CN105087952A - Method for removing sulfur and gathering copper, silver and antimony from sulfur-containing multi-metal smelting slag through vacuum distillation - Google Patents
Method for removing sulfur and gathering copper, silver and antimony from sulfur-containing multi-metal smelting slag through vacuum distillation Download PDFInfo
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- CN105087952A CN105087952A CN201510572688.5A CN201510572688A CN105087952A CN 105087952 A CN105087952 A CN 105087952A CN 201510572688 A CN201510572688 A CN 201510572688A CN 105087952 A CN105087952 A CN 105087952A
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- sulfur
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- antimony
- slag
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 52
- 239000002184 metal Substances 0.000 title claims abstract description 52
- 239000002893 slag Substances 0.000 title claims abstract description 51
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 49
- 239000010949 copper Substances 0.000 title claims abstract description 48
- 238000003723 Smelting Methods 0.000 title claims abstract description 47
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000011593 sulfur Substances 0.000 title claims abstract description 46
- 229910052802 copper Inorganic materials 0.000 title abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract description 28
- 229910052709 silver Inorganic materials 0.000 title abstract description 10
- 239000004332 silver Substances 0.000 title abstract description 10
- 229910052787 antimony Inorganic materials 0.000 title abstract description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title abstract description 4
- 238000005292 vacuum distillation Methods 0.000 title abstract 4
- 238000004821 distillation Methods 0.000 claims abstract description 12
- 229910001245 Sb alloy Inorganic materials 0.000 claims abstract description 11
- 239000002140 antimony alloy Substances 0.000 claims abstract description 11
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 10
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 8
- LGFYIAWZICUNLK-UHFFFAOYSA-N antimony silver Chemical compound [Ag].[Sb] LGFYIAWZICUNLK-UHFFFAOYSA-N 0.000 claims description 12
- 238000006477 desulfuration reaction Methods 0.000 claims description 12
- 230000023556 desulfurization Effects 0.000 claims description 12
- SGJOWJWUVVFZJV-UHFFFAOYSA-N [Cu].[Ag].[Sb] Chemical group [Cu].[Ag].[Sb] SGJOWJWUVVFZJV-UHFFFAOYSA-N 0.000 claims description 10
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- 239000003818 cinder Substances 0.000 claims description 2
- 239000011133 lead Substances 0.000 abstract description 33
- 239000002994 raw material Substances 0.000 abstract description 11
- 238000009833 condensation Methods 0.000 abstract description 10
- 230000005494 condensation Effects 0.000 abstract description 10
- 229910001316 Ag alloy Inorganic materials 0.000 abstract description 4
- 229910000881 Cu alloy Inorganic materials 0.000 abstract description 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 3
- 238000005272 metallurgy Methods 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract description 2
- 229910000796 S alloy Inorganic materials 0.000 abstract 1
- -1 ferrous metals Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 10
- 239000000498 cooling water Substances 0.000 description 10
- 239000007859 condensation product Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000007664 blowing Methods 0.000 description 5
- 125000000101 thioether group Chemical group 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 230000001698 pyrogenic effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WIKSRXFQIZQFEH-UHFFFAOYSA-N [Cu].[Pb] Chemical compound [Cu].[Pb] WIKSRXFQIZQFEH-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 2
- YCKOAAUKSGOOJH-UHFFFAOYSA-N copper silver Chemical compound [Cu].[Ag].[Ag] YCKOAAUKSGOOJH-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241000722270 Regulus Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- JEMGLEPMXOIVNS-UHFFFAOYSA-N arsenic copper Chemical compound [Cu].[As] JEMGLEPMXOIVNS-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- LWUVWAREOOAHDW-UHFFFAOYSA-N lead silver Chemical compound [Ag].[Pb] LWUVWAREOOAHDW-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The invention relates to a method for removing sulfur and gathering copper, silver and antimony from sulfur-containing multi-metal smelting slag through vacuum distillation and belongs to the technical field of thermometallurgy and vacuum metallurgy of non-ferrous metals. Firstly, the sulfur-containing multi-metal smelting slag is placed in a vacuum furnace; distillation is conducted for 3-8 h under the conditions that the intensity of pressure in the furnace is 20-400 Pa and the distillation temperature is 1000-1250 DEG C; sulfide comprising 8-30wt% of S and metal alloy are obtained on a primary condenser; lead bullion comprising 85-95wt% of Pb and less than 2% of copper is obtained on a secondary condenser; and residues are copper, silver and antimony alloy. According to the method, the sulfur-containing multi-metal smelting slag is used as raw materials, and valuable metals of copper, silver and antimony in the sulfur-containing multi-metal smelting slag are gathered through vacuum distillation; no reagent needs to be added in the process, fractional condensation is conducted on the sulfur-containing multi-metal smelting slag through vacuum distillation, and lead bullion condensate comprising less than 2% of copper, the sulfide comprising 8%-30% of S, the metal alloy and the copper, silver and antimony alloy comprising less than 1% of Pb and less than 0.5% of S can be obtained.
