CN1051115C - Temp. regulating fibre and its products - Google Patents
Temp. regulating fibre and its products Download PDFInfo
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- CN1051115C CN1051115C CN96105229A CN96105229A CN1051115C CN 1051115 C CN1051115 C CN 1051115C CN 96105229 A CN96105229 A CN 96105229A CN 96105229 A CN96105229 A CN 96105229A CN 1051115 C CN1051115 C CN 1051115C
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Abstract
The present invention relates to a technology for manufacturing functional fibers, which is characterized in that a thermoplastic polymer A is used as a core component or an island component of a fiber, wherein the melting temperature of the thermoplastic polymer A is 20 to 40 DEG C, the melting heat of the thermoplastic polymer A is more than 30 J/g, the crystallization temperature is 20 to 5 DEG C, and the crystallization heat is more than 30 J/g; a conventional thermoplastic polymer B is used as a sheath component or a sea component, wherein the melting temperature of the melting temperature is more than 150 DEG C; the weight ratio of the polymer A to the polymer B is 2 to 8: 8 to 2; a functional fiber is formed by compound melt spinning. The fiber is knitted and processed in a conventional or unconventional mode to form a product; under the temperature of 10 DEG C, the surface temperature of the fiber is 2 to 6 DEG C higher than that of a compared fabric; under the temperature of 40 DEG C, the surface temperature of the fiber is 2 to 6 DEG C lower than that of the compared fabric. The fiber has a good temperature adjusting function.
Description
The present invention relates to the manufacturing technology of a kind of new function fiber and goods thereof, specifically be a kind of when variation of ambient temperature, take place to change mutually to absorb or discharge heat energy by the polymer of forming fiber, thereby make fiber and goods have the manufacturing technology of the fibrous and goods of two-way adjustment effect.
Just string (as cotton, fiber crops etc.) and animal fiber (as silk, hair, eider down and fur etc.) the making resisting cold clothes that utilize occurring in nature to have good heat preservation effect have been understood though ancient times is human, but arrived the twentieth century middle and later periods, growth along with world population, no matter natural fabric on output, still all can not satisfy human growing demand qualitatively.So, artificial fibre and synthetic fiber technology have obtained extensive studies and development, with viscose glue, polyvinyl, polyamide fibre, terylene, acrylic fibers etc. is that the imitative cotton, simulate wool of raw material, imitative fiber crops, imitative silk and down-like fiber are dropped into suitability for industrialized production in succession, and becomes the main flow of insulation dress material research and development gradually.
Present existing animal and plant fiber and space or the inside and outside circulation of air of the isolated clothes of interlayer artificial and that synthetic fiber all utilize fibrous woven or braiding back to form reach the insulation purpose.When ambient temperature raises or reduce, temperature also can correspondingly increase or reduce in the clothes, and it is sultry or cold that people will feel, but when the amplitude of variation of ambient temperature exceeds the regulating power of human body self, can cause the many discomforts of human body, even cause disease.
In recent years, along with the raising day by day and the related discipline of people's quality of life constantly makes progress, especially air conditioner refrigerating broad application, people no longer are satisfied with the original passive insulation effect that can only be risen by secluding air circulation of conventional textile fabric, wish to develop the fiber that itself has temp regulating function, for example, European patent EP 302141 discloses a kind of carbide and aluminium micro mist with the IV transiting group metal elements and sneaks into thermoplastic polymer together, and further makes the method with energy absorption fiber after the spinning.This fabric is after having absorbed the infrared ray in the sunshine, and temperature can be high 3～8 ℃ than the conventional fibre fabric in the clothes, improved the insulation usefulness of fiber.But it is at the cloudy day or when night, environment temperature descended, and temperature also descends thereupon in the clothes, and the temperature difference of its result and conventional fibre inner not quite that is to say that its temp regulating function is unidirectional.
