CN105093868A - Powdered ink for printing red-head document - Google Patents

Powdered ink for printing red-head document Download PDF

Info

Publication number
CN105093868A
CN105093868A CN201410458548.0A CN201410458548A CN105093868A CN 105093868 A CN105093868 A CN 105093868A CN 201410458548 A CN201410458548 A CN 201410458548A CN 105093868 A CN105093868 A CN 105093868A
Authority
CN
China
Prior art keywords
red
additive
pigment
printing
adhesive resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201410458548.0A
Other languages
Chinese (zh)
Inventor
张明熠
姜真
冯华栋
刁运佳
涂海平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN ZHONGHUAN TCOA ELECTRONICS CO Ltd
Original Assignee
TIANJIN ZHONGHUAN TCOA ELECTRONICS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TIANJIN ZHONGHUAN TCOA ELECTRONICS CO Ltd filed Critical TIANJIN ZHONGHUAN TCOA ELECTRONICS CO Ltd
Priority to CN201410458548.0A priority Critical patent/CN105093868A/en
Publication of CN105093868A publication Critical patent/CN105093868A/en
Withdrawn legal-status Critical Current

Links

Abstract

The invention relates to a powdered ink for printing a red-head document. Adhesive resin is a styrene-acrylic copolymer, a pigment is bronze red C, a charge modifier is selected from a quaternary ammonium salt, an internal additive is selected from low-molecule polypropylene wax, an external additive is selected from at least one of hydrophobic silicon dioxide, aluminum oxide, zinc stearate, titanium dioxide and strontium titanate, and the powered ink comprises the following constituents based on percent by weight: 78-90% of adhesive resin, 3-10% of pigment, 1-8% of charge modifier, 0.1-0.8% of internal additive and 0.1-4% of external additive. In the powdered ink, the bronze red C is selected as the pigment of the powdered ink, the color of printed characters and patterns is vivid, and the powdered ink has the characteristics of displaying strong golden color; moreover, the golden color is durable and firm, the problems of color cast on red output, inaccurate chromatography and the like during printing the red-head document are solved, "red" characteristics particularly belonging to the red-head document is accurately represented, and a better visual effect can be obtained.