Description
Technical field
The present invention relates to a kind of method of vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, belong to non-ferrous metal pyrometallurgy and vacuum metallurgy technology field.
Background technology
Sulfur-bearing many Metal smeltings slag is lead bullion liquation decoppering and the sulfur-bearing metallurgical slag adding sulphur copper removal process and produce.In liquation decoppering process, the reduction of the solubility with temperature of Cu in plumbous liquid and reducing, when plumbous liquid temp drops to below 1225K, the crystallization of precipitation is not fine copper, but containing the copper-lead sosoloid of Pb, it floats on plumbous liquid level with solid state.As simultaneously in lead bullion and Sb and Cu formation copper arsenic and copper-lead compound, and the impurity element such as nearly all Fe, Ni, Co, S, also float on plumbous liquid level because being insoluble to lead.Lead bullion is after liquation decoppering, and the copper remained in lead generally adopts the method removing adding sulphur copper removal, the Cu of formation
2s density ratio lead is little, is insoluble to again in lead, floats on plumbous liquid level in solid dross state.In sulfur-bearing many Metal smeltings slag, lead tolerance is very high but can not directly enter plumbous refinery practice, because the character of the impurity such as Cu, Ag, Sb, S, As, Fe, Ni, Co wherein to lead has a great impact, such as make its hardness increase toughness to reduce, erosion resistance weakens.Therefore sulfur-bearing many Metal smeltings slag otherwise processed is tackled, and the various valuable metal of synthetical recovery.
At present, sulfur-bearing many Metal smeltings slag generally adopts soda iron chip filter to process, to reclaim copper, lead and precious metal wherein.Conventional pyrogenic process recovery process also has reverberatory smelting method, blast-furnace method, converter smelting process, electric furnace smelting process.Wet processing has pickling process, ammonia leaching process and alkaline leaching.The lead bullion that pyrogenic process recovery process obtains returns refining, and copper matte regulus reclaims copper, and pyrogenic process recovery process energy consumption is high, long flow path, noble metal dispersion, and production cost is high.Wet recycling process produces a large amount of waste water, waste liquid, adds the cost of sewage disposal.In addition, sulfur-bearing many Metal smeltings slag lead skim that meeting output is a large amount of when leaching, carrys out difficulty greatly to liquid-solid decoupled band.
