CN105130192B - The electrostatic of enamel vitreous enamel frit wraps up liquid, electrostatic enamel powder and preparation method thereof - Google Patents
The electrostatic of enamel vitreous enamel frit wraps up liquid, electrostatic enamel powder and preparation method thereof Download PDFInfo
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- CN105130192B CN105130192B CN201510549891.0A CN201510549891A CN105130192B CN 105130192 B CN105130192 B CN 105130192B CN 201510549891 A CN201510549891 A CN 201510549891A CN 105130192 B CN105130192 B CN 105130192B
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Abstract
The invention discloses a kind of electrostatic of enamel vitreous enamel frit parcel liquid, electrostatic enamel powder and preparation method thereof, it is related to enamel technical field.Electrostatic wraps up liquid, by weight by following material composition：0.002 0.01 parts of titanate coupling agent, 0.002 0.01 parts of Carboxyl Modified Polydimethylsiloxane, 0.002 0.01 parts of silane coupler, 10 20 parts of industrial alcohol.Electrostatic enamel powder, including enamel vitreous enamel frit and electrostatic parcel liquid, electrostatic parcel liquid account for the 10 20% of enamel vitreous enamel frit gross weight, and enamel vitreous enamel frit adds water to mix, made of levigate, drying after smashing with electrostatic parcel liquid.Electrostatic parcel liquid of the present invention can be wrapped up arbitrary enamel vitreous enamel frit powder.Electrostatic enamel powder easily stores, and strong adsorption force, price is low, height noninflammability, non-volatility, moistureproof, and anti-soda acid, case hardness is high, and toughness is good, and impact resistance is strong, durable in use；Electrostatic enamel powder, preparation method thereof is simple, saves production cost.
Description
Technical field
The present invention relates to enamel technical field.
Background technology
The making of U.S.'s dry method electrostatic enamel powder needs enamel vitreous enamel frit being ground to 300 mesh or so drying, water content
It is required that no more than 0.03% or so, operation is very troublesome cumbersome.Enamel vitreous enamel frit powder after other ground drying must be anti-
Answer in kettle and carry out moment reaction with parcel liquid, this reactor equipment costly, China there is presently no.Its dry method
Electrostatic enamel powder price must store at 26000 yuan per ton or so in constant temperature.The market demand of electrostatic enamel powder is very at present
Greatly, most of enterprise adds life using the dry method electrostatic enamel powder of Ferro companies of the U.S. and Japanese Duo Ma morals company to enterprise
Produce cost.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of enamel vitreous enamel frit electrostatic parcel liquid, electrostatic enamel powder and
Its preparation method, electrostatic parcel liquid can carry out being wrapped to form film to arbitrary enamel vitreous enamel frit powder；The electrostatic enamel
Powder storage is not subject to conditions, easily storage, and strong adsorption force, price is low, height noninflammability, non-volatility, sprays on workpiece and burns
The workpiece glaze paint light gone out is smooth, is tapped with iron hammer and does not leak substrate, and high temperature resistant property is good, moistureproof, and anti-soda acid, case hardness is high,
Toughness is good, and impact resistance is strong, durable in use；The preparation method technique of the electrostatic enamel powder is simple, and easy to operate, device therefor is simple
It is cheap, save production cost.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of electrostatic bag of enamel vitreous enamel frit
Liquid is wrapped up in, is counted in parts by weight, by following material composition：Titanate coupling agent 0.002-0.01 parts, Carboxyl Modified Polydimethylsiloxane 0.002-
0.01 part, silane coupler 0.002-0.01 parts, industrial alcohol 10-20 parts；It is agitated uniformly manufactured.
And a kind of electrostatic enamel powder, including enamel vitreous enamel frit, in addition to electrostatic parcel liquid, electrostatic parcel liquid, which accounts for, to be warded off
The 10-20% of enamel porcelain frit gross weight, enamel vitreous enamel frit adds water to mix after smashing with electrostatic parcel liquid, levigate, drying is made
Into.