The manufacture method of another kind of temperature-regulating fiber again for example, is disclosed in the U.S. Pat 3607591.After it dissolves in solvent with gases such as carbon dioxide, be filled in the hollow space of fiber, and before weaving processing, hollow space sealed.This fiber dissolves in solvent at low temperatures by carbon dioxide and the energy variation when at high temperature separating out from solvent, can obtain having the fiber of energy absorption and release action.Though this fiber is two-way on temperature adjustment function, be unsettled on performance, such as when fiber in use is subjected to ambient pressure, very easily gas being leaked, cause losing suddenly or gradually of temperature adjustment function, while manufacturing technique complexity, cost height.
Again for example, a day disclosure is speciallyyed permit to disclose among the flat 4-163370 and is a kind ofly mixed 70 parts of paraffin (fusing point is 52 ℃) and 30 parts of high density polyethylene (HDPE)s afterwards that the melt spinning manufacturings have the method for temp regulating function fiber.When environment temperature raise, the paraffin in this fiber can pass through to absorb external heat and fusion; When ambient temperature reduced, liquid paraffin crystallization curing discharged the heat of transformation, thereby makes fiber have two-way adjustment effect, kept the temperature in the clothes relatively stable.But in order to prevent that paraffin from use from the fiber surface escape, needing at fiber surface coating epoxy resin, this obviously makes the weaving of fiber and takes performance can not be satisfactory, and technology is also complicated.
The objective of the invention is at above-mentioned defective, provide that a kind of technology is simple, cost is low, and have the fiber of better two-way adjustment effect, stable performance.This fiber and goods thereof can be according to the variations of ambient temperature, the transformation mutually of the polymer by forming fiber, absorb or discharge heat energy, thereby make fiber and goods thereof have the active temperature regulatory function, but and keep or says and do not reduce the original textile processibility of fiber and take comfortableness.
The object of the present invention is achieved like this: with melt temperature is 20～40 ℃, more than the melting heat 30J/g, 20～5 ℃ of crystallization temperatures, the above thermoplastic polymer of crystallization heat 30J/g is a polymer A, is polymer B with melt temperature at the conventional thermoplastic polymer more than 150 ℃, polymer A is the principal component of fibre core or island component, polymer B is the principal component of fibrous sheath or sea component, and the weight ratio of polymer A and polymer B is 2～8: 8～2, handle through the composite molten spinning and through drawing-off, the typing of routine, can obtain the fiber of the object of the invention.
The present invention is only by a melt spinning moulding, and do not need through other special post processing, can obtain having the fiber of two-way adjustment effect, therefore technology is simple, cost is low, and contained at fibrous inside by the sheath of fiber or sea component with the core of fiber or the form of island component owing to have the material-polymer A of heat absorption and release function, avoided fibre property deterioration in use, so stable performance of fiber and goods thereof, temperature adjustment function is better, but the while does not also influence or says the textile processibility energy that does not reduce fiber at least and take performance.
Polymer A of the present invention comprises a kind of in the following substances: the paraffin class material; Polyethers; Aliphatic polyester; Aromatic polyester ether and aliphatic polyester ether.The paraffin class material is meant that carbon number is 10～40 hydro carbons specifically; Polyethers is meant that molecular weight is that 600～4000 aliphatic polyether, especially polyethylene glycol and polytetramethylene glycol more can meet the demands, and other performance polypropylene glycol and polyethylene glycol-butanediol, polypropylene glycol-butanediol similarly also can satisfy requirement of the present invention; Own diester of poly-glutaric acid and poly-adipic acid penta diester in the aliphatic polyester can satisfy requirement of the present invention, other performance aliphatic diacid that contains 4～10 carbon atoms similarly and the aliphatic polyester that the aliphatic diol that contains 2～8 carbon atoms is copolymerized into also can satisfy requirement of the present invention as succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, decanedioic acid etc. and the aliphatic polyester that ethylene glycol, butanediol, pentanediol, hexylene glycol, ethohexadiol etc. aggregate into; Aromatic polyester ether is meant raw material pfpe molecule amount more than 1000, and the polyethers percentage by weight is the aromatic polyester ether more than 45, as poly terephthalic acid ethylene glycol-polyethylene glycol and poly terephthalic acid ethylene glycol-polytetramethylene glycol.Other polyester ether can be used for the object of the invention as poly terephthalic acid ethylene glycol-polypropylene glycol, polybutylene terephthalate-polyethylene glycol, polybutylene terephthalate-polypropylene glycol and polybutylene terephthalate-polytetramethylene glycol.The pfpe molecule amount is more than 1000, and the polyethers percentage by weight is that aliphatic polyester ether more than 45 is as poly-glutaric acid butanediol-polyethylene glycol, poly-glutaric acid butanediol-polypropylene glycol, poly-glutaric acid butanediol-polytetramethylene glycol, poly-glutaric acid hexylene glycol-polyethylene glycol, poly-glutaric acid hexylene glycol-polypropylene glycol, poly-glutaric acid hexylene glycol-polytetramethylene glycol, poly-glutaric acid pentanediol-polyethylene glycol, poly-glutaric acid pentanediol-polypropylene glycol, poly-glutaric acid pentanediol-polytetramethylene glycol and poly-decanedioic acid propylene glycol-polyethylene glycol, poly-decanedioic acid propylene glycol-polypropylene glycol, poly-decanedioic acid propylene glycol-polytetramethylene glycol also can be used for the object of the invention.