Description

For printing the ink powder of official document
Technical field
The present invention relates to the technical field of ink powder of laser printer, is a kind of ink powder for printing official document specifically.
Background technology
Official document normally government organs or higher level to the various notices of subordinate, as the important channel assigned of resolving, rigorous, be solemnly official document export important feature, so all very high to the accuracy requirement of the requirement of color, output in the printing of official document.But the red ink powder that existing laser printer is used, all there is aberration in its color, cannot get required color effect, and printing precision is also not fully up to expectations usually.For meet color requirement and select digital printing equipment then needs drop into excessive cost, as print job outsourcing obviously not met again the security requirements to file.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of ink powder for printing official document.
The technical scheme that the present invention takes for the technical matters existed in solution known technology is:
Ink powder for printing official document of the present invention, by adhesive resin, pigment, charge adjusting agent, in add agent and additive forms, above-mentioned adhesive resin is Styrene-acrylic copolymer, pigment is everbright red toner C, described charge adjusting agent selects quaternary ammonium salt, add agent in described and select low-molecular polypropylene wax, described additive selects at least one in hydrophobic silica, aluminium oxide, zinc stearate, titania and strontium titanates, and the percentage by weight of above-mentioned each component is:
Adhesive resin 78 ~ 90%,
Pigment 3 ~ 10%,
Charge adjusting agent 1 ~ 8%,
Inside add agent 0.1 ~ 0.8%,
Additive 0.1 ~ 4%.
The present invention can also adopt following technical measures:
In adhesive resin, the mean molecular weight of Styrene-acrylic copolymer is 10 ~ 200,000, melting index MI is 1.5 ~ 5.5.
The hydrophobic deg of described hydrophobic silica is 20 ~ 40.
The particle diameter of described strontium titanates is 0.1 ~ 1.5 μm.
The advantage that the present invention has and good effect are:
Of the present invention for printing in the ink powder of official document, select everbright red toner C as the pigment of ink powder, the word printed and pattern bright-colored, have the advantages that to show strong golden light colour, and golden light is comparatively firmly durable, solves the problems such as redness when printing official document exports colour cast, chromatography is forbidden, easily can show the highdensity figure of high-resolution and word, especially distinctive for official document " red " color characteristic is accurately showed, better visual effect can be obtained.
Embodiment
Referring to embodiment, the present invention will be described in detail.
Embodiment 1, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 1.5 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects particle diameter to be 1.5 μm of strontium titanates, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 90%,
Everbright red toner C accounts for 6%,
Quaternary ammonium salt accounts for 3%,
Low-molecular polypropylene wax accounts for 0.8%,
Strontium titanates accounts for 0.2%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.6l μm, less than 5.04 μm: 23.57%,
Volume mean diameter: 9.37 μm, more than 16.O μm: 1.17%
Added in above-mentioned classification product by strontium titanates additive, namely abundant mixing obtains required ink powder.
Embodiment 2, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 5.5 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects the potpourri of hydrophobic silica, aluminium oxide, zinc stearate, titania and strontium titanates as additive, and wherein strontium titanates particle diameter is 1.2 μm, the hydrophobic deg of hydrophobic silica is 30, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 78%,
Everbright red toner C accounts for 10%,
Quaternary ammonium salt accounts for 7.8%,
Low-molecular polypropylene wax accounts for 0.2%,
Additive accounts for 4%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.56 μm, less than 5.04 μm: 25.21%,
Volume mean diameter: 9.33 μm more than 16.O μm: 1.10%
Added in above-mentioned classification product by additive potpourri, namely abundant mixing obtains required ink powder.
Embodiment 3, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 3.0 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects the potpourri of hydrophobic silica and strontium titanates as additive, and wherein strontium titanates particle diameter is 0.1 μm, the hydrophobic deg of hydrophobic silica is 20, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 88.8%,
Everbright red toner C accounts for 3%,
Quaternary ammonium salt accounts for 8%,
Low-molecular polypropylene wax accounts for 0.1%,
Additive accounts for 0.1%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.66 μm, less than 5.04 μm: 23.81%,
Volume mean diameter: 9.35 μm more than 16.O μm: 1.20%
Added in above-mentioned classification product by additive potpourri, namely abundant mixing obtains required ink powder.
Embodiment 4, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 4.0 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects hydrophobic silica as additive, and the hydrophobic deg of hydrophobic silica is 25, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 81%,
Everbright red toner C accounts for 8%,
Quaternary ammonium salt accounts for 7.5%,
Low-molecular polypropylene wax accounts for 0.5%,
Additive accounts for 3%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.73 μm, less than 5.04 μm: 24.87%,
Volume mean diameter: 9.54 μm more than 16.O μm: 1.32%
Added in above-mentioned classification product by additive potpourri, namely abundant mixing obtains required ink powder.
Embodiment 5, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 3.5 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects titania, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 85%,
Everbright red toner C accounts for 6%,
Quaternary ammonium salt accounts for 6.4%,
Low-molecular polypropylene wax accounts for 0.6%,
Additive accounts for 2%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.56 μm, less than 5.04 μm: 25.63%,
Volume mean diameter: 9.44 μm more than 16.O μm: 1.18%
Added in above-mentioned classification product by additive potpourri, namely abundant mixing obtains required ink powder.
Embodiment 6, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 3.0 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects zinc stearate, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 84%,
Everbright red toner C accounts for 6.1%,
Quaternary ammonium salt accounts for 7.3%,
Low-molecular polypropylene wax accounts for 0.5%,
Additive accounts for 2.1%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.67 μm, less than 5.04 μm: 24.38%,
Volume mean diameter: 9.37 μm more than 16.O μm: 1.14%
Added in above-mentioned classification product by additive potpourri, namely abundant mixing obtains required ink powder.
Embodiment 7, of the present invention for printing in the ink powder of official document, adhesive resin to be MI be 3.5 Styrene-acrylic copolymer, pigment is everbright red toner C, charge adjusting agent selects quaternary ammonium salt, inside add agent and select low-molecular polypropylene wax, additive selects aluminium oxide, and the percentage by weight of above-mentioned each component is:
Styrene-acrylic copolymer accounts for 83%,
Everbright red toner C accounts for 7%,
Quaternary ammonium salt accounts for 7.4%,
Low-molecular polypropylene wax accounts for 0.7%,
Additive accounts for 1.9%.
After Styrene-acrylic copolymer, everbright red toner C, quaternary ammonium salt, the mixing of low-molecular polypropylene wax, use special high precision mixing facilities constant temperature mixing, the material such as polypropylene, charge adjusting agent is distributed in potpourri equably, raw material after mixing, then obtains the classification product of following size-grade distribution after cooling, precomminution, coarse crushing and Crushing of Ultrafine, classification:
Number average diameter: 5.53 μm, less than 5.04 μm: 25.62%,
Volume mean diameter: 9.34 μm more than 16.O μm: 1.24%
Added in above-mentioned classification product by additive potpourri, namely abundant mixing obtains required ink powder.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, although the present invention with preferred embodiment openly as above, but, and be not used to limit the present invention, any those skilled in the art, do not departing within the scope of technical solution of the present invention, certainly the technology contents of announcement can be utilized to make a little change or modification, become the Equivalent embodiments of equivalent variations, in every case be the content not departing from technical solution of the present invention, according to any simple modification that technical spirit of the present invention is done above embodiment, equivalent variations and modification, all belong in the scope of technical solution of the present invention.