Enamel vitreous enamel frit be as following material through being mixed, heat fusing, water quenching, leach moisture made from；In parts by weight
Meter：39.8 parts of silica, 17.5 parts of borax, 13 parts of sodium carbonate, 5 parts of potassium carbonate, 3 parts of calcirm-fluoride, 9 parts of barium carbonate, zinc oxide 2
Part, 2 parts of precipitated calcium carbonate, 3 parts of lithium carbonate, 1.3 parts of cobalt oxide, 0.8 part of nickel oxide, 1.8 parts of di-iron trioxide, manganese dioxide
1.5 parts, 0.3 part of chrome green.Enamel vitreous enamel frit can also warding off using other manufacturer productions that in the market can be bought
Enamel porcelain frit, for example, the enamel vitreous enamel of the production such as Handan Hua Yuan metallic enamels Co., Ltd, Japanese Duo Ma morals company melts
Block.
Preferably, heat fusing temperature is 1200 DEG C -1300 DEG C.
And the preparation method of electrostatic enamel powder, comprise the following steps：
Enamel vitreous enamel frit powder is broken to more than 50 mesh；
Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into agitating ball mill
In, released after levigate, drying；Pure water accounts for the 35-50% of enamel vitreous enamel frit gross weight.
Preferably, electrostatic parcel liquid is added in pure water, stirs evenly rear be put into the enamel vitreous enamel frit crushed and stir
Mix in ball mill, released after being milled to 300-350 mesh, then dried at 150 DEG C -250 DEG C.
The resistivity of this electrostatic enamel powder is 10-13Ohm, fully meets the requirement of electrostatic painting process.
The application method of electrostatic enamel powder is：The electrostatic enamel powder made equably is sprayed onto workpiece with electrostatic gun
On, burnt till subsequently into streamline, 800 DEG C or so of furnace temperature, one to three minute, the workpiece glaze paint light burnt is smooth, thick
Degree is tapped with iron hammer at 60-200 μm and does not leak substrate, meet national standard.
The purposes of electrostatic enamel powder is：Suitable for carrying out electrostatic enamel spraying to metallic matrix, it is built-in to be mainly used in subway
The uses such as decorations, city tunnel passage decoration, enamel-plate curtain wall, building decoration are very wide, and outdoor fitness equipment, lamp stand, lamppost,
Indoor cooker, tableware, household electrical appliance, water heater liner etc..
It is using beneficial effect caused by above-mentioned technical proposal：
（1）Electrostatic parcel liquid of the present invention can carry out being wrapped to form film to arbitrary enamel vitreous enamel frit powder, to enamel
The water content of vitreous enamel frit is not strict with（Enamel vitreous enamel frit leaches moisture after water quenching, without drying）, operation
Simply.
（2）Electrostatic enamel powder storage of the present invention is not subject to conditions, and easily storage, strong adsorption force, price is low, and per ton 16000
Member, it is smooth to spray to the workpiece glaze paint light burnt on workpiece, is tapped with iron hammer and does not leak substrate, acid and alkali-resistance, wear-resisting, high temperature resistance
Can be good；The heavy metals such as this electrostatic enamel powder is not leaded, cadmium, it is safe and nontoxic.The enamel layer thickness prepared with this electrostatic enamel powder exists
60-200 μm, it can select as needed；Electrostatic ceramic powder is simple using technique, and saving of labor is laborsaving, saves substantial amounts of manpower thing
Power.
（3）Electrostatic enamel powder of the present invention has height noninflammability, and non-volatility is moistureproof, and anti-soda acid, case hardness is high, hard
Good toughness, impact resistance is strong, durable in use, good decorating effect, no color differnece rich in color, the long-term non-fading feature of fidelity.
（4）The preparation method technique of electrostatic enamel powder of the present invention is simple, and easy to operate, device therefor is simply cheap, will
Electrostatic parcel liquid is added in pure water, is put into after stirring evenly with enamel vitreous enamel frit in agitating ball mill, and drying is released after levigate
, pure water is creatively added in preparation method, the water content of enamel vitreous enamel frit is not strict with, and is saved
Production cost.
（5）The resistivity of this electrostatic enamel powder is 10-13Ohm, fully meets the requirement of electrostatic painting process, uses technique
Simply, saving of labor, it is laborsaving, save substantial amounts of manpower and materials.
Embodiment
Embodiment 1
A kind of electrostatic parcel liquid of enamel vitreous enamel frit, is counted, by following material composition in parts by weight：Titanate coupling agent
0.002 part, 0.003 part of Carboxyl Modified Polydimethylsiloxane, 0.004 part of silane coupler, 15 parts of industrial alcohol；It is agitated uniformly manufactured.
