CN105113245A - Method for treating anti-wrinkle antibacterial anti-ultraviolet easy-care real silk shirt - Google Patents
Method for treating anti-wrinkle antibacterial anti-ultraviolet easy-care real silk shirt Download PDFInfo
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- CN105113245A CN105113245A CN201510562286.7A CN201510562286A CN105113245A CN 105113245 A CN105113245 A CN 105113245A CN 201510562286 A CN201510562286 A CN 201510562286A CN 105113245 A CN105113245 A CN 105113245A
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Abstract
The invention relates to a method for treating an anti-wrinkle antibacterial anti-ultraviolet easy-care real silk shirt. The method comprises the following steps: treating a real silk fabric with liquid ammonia, performing shrunk finish on the fabric by using a pre-shrinking machine, performing electrostatic spraying on the pre-shrunk shirt fabric by using an anti-wrinkle antibacterial anti-ultraviolet finishing agent, performing microwave treatment on the real silk fabric after electrostatic spraying, vacuuming the real silk fabric after microwave treatment, putting the vacuumed real silk fabric into a freezing chamber for freeze drying treatment, putting the real silk fabric after freeze drying treatment into steeping liquor containing an anti-wrinkle antibacterial anti-ultraviolet hydrophilic easy-care finishing agent for padding treatment, further baking the real silk fabric after padding treatment, cutting, making the shirt, ironing and shaping the finished shirt by using a baking and shaping machine, finishing, packaging, and storing in a warehouse. The method is remarkable in anti-wrinkle antibacterial anti-ultraviolet easy-care effect, is free of fabric damage, and is applicable to treatment on real silk shirts.
Description
Technical field
The present invention relates to weaving, clothing technology field, be specifically related to the processing method of the non-ironing silk shirt of a kind of creasing anti-bacterial antiultraviolet.
Background technology
Real silk fabric has much excellent performance, as gas permeability and hygroscopicity, also has excellent drapability, soft gloss, special scrooping sense, wears soft comfortable, very popular.Along with continuing to bring out of new chemical fiber in recent years, silk defect is inherently more and more obvious, traditional silk product receives serious challenge, improve its wrinkle resistance and give its multiple specific function, improve the added value of silk be silk production enterprise establish oneself in an unassailable position in the urgent need to.Existing useless silk, as the principal by product of silk textile industry, is not utilized effectively.
Be mainly or all cocoon fiber in the face liber composition of real silk matter shirt.Cocoon fiber has good gas permeability, and under normal conditions, fiber can absorb moisture in peripherad air, and its moisture content is 8% ~ 10%, so the skin of its contact people, makes people feel soft and not stiff.If cloth of real silk humidity increases, environment temperature is higher, and the amount of moisture contained in fiber can all leave in evaporation, makes fabric keep water equilibrated state, makes people feel comfortable.Therefore, compared with chemical fiber plus material, real silk matter material shirt has excellent air permeable humidity retaining.But cocoon fiber exists wrinkle resistance difference, easily deformation, washing shrinkage is large, fine wrinkle such as not easily to remove at the shortcoming.And existing fabric removes technique and method, be all easily go for chemical fibre or blended fibre knitwears fabric processing method of wrinkling.How according to the characteristic of cocoon fiber, design a kind of be applicable to silk shirt easily go processing method of wrinkling, having become those skilled in the art has technical problem to be solved.
Summary of the invention
The object of the invention is to overcome defect of the prior art, design one is crease-resistant, antibacterial, preventing ultraviolet effect remarkable, to fabric without any damage, is applicable to the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet of silk shirt.
For achieving the above object, the technical solution adopted in the present invention is:
A processing method for the non-ironing silk shirt of creasing anti-bacterial antiultraviolet, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to silk fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5kg/m
2~ 6kg/m
2, steam consumption is 30kg/h ~ 45kg/h;
3rd step, with the silk fabric after crease-resistant, antibacterial, anti-ultraviolet finishing agent electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the silk fabric after electrostatic spraying;
5th step, vacuumizes process to the silk fabric after microwave treatment, is evacuated to vacuum for-0.04Mpa ~-0.03Mpa;
6th step, puts into refrigerating chamber carry out freeze drying process by vacuumizing the silk fabric after process;
7th step, by the silk fabric after freeze drying process, then drops in the maceration extract containing crease-resistant, antibacterial, antiultraviolet, hydrophilic wash and wear finisher and carries out padding process, maceration extract pressure 1.5kg/cm
2~ 2kg/cm
2, liquid carrying rate 70% ~ 90%;
8th step, by padding that the silk fabric after process carries out baking, cutting, clothing;
9th step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 10 ~ 20 minutes at 140 DEG C ~ 150 DEG C, then carries out arranging, packs, puts in storage.
