CN105131679A - Graphene anticorrosive paint and preparation method thereof - Google Patents
Graphene anticorrosive paint and preparation method thereof Download PDFInfo
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- CN105131679A CN105131679A CN201510701692.7A CN201510701692A CN105131679A CN 105131679 A CN105131679 A CN 105131679A CN 201510701692 A CN201510701692 A CN 201510701692A CN 105131679 A CN105131679 A CN 105131679A
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Abstract
The invention discloses graphene anticorrosive paint and a preparation method thereof. The graphene anticorrosive paint is prepared from graphene, zinc silicate, talcum powder, hexafluorobutyl methacrylate-acrylic ester copolymer emulsion, organosilicone modification fluorocarbon resin, hydroxyethyl cellulose, acrylic acid, 2, 4, 6-tri(dimethyl aminomethyl) phenol, dibutyltin dilaurate, styrene-acrylic emulsion, sodium triphosphate, gaseous phase aluminum oxide, alumina silicate fibers, isopropyl phenyl diphenyl phosphate, ammonium carbonate, titanium dioxide, toughening agents, coagulating agents, thinning agents, iron powder and silica sol, and the graphene anticorrosive paint is prepared out through a step-by-step mixing method. The graphene anticorrosive paint is corrosion-resistant, abrasion-resistant, capable of absorbing heat and applicable to outdoor equipment of an electric power grid.
Description
Technical field
The invention belongs to protective system technical field, particularly a kind of Graphene protective system be applied on electric power network outdoor equipment and preparation method thereof.
Background technology
Power equipment (powersystem) mainly comprises with generating set and the large class of power-supply unit two, generating set is station boiler, steam turbine, internal combustion turbine, water turbine, generator, transformer etc. mainly, the transmitting line, mutual inductor, contactor etc. of power-supply unit mainly various voltage range.
Along with industrial expansion, use at electric power network outdoor equipment, Graphene protective system for main coating can play anticorrosion, wear-resisting, acid and alkali-resistance effect is more and more important, at present, common Graphene coating is easily corroded with aging, can not play automatically cleaning, acid and alkali-resistance effect.
Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of wear-resisting, corrosion-resistant, the Graphene protective system that can absorb heat and the preparation method of this Graphene protective system, wherein this Graphene protective system is useful on electric power network outdoor equipment and uses.
A kind of Graphene protective system, this Graphene protective system is made up of following weight part material: black alkene 25-60 part; Zinc silicate 25-60 part; Talcum powder 25-60 part; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-60 part; Organic-silicon-modified fluorocarbon resin 25-60 part; Natvosol 25-60 part; Vinylformic acid 1-20 part; 2,4,6-tri(dimethylaminomethyl)phenol 1-20 part; Dibutyl tin laurate 1-20 part; Benzene emulsion 1-20 part; Tripoly phosphate sodium STPP 1-20 part; Gas phase aluminium sesquioxide 1-20 part; Aluminum silicate fiber 1-20 part; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1-20 part; Volatile salt 1-20 part; Titanium dioxide 1-20 part; Toughner 1-20 part; Peptizer 1-20 part; Thinner 1-20 part; Iron powder 1-20 part; Silicon sol 1-20 part.
As preferred version of the present invention, this Graphene protective system is made up of following weight part material: Graphene 37 parts; Zinc silicate 37 parts; Talcum powder 37 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 37 parts; Organic-silicon-modified fluorocarbon resin 37 parts; Natvosol 37 parts; 7 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 7 parts; Dibutyl tin laurate 7 parts; Benzene emulsion 7 parts; Tripoly phosphate sodium STPP 7 parts; Gas phase aluminium sesquioxide 7 parts; Aluminum silicate fiber 7 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 7 parts; Volatile salt 7 parts; Titanium dioxide 7 parts; Toughner 7 parts; 7 parts, peptizer; Thinner 7 parts; Iron powder 7 parts; Silicon sol 7 parts.
As preferred version of the present invention, the particle diameter of described Graphene is 25-60nm.
Present invention also offers a kind of preparation method preparing above-mentioned Graphene protective system, it comprises the steps:
(1), prepare burden according to the composition of Graphene protective system;
(2), Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add Natvosol more subsequently, stir 25min with homogenizer;
(3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain Graphene protective system.