A kind of electrostatic enamel powder, including enamel vitreous enamel frit, in addition to above-mentioned electrostatic parcel liquid, electrostatic parcel liquid account for enamel
The 10% of vitreous enamel frit gross weight.
Enamel vitreous enamel frit be by following material through being mixed, 1200 DEG C of -1300 DEG C of heat fusings, water quenching, leach moisture be made
's；Count in parts by weight：39.8 parts of silica, 17.5 parts of borax, 13 parts of sodium carbonate, 5 parts of potassium carbonate, 3 parts of calcirm-fluoride, carbonic acid
9 parts of barium, 2 parts of zinc oxide, 2 parts of precipitated calcium carbonate, 3 parts of lithium carbonate, 1.3 parts of cobalt oxide, 0.8 part of nickel oxide, di-iron trioxide 1.8
Part, 1.5 parts of manganese dioxide, 0.3 part of chrome green.
The preparation method of above-mentioned electrostatic enamel powder is to comprise the following steps：
（1）Enamel vitreous enamel frit powder is broken to more than 50 mesh；
（2）Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into stirring ball
In grinding machine, release, then dried at 230 DEG C -250 DEG C, it is total that pure water accounts for enamel vitreous enamel frit after being milled to 300-350 mesh
The 50% of weight.
The electrostatic enamel powder made equably is sprayed onto on workpiece with electrostatic gun, burnt till subsequently into streamline, stove
800 DEG C or so of temperature, one to three minute, the workpiece glaze paint burnt was black, and bright smooth, thickness uses iron at 60-200 μm
Hammer, which taps, does not leak substrate, and acid and alkali-resistance, wear-resisting, shock resistance, high temperature resistant property are good.With 500 grams of iron balls in 1 meter of height freely falling body
Onto the workpiece glaze paint burnt, substrate is not leaked.
Embodiment 2
A kind of electrostatic parcel liquid of enamel vitreous enamel frit, is counted, by following material composition in parts by weight：Titanate coupling agent
0.008 part, 0.005 part of Carboxyl Modified Polydimethylsiloxane, 0.008 part of silane coupler, 20 parts of industrial alcohol；It is agitated uniformly manufactured.
A kind of electrostatic enamel powder, including enamel vitreous enamel frit, in addition to above-mentioned electrostatic parcel liquid, electrostatic parcel liquid account for enamel
The 12% of vitreous enamel frit gross weight.
Enamel vitreous enamel frit uses the porcelain of the model 826,839 and 1631 of Handan Hua Yuan metallic enamels Co., Ltd
Frit, three kinds of models are respectively with 1/3rd mixing.
The preparation method of above-mentioned electrostatic enamel powder, comprises the following steps：
（1）Enamel vitreous enamel frit powder is broken to more than 50 mesh；
（2）Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into stirring ball
In grinding machine, release, then dried at 150 DEG C -170 DEG C, it is total that pure water accounts for enamel vitreous enamel frit after being milled to 300-350 mesh
The 35% of weight.
The electrostatic enamel powder made equably is sprayed onto on workpiece with electrostatic gun, burnt till subsequently into streamline, stove
800 DEG C or so of temperature, one to three minute, the workpiece glaze paint burnt, bright smooth, thickness was tapped at 60-200 μm with iron hammer
Substrate is not leaked, acid and alkali-resistance, wear-resisting, shock resistance, high temperature resistant property are good.With 500 grams of iron balls in 1 meter of height freely falling body to burning
Workpiece glaze paint on, do not leak substrate.Glaze face color is according to user's request, it is desirable to which what color just adds what color in ball milling
Element, the color such as ash, indigo plant, Huang Hong can.
Embodiment 3
A kind of electrostatic parcel liquid of enamel vitreous enamel frit, is counted, by following material composition in parts by weight：Titanate coupling agent
0.004 part, 0.002 part of Carboxyl Modified Polydimethylsiloxane, 0.01 part of silane coupler, 18 parts of industrial alcohol；It is agitated uniformly manufactured.
A kind of electrostatic enamel powder, including enamel vitreous enamel frit, in addition to above-mentioned electrostatic parcel liquid, electrostatic parcel liquid account for enamel
The 15% of vitreous enamel frit gross weight.
