CN105124809A - Protective gloves for paraxylene - Google Patents

Protective gloves for paraxylene Download PDF

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Publication number
CN105124809A
CN105124809A CN201510686913.8A CN201510686913A CN105124809A CN 105124809 A CN105124809 A CN 105124809A CN 201510686913 A CN201510686913 A CN 201510686913A CN 105124809 A CN105124809 A CN 105124809A
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China
Prior art keywords
paraxylene
layer
molecular sieve
micro
nano
Prior art date
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Pending
Application number
CN201510686913.8A
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Chinese (zh)
Inventor
王亚宁
宋文东
应知伟
宋付权
纪丽丽
李世杰
胡世伟
姜维
蔡璐
郭健
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Zhejiang Ocean University ZJOU
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Zhejiang Ocean University ZJOU
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Priority to CN201510686913.8A priority Critical patent/CN105124809A/en
Publication of CN105124809A publication Critical patent/CN105124809A/en
Pending legal-status Critical Current

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Abstract

The invention discloses protective gloves for paraxylene. Each protective glove comprises a glove body, wherein the glove body comprises a glove body layer, an adsorption layer, a filtering layer, and a glove body layer on the other side in sequence from inside to outside, an adsorption agent is placed in the adsorption layer, the filtering layer is provided with a mixed fiber millipore filter membrane, the adsorption agent contains one or a mixture of activated carbon, zeolite, a molecular sieve and micro-nano shell powder, the mixed fiber millipore filter membrane in the filtering layer, and the adsorption agent in the adsorption layer can successively efficiently adsorb paraxylene, so that paraxylene is prevented from indirectly contacting the human skin effectively, the harm of paraxylene to the skin and the residue of paraxylene are prevented, and the protecting effect for paraxylene can be improved; the filtering layer firstly filters part of the harmful substances, so that the amount of the adsorption agent consumed by the to-be-adsorbed paraxylene is reduced, and further, the effective service life of the adsorption layer is prolonged. Therefore, the protective gloves have the advantages that the gloves can be applied to hand protection against paraxylene, and are convenient to use and long in effective protection life.