For method process sulfur-bearing many Metal smeltings slag of vacuum distilling, Chinese invention patent application publication No. CN102676832A discloses a kind of copper dross slag vacuum distilling separating copper and plumbous method, it provide a kind of copper dross slag vacuum distilling separating copper and plumbous method, copper dross slag is placed in vacuum environment, add reductive agent coke powder, pressure be 5-200Pa, temperature carries out fractionation by distillation 30-180 minute under being the condition of 900-1300 DEG C, Pb and PbS in copper dross slag enters gas phase under distillation, after condensation, namely obtain lead bullion; Cu in copper dross slag
2s, Cu stay in distillation residue matte, thus realize being separated of copper and lead in copper dross slag.Chinese invention patent application publication No. 102373336A discloses a kind of method being separated copper and silver in refining plumbous product copper dross slag, provide a kind of method being separated copper and silver in refining plumbous product copper dross slag, it is solid alloy material that refining lead is produced copper dross slag through reduction treatment, 5Pa is less than, 1100 ~ 1200 DEG C, insulation 30 ~ 60min at pressure, 1400 ~ 1600 DEG C, insulation 1 ~ 3h, the volatile matter obtained is pb-ag alloy, and resistates is copper alloy; Again pb-ag alloy is entered conventional plumbous smelting procedure or electrorefining operation as raw material, silver is enriched in the anode sludge, is namely recycled silver; Copper alloy, directly as raw material, is namely recycled metallic copper in conventional manner.
The present invention is identical with the method that appeal patent is studied, and all have employed the method for vacuum distilling, but there is the difference of many keys, one, the present invention directly carries out vacuum distilling concentration of valuable metals to sulfur-bearing many Metal smeltings slag, does not need to adopt coke powder reduction, simplifies technical process; Its two, the present invention is to the particle diameter of handled sulfur-bearing many Metal smeltings slag and shape not requirement, and without the need to ball milling pretreatment or be reduced into solid materials, adaptability to raw material is strong; Its three, experimental size of the present invention is the experimental size that 500Kg/ stove is far longer than patent CN102676832A2.5Kg/ stove and patent 102373336A20Kg; They are four years old, what the present invention adopted is the separation that vacuum distilling fractional condensation technology not only achieves the lead bronze described in patent CN102676832A, also achieve being separated of metal and metallic sulfide, and the present invention is not separated to copper silver and has been separated larger difference with the copper silver of patent 102373336A.
To sum up, the present invention directly adopts the method desulfurization enriching Cu silver antimony of vacuum distilling to sulfur-bearing many Metal smeltings slag, metallic sulfide and metal is carried out fractional condensation, achieves being separated of metal and metallic sulfide, and being separated of lead and copper silver antimony, simplify technical process.Both improve effective rate of utilization and the economic benefit of resource, alleviated again the pollution to environment, and had and smelt the advantages such as flow process is short, environmentally friendly, labor condition is good, meet energy-conservation and requirement that is cleaner production.
Summary of the invention
For above-mentioned prior art Problems existing and deficiency, the invention provides a kind of method of vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag.The present invention with sulfur-bearing many Metal smeltings slag for raw material, by vacuum distilling enrichment valuable metal copper, silver, antimony wherein, this technique is without the need to adding any reagent, sulfur-bearing many Metal smeltings slag is by vacuum distilling fractional condensation, cupric can be obtained lower than the lead bullion condensation product of 2%, be sulfide and the metal alloy of 8 ~ 30% containing S, and contain Pb lower than 1%, containing S lower than 0.5% copper silver-antimony alloy, the present invention is achieved through the following technical solutions.
A kind of method of vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, its concrete steps are as follows: first by sulfur-bearing many Metal smeltings slag as in vacuum oven, in stove pressure be 20 ~ 400Pa, distillation temperature be under 1000 ~ 1250 DEG C of conditions distill 3 ~ 8h, first-stage condenser obtains the sulfide containing S8 ~ 30wt% and metal alloy, on secondary condenser obtain containing Pb85 ~ 95wt%, cupric lower than 2% lead bullion, can directly enter lead bullion electrorefining, residue is copper silver-antimony alloy.
Described sulfur-bearing many Metal smeltings cinder ladle draws together following mass percent component: Pb40 ~ 80%, Cu10 ~ 25%, Ag100 ~ 4000g/t, Sb5 ~ 30%, S<10%, As<10%.
Described vacuum oven list stove treatment capacity is 500Kg/ stove.