Enamel vitreous enamel frit be by following material through being mixed, 1200 DEG C of -1300 DEG C of heat fusings, water quenching, leach moisture be made
's；Count in parts by weight：39.8 parts of silica, 17.5 parts of borax, 13 parts of sodium carbonate, 5 parts of potassium carbonate, 3 parts of calcirm-fluoride, carbonic acid
9 parts of barium, 2 parts of zinc oxide, 2 parts of precipitated calcium carbonate, 3 parts of lithium carbonate, 1.3 parts of cobalt oxide, 0.8 part of nickel oxide, di-iron trioxide 1.8
Part, 1.5 parts of manganese dioxide, 0.3 part of chrome green.
The preparation method of above-mentioned electrostatic enamel powder, comprises the following steps：
（1）Enamel vitreous enamel frit powder is broken to more than 50 mesh；
（2）Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into stirring ball
In grinding machine, release, then dried at 190 DEG C -210 DEG C, it is total that pure water accounts for enamel vitreous enamel frit after being milled to 300-350 mesh
The 40% of weight.
The electrostatic enamel powder made equably is sprayed onto on workpiece with electrostatic gun, burnt till subsequently into streamline, stove
800 DEG C or so of temperature, one to three minute, the workpiece glaze paint burnt was black, and bright smooth, thickness uses iron at 60-200 μm
Hammer, which taps, does not leak substrate, and acid and alkali-resistance, wear-resisting, shock resistance, high temperature resistant property are good.With 500 grams of iron balls in 1 meter of height freely falling body
Onto the workpiece glaze paint burnt, substrate is not leaked.
Embodiment 4
A kind of electrostatic parcel liquid of enamel vitreous enamel frit, is counted, by following material composition in parts by weight：Titanate coupling agent
0.01 part, 0.008 part of Carboxyl Modified Polydimethylsiloxane, 0.006 part of silane coupler, 12 parts of industrial alcohol；It is agitated uniformly manufactured.
A kind of electrostatic enamel powder, including enamel vitreous enamel frit, in addition to above-mentioned electrostatic parcel liquid, electrostatic parcel liquid account for enamel
The 18% of vitreous enamel frit gross weight.
Enamel vitreous enamel frit be by following material through being mixed, 1200 DEG C of -1300 DEG C of heat fusings, water quenching, leach moisture be made
's；Count in parts by weight：39.8 parts of silica, 17.5 parts of borax, 13 parts of sodium carbonate, 5 parts of potassium carbonate, 3 parts of calcirm-fluoride, carbonic acid
9 parts of barium, 2 parts of zinc oxide, 2 parts of precipitated calcium carbonate, 3 parts of lithium carbonate, 1.3 parts of cobalt oxide, 0.8 part of nickel oxide, di-iron trioxide 1.8
Part, 1.5 parts of manganese dioxide, 0.3 part of chrome green.
The preparation method of above-mentioned electrostatic enamel powder, comprises the following steps：
（1）Enamel vitreous enamel frit powder is broken to more than 50 mesh；
（2）Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into stirring ball
In grinding machine, release, then dried at 210 DEG C -230 DEG C, it is total that pure water accounts for enamel vitreous enamel frit after being milled to 300-350 mesh
The 45% of weight.
The electrostatic enamel powder made equably is sprayed onto on workpiece with electrostatic gun, burnt till subsequently into streamline, stove
800 DEG C or so of temperature, one to three minute, the workpiece glaze paint burnt was black, and bright smooth, thickness uses iron at 60-200 μm
Hammer, which taps, does not leak substrate, and acid and alkali-resistance, wear-resisting, shock resistance, high temperature resistant property are good.With 500 grams of iron balls in 1 meter of height freely falling body
Onto the workpiece glaze paint burnt, substrate is not leaked.
Embodiment 5
A kind of electrostatic parcel liquid of enamel vitreous enamel frit, is counted, by following material composition in parts by weight：Titanate coupling agent
0.006 part, 0.01 part of Carboxyl Modified Polydimethylsiloxane, 0.002 part of silane coupler, 10 parts of industrial alcohol；It is agitated uniformly manufactured.
A kind of electrostatic enamel powder, including enamel vitreous enamel frit, in addition to above-mentioned electrostatic parcel liquid, electrostatic parcel liquid account for enamel
The 20% of vitreous enamel frit gross weight.