By the use of technique scheme, the present invention has following beneficial effect:
(1), adopt Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate, organic-silicon-modified fluorocarbon resin and Natvosol are as the main component of Graphene protective system, Graphene is as the main component of coating, electroconductibility or salt spray resistance can not only be improved, coat-thickness can also be reduced further simultaneously, increase the sticking power to base material, promote wear resistance and the antiseptic property of coating, and the compound use of resin and organic-silicon-modified fluorocarbon resin, to greatly strengthen the wear-resisting of Graphene protective system, the performance of corrosion-resistant and acid and alkali-resistance, and inorganic materials talcum powder and Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate, because self is for the reinforced effects of coating, as main component, the preservative property of coating are strengthened greatly.
(2), have selected vinylformic acid, 2, 4, 6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol are ancillary component, not only make the wear-resisting of this Graphene protective system, corrosion-resistant, acid-proof alkaline is improved, or good hydrophobic performance must be had by this Graphene protective system, and owing to the addition of solar selectively absorptive function iron powder and silicon sol combination, this Graphene protective system is made to can be used in the relevant electric power network outdoor equipment of sun power.
(3), this Graphene protective system preparation technology is simple, and be easy to industrialization, raw material sources are extensive, are applicable to very much being applied to production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1
The Graphene protective system of the present embodiment is made up of following weight part material: Graphene 37 parts; Zinc silicate 37 parts; Talcum powder 37 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 37 parts; Organic-silicon-modified fluorocarbon resin 37 parts; Natvosol 37 parts; 7 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 7 parts; Dibutyl tin laurate 7 parts; Benzene emulsion 7 parts; Tripoly phosphate sodium STPP 7 parts; Gas phase aluminium sesquioxide 7 parts; Aluminum silicate fiber 7 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 7 parts; Volatile salt 7 parts; Titanium dioxide 7 parts; Toughner 7 parts; 7 parts, peptizer; Thinner 7 parts; Iron powder 7 parts; Silicon sol 7 parts.The particle diameter of wherein said Graphene is 30nm.
The preparation method of the Graphene protective system of the present embodiment is as follows: (1), prepare burden according to the composition of Graphene protective system; (2), Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add Natvosol more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain Graphene protective system.
Embodiment 2
The Graphene protective system of the present embodiment is made up of following weight part material: Graphene 46 parts; Zinc silicate 46 parts; Talcum powder 46 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 46 parts; Organic-silicon-modified fluorocarbon resin 46 parts; Natvosol 46 parts; 6 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 6 parts; Dibutyl tin laurate 6 parts; Benzene emulsion 6 parts; Tripoly phosphate sodium STPP 6 parts; Gas phase aluminium sesquioxide 6 parts; Aluminum silicate fiber 6 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 6 parts; Volatile salt 6 parts; Titanium dioxide 6 parts; Toughner 6 parts; 6 parts, peptizer; Thinner 6 parts; Iron powder 6 parts; Silicon sol 6 parts.The particle diameter of wherein said Graphene is 30nm.
The preparation method of the Graphene protective system of the present embodiment is as follows: (1), prepare burden according to the composition of Graphene protective system; (2), Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add Natvosol more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain Graphene protective system.
Embodiment 3
The Graphene protective system of the present embodiment is made up of following weight part material: Graphene 30 parts; Zinc silicate 30 parts; Talcum powder 30 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 30 parts; Organic-silicon-modified fluorocarbon resin 30 parts; Natvosol 30 parts; 1 part, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 1 part; Dibutyl tin laurate 1 part; Benzene emulsion 1 part; Tripoly phosphate sodium STPP 1 part; Gas phase aluminium sesquioxide 1 part; Aluminum silicate fiber 1 part; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1 part; Volatile salt 1 part; Titanium dioxide 1 part; Toughner 1 part; 1 part, peptizer; Thinner 1 part; Iron powder 1 part; Silicon sol 1 part.The particle diameter of wherein said Graphene is 40nm.
The preparation method of the Graphene protective system of the present embodiment is as follows: (1), prepare burden according to the composition of Graphene protective system; (2), Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add Natvosol more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain Graphene protective system.
Embodiment 4
The Graphene protective system of the present embodiment is made up of following weight part material: Graphene 27 parts; Zinc silicate 27 parts; Talcum powder 27 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 27 parts; Organic-silicon-modified fluorocarbon resin 27 parts; Natvosol 27 parts; 20 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 20 parts; Dibutyl tin laurate 20 parts; Benzene emulsion 20 parts; Tripoly phosphate sodium STPP 20 parts; Gas phase aluminium sesquioxide 20 parts; Aluminum silicate fiber 20 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 20 parts; Volatile salt 20 parts; Titanium dioxide 20 parts; Toughner 20 parts; 20 parts, peptizer; Thinner 20 parts; Iron powder 20 parts; Silicon sol 20 parts.The particle diameter of wherein said Graphene is 40nm.