Polymer B of the present invention should be melt temperature at the conventional thermoplastic polymer more than 150 ℃, for example be polypropylene, poly terephthalic acid ethylene glycol, polybutylene terephthalate, polycaprolactam, polydecamethylene adipamide or their mixture and copolymer.
Feature of the present invention also is, was added with heat fusing and prevents from agent and cross cold crystallization to prevent agent in polymer A.Its effect is to guarantee that polymer A is in the variation of ambient temperature process, can when reaching phase transition temperature, take place exactly to change mutually, thereby absorb well or emit energy, be lower than the crystallization temperature of polymer A when a lot of and be unlikely to take place environment temperature, still non-crystallizable, or environment temperature is higher than the melt temperature of polymer A when a lot, still the phenomenon of not fusion.
The heat fusing of crossing that adds in the polymer A prevents from agent and crosses cold crystallization to prevent that agent from can be respectively or be both a kind of in the following substances or two kinds: the oxide of metallic element and their stearate; Phenol type substances; Amine substance and polyethers.As titanium oxide, zinc stearate, 2,6-di-t-butyl-4-normal-butyl phenol, N-cyclohexyl-N '-diphenyl-para-phenylene diamine and molecular weight are more than or equal to 4000 aliphatic polyether such as polyethylene glycol and polytetramethylene glycol.The oxide of other metallic element such as aluminium oxide, zinc oxide, calcium oxide, magnesia etc. also can be used for the object of the invention; The stearate of other metallic element such as aluminum stearate, stearic acid titanium, calcium stearate, dolomol also can be used for purpose of the present invention; Other phenol type substances such as 4-hydroxyl-2,6-DI-tert-butylphenol compounds, 4,4 '-two (2, the 6-DI-tert-butylphenol compounds) also can be used for purpose of the present invention; Other amine substance such as N, N '-diphenyl ethylene diamin(e), N, N '-diphenyl-para-phenylene diamine also can be used for purpose of the present invention.
In order to realize purpose of the present invention better, cross heat fusing in the fiber of the present invention and prevent from agent or cross cold crystallization to prevent that the consumption of agent from should be 0.1～3% of polymer A weight.Crossing heat fusing prevents from agent or crosses cold crystallization to prevent that the consumption of agent is lower than at 0.1% o'clock, then can not bring into play its function well, and consumption may cause waste greater than 3%, although heat fusing prevents that agent and mistake cold crystallization from preventing that the consumption of agent from surpassing at 3% o'clock, still can realize purpose of the present invention excessively.
In order to obtain the good fiber of the present invention of weaving property and taking, the weight ratio of polymer A and B should be 2～8: between 8～2, be 4～6 preferably: between 6～4.Core or island component ratio are low excessively, are difficult to obtain having the fiber of good two-way temp regulating function, lose meaning of the present invention.And core or island component ratio are too high, and then it is difficult to be coated by sheath composition or sea component well, and the serviceability of fiber is undesirable.