In order to adapt to the characteristic of silk fabric, effective ingredient in crease-resistant, antibacterial, anti-ultraviolet finishing agent all can be penetrated into the inside of cocoon fiber, its preferred technical scheme is, in described 3rd step, the spray distance of electrostatic spraying is 120mm ~ 150mm, the voltage of electrostatic spraying is 90V ~ 120V, the air pressure of electrostatic spraying is 0.05 ~ 0.08Mpa, and quantity for spray is every square metre of fabric 100ml/m
2~ 300ml/m
2.
In order to make the shirt made, there is well crease-resistant, antibacterial, preventing ultraviolet effect, and above-mentioned effect still remains unchanged after cyclic washing, preferred technical scheme also has further, and crease-resistant, antibacterial, anti-ultraviolet finishing agent in described 3rd step adopt following method to make:
Prepare fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent:
Prepared by A liquid: with the useless silk of potassium hydroxide hydrolysis, obtained Fibroin Hydrolysis liquid;
Prepared by B liquid: get n-butyl titanium, glacial acetic acid adds deionized water, be added in dilute hydrochloric acid solution after stirring, after peptization, cooling and aging, obtains nano titanic oxide sol;
Composite: to regulate pH to be 3 ~ 5 respectively A liquid and B liquid, more composite in the ratio mixing of 5:3, obtain stable fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent;
In order to make the shirt made, there is well crease-resistant, antibacterial, preventing ultraviolet effect, and above-mentioned effect still remains unchanged after cyclic washing, preferred technical scheme also has further, in the preparation of described fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent, time prepared by A liquid, the concentration of potassium hydroxide is 3mol/L ~ 7mol/L, useless silk consumption is 3g ~ 7g, potassium hydroxide consumption is 80ml ~ 300ml, and hydrolysis temperature is 60 DEG C, and hydrolysis time is 1.5 ~ 3 hours; Time prepared by B liquid, get n-butyl titanium 6.5g ~ 65g, glacial acetic acid 0.8 ~ 8ml, add 20-130ml deionized water magnetic stirrer evenly after, be added dropwise in the hydrochloric acid solution of 60ml0.1mol/L concentration, simultaneously at 20 DEG C after temperature constant magnetic stirring 50min, be warming up to 60 DEG C of continuation stirring 50min and make it peptization, take out nature cooling and aging, obtain nanometer titanium dioxide ferrum collosol.
In order to make anti-ultraviolet effect of fibroin Nano sol creasing anti-bacterial of enhancing cocoon fiber, the wrinkle resistance simultaneously improving cocoon fiber is poor, easy deformation, the shortcomings such as washing shrinkage is large, and the beneficial functional of cocoon fiber is further strengthened, preferred technical scheme also has, in described 7th step, the proportioning of fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent and hydrophilic wash and wear finisher is 6:4, wherein hydrophilic wash and wear finisher is the hydrophilic wash and wear finisher that great Hua Amada Co., Ltd. produces, the consumption of hydrophilic wash and wear finisher is 40g/L ~ 45g/L, pick-up rate is 85%, dipping is two leaching two bundles.
After penetrating into cocoon fiber to make the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred technical scheme also has, microwave treatment in described 4th step, its microwave frequency is 130MHz ~ 280MHz, and microwave treatment time is 6min ~ 8min.
After penetrating into cocoon fiber to make the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred technical scheme also has, in described 6th step, the cryogenic temperature of freeze drying process is 0 DEG C ~ 6 DEG C, and cooling time is 10mim ~ 25min.
Preferred technical scheme also has, and described real silk worsted fabric is the high-accuracy real silk yarn knitted fabric of 120.