Claims (4)

1. one kind for printing the ink powder of official document, by adhesive resin, pigment, charge adjusting agent, in add agent and additive forms, it is characterized in that: above-mentioned adhesive resin is Styrene-acrylic copolymer, pigment is everbright red toner C, described charge adjusting agent selects quaternary ammonium salt, add agent in described and select low-molecular polypropylene wax, described additive selects at least one in hydrophobic silica, aluminium oxide, zinc stearate, titania and strontium titanates, and the percentage by weight of above-mentioned each component is:
Adhesive resin 78 ~ 90%,
Pigment 3 ~ 10%,
Charge adjusting agent 1 ~ 8%,
Inside add agent 0.1 ~ 0.8%,
Additive 0.1 ~ 4%.
2. the ink powder for printing official document according to claim 1, is characterized in that: in adhesive resin, the mean molecular weight of Styrene-acrylic copolymer is 10 ~ 200,000, melting index MI is 1.5 ~ 5.5.
3. the ink powder for printing official document according to claim 1, is characterized in that: the hydrophobic deg of described hydrophobic silica is 20 ~ 40.
4. the ink powder for printing official document according to claim 1, is characterized in that: the particle diameter of described strontium titanates is 0.1 ~ 1.5 μm.
CN201410458548.0A 2014-09-11 2014-09-11 Powdered ink for printing red-head document Withdrawn CN105093868A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410458548.0A CN105093868A (en) 2014-09-11 2014-09-11 Powdered ink for printing red-head document

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410458548.0A CN105093868A (en) 2014-09-11 2014-09-11 Powdered ink for printing red-head document

Publications (1)

Publication Number Publication Date
CN105093868A true CN105093868A (en) 2015-11-25

Family

ID=54574604

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410458548.0A Withdrawn CN105093868A (en) 2014-09-11 2014-09-11 Powdered ink for printing red-head document

Country Status (1)