Description

A kind of protective gloves of paraxylene
Technical field
The present invention relates to a kind of special type protection articles for use, particularly relate to a kind of protective gloves of paraxylene.
Background technology
Gloves commercially available at present are mainly used for blocking the use of dust, protection hand, and when running into special occasion after, commercially available conventional glove does not have the effect of protection, can affect rescue on the contrary to a certain extent, reduction operating efficiency.Prior art is as the application for a patent for invention " a kind of medical gloves " of publication No. CN104287845A, a kind of medical gloves of this disclosure of the invention, comprise glove bodies, glove bodies includes cotton layer, watertight composition, adsorption layer, surface light slip layer from the inside to the outside, the surrounding of adsorption layer has all been coated with Parylene coating, the center of surface light slip layer is provided with scraggly massage point, and the edge of glove bodies is connected by zipper extension, and the material of extension adopts perspex.Structure is simple, after glove bodies arranges Parylene coating, effectively can improve the performance of gloves, use more convenient, long product lifecycle, and the injury again to patient can be reduced, Parylene is the polymer of paraxylene, can as the novel conformal coat material of one, Practical Performance is excellent, and Scalable Performance is excellent, novel in design, be a kind of well innovation scheme, have very much marketing prospect.But it does not have protective characteristic for paraxylene.Along with development and human living standard's fast development of science and technology, the requirement of shelter of people to health is more and more higher, the society of the emergency situations that takes place frequently in chemical plant, lacks and has just to the protective gloves of the paraxylene of property protective action.Thus need us constantly to research and develop thus promote the function of protective gloves targetedly.
Summary of the invention
The object of the invention is to provide a kind of for prior art and can be applied to paraxylene hand protection, easy to use, effective protective gloves protecting a kind of paraxylene of life-span length.
The present invention solves the problems of the technologies described above adopted technical scheme: a kind of protective gloves of paraxylene, comprises glove bulk, wherein: glove bulk comprises the glove bulk layer of glove bulk layer, adsorption layer, filter course and another side from inside to outside successively; Adsorption layer is placed with adsorbent; Filter course has composite fibre miillpore filter; Adsorbent contains one or more mixtures composition in active carbon, zeolite, molecular sieve, micro-nano oyster shell whiting.The composite fibre miillpore filter of filter course, the adsorbent of adsorbent layer in succession all can efficient adsorption paraxylene, effectively can stop that paraxylene mediate contact is to human body skin, prevent paraxylene to the injury of skin with residual, improve the protection effect of paraxylene.The leading filtration fraction nuisance of filter course, and then reduce the paraxylene upon adsorption consumption to adsorbent, the Acceptable life of adsorption layer can be extended.
For optimizing technique scheme, the measure taked also comprises: the preparation method of micro-nano oyster shell whiting is as follows: the organic matter of shell surface is removed by the hydrochloric acid solution with 0.5%, clear water is washed till neutrality, place it in the drying in oven of 105 DEG C, 200 object oyster shell whitings are crushed to pulverizer, calcine expanded, cooling, micro-nano pulverization process, obtain the micro-nano oyster shell whiting in ocean; Calcining expanded temperature is 1100 DEG C, and the time is 6h; Micro-nano pulverization process be by calcining expanding treatment after oyster shell whiting ultra micro nano grinder process, until reach 100nm.Micro-nano oyster shell whiting can obtain beyond thought paraxylene adsorption removal effect after above-mentioned process.It is one or more mixtures in scallop, mussel, conch, oyster, abalone or pearl shell that described oyster shell whiting can come from the micro-nano oyster shell whiting in ocean; The thickness of described adsorbent layer is 0.3-0.6mm.Blocked up adsorbent layer can cause handicapped, reduces flexibility.Molecular sieve is the molecular sieve that barium exchanges; The preparation method of the molecular sieve that this barium exchanges is as follows: 1) with Klorvess Liquid and 13X molecular sieve, continuous stirring exchanges 2h, repeat 2-4 time to exchange, after each exchange terminates, spend deionized water for several times in cleaning solution without potassium ion, product is placed in the dry 12h of baking oven of 50 DEG C, obtains high potassium KX sieve sample; 2) KX sieve sample and barium chloride solution are exchanged under preference temperature, continuous stirring exchanges 1h, repeat 2-4 time to exchange, after each exchange terminates, spend deionized water for several times in cleaning solution without barium ions, dry the molecular sieve after washing, activated molecular sieve at a certain temperature, obtain the molecular sieve that barium exchanges.The molecular sieve organic pollution exchanged through barium and some inorganic matter comprise some poisonous heavy metal, can be greatly diminished, to reduce heavy metal and other organic-inorganic pollutants to the impact of human body skin.Adsorbent is by weight containing one or more mixtures composition in 1-5 part active carbon, 1-3.3 part zeolite, 0.1-0.5 part molecular sieve, the micro-nano oyster shell whiting of 5-10 part.Specific proportioning can make assimilation effect and life-span reach beyond thought double grading.The present embodiment preferred 4g active carbon, 3.3g zeolite powder, 0.2g molecular sieve, the micro-nano oyster shell whiting of 8.7g.The composite fibre miillpore filter of filter course, the adsorbent of adsorbent layer in succession all can efficient adsorption paraxylene, effectively can stop that paraxylene mediate contact is to human body skin, prevent paraxylene to the injury of skin with residual, improve the protection effect of paraxylene.What the cotton layer of the electro static filtering of KP95 standard or nonwoven layer all can be used as composite fibre miillpore filter treats material selection.