Enamel vitreous enamel frit use Japanese Duo Ma morals company model TMG031, TMG070 and TMG112 porcelain frit, three
Kind model is respectively with 1/3rd mixing.
The preparation method of above-mentioned electrostatic enamel powder, comprises the following steps：
（1）Enamel vitreous enamel frit powder is broken to more than 50 mesh；
（2）Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into stirring ball
In grinding machine, release, then dried at 170 DEG C -190 DEG C, it is total that pure water accounts for enamel vitreous enamel frit after being milled to 300-350 mesh
The 48% of weight.
The electrostatic enamel powder made equably is sprayed onto on workpiece with electrostatic gun, burnt till subsequently into streamline, stove
800 DEG C or so of temperature, one to three minute, the workpiece glaze paint burnt, bright smooth, thickness was tapped at 60-200 μm with iron hammer
Substrate is not leaked, acid and alkali-resistance, wear-resisting, shock resistance, high temperature resistant property are good.With 500 grams of iron balls in 1 meter of height freely falling body to burning
Workpiece glaze paint on, do not leak substrate.Glaze face color is according to user's request, it is desirable to which what color just adds what color in ball milling
Element, the color such as ash, indigo plant, Huang Hong can.
Electrostatic enamel powder of the present invention contrasts with U.S.'s dry method electrostatic enamel powder, see the table below：
| Preparation method | Device therefor | Price | Production Product Matter Amount | |
| This hair It is bright quiet Electricity is warded off Porcelain powder | Simply, it is easy to operate：Electrostatic parcel liquid is added to pure water In, stir evenly enamel vitreous enamel that is rear and being crushed to more than 50 mesh Frit is put into agitating ball mill, and drying is released after levigate | Stirring ball-milling, drying plant are used, Device therefor is simple, cheap | It is per ton 1600 0 yuan Left and right | It is excellent It is good |
| The U.S. Dry method Electrostatic Enamel Powder | It is cumbersome, it is not easy to operate：Need to grind enamel vitreous enamel frit To 300 mesh or so drying, water content requirement is no more than 0.03% or so | Use moment reactor, drying plant Deng wherein moment reactor is relatively high Expensive, in China, there is presently no this to set It is standby | It is per ton 2600 0 yuan Left and right | It is excellent It is good |
Electrostatic parcel liquid of the present invention can carry out being wrapped to form film to arbitrary enamel vitreous enamel frit powder, to enamel vitreous enamel
The water content of frit is not strict with（Enamel vitreous enamel frit leaches moisture after water quenching, without drying）, it is simple to operate.
Electrostatic enamel powder storage of the present invention is not subject to conditions, and easily storage, strong adsorption force, price is low, 16000 yuan per ton,
It is smooth to spray to the workpiece glaze paint light burnt on workpiece, is tapped with iron hammer and does not leak substrate, acid and alkali-resistance, wear-resisting, high temperature resistant property
It is good；The heavy metals such as this electrostatic enamel powder is not leaded, cadmium, it is safe and nontoxic.The enamel layer thickness prepared with this electrostatic enamel powder exists
60-200 μm, it can select as needed；Electrostatic ceramic powder is simple using technique, and saving of labor is laborsaving, saves substantial amounts of manpower thing
Power.
Electrostatic enamel powder of the present invention has height noninflammability, and non-volatility is moistureproof, and anti-soda acid, case hardness is high, toughness
Good, impact resistance is strong, durable in use, good decorating effect, no color differnece rich in color, the long-term non-fading feature of fidelity.
The preparation method technique of electrostatic enamel powder of the present invention is simple, and easy to operate, device therefor is simply cheap, by electrostatic
Parcel liquid is added in pure water, is put into after stirring evenly with enamel vitreous enamel frit in agitating ball mill, and drying is released after levigate,
Pure water is creatively added in preparation method, the water content of enamel vitreous enamel frit is not strict with, has saved production
Cost.
The resistivity of this electrostatic enamel powder is 10-13Ohm, fully meets the requirement of electrostatic painting process, uses technique letter
Single, saving of labor is laborsaving, saves substantial amounts of manpower and materials.