Specific embodiment of the invention scheme is: be directly placed in vacuum oven by sulfur-bearing many Metal smeltings slag raw material, opens vacuum pump and recirculated cooling water, pressure is evacuated to highest attainable vacuum 20Pa; Then open heater switch, make in-furnace temperature rise to required experimental temperature, pressure is 20 ~ 400Pa, constant temperature certain hour, and one-level condensation product is sulfide and metal alloy, and B-grade condensation thing is lead bullion, and the resistates naturally cooling in crucible is copper silver-antimony alloy; After distillation terminates, close heater switch, continue logical circulating cooling water cooling, when furnace temperature is down to below 100 DEG C, blowing out is opened vacuum oven and is taken out volatile matter and residue.
Described residue is copper silver-antimony alloy, and being 35 ~ 70wt% containing Cu, is 15 ~ 50wt% containing Sb, containing S<1%, is 4000 ~ 10000g/t containing Ag.The direct yield of the decreasing ratio of Pb and S is respectively 90% ~ 99%, 90 ~ 99%, Cu direct yields to be the direct yield of 95 ~ 99%, Ag be 85% ~ 97%, Sb is 85 ~ 95%.
The invention has the beneficial effects as follows:
1, adaptability to raw material of the present invention is strong, and the method can process various sulfur-bearing many Metal smeltings slag.
2, in described sulfur-bearing many Metal smeltings slag without the need to adding any reagent, be directly placed in process in vacuum oven, simplify technical process.
3, single stove processing power of the method vacuum oven used is 500Kg/ stove, and the cycle is 7 ~ 12 hours.
Accompanying drawing explanation
Fig. 1 is present invention process schema.
Embodiment
Below in conjunction with the drawings and specific embodiments, the invention will be further described.
Embodiment 1
As shown in Figure 1, be somebody's turn to do the method for vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, its concrete steps are as follows:
500Kg sulfur-bearing many Metal smeltings slag raw material is directly placed in vacuum oven, opens vacuum pump and recirculated cooling water, pressure is evacuated to highest attainable vacuum 20Pa; Then open heater switch, make in-furnace temperature rise to required 1250 DEG C, constant temperature distills 5 hours, furnace pressure 160Pa, and one-level condensation product is sulfide and metal alloy, and B-grade condensation thing is lead bullion, and the resistates naturally cooling in crucible is copper silver-antimony alloy; After distillation terminates, close heater switch, continue logical circulating cooling water cooling, when furnace temperature is down to below 100 DEG C, blowing out is opened vacuum oven and is taken out volatile matter and residue.Experimental result is shown in Table 1.
Table 1 sulfur-bearing many Metal smeltings slag vacuum distilling interpretation of result
。
Embodiment 2
As shown in Figure 1, be somebody's turn to do the method for vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, its concrete steps are as follows:
500Kg sulfur-bearing many Metal smeltings slag raw material is directly placed in vacuum oven, opens vacuum pump and recirculated cooling water, pressure is evacuated to highest attainable vacuum 20Pa; Then open heater switch, make in-furnace temperature rise to required 1050 DEG C, constant temperature distills 8 hours, furnace pressure 100Pa, and one-level condensation product is sulfide and metal alloy, and B-grade condensation thing is lead bullion, and the resistates naturally cooling in crucible is copper silver-antimony alloy; After distillation terminates, close heater switch, continue logical circulating cooling water cooling, when furnace temperature is down to below 100 DEG C, blowing out is opened vacuum oven and is taken out volatile matter and residue.Experimental result is shown in Table 2.
Table 2 sulfur-bearing many Metal smeltings slag vacuum distilling interpretation of result
。
Embodiment 3
As shown in Figure 1, be somebody's turn to do the method for vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, its concrete steps are as follows:
500Kg sulfur-bearing many Metal smeltings slag raw material is directly placed in vacuum oven, opens vacuum pump and recirculated cooling water, pressure is evacuated to highest attainable vacuum 20Pa; Then open heater switch, make in-furnace temperature rise to required 1000 DEG C, constant temperature distills 3 hours, furnace pressure 100Pa, and one-level condensation product is sulfide and metal alloy, and B-grade condensation thing is lead bullion, and the resistates naturally cooling in crucible is copper silver-antimony alloy; After distillation terminates, close heater switch, continue logical circulating cooling water cooling, when furnace temperature is down to below 100 DEG C, blowing out is opened vacuum oven and is taken out volatile matter and residue.Experimental result is shown in Table 3.