The cross sectional shape of fiber of the present invention is to the not influence of two-way adjustment effect of fiber of the present invention.According to product requirements, it can be circle, trilobal or square-section, can also be single hollow type or many hollow types cross section, and single core sheath cross section or multicore sheath cross section.
The forming method of fiber of the present invention is the composite molten spin processes, and forming temperature is different and slightly different according to the kind of used sheath composition or sea component polymer B, but general and not obviously difference of conventional thermoplastic polymer melt spinning.General spinning temperature is 230～320 ℃.
Also can contain in the fiber of the present invention the nontoxic heat stabilizer of human body, antioxidant and uvioresistant photo etching and fire retardant etc., its kind and consumption and conventional func fiber be obviously difference not.
The use of fiber of the present invention is identical with other textile fabric, can conventional weaving processing, as spinning, knitting or tatting etc.; Also can be through the processing of unconventional weaving techniques, all thickness of making as methods such as non-woven, laminations and the goods of structure.
Although the processing of fiber of the present invention and conventional fibre be obviously difference not, but its goods and conventional fibre goods have evident difference, be the effect that it has with variation of ambient temperature automatic bidirectional adjusting temperature in certain temperature range, have significantly technique effect.
The test of employing differential scanning calorimeter, heat absorption and release function that weaving that fiber process of the present invention becomes or non-textile have 10～70J/g.Adopt the test of highly sensitive infrared radiation thermometer, at weaving or the non-textile that 10 ℃ of following fiber process of the present invention become, its surface temperature is higher than 2～6 ℃ of conventional weaving or non-textiles; Under 40 ℃, the surface temperature of these weavings or non-textile is lower than 2～6 ℃ of conventional weaving or non-textiles again, has conventional weaving or that non-textile did not have and comparatively tangible temp regulating function.
Fiber of the present invention especially is fit to make various civilian clothes: as T-shirt, shirt, one-piece dress, underwear and nightwear skirt etc.; Bedding: as quilt, cotton-padded mattress, pillow and sheet etc.; Interior decoration cloth: as curtain, slip cover, back cushion and camping tent etc.; Health care clothes: as burn patient's gown, patient's the old and the weak clothes and children's dress etc.; Sportswear: as ski-wear, swimsuit, gym outfit and polar region exploration clothes etc.; Business wear: as fire-entry suit liner, steel-making clothes liner, diving suit liner, military clothes and suit liner etc.
With embodiment the present invention is described more specifically below:
Embodiment 1 is that 800 polyethylene glycol (33 ℃ of fusing points) is a polymer A with number-average molecular weight, and to add 1% average particulate diameter therein be that 1.5 microns titanium oxide prevents agent as crossing heat fusing and crossing cold crystallization, and 0.3% antioxidant 1010; With at 1: 1 phenol-1,1,2, intrinsic viscosity is that 0.68 polycaprolactam is a polymer B in the 2-tetrachloroethanes, and in polymer B, add 2% ultraviolet absorbent uv-326 of (is benchmark with polymer B weight, down with), polymer A is the sandwich layer of fiber, polymer B is the sheath layer of fiber, the weight ratio of A and B is 4: 6, adopts Φ 160 * 400 hole concentric circles core sheath composite spinnerets, orifice diameter 0.28mm, 280 ℃ of following fusions, with 500 meters/minute winding speed spinning, obtain the undrawn yarn that filament number is 6.6dtex, behind the boundling, 4.0 times of drawing-offs altogether in the steam bath of 65～70 ℃ water-baths and 110 ℃, carrying out machine crimp, behind the relaxation heat setting, be cut to the staple fibre of 38mm, its filament number is 1.7dtex, the filament fracture strength is 3.2CN/dtex, extension at break 28%.
Be spun into 32 count yarns with this fiber, through the woven 180g/M that is processed into
2Woven cloth.Its fusion heat absorption in the time of 33 ℃ is 50J/g after tested, and the crystallization heat release under 5 ℃ is 48J/g.Be processed into T-shirt, one-piece dress with this woven cloth, wear summer and have good adjustment effect, so comfortable especially.