The glove bulk layer of glove bulk layer, adsorption layer, filter course and another side is comprised from inside to outside successively owing to present invention employs glove bulk; Adsorption layer is placed with adsorbent; Filter course has composite fibre miillpore filter; Adsorbent contains one or more mixtures composition in active carbon, zeolite, molecular sieve, micro-nano oyster shell whiting.The composite fibre miillpore filter of filter course, the adsorbent of adsorbent layer in succession all can efficient adsorption paraxylene, effectively can stop that paraxylene mediate contact is to human body skin, prevent paraxylene to the injury of skin with residual, improve the protection effect of paraxylene.The leading filtration fraction nuisance of filter course, and then reduce the paraxylene upon adsorption consumption to adsorbent, the Acceptable life of adsorption layer can be extended.Thus the present invention has the advantage that can be applied to paraxylene hand protection, easy to use, effective protection life-span length.
Accompanying drawing explanation
Fig. 1 is embodiment of the present invention overall structure schematic diagram;
Fig. 2 is embodiment of the present invention lamellar structure schematic diagram.
Detailed description of the invention
Below in conjunction with attached embodiment, the present invention is described in further detail.
Drawing reference numeral illustrates: glove bulk layer 1, filter course 2, adsorption layer 3.
Embodiment: referring to figs. 1 through Fig. 2, a kind of protective gloves of paraxylene, comprises glove bulk, wherein: glove bulk comprises the glove bulk layer 1 of glove bulk layer 1, adsorption layer 3, filter course 2 and another side from inside to outside successively; Adsorption layer 3 is placed with adsorbent; Filter course 2 has composite fibre miillpore filter; Adsorbent contains one or more mixtures composition in active carbon, zeolite, molecular sieve, micro-nano oyster shell whiting.The composite fibre miillpore filter of filter course 2, the adsorbent of adsorbent layer 3 in succession all can efficient adsorption paraxylene, effectively can stop that paraxylene mediate contact is to human body skin, prevent paraxylene to the injury of skin with residual, the protection effect of raising paraxylene.The leading filtration fraction nuisance of filter course 2, and then reduce the paraxylene upon adsorption consumption to adsorbent, the Acceptable life of adsorption layer 2 can be extended.The preparation method of micro-nano oyster shell whiting is as follows: the organic matter of shell surface is removed by the hydrochloric acid solution with 0.5%, clear water is washed till neutrality, place it in the drying in oven of 105 DEG C, 200 object oyster shell whitings are crushed to pulverizer, calcine expanded, cooling, micro-nano pulverization process, obtain the micro-nano oyster shell whiting in ocean; Calcining expanded temperature is 1100 DEG C, and the time is 6h; Micro-nano pulverization process be by calcining expanding treatment after oyster shell whiting ultra micro nano grinder process, until reach 100nm.Micro-nano oyster shell whiting can obtain beyond thought paraxylene adsorption removal effect after above-mentioned process.It is one or more mixtures in scallop, mussel, conch, oyster, abalone or pearl shell that described oyster shell whiting can come from the micro-nano oyster shell whiting in ocean; The thickness of described adsorbent layer 3 is 0.3-0.6mm.Blocked up adsorbent layer 3 can cause handicapped, reduces flexibility.Molecular sieve is the molecular sieve that barium exchanges; The preparation method of the molecular sieve that this barium exchanges is as follows: 1) with Klorvess Liquid and 13X molecular sieve, continuous stirring exchanges 2h, repeat 2-4 time to exchange, after each exchange terminates, spend deionized water for several times in cleaning solution without potassium ion, product is placed in the dry 12h of baking oven of 50 DEG C, obtains high potassium KX sieve sample; 2) KX sieve sample and barium chloride solution are exchanged under preference temperature, continuous stirring exchanges 1h, repeat 2-4 time to exchange, after each exchange terminates, spend deionized water for several times in cleaning solution without barium ions, dry the molecular sieve after washing, activated molecular sieve at a certain temperature, obtain the molecular sieve that barium exchanges.The molecular sieve organic pollution exchanged through barium and some inorganic matter comprise some poisonous heavy metal, can be greatly diminished, to reduce heavy metal and other organic-inorganic pollutants to the impact of human body skin.Adsorbent is by weight containing one or more mixtures composition in 1-5 part active carbon, 1-3.3 part zeolite, 0.1-0.5 part molecular sieve, the micro-nano oyster shell whiting of 5-10 part.Specific proportioning can make assimilation effect and life-span reach beyond thought double grading.The present embodiment preferred 4g active carbon, 3.3g zeolite powder, 0.2g molecular sieve, the micro-nano oyster shell whiting of 8.7g.The composite fibre miillpore filter of filter course 2, the adsorbent of adsorbent layer in succession all can efficient adsorption paraxylene, effectively can stop that paraxylene mediate contact is to human body skin, prevent paraxylene to the injury of skin with residual, the protection effect of raising paraxylene.What the cotton layer of the electro static filtering of KP95 standard or nonwoven layer all can be used as composite fibre miillpore filter treats material selection.
Although describe the present invention in conjunction with preferred embodiment; so itself and be not used to limit the present invention; any those skilled in the art; without departing from the spirit and scope of the present invention; can implement various change, the displacement of coordinate and amendment here to the theme listed, therefore protection scope of the present invention be as the criterion when the scope limited depending on proposed claim.