Be firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid; preferred technical scheme also has; the key component of the hydrophilic non-ironing liquid in described 7th step is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 60g/L ~ 200g/L, fiber protection agent 10g/L ~ 50g/L, softener 20g/L ~ 60g/L, catalyst 15g/L ~ 25g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 4 ~ 6.
Be firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid, preferred technical scheme also has further, and described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea; Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate, described hydroxycarboxylic acid is citric acid, dihydromethyl propionic acid, 2, at least one in 3-dyhydrobutanedioic acid, in described composite catalyst, the percentage by weight of metal salt catalyst is 80% ~ 90%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
Advantage of the present invention and beneficial effect are: the processing method of the non-ironing silk shirt of described creasing anti-bacterial antiultraviolet, the active ingredient in crease-resistant, antibacterial, antiultraviolet and wash and wear finisher and cocoon fiber organically, firmly can be combined.Up to a hundred times of silk shirt cyclic washing after said method process, its easy decontamination, non-ironing effect still can be maintained.Silk shirt simultaneously after said method process, can also improve the defects such as poor, the easy deformation of wrinkle resistance of cocoon fiber, washing shrinkage are large simultaneously.
Useless natural silk degumming is hydrolyzed the Fibroin Finishing Agent made, there is a certain amount of free clean property group, as connected base, amino, completing base etc., can ask with silk fiber molecule the chemical bond that formation is comparatively stable, or be deposited in the unformed area of fiber, thus improve the wrinkle resistance of silk broadcloth.
The ferrous oxide generated in Nano sol, has antibacterial and uvioresistant function preferably; The performances such as nano material is large with its surface area, Active sites is many, high adsorption capacity, can also as the catalyst of fibroin anti-crease finishing.
By Fibroin Hydrolysis liquid and Nano sol under certain pH condition, be re-dubbed stable finishing agent by a certain percentage, there is synergistic function, make the real silk fabric after arrangement have good anti-creasing anti-bacterial anti-violet composite function.
The present invention for raw material, is conducive to resource regeneration with useless silk; Useless silk belongs to natural green product, the anti-creasing anti-bacterial anti-violet composite function silk fabric of exploitation meets the finishing functions of 21 century textiles should with comfortable, clean and carry out the developing direction arranging and process for keynote safely, and catered to the consumption concept of people's " environmental protection, health, fashion ", easy to process, cost is low.Product after tested, has good creasing anti-bacterial ultraviolet-resistant composite function, and wherein wrinkle resistance improves 10% ~ 30%, uvioresistant UPF class 40 ° ~ 50 °, to the antibacterial of Escherichia coli and staphylococcus aureus because 1mm ~ 10mm, soft in sense, comfortable and easy to wear, meet and take requirement.
Detailed description of the invention
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
Embodiment 1
A processing method for the non-ironing silk shirt of creasing anti-bacterial antiultraviolet, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to silk fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5kg/m
2, steam consumption is 30kg/h;
3rd step, with the silk fabric after crease-resistant, antibacterial, anti-ultraviolet finishing agent electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the silk fabric after electrostatic spraying;
5th step, vacuumizes process to the silk fabric after microwave treatment, is evacuated to vacuum for-0.03Mpa;
6th step, puts into refrigerating chamber carry out freeze drying process by vacuumizing the silk fabric after process;
7th step, by the silk fabric after freeze drying process, then drops in the maceration extract containing crease-resistant, antibacterial, antiultraviolet, hydrophilic wash and wear finisher and carries out padding process, maceration extract pressure 1.5kg/cm
2, liquid carrying rate 70%;
8th step, by padding that the silk fabric after process carries out baking, cutting, clothing;
9th step, by the ready-made clothes made with baking and banking up with earth setting machine at 140 DEG C after whole boiling hot sizing 10mim, then carries out arranging, packs, puts in storage.
The present invention is in order to adapt to the characteristic of silk fabric, effective ingredient in crease-resistant, antibacterial, anti-ultraviolet finishing agent all can be penetrated into the inside of cocoon fiber, its preferred embodiment is, in described 3rd step, the spray distance of electrostatic spraying is 120mm, the voltage of electrostatic spraying is 90V, the air pressure of electrostatic spraying is 0.05Mpa, and quantity for spray is every square metre of fabric 100ml/m
2.