Claims (6)
- A kind of 1. electrostatic parcel liquid of enamel vitreous enamel frit, it is characterised in that：Electrostatic parcel liquid is counted in parts by weight, by with Lower material composition：Titanate coupling agent 0.002-0.01 parts, Carboxyl Modified Polydimethylsiloxane 0.002-0.01 parts, silane coupler 0.002- 0.01 part, industrial alcohol 10-20 parts；It is agitated uniformly manufactured.
- 2. a kind of electrostatic enamel powder, including enamel vitreous enamel frit, it is characterised in that：Also include electrostatic as claimed in claim 1 Liquid is wrapped up, electrostatic parcel liquid accounts for the 10-20% of enamel vitreous enamel frit gross weight, and enamel vitreous enamel frit wraps up after smashing with electrostatic Liquid adds water mix, be levigate, made of drying.
- 3. electrostatic enamel powder according to claim 2, it is characterised in that enamel vitreous enamel frit is through mixed by following material , heat fusing, water quenching, leach moisture made from；Count in parts by weight：39.8 parts of silica, 17.5 parts of borax, sodium carbonate 13 Part, 5 parts of potassium carbonate, 3 parts of calcirm-fluoride, 9 parts of barium carbonate, 2 parts of zinc oxide, 2 parts of precipitated calcium carbonate, 3 parts of lithium carbonate, cobalt oxide 1.3 Part, 0.8 part of nickel oxide, 1.8 parts of di-iron trioxide, 1.5 parts of manganese dioxide, 0.3 part of chrome green.
- 4. electrostatic enamel powder according to claim 3, it is characterised in that heat fusing temperature is 1200 DEG C -1300 DEG C.
- 5. the preparation method of the electrostatic enamel powder as described in claim any one of 2-4, it is characterised in that comprise the following steps：Enamel vitreous enamel frit powder is broken to more than 50 mesh；Electrostatic parcel liquid is added in pure water, enamel vitreous enamel frit that is rear and crushing is stirred evenly and is put into agitating ball mill, Released after levigate, drying；Pure water accounts for the 35-50% of enamel vitreous enamel frit gross weight.
- 6. the preparation method of electrostatic enamel powder according to claim 5, it is characterised in that be added to electrostatic parcel liquid pure In water purification, stir evenly enamel vitreous enamel frit that is rear and crushing and be put into agitating ball mill, released after being milled to 300-350 mesh, then Dried at 150 DEG C -250 DEG C.
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| CN201510549891.0A CN105130192B (en) | 2015-09-01 | 2015-09-01 | The electrostatic of enamel vitreous enamel frit wraps up liquid, electrostatic enamel powder and preparation method thereof |
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Families Citing this family (4)
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| CN108203244B (en) * | 2016-12-17 | 2022-02-08 | 江西科盛环保股份有限公司 | Preparation method of double-sided enamel anti-scaling static dry powder for common cold-rolled and hot-rolled plates |
| CN106746660A (en) * | 2016-12-30 | 2017-05-31 | 郁宏电力设备工程有限公司 | A kind of susceptible electrostatic enamel material and preparation method thereof and its technique for being used for electrostatic dry powder enamel spraying heat transfer element |
| CN106746662B (en) * | 2017-02-05 | 2019-05-14 | 湖南信诺颜料科技有限公司 | Antiknock enamel electrostatic powder and preparation |
| CN113024116B (en) * | 2021-05-25 | 2021-09-03 | 佛山市三水区康立泰无机合成材料有限公司 | Matte glaze powder suitable for electrostatic spraying and preparation method thereof |
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| CN104817271A (en) * | 2015-02-11 | 2015-08-05 | 襄阳高铭矿业有限公司 | Preparation method of enamel electrostatic glaze powder and enamel electrostatic glaze powder prepared by method |
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2015
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|---|---|---|---|---|
| US5145804A (en) * | 1985-04-04 | 1992-09-08 | Bayer Aktiengesellschaft | Enamel powder for electrostatic application |
| CN1772675A (en) * | 2005-09-20 | 2006-05-17 | 谢安建 | Low temperature electrostatic enamel powder for steel plate coating and its prepn |
| CN101602572A (en) * | 2009-07-03 | 2009-12-16 | 佛山市唯艺金属制品有限公司 | A kind of aluminium enamel powdered frit and utilize this powdered frit to carry out the method for aluminium enamel spraying |
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| CN105130192A (en) | 2015-12-09 |
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