two, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 9% of the mixture of described fiber-like tackiness agent and saleratus.The moisture content of described biomass fuel substrate is 9%.Described biomass fuel substrate comprises biomass crumb feedstock, and described biomass crumb feedstock comprises agricultural wastes, xylogen and oil crops waste.Described agricultural wastes comprise one or more the mixture in stalk, corn cob, bagasse, algae and Herba Eichhorniae.Described xylogen comprises one or more the mixture in wooden unit, wood chip and bark.Described oil crops waste comprises one or more the mixture in cottonseed, numb seed and tung oil tree.Described fiber-like tackiness agent is paper waste and/hydrolysis fiber.The Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:50.Described Puffer-type biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, mixes.
Embodiment 5
Embodiment 5 is for having the aeration divergence type biomass molding fuel of five-layer structure, comprise three biomass fuel substrates laminated into type, aeration tack coat is provided with between described biomass fuel substrate adjacent between two, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 9% of the mixture of described fiber-like tackiness agent and saleratus.The moisture content of described biomass fuel substrate is 12%.Described biomass fuel substrate comprises biomass crumb feedstock, and described biomass crumb feedstock comprises agricultural wastes, xylogen and oil crops waste.Described agricultural wastes comprise one or more the mixture in stalk, corn cob, bagasse, algae and Herba Eichhorniae.Described xylogen comprises one or more the mixture in wooden unit, wood chip and bark.Described oil crops waste comprises one or more the mixture in cottonseed, numb seed and tung oil tree.Described fiber-like tackiness agent is paper waste and/hydrolysis fiber.The Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:50.Described biomass fuel substrate is Puffer-type biomass fuel substrate, and described Puffer-type biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, and inflation mixes.
Embodiment 6
Embodiment 6 is for having the aeration divergence type biomass molding fuel of five-layer structure, comprise three biomass fuel substrates laminated into type, aeration tack coat is provided with between described biomass fuel substrate adjacent between two, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 9% of the mixture of described fiber-like tackiness agent and saleratus.The moisture content of described biomass fuel substrate is 9%.Described biomass fuel substrate comprises biomass crumb feedstock, and described biomass crumb feedstock is oil crops waste.Described oil crops waste comprises one or more the mixture in cottonseed, numb seed and tung oil tree.Described fiber-like tackiness agent is paper waste and/hydrolysis fiber.The Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:70.Described Puffer-type biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, mixes.
Meanwhile, in order to assess the concrete technique effect of the biological shaped fuel of aeration type of the present invention, test from the concrete combustionproperty of aspect to embodiment 1 ~ 6 such as calorific value, rate of combustion and heating rates respectively.Concrete test data is as shown in table 1:
The concrete combustionproperty test data of the different embodiment of table 1
Group number Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Calorific value (kcal/kg) 5240 5540 5530 5370 5580 5670
Rate of combustion (%) 96.6 95.7 95.8 96.8 98.2 97.3
Thermo-efficiency (%) 93.0 94.5 95.3 94.9 96.8 96.5
As can be seen from Table 1, the present invention prepares the biomass molding fuel calorific value of gained at more than 5200lcal/Kg, and rate of combustion is more than 95%, and thermo-efficiency is more than 92%.And the concrete combustionproperty of traditional biomass molding fuel is: calorific value is at 4500 ~ 4800kcal/kg, and rate of combustion is between 90 ~ 96, and heating rate is between 80 ~ 90.By contrast, aeration divergence type biomass molding fuel of the present invention all has significant lifting in combustionproperty indexs such as calorific value, rate of combustion and heating rates, is with a wide range of applications.
And can see from table 1 data, embodiment 4 and the embodiment 5 of same material contrast, and adopt Puffer-type biomass molding fuel to be to provide biomass extrusion materials combustionproperty and have certain effect; Contrasted by embodiment 3 and embodiment 6, increase the content of aeration agent saleratus, also obviously can promote the combustionproperty of biomass extrusion materials.
The above, be only preferred embodiment of the present invention, not does any pro forma restriction to the present invention; The those of ordinary skill of all industry all can shown in by specification accompanying drawing and the above and implement the present invention swimmingly; But all those skilled in the art are not departing within the scope of technical solution of the present invention, disclosed above technology contents can be utilized and make a little change, modify with differentiation equivalent variations, be Equivalent embodiments of the present invention; Meanwhile, all according to substantial technological of the present invention to the change of any equivalent variations that above embodiment is done, modify and differentiation etc., within the protection domain all still belonging to technical scheme of the present invention.