Embodiment 2 is that 3000 polytetramethylene glycol (35 ℃ of fusing points) is a polymer A with number-average molecular weight, and add therein 1% 2,6-di-t-butyl-4-normal-butyl phenol prevents agent as crossing heat fusing, adds 2% molecular weight again and is 6000 polytetramethylene glycol and prevent agent as crossing cold crystallization; With at 1: 1 phenol-1,1,2, intrinsic viscosity is that 0.65 poly terephthalic acid ethylene glycol is polymer B in the 2-tetrachloroethanes, and to add 0.15% triphenyl phosphite therein be heat stabilizer.Polymer A is the sandwich layer of fiber, polymer B is the sheath layer of fiber, and the weight ratio of A and B is 4: 6, adopts Φ 160 * 400 holes, the trilobal core sheath composite spinneret of circumscribed circle diameter 0.30mm, 300 ℃ of following fusions, the winding speed spinning with 800 meters/minute obtains the trifoil cross-section undrawn yarn, behind the boundling, 3.5 times of drawing-offs altogether after carrying out machine crimp, relaxation heat setting, are cut to the staple fibre of 72mm in the steam bath of 65～70 ℃ water-baths and 130 ℃.Filament number is 2.3dtex, and the filament fracture strength is 3.1CN/dtex, extension at break 32%.
Become 210g/M with this fiber process
2Non-weaving cloth.After tested, its melting heat under 35 ℃ is 60J/g, and the crystallization heat release under 7 ℃ is 52J/g, is processed into the bed clothes liner with it, has good temp regulating function, thereby can make bed clothes lighter, thinner, and bedding is more comfortable.
Embodiment 3 is with 1, and intrinsic viscosity is that 0.69 poly-glutaric acid hexylene glycol (32 ℃ of fusing points) is a polymer A in the 2-dichloroethanes, and N-cyclohexyl-N '-diphenyl-para-phenylene diamine of adding 1% in polymer A and 1% zinc stearate; Fibrous polypropylene with melt index 25g/10Min is a polymer B; Polymer A is the island component of fiber, polymer B is the sea component of fiber, and the weight ratio of A and B is 5: 5, adopts Φ 90 * 48 holes, the fabric of island-in-sea type composite spinneret of orifice diameter 0.25mm, 260 ℃ of following fusions,, obtain the P0Y silk of filament number 5.1dtex with 2500 meters/minute hauling speed spinning, 3.0 times of drawing-offs altogether on hot plate 65～70 ℃ water-bath and 110 ℃, obtain filament number 1.8dtex, fracture strength is 2.8CN/dtex, the fiber of extension at break 31%.
With this fiber knitted 210g/M that is processed into
2Knitted cloth, the more conventional COTTON FABRIC of its surface temperature at 40 ℃ of following clothes is low 4 ℃ after tested, the surface temperature of 10 ℃ of following clothes is higher than 3 ℃ of conventional COTTON FABRIC, available its is processed into knitted underwear trousers, nightwear skirt, when variation of ambient temperature, have good environmental adaptability and take comfortableness.
Embodiment 4 is that 4000 polyethylene glycol and dimethyl terephthalate (DMT), ethylene glycol are raw material with number-average molecular weight, zinc acetate and antimonous oxide are catalyst, it is poly terephthalic acid ethylene glycol-polyethylene glycol of 50% that polycondensation becomes the polyethylene glycol weight content, it was at 1: 1 phenol-1,1,2, intrinsic viscosity is 0.58 in the 2-tetrachloroethanes, as polymer A, and to add 1% number-average molecular weight therein be that 6000 polyethylene glycol was heat fusing and crossed cold crystallization and prevent agent; With at 1: 1 phenol-1,1,2, intrinsic viscosity is that 0.68 poly terephthalic acid ethylene glycol is polymer B in the 2-tetrachloroethanes, and adds the tetrabromo biphenyl ether of 2% antimonous oxide and 3% and 1% ultraviolet absorbent UV-531 in polymer B.Polymer A is the sandwich layer of fiber, and polymer B is the sheath layer of fiber, and the weight ratio of A and B is 6: 4; Adopt Φ 160 * 500 holes, length and width are respectively the rectangular core sheath composite spinneret of 0.20mm * 0.15mm, 290 ℃ of following fusions, with 800 meters/minute winding speed spinning, obtain the undrawn yarn that filament number is 7.2dtex, behind the boundling, 3.5 times of drawing-offs altogether in the steam bath of 6 5～70 ℃ water-baths and 125 ℃ are after machine crimp, loose HEAT SETTING, be cut to 38mm, filament number is the staple fibre of 2.1dtex, and the filament fracture strength is 2.9CN/dtex, extension at break 33%.