Table 3 sulfur-bearing many Metal smeltings slag vacuum distilling interpretation of result
。
Embodiment 4
As shown in Figure 1, be somebody's turn to do the method for vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, its concrete steps are as follows:
500Kg sulfur-bearing many Metal smeltings slag raw material is directly placed in vacuum oven, opens vacuum pump and recirculated cooling water, pressure is evacuated to highest attainable vacuum 20Pa; Then open heater switch, make in-furnace temperature rise to required 1100 DEG C, constant temperature distills 5 hours, furnace pressure 400Pa, and one-level condensation product is sulfide and metal alloy, and B-grade condensation thing is lead bullion, and the resistates naturally cooling in crucible is copper silver-antimony alloy; After distillation terminates, close heater switch, continue logical circulating cooling water cooling, when furnace temperature is down to below 100 DEG C, blowing out is opened vacuum oven and is taken out volatile matter and residue.Experimental result is shown in Table 4.
Table 4 sulfur-bearing many Metal smeltings slag vacuum distilling interpretation of result
Below by reference to the accompanying drawings the specific embodiment of the present invention is explained in detail, but the present invention is not limited to above-mentioned embodiment, in the ken that those of ordinary skill in the art possess, various change can also be made under the prerequisite not departing from present inventive concept.
Claims (3)
1. the method for a vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag, it is characterized in that concrete steps are as follows: first by sulfur-bearing many Metal smeltings slag as in vacuum oven, in stove pressure be 20 ~ 400Pa, distillation temperature be under 1000 ~ 1250 DEG C of conditions distill 3 ~ 8h, first-stage condenser obtains the sulfide containing S8 ~ 30wt% and metal alloy, on secondary condenser obtain containing Pb85 ~ 95wt%, cupric lower than 2% lead bullion, residue is copper silver-antimony alloy.
2. the method for vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag according to claim 1, it is characterized in that: described sulfur-bearing many Metal smeltings cinder ladle draws together following mass percent component: Pb40 ~ 80%, Cu10 ~ 25%, Ag100 ~ 4000g/t, Sb5 ~ 30%, S<10%, As<10%.
3. the method for vacuum distilling desulfurization enriching Cu silver antimony from sulfur-bearing many Metal smeltings slag according to claim 1, is characterized in that: described vacuum oven list stove treatment capacity is 500Kg/ stove.
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CN107218809A (en) * | 2016-12-30 | 2017-09-29 | 郴州万墨环保科技有限公司 | A kind of many metal distillation temperature control condensed components evaporate single crude product vacuum drying oven |
CN108823427A (en) * | 2018-06-15 | 2018-11-16 | 昆明理工大学 | A method of lead is separated and recovered by lead-antimony alloy |
CN108842068A (en) * | 2018-06-15 | 2018-11-20 | 昆明理工大学 | A kind of method of refining of lead sponge |
RU2693670C1 (en) * | 2018-05-07 | 2019-07-03 | Акционерное общество "Уралэлектромедь" | Method of processing silicate reduced slag by vacuum distillation, containing antimony, lead and silver |
RU2729521C1 (en) * | 2019-11-13 | 2020-08-07 | Акционерное общество "Уралэлектромедь" | Method of extracting tin from crude lead with refining from impurities |
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CN115011797A (en) * | 2022-06-07 | 2022-09-06 | 湖北大江环保科技股份有限公司 | Method for smelting copper by using vacuum distillation equipment |
CN116426766A (en) * | 2023-06-12 | 2023-07-14 | 昆明理工大学 | Method for extracting silver from complex lead bullion |
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