Claims (10)

1. an aeration divergence type biomass molding fuel, it is characterized in that: comprise some biomass fuel substrates laminated into type, aeration tack coat is provided with between described biomass fuel substrate adjacent between two, described aeration tack coat is the mixture of fiber-like tackiness agent and saleratus, and the quality proportioning of described saleratus is 4 ~ 9% of the mixture of described fiber-like tackiness agent and saleratus.
2. aeration divergence type biomass molding fuel according to claim 1, is characterized in that: the moisture content of described biomass fuel substrate is 8% to 15%.
3. aeration divergence type biomass molding fuel according to claim 2, it is characterized in that: described biomass fuel substrate comprises biomass crumb feedstock, described biomass crumb feedstock comprises agricultural wastes, xylogen and/or oil crops waste.
4. aeration divergence type biomass molding fuel according to claim 3, is characterized in that: described agricultural wastes comprise one or more the mixture in stalk, corn cob, bagasse, algae and Herba Eichhorniae.
5. aeration divergence type biomass molding fuel according to claim 3, is characterized in that: described xylogen comprises one or more the mixture in wooden unit, wood chip and bark.
6. aeration divergence type biomass molding fuel according to claim 3, is characterized in that: described oil crops waste comprises one or more the mixture in cottonseed, numb seed and tung oil tree.
7. the aeration divergence type biomass molding fuel according to any one of claim 3 ~ 5 right, is characterized in that: described fiber-like tackiness agent is paper waste and/hydrolysis fiber.
8. aeration divergence type biomass molding fuel according to claim 7, is characterized in that: the Thickness Ratio of described aeration tack coat and described biomass fuel substrate is 1:30 ~ 1:70.
9. aeration divergence type biomass molding fuel according to claim 8, it is characterized in that: described biomass fuel substrate is Puffer-type biomass fuel substrate, described Puffer-type biomass fuel substrate adds and is equivalent to the unslaked lime of biomass crumb feedstock siccative weight 3 ~ 8%, the kaolin of 2 ~ 5% in preparation process, and inflation mixes.
10. aeration divergence type biomass molding fuel according to claim 8, is characterized in that: the number of plies of described biomass fuel substrate be two-layer and more than.
CN201510609417.2A 2015-09-22 2015-09-22 Aeration separation type biomass briquette Pending CN105132070A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101077986A (en) * 2006-05-25 2007-11-28 林鼎华 Multifunctional and highly effective synthesis ammonia gas preparation molded coal cementing agent
CN101440328A (en) * 2008-12-24 2009-05-27 李政 Environment-protecting synergistic agent for fuel coal
JP2009120776A (en) * 2007-11-19 2009-06-04 Nishizuka Shoten:Kk Solid fuel and production method of solid fuel
CN104342221A (en) * 2014-10-28 2015-02-11 惠州市拓丰实业有限公司 Method for preparing laminated biomass molded fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101077986A (en) * 2006-05-25 2007-11-28 林鼎华 Multifunctional and highly effective synthesis ammonia gas preparation molded coal cementing agent
JP2009120776A (en) * 2007-11-19 2009-06-04 Nishizuka Shoten:Kk Solid fuel and production method of solid fuel
CN101440328A (en) * 2008-12-24 2009-05-27 李政 Environment-protecting synergistic agent for fuel coal
CN104342221A (en) * 2014-10-28 2015-02-11 惠州市拓丰实业有限公司 Method for preparing laminated biomass molded fuel

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Application publication date: 20151209