The present invention has well crease-resistant, antibacterial, preventing ultraviolet effect to make the shirt made, and above-mentioned effect still remains unchanged after cyclic washing, further preferred embodiment also has, and crease-resistant, antibacterial, anti-ultraviolet finishing agent in described 3rd step adopt following method to make:
Prepare fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent:
Prepared by A liquid: with the useless silk of potassium hydroxide hydrolysis, obtained Fibroin Hydrolysis liquid;
Prepared by B liquid: get n-butyl titanium, glacial acetic acid adds deionized water, be added in dilute hydrochloric acid solution after stirring, after peptization, cooling and aging, obtains nano titanic oxide sol;
Composite: to regulate pH to be 3 respectively A liquid and B liquid, more composite in the ratio mixing of 5:3, obtain stable fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent;
The present invention has well crease-resistant, antibacterial, preventing ultraviolet effect to make the shirt made, and above-mentioned effect still remains unchanged after cyclic washing, further preferred embodiment also has, in the preparation of described fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent, time prepared by A liquid, the concentration of potassium hydroxide is 3mol/L, useless silk consumption is 3g, potassium hydroxide consumption is 80ml, and hydrolysis temperature is 60 DEG C, and hydrolysis time is 1.5 hours; Time prepared by B liquid, get n-butyl titanium 6.5g, glacial acetic acid 0.8ml, add 20ml deionized water magnetic stirrer evenly after, be added dropwise in the hydrochloric acid solution of 60ml0.1mol/L concentration, simultaneously at 20 DEG C after temperature constant magnetic stirring 50min, be warming up to 60 DEG C of continuation stirring 50min and make it peptization, take out nature cooling and aging, obtain nanometer titanium dioxide ferrum collosol.
The present invention is in order to make anti-ultraviolet effect of fibroin Nano sol creasing anti-bacterial of enhancing cocoon fiber, the wrinkle resistance simultaneously improving cocoon fiber is poor, easy deformation, the shortcomings such as washing shrinkage is large, and the beneficial functional of cocoon fiber is further strengthened, preferred embodiment also has, in described 7th step, the proportioning of fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent and hydrophilic wash and wear finisher is 6:4, wherein hydrophilic wash and wear finisher is the hydrophilic wash and wear finisher that great Hua Amada Co., Ltd. produces, the consumption of hydrophilic wash and wear finisher is 40g/L, pick-up rate is 85%, dipping is two leaching two bundles.
The present invention is in order to after making the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent penetrate into cocoon fiber, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred embodiment also has, microwave treatment in described 4th step, its microwave frequency is 130MHz, and microwave treatment time is 6min.
The present invention is in order to after making the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent penetrate into cocoon fiber, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred embodiment also has, in described 6th step, the cryogenic temperature of freeze drying process is 0 DEG C, and cooling time is 10min.
The preferred embodiment of the invention also has, and described real silk worsted fabric is the high-accuracy real silk yarn knitted fabric of 120.
The present invention is firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid; preferred embodiment also has; the key component of the hydrophilic non-ironing liquid in described 7th step is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 60g/L, fiber protection agent 10g/L, softener 20g/L, catalyst 15g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 4.
The present invention is firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid, further preferred embodiment also has, and described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea; Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate, described hydroxycarboxylic acid is citric acid, dihydromethyl propionic acid, 2, at least one in 3-dyhydrobutanedioic acid, in described composite catalyst, the percentage by weight of metal salt catalyst is 80%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
Embodiment 2
A processing method for the non-ironing silk shirt of creasing anti-bacterial antiultraviolet, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to silk fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5.5kg/m
2, steam consumption is 37.5kg/h;
3rd step, with the silk fabric after crease-resistant, antibacterial, anti-ultraviolet finishing agent electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the silk fabric after electrostatic spraying;
5th step, vacuumizes process to the silk fabric after microwave treatment, is evacuated to vacuum for-0.035Mpa;
6th step, puts into refrigerating chamber carry out freeze drying process by vacuumizing the silk fabric after process;
7th step, by the silk fabric after freeze drying process, then drops in the maceration extract containing crease-resistant, antibacterial, antiultraviolet, hydrophilic wash and wear finisher and carries out padding process, maceration extract pressure 1.75kg/cm
2, liquid carrying rate 80%;
8th step, by padding that the silk fabric after process carries out baking, cutting, clothing;
9th step, by the ready-made clothes made with baking and banking up with earth setting machine at 145 DEG C after whole boiling hot sizing 15min, then carries out arranging, packs, puts in storage.