The preparation method of the Graphene protective system of the present embodiment is as follows: (1), prepare burden according to the composition of Graphene protective system; (2), Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add Natvosol more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain Graphene protective system.
Carry out salt-fog test and scuffing results of property to the Graphene anti-corrosion paint prepared by embodiment 1-4 at electric power network outdoor equipment, result is as follows:
| Erosion resistance (salt-fog test) | Scratch resistant | |
| Embodiment 1 | 677 hours | 0 |
| Embodiment 2 | 679 hours | 0 |
| Embodiment 3 | 688 hours | 0 |
| Embodiment 4 | 681 hours | 0 |
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. a Graphene protective system, is characterized in that: this Graphene protective system is made up of following weight part material: Graphene 25-60 part; Zinc silicate 25-60 part; Talcum powder 25-60 part; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-60 part; Organic-silicon-modified fluorocarbon resin 25-60 part; Natvosol 25-60 part; Vinylformic acid 1-20 part; 2,4,6-tri(dimethylaminomethyl)phenol 1-20 part; Dibutyl tin laurate 1-20 part; Benzene emulsion 1-20 part; Tripoly phosphate sodium STPP 1-20 part; Gas phase aluminium sesquioxide 1-20 part; Aluminum silicate fiber 1-20 part; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1-20 part; Volatile salt 1-20 part; Titanium dioxide 1-20 part; Toughner 1-20 part; Peptizer 1-20 part; Thinner 1-20 part; Iron powder 1-20 part; Silicon sol 1-20 part.
2. Graphene protective system according to claim 1, is characterized in that: this Graphene protective system is made up of following weight part material: Graphene 37 parts; Zinc silicate 37 parts; Talcum powder 37 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 37 parts; Organic-silicon-modified fluorocarbon resin 37 parts; Natvosol 37 parts; 7 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 7 parts; Dibutyl tin laurate 7 parts; Benzene emulsion 7 parts; Tripoly phosphate sodium STPP 7 parts; Gas phase aluminium sesquioxide 7 parts; Aluminum silicate fiber 7 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 7 parts; Volatile salt 7 parts; Titanium dioxide 7 parts; Toughner 7 parts; 7 parts, peptizer; Thinner 7 parts; Iron powder 7 parts; Silicon sol 7 parts.
3. the Graphene protective system according to claims 1 or 2, is characterized in that: the particle diameter of described Graphene is 25-60nm.
4. prepare a method for Graphene protective system according to claim 1, it is characterized in that: comprise the steps:
(1), prepare burden according to the composition of Graphene protective system;
(2), Graphene, zinc silicate, talcum powder, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add Natvosol more subsequently, stir 25min with homogenizer;
(3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, benzene emulsion, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, toughner, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain Graphene protective system.
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| CN201510701692.7A CN105131679A (en) | 2015-10-26 | 2015-10-26 | Graphene anticorrosive paint and preparation method thereof |
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Cited By (5)
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| CN107715492A (en) * | 2017-11-13 | 2018-02-23 | 广西华银铝业有限公司 | Evaporator group incoagulable gas collects injection energy-saving device |
| CN108299997A (en) * | 2016-08-15 | 2018-07-20 | 中国科学院宁波材料技术与工程研究所 | Fiber reinforcement anticorrosive paint and its preparation method and application |
| CN109439120A (en) * | 2018-11-22 | 2019-03-08 | 福州大学 | A kind of preparation method of the modified acrylic ester aqueous anticorrosive paint of graphene/Organic fluoride |
| CN110820319A (en) * | 2019-10-09 | 2020-02-21 | 凡港(厦门)科技有限公司 | Nano-graphene-based refined wax tape and preparation method thereof |
| CN111978797A (en) * | 2020-08-27 | 2020-11-24 | 深圳市嘉固工业地坪有限公司 | Water-based composite nano toner and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108299997A (en) * | 2016-08-15 | 2018-07-20 | 中国科学院宁波材料技术与工程研究所 | Fiber reinforcement anticorrosive paint and its preparation method and application |
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| CN109439120B (en) * | 2018-11-22 | 2020-10-09 | 福州大学 | Preparation method of graphene/organic fluorine modified acrylate water-based anticorrosive paint |
| CN110820319A (en) * | 2019-10-09 | 2020-02-21 | 凡港(厦门)科技有限公司 | Nano-graphene-based refined wax tape and preparation method thereof |
| CN111978797A (en) * | 2020-08-27 | 2020-11-24 | 深圳市嘉固工业地坪有限公司 | Water-based composite nano toner and preparation method thereof |
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