Country Link
CN (1) CN105093868A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106444309A (en) * 2016-07-27 2017-02-22 北京嘉和顶新科贸有限公司 Special toner for red tape and digital printing device and method
CN109613805A (en) * 2018-12-28 2019-04-12 天津市中环天佳电子有限公司 A kind of non magnetic elecrtonegativity duplicator color toner and preparation method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1718647A (en) * 2005-07-09 2006-01-11 胡荣华 Printing ink
CN101196699A (en) * 2006-12-06 2008-06-11 北京国信防伪技术有限公司 Carbon powder especially for credit bill and certificate and its manufacturing process
CN101788774A (en) * 2009-11-13 2010-07-28 无锡佳腾磁性粉有限公司 Red durability anti-counterfeit developer of colored laser printer and preparation method thereof
CN103497580A (en) * 2013-09-17 2014-01-08 韦丽梅 Manufacturing method of golden red ink for plastic printing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1718647A (en) * 2005-07-09 2006-01-11 胡荣华 Printing ink
CN101196699A (en) * 2006-12-06 2008-06-11 北京国信防伪技术有限公司 Carbon powder especially for credit bill and certificate and its manufacturing process
CN101788774A (en) * 2009-11-13 2010-07-28 无锡佳腾磁性粉有限公司 Red durability anti-counterfeit developer of colored laser printer and preparation method thereof
CN103497580A (en) * 2013-09-17 2014-01-08 韦丽梅 Manufacturing method of golden red ink for plastic printing

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106444309A (en) * 2016-07-27 2017-02-22 北京嘉和顶新科贸有限公司 Special toner for red tape and digital printing device and method
CN109613805A (en) * 2018-12-28 2019-04-12 天津市中环天佳电子有限公司 A kind of non magnetic elecrtonegativity duplicator color toner and preparation method

Similar Documents

Publication Publication Date Title
CN103788564A (en) Light-sensitive color-change 3D printing lines and production method thereof
CN103102773B (en) There is the powder coating of high-wear resistance
CN102382507B (en) Hydrophilic ink for intaglio printing on surfaces of aluminum foils and preparation method thereof
CN105324446A (en) Heat sensitive tamper indicating markings
CN102649890B (en) Solvent type optically variable anti-counterfeiting ink applicable to different printing modes
US20170218203A1 (en) Yellow Colorant Composition Having Improved Chroma And Hue, Pigment Composition Therefor, And Use Thereof
CN104204741A (en) Coating color evaluation method
CN105093868A (en) Powdered ink for printing red-head document
TWI686354B (en) Near-infrared absorbing fine particle dispersion liquid and its manufacturing method, anti-counterfeit ink composition using near-infrared absorbing fine particle dispersion liquid, and anti-counterfeiting printed matter using near-infrared absorbing fine particle dispersion liquid
EP1521128B1 (en) Coloured magnetically attractable toner powder
DE102016217348B4 (en) COLOR SHIFT MATERIAL FOR THREE-DIMENSIONAL PRINTING, THREE-DIMENSIONAL PRODUCT AND METHOD FOR THREE-DIMENSIONAL PRINTING
CN102876126B (en) Gravure fluorescent infrared matching printing ink for engraved intaglio plate printing machine
CN102998916A (en) Ground color-free three-layer coating process and photoconductor drum prepared by adopting same
CN104293046B (en) A kind of goth black automobile coating of one-component blue phase and preparation method thereof
CN104194561B (en) A kind of slim salt spray resistance automobile Antirust epoxy priming paint and preparation method thereof
CN103911036B (en) Silk screen printing bright black ink
CN101320229B (en) Colorful ink powder and preparation method thereof
CN103529669A (en) Non-magnetic single-component electropositive color matching agent for laser printer
US9139768B2 (en) Variable data printing for security purposes using ceramic sub-micron infrared-luminescent particles in inkjet ink
CN103627251A (en) Anti-forgery ink
CN101864209A (en) Temperature sensitive ink
CN102998918B (en) Four-layer coating process of organic photoconductor drum and organic photoconductor drum prepared by adopting same
CN105093870A (en) Fluorescent anti-counterfeiting ceramic toner
CN108239335A (en) Plastic matrix with luminosity and preparation method thereof
US9714352B2 (en) Dispersed white inks

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20151125