The present invention is in order to adapt to the characteristic of silk fabric, effective ingredient in crease-resistant, antibacterial, anti-ultraviolet finishing agent all can be penetrated into the inside of cocoon fiber, its preferred embodiment is, in described 3rd step, the spray distance of electrostatic spraying is 135mm, the voltage of electrostatic spraying is 105V, the air pressure of electrostatic spraying is 0.065Mpa, and quantity for spray is every square metre of fabric 200ml/m
2.
The present invention has well crease-resistant, antibacterial, preventing ultraviolet effect to make the shirt made, and above-mentioned effect still remains unchanged after cyclic washing, further preferred embodiment also has, and crease-resistant, antibacterial, anti-ultraviolet finishing agent in described 3rd step adopt following method to make:
Prepare fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent:
Prepared by A liquid: with the useless silk of potassium hydroxide hydrolysis, obtained Fibroin Hydrolysis liquid;
Prepared by B liquid: get n-butyl titanium, glacial acetic acid adds deionized water, be added in dilute hydrochloric acid solution after stirring, after peptization, cooling and aging, obtains nano titanic oxide sol;
Composite: to regulate pH to be 4 respectively A liquid and B liquid, more composite in the ratio mixing of 5:3, obtain stable fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent;
The present invention has well crease-resistant, antibacterial, preventing ultraviolet effect to make the shirt made, and above-mentioned effect still remains unchanged after cyclic washing, further preferred embodiment also has, in the preparation of described fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent, time prepared by A liquid, the concentration of potassium hydroxide is 5mol/L, useless silk consumption is 5g, potassium hydroxide consumption is 190ml, and hydrolysis temperature is 60 DEG C, and hydrolysis time is 2 hours; Time prepared by B liquid, get n-butyl titanium 36g, glacial acetic acid 4.4ml, add 75ml deionized water magnetic stirrer evenly after, be added dropwise in the hydrochloric acid solution of 60ml0.1mol/L concentration, simultaneously at 20 DEG C after temperature constant magnetic stirring 50min, be warming up to 60 DEG C of continuation stirring 50min and make it peptization, take out nature cooling and aging, obtain nanometer titanium dioxide ferrum collosol.
The present invention is in order to make anti-ultraviolet effect of fibroin Nano sol creasing anti-bacterial of enhancing cocoon fiber, the wrinkle resistance simultaneously improving cocoon fiber is poor, easy deformation, the shortcomings such as washing shrinkage is large, and the beneficial functional of cocoon fiber is further strengthened, preferred embodiment also has, in described 7th step, the proportioning of fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent and hydrophilic wash and wear finisher is 6:4, wherein hydrophilic wash and wear finisher is the hydrophilic wash and wear finisher that great Hua Amada Co., Ltd. produces, the consumption of hydrophilic wash and wear finisher is 42.5g/L, pick-up rate is 85%, dipping is two leaching two bundles.
The present invention is in order to after making the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent penetrate into cocoon fiber, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred embodiment also has, microwave treatment in described 4th step, its microwave frequency is 210MHz, and microwave treatment time is 7min.
The present invention is in order to after making the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent penetrate into cocoon fiber, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred embodiment also has, in described 6th step, the cryogenic temperature of freeze drying process is 3 DEG C, and cooling time is 17min.
The preferred embodiment of the invention also has, and described real silk worsted fabric is the high-accuracy real silk yarn knitted fabric of 120.
The present invention is firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid; preferred embodiment also has; the key component of the hydrophilic non-ironing liquid in described 7th step is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 130g/L, fiber protection agent 30g/L, softener 40g/L, catalyst 20g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 5.