Be spun into 27 count yarns with this fiber, through the woven 220g/M that is processed into
2Woven cloth, it is 25J/g in fusion of 35 ℃ heat absorption, the crystallization heat release under 5 ℃ is 22J/g, limited oxygen index is 27%.This knitted cloth is used as the fire-entry suit internal layer, has adjustment effect preferably and flame retardant effect when wearing.
Embodiment 5 is with 1,6-adipic acid, 1,5-pentanediol, number-average molecular weight are that 4000 polyethylene glycol is a raw material, under tetrabutyl titanate catalysis, polycondensation obtains 1, and inherent viscosity is poly-adipic acid pentanediol-macrogol ester of 0.68 in the 2-dichloroethane solution, with this aliphatic polyester ether is polymer A, and add 2 therein, 6-di-t-butyl-4-normal-butyl phenol and N, N '-diphenyl-para-phenylene diamine each 0.1%.With at 1: 1 phenol-1,1,2, intrinsic viscosity is that 0.58 PA 66 is a polymer B in the 2-tetrachloroethanes.With the polymer A is the island component of fiber, polymer B is the sea component of fiber, the weight ratio of polymer A and polymer B is 3: 7, adopt Φ 90 * 48 holes, diameter be the fabric of island-in-sea type spinnerets of 0.28mm at 270 ℃ of following melt spinnings, winding speed is 1500 meters/Min, obtain the long filament that filament number is 7.1dtex, handling the fiber number that obtains finished fiber through further drafting forming is 2.1dtex, tensile break strength 3.2CN/dtex, extension at break 28%.
The knitted cloth that this fiber obtains after knitting has the caloric receptivity of 18J/g under 34 ℃, its surface temperatures are high 2.1 ℃ than comparison fabric down at 10 ℃.
Claims (9)
1, a kind of fiber that has two-way temp regulating function with variation of ambient temperature, it is characterized in that it is the principal component of fibre core or island component with particular thermal thermoplastic polymer A, with the conventional thermoplastic polymer B principal component that is fibrous sheath or sea component, make through the composite molten spin processes, described particular thermal thermoplastic polymer A is meant that melt temperature is 20～40 ℃, more than the melting heat 30J/g, 20～5 ℃ of crystallization temperatures, the thermoplastic polymer that crystallization heat 30J/g is above; Described conventional thermoplastic polymer B refers to melt temperature at the thermoplastic polymer more than 150 ℃, and the weight ratio of polymer A and polymer B is 2～8: 8～2.
2, fiber according to claim 1, the weight ratio that it is characterized in that polymer A and polymer B is 4～6: 6～4.
3, fiber according to claim 1 and 2 is characterized in that described thermoplastic polymer A comprises a kind of in the following substances: polyethers, aliphatic polyester or aromatic polyester ether.
4, fiber according to claim 3 is characterized in that described polyethers is meant that molecular weight is 600～4000 polyethylene glycol and polytetramethylene glycol; Aliphatic polyester is meant poly-own diester of glutaric acid and poly-adipic acid penta diester; Aromatic polyester ether is meant raw material pfpe molecule amount more than 1000, and the polyethers percentage by weight is the poly terephthalic acid ethylene glycol-polyethylene glycol more than 45.
5,, it is characterized in that also being added with among the described thermoplastic polymer A heat fusing of crossing that accounts for its weight 0.1～3% and prevent from agent and cross cold crystallization to prevent agent according to claim 1,2 or 4 described fibers.