Claims (5)

1. a protective gloves for paraxylene, comprises glove bulk, it is characterized in that: described glove bulk comprises the glove bulk layer (1) of glove bulk layer (1), adsorption layer (3), filter course (2) and another side from inside to outside successively; Described adsorption layer (3) is placed with adsorbent; Described filter course (2) has composite fibre miillpore filter; Described adsorbent contains one or more mixtures composition in active carbon, zeolite, molecular sieve, micro-nano oyster shell whiting.
2. the protective gloves of a kind of paraxylene according to claim 1, it is characterized in that: the preparation method of described micro-nano oyster shell whiting is as follows: the organic matter of shell surface is removed by the hydrochloric acid solution with 0.5%, clear water is washed till neutrality, place it in the drying in oven of 105 DEG C, 200 object oyster shell whitings are crushed to pulverizer, calcine expanded, cooling, micro-nano pulverization process, obtain the micro-nano oyster shell whiting in ocean; The expanded temperature of described calcining is 1100 DEG C, and the time is 6h; Described micro-nano pulverization process be by calcining expanding treatment after oyster shell whiting ultra micro nano grinder process, until reach 100nm.
3. the protective gloves of a kind of paraxylene according to claim 1, is characterized in that: described adsorbent is by weight containing one or more mixtures composition in 1-5 part active carbon, 1-3.3 part zeolite, 0.1-0.5 part molecular sieve, the micro-nano oyster shell whiting of 5-10 part.
4. the protective gloves of a kind of paraxylene according to claim 2, is characterized in that: it is one or more mixtures in scallop, mussel, conch, oyster, abalone or pearl shell that described described oyster shell whiting can come from the micro-nano oyster shell whiting in described ocean; The thickness of described adsorbent layer (3) is 0.3-0.6mm.
5. the protective gloves of a kind of paraxylene according to claim 2, is characterized in that: described molecular sieve is the molecular sieve that barium exchanges; The preparation method of the molecular sieve that this barium exchanges is as follows: 1) with Klorvess Liquid and 13X molecular sieve, continuous stirring exchanges 2h, repeat 2-4 time to exchange, after each exchange terminates, spend deionized water for several times in cleaning solution without potassium ion, product is placed in the dry 12h of baking oven of 50 DEG C, obtains high potassium KX sieve sample; 2) described KX sieve sample and barium chloride solution are exchanged under preference temperature, continuous stirring exchanges 1h, repeat 2-4 time to exchange, after each exchange terminates, spend deionized water for several times in cleaning solution without barium ions, dry the molecular sieve after washing, activated molecular sieve at a certain temperature, obtain the molecular sieve that barium exchanges.
CN201510686913.8A 2015-10-22 2015-10-22 Protective gloves for paraxylene Pending CN105124809A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112075699A (en) * 2020-09-29 2020-12-15 江苏顶洁医疗器械有限公司 PVC gloves convenient to inside circulation of air

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102335589A (en) * 2011-09-16 2012-02-01 昆明理工大学 Adsorbent and preparation method and use thereof
CN102773140A (en) * 2011-05-09 2012-11-14 王志平 Manufacturing method for ultrafine shell powder
CN102907803A (en) * 2012-10-26 2013-02-06 贺广喜 Protective glove
CN102921384A (en) * 2012-11-22 2013-02-13 天津理工大学 Method for preparing high-efficiency fluorine removal agent from solid wastes
CN103585950A (en) * 2013-12-02 2014-02-19 浙江海洋学院 Preparation method of natural shell adsorbent
US20140173805A1 (en) * 2003-12-19 2014-06-26 Ansell Healthcare Products Llc Polymer bonded fibrous coating on dipped rubber articles skin contacting external surface

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140173805A1 (en) * 2003-12-19 2014-06-26 Ansell Healthcare Products Llc Polymer bonded fibrous coating on dipped rubber articles skin contacting external surface
CN102773140A (en) * 2011-05-09 2012-11-14 王志平 Manufacturing method for ultrafine shell powder
CN102335589A (en) * 2011-09-16 2012-02-01 昆明理工大学 Adsorbent and preparation method and use thereof
CN102907803A (en) * 2012-10-26 2013-02-06 贺广喜 Protective glove
CN102921384A (en) * 2012-11-22 2013-02-13 天津理工大学 Method for preparing high-efficiency fluorine removal agent from solid wastes
CN103585950A (en) * 2013-12-02 2014-02-19 浙江海洋学院 Preparation method of natural shell adsorbent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112075699A (en) * 2020-09-29 2020-12-15 江苏顶洁医疗器械有限公司 PVC gloves convenient to inside circulation of air

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Application publication date: 20151209