The present invention is firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid, preferred technical scheme also has further, and described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea; Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate, described hydroxycarboxylic acid is citric acid, dihydromethyl propionic acid, 2, at least one in 3-dyhydrobutanedioic acid, in described composite catalyst, the percentage by weight of metal salt catalyst is 85%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
Embodiment 3
A processing method for the non-ironing silk shirt of creasing anti-bacterial antiultraviolet, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to silk fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 6kg/m
2, steam consumption is 45kg/h;
3rd step, with the silk fabric after crease-resistant, antibacterial, anti-ultraviolet finishing agent electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the silk fabric after electrostatic spraying;
5th step, vacuumizes process to the silk fabric after microwave treatment, is evacuated to vacuum for-0.04Mpa;
6th step, puts into refrigerating chamber carry out freeze drying process by vacuumizing the silk fabric after process;
7th step, by the silk fabric after freeze drying process, then drops in the maceration extract containing crease-resistant, antibacterial, antiultraviolet, hydrophilic wash and wear finisher and carries out padding process, maceration extract pressure 2kg/cm
2, liquid carrying rate 90%;
8th step, by padding that the silk fabric after process carries out baking, cutting, clothing;
9th step, by the ready-made clothes made with baking and banking up with earth setting machine at 150 DEG C after whole boiling hot sizing 20min, then carries out arranging, packs, puts in storage.
The present invention is in order to adapt to the characteristic of silk fabric, effective ingredient in crease-resistant, antibacterial, anti-ultraviolet finishing agent all can be penetrated into the inside of cocoon fiber, its preferred embodiment is, in described 3rd step, the spray distance of electrostatic spraying is 150mm, the voltage of electrostatic spraying is 120V, the air pressure of electrostatic spraying is 0.08Mpa, and quantity for spray is every square metre of fabric 300ml/m
2.
The present invention has well crease-resistant, antibacterial, preventing ultraviolet effect to make the shirt made, and above-mentioned effect still remains unchanged after cyclic washing, further preferred embodiment also has, and crease-resistant, antibacterial, anti-ultraviolet finishing agent in described 3rd step adopt following method to make:
Prepare fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent:
Prepared by A liquid: with the useless silk of potassium hydroxide hydrolysis, obtained Fibroin Hydrolysis liquid;
Prepared by B liquid: get n-butyl titanium, glacial acetic acid adds deionized water, be added in dilute hydrochloric acid solution after stirring, after peptization, cooling and aging, obtains nano titanic oxide sol;
Composite: to regulate pH to be 5 respectively A liquid and B liquid, more composite in the ratio mixing of 5:3, obtain stable fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent;
The present invention has well crease-resistant, antibacterial, preventing ultraviolet effect to make the shirt made, and above-mentioned effect still remains unchanged after cyclic washing, further preferred embodiment also has, in the preparation of described fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent, time prepared by A liquid, the concentration of potassium hydroxide is 7mol/L, useless silk consumption is 7g, potassium hydroxide consumption is 300ml, and hydrolysis temperature is 60 DEG C, and hydrolysis time is 3 hours; Time prepared by B liquid, get n-butyl titanium 65g, glacial acetic acid 8ml, add 130ml deionized water magnetic stirrer evenly after, be added dropwise in the hydrochloric acid solution of 60ml0.1mol/L concentration, simultaneously at 20 DEG C after temperature constant magnetic stirring 50min, be warming up to 60 DEG C of continuation stirring 50min and make it peptization, take out nature cooling and aging, obtain nanometer titanium dioxide ferrum collosol.
The present invention is in order to make anti-ultraviolet effect of fibroin Nano sol creasing anti-bacterial of enhancing cocoon fiber, the wrinkle resistance simultaneously improving cocoon fiber is poor, easy deformation, the shortcomings such as washing shrinkage is large, and the beneficial functional of cocoon fiber is further strengthened, preferred embodiment also has, in described 7th step, the proportioning of fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent and hydrophilic wash and wear finisher is 6:4, wherein hydrophilic wash and wear finisher is the hydrophilic wash and wear finisher that great Hua Amada Co., Ltd. produces, the consumption of hydrophilic wash and wear finisher is 45g/L, pick-up rate is 85%, dipping is two leaching two bundles.
The present invention is in order to after making the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent penetrate into cocoon fiber, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred embodiment also has, microwave treatment in described 4th step, its microwave frequency is 280MHz, and microwave treatment time is 8min.