6, fiber according to claim 5, it is characterized in that heat fusing prevented from agent and cross cold crystallization to prevent that agent from can be respectively a kind of in the following substances or two kinds: titanium oxide, zinc stearate, 2,6-di-t-butyl-4-normal-butyl phenol, N-cyclohexyl-N '-diphenyl-para-phenylene diamine, molecular weight are more than or equal to 4000 polyethylene glycol and polytetramethylene glycol.
7,, it is characterized in that the cross sectional shape of fiber is circle, trilobal or rectangle according to claim 1,2,4 or 6 described fibers.
8, the goods of making through conventional spinning or unconventional spinning process according to claim 1,2,4 or 6 described fibers.
9, the goods made through routine weaving or unconventional weaving techniques of fiber according to claim 7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96105229A CN1051115C (en) | 1996-05-22 | 1996-05-22 | Temp. regulating fibre and its products |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96105229A CN1051115C (en) | 1996-05-22 | 1996-05-22 | Temp. regulating fibre and its products |
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| Publication Number | Publication Date |
|---|---|
| CN1165877A CN1165877A (en) | 1997-11-26 |
| CN1051115C true CN1051115C (en) | 2000-04-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN96105229A Expired - Fee Related CN1051115C (en) | 1996-05-22 | 1996-05-22 | Temp. regulating fibre and its products |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325710C (en) * | 2002-12-17 | 2007-07-11 | 苗晓光 | Heat-storage bidirectional temperature-regulating cashmere product and preparing method thereof |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7160612B2 (en) * | 2000-09-21 | 2007-01-09 | Outlast Technologies, Inc. | Multi-component fibers having enhanced reversible thermal properties and methods of manufacturing thereof |
| US9434869B2 (en) | 2001-09-21 | 2016-09-06 | Outlast Technologies, LLC | Cellulosic fibers having enhanced reversible thermal properties and methods of forming thereof |
| CN101671901B (en) * | 2009-09-17 | 2011-05-18 | 宁波雅戈尔毛纺织染整有限公司 | Fabrication method of worsted fabric with function of temperature adjustment |
| CN101849753A (en) * | 2010-05-18 | 2010-10-06 | 南通居梦莱家用纺织品有限公司 | Temperature-regulating quilt core |
| CN102613759A (en) * | 2012-01-18 | 2012-08-01 | 天津工业大学 | Heat accumulation and temperature adjustment wig and preparation method thereof |
| CN102704037B (en) * | 2012-07-03 | 2014-01-22 | 天津工业大学 | Heat accumulating temperature regulating fiber and method for preparing same |
| CN113930860B (en) * | 2021-09-22 | 2023-09-01 | 暖博士新材料（无锡）有限公司 | shellfish nanofiber |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987007854A1 (en) * | 1986-06-19 | 1987-12-30 | United States Of America, Represented By The Secre | Temperature adaptable textile fibers and method of preparing same |
| US7371779B2 (en) * | 2001-07-04 | 2008-05-13 | The Secretary Of State For Defense Science And Technology | Synergistic compositions of N-acylhomoserine lactones and 4-quinolones |
| US7491905B2 (en) * | 2004-12-21 | 2009-02-17 | Symbol Technologies, Inc. | Scanner with vertical plate force detection and compensation |
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1996
- 1996-05-22 CN CN96105229A patent/CN1051115C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1987007854A1 (en) * | 1986-06-19 | 1987-12-30 | United States Of America, Represented By The Secre | Temperature adaptable textile fibers and method of preparing same |
| US7371779B2 (en) * | 2001-07-04 | 2008-05-13 | The Secretary Of State For Defense Science And Technology | Synergistic compositions of N-acylhomoserine lactones and 4-quinolones |
| US7491905B2 (en) * | 2004-12-21 | 2009-02-17 | Symbol Technologies, Inc. | Scanner with vertical plate force detection and compensation |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325710C (en) * | 2002-12-17 | 2007-07-11 | 苗晓光 | Heat-storage bidirectional temperature-regulating cashmere product and preparing method thereof |
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| CN1165877A (en) | 1997-11-26 |
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