The present invention is in order to after making the effective ingredient in fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent penetrate into cocoon fiber, can for a long time and still can keep after cyclic washing its pin active ingredient, do not come off, preferred embodiment also has, in described 6th step, the cryogenic temperature of freeze drying process is 6 DEG C, and cooling time is 25min.
The preferred embodiment of the invention also has, and described real silk worsted fabric is the high-accuracy real silk yarn knitted fabric of 120.
The present invention is firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid; preferred embodiment also has; the key component of the hydrophilic non-ironing liquid in described 7th step is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 200g/L, fiber protection agent 50g/L, softener 60g/L, catalyst 25g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 6.
The present invention is firmly attached in cocoon fiber to make the active ingredient in hydrophilic non-ironing treatment fluid, further preferred embodiment also has, and described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea; Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate, described hydroxycarboxylic acid is citric acid, dihydromethyl propionic acid, 2, at least one in 3-dyhydrobutanedioic acid, in described composite catalyst, the percentage by weight of metal salt catalyst is 90%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. a processing method for the non-ironing silk shirt of creasing anti-bacterial antiultraviolet, is characterized in that, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to silk fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5kg/m
2~ 6kg/m
2, steam consumption is 30kg/h ~ 45kg/h;
3rd step, with the silk fabric after crease-resistant, antibacterial, anti-ultraviolet finishing agent electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the silk fabric after electrostatic spraying;
5th step, vacuumizes process to the silk fabric after microwave treatment, is evacuated to vacuum for-0.04Mpa ~-0.03Mpa;
6th step, puts into refrigerating chamber carry out freeze drying process by vacuumizing the silk fabric after process;
7th step, by the silk fabric after freeze drying process, then drops in the maceration extract containing crease-resistant, antibacterial, antiultraviolet, hydrophilic wash and wear finisher and carries out padding process, maceration extract pressure 1.5kg/cm
2~ 2kg/cm
2, liquid carrying rate 70% ~ 90%;
8th step, by padding that the silk fabric after process carries out baking, cutting, clothing;
9th step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 10 ~ 20 minutes at 140 ~ 150 DEG C, then carries out arranging, packs, puts in storage.
2. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 1, it is characterized in that, in described 3rd step, the spray distance of electrostatic spraying is 120mm ~ 150mm, the voltage of electrostatic spraying is 90V ~ 120V, the air pressure of electrostatic spraying is 0.05Mpa ~ 0.08Mpa, and quantity for spray is every square metre of fabric 100ml/m
2~ 300ml/m
2.
3. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 2, it is characterized in that, crease-resistant, antibacterial, anti-ultraviolet finishing agent in described 3rd step adopt following method to make:
Prepare fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent:
Prepared by A liquid: with the useless silk of potassium hydroxide hydrolysis, obtained Fibroin Hydrolysis liquid;
Prepared by B liquid: get n-butyl titanium, glacial acetic acid adds deionized water, be added in dilute hydrochloric acid solution after stirring, after peptization, cooling and aging, obtains nano titanic oxide sol;
Composite: to regulate pH to be 3 ~ 5 respectively A liquid and B liquid, more composite in the ratio mixing of 5:3, obtain stable fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent.
4. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 3, it is characterized in that, in the preparation of described fibroin Nano sol creasing anti-bacterial anti-ultraviolet finishing agent, time prepared by A liquid, the concentration of potassium hydroxide is 3mol/L ~ 7mol/L, and useless silk consumption is 3g ~ 7g, and potassium hydroxide consumption is 80ml ~ 300ml, hydrolysis temperature is 60 DEG C, and hydrolysis time is 1.5 ~ 3 hours; Time prepared by B liquid, get n-butyl titanium 6.5g ~ 65g, glacial acetic acid 0.8ml ~ 8ml, add 20ml ~ 130ml deionized water magnetic stirrer evenly after, be added dropwise in the hydrochloric acid solution of 60ml0.1mol/L concentration, simultaneously at 20 DEG C after temperature constant magnetic stirring 50min, be warming up to 60 DEG C of continuation stirring 50min and make it peptization, take out nature cooling and aging, obtain nanometer titanium dioxide ferrum collosol.
5. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 4, it is characterized in that, in described 7th step, the proportioning of fibroin Nano sol creasing anti-bacterial uvioresistant finishing agent and hydrophilic wash and wear finisher is 6:4, wherein hydrophilic wash and wear finisher is the hydrophilic wash and wear finisher that great Hua Amada Co., Ltd. produces, the consumption of hydrophilic wash and wear finisher is 40g/L ~ 45g/L, pick-up rate is 85%, and dipping is two leaching two bundles.
6. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 1, it is characterized in that, the microwave treatment in described 4th step, its microwave frequency is 130MHz ~ 280MHz, and microwave treatment time is 6min ~ 8min.
7. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 1, it is characterized in that, in described 6th step, the cryogenic temperature of freeze drying process is 0 DEG C ~ 6 DEG C, and cooling time is 10min ~ 25min.
8. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 1, it is characterized in that, described real silk worsted fabric is the high-accuracy real silk yarn knitted fabric of 120.
9. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 1; it is characterized in that; the key component of the hydrophilic non-ironing liquid in described 7th step is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 60g/L ~ 200g/L, fiber protection agent 10g/L ~ 50g/L, softener 20g/L ~ 60g/L, catalyst 15g/L ~ 25g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 4 ~ 6.
10. the processing method of the non-ironing silk shirt of creasing anti-bacterial antiultraviolet as claimed in claim 9, it is characterized in that, described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea; Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate, described hydroxycarboxylic acid is citric acid, dihydromethyl propionic acid, 2, at least one in 3-dyhydrobutanedioic acid, in described composite catalyst, the percentage by weight of metal salt catalyst is 80% ~ 90%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
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| CN106835439A (en) * | 2016-12-26 | 2017-06-13 | 吴中区穹窿山倪源交通器材经营部 | A kind of crease-resistant type ultraviolet-resistant fabric and preparation method thereof |
| CN106906640A (en) * | 2017-03-21 | 2017-06-30 | 邢志存 | A kind of mulberry silk radiation-proof fabric and prepare the aviation magnetic wave process of the fabric |
| CN108330678A (en) * | 2018-02-02 | 2018-07-27 | 宜州市壮之都丝绸家纺有限公司 | A kind of maintenance method of silk |
| CN108411635A (en) * | 2018-02-02 | 2018-08-17 | 宜州市壮之都丝绸家纺有限公司 | A kind of silk shirt |
| CN110230140A (en) * | 2019-06-25 | 2019-09-13 | 芜湖昊顺服饰有限公司 | A kind of pressing method of textile fabric |
| CN110820333A (en) * | 2019-11-19 | 2020-02-21 | 河南民兴生物科技股份有限公司 | Preparation method for improving tussah silk fiber strength |
| CN111395015A (en) * | 2020-04-15 | 2020-07-10 | 淄博大染坊丝绸集团有限公司 | Dyeing and finishing process of real silk fabric for summer wear |
| CN112048913A (en) * | 2020-09-02 | 2020-12-08 | 浙江丝绸科技有限公司 | Durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabric |
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| CN106835439A (en) * | 2016-12-26 | 2017-06-13 | 吴中区穹窿山倪源交通器材经营部 | A kind of crease-resistant type ultraviolet-resistant fabric and preparation method thereof |
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| CN110820333A (en) * | 2019-11-19 | 2020-02-21 | 河南民兴生物科技股份有限公司 | Preparation method for improving tussah silk fiber strength |
| CN111395015A (en) * | 2020-04-15 | 2020-07-10 | 淄博大染坊丝绸集团有限公司 | Dyeing and finishing process of real silk fabric for summer wear |
| CN112048913A (en) * | 2020-09-02 | 2020-12-08 | 浙江丝绸科技有限公司 | Durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabric |
| CN112048913B (en) * | 2020-09-02 | 2023-02-10 | 浙江丝绸科技有限公司 | Durable uvioresistant finishing process for light and thin real silk or silk-containing fabric |
| CN112941898A (en) * | 2021-03-05 | 2021-06-11 | 鲁泰纺织股份有限公司 | Preparation method of pure cotton antibacterial fabric |
| CN115323764A (en) * | 2022-09-14 | 2022-11-11 | 浙江加佳领带服装有限公司 | Antibacterial finishing process for clothes |
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