CN105072215B - A kind of PVD sprays androgynous plastic housing and preparation method thereof - Google Patents

A kind of PVD sprays androgynous plastic housing and preparation method thereof Download PDF

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Publication number
CN105072215B
CN105072215B CN201510291769.8A CN201510291769A CN105072215B CN 105072215 B CN105072215 B CN 105072215B CN 201510291769 A CN201510291769 A CN 201510291769A CN 105072215 B CN105072215 B CN 105072215B
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pvd
spraying
alloy
androgynous
spray
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CN105072215A (en
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谭炳元
金耀青
王岩良
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Guangdong Green Precision Parts Ltd By Share Ltd
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Guangdong Green Precision Parts Ltd By Share Ltd
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Abstract

The present invention relates to a kind of phone housings and preparation method thereof more particularly to a kind of PVD to spray androgynous plastic housing and preparation method thereof.The PVD sprays the metal alloy mobile phone shell that androgynous plastic housing is the injection molding of lower portion nesting, and the metal alloy mobile phone shell frame carries out PVD processing.Preparation method comprises the steps of: metal alloy phone housing die cast;The injection molding of metal alloy nesting;Primary spraying primer priming paint;Primary polishing;Secondary spraying primer priming paint;Secondary polishing;Spray-applied primer;Spray colored paint;Spray paint;CNC processes frame;PVD processes frame.The present invention in the interior injection moulding plastic material of alloy by solving the problems, such as the alloy because part processing technology is restricted prevent mobile phone shell is from using full alloy;It is sprayed by alloy surface, and carries out PVD on the basis of spraying to solve the oxidizable inaesthetic defect of alloy, enhance the corner volume wear-resisting property of shell and realize beautiful and durable combination.

Description

A kind of PVD sprays androgynous plastic housing and preparation method thereof
Technical field
The present invention relates to a kind of phone housings and preparation method thereof more particularly to a kind of PVD to spray androgynous plastic housing and its system Preparation Method.
Background technique
PVD (Physical Vapor Deposition) refers to and realizes that substance shifts using physical process, by atom or divides Son is transferred to the process on substrate surface by source.Its effect is can to make certain have specific characteristics can be (intensity height, wearability, scattered Hot, rotproofness etc.) particle be sprayed on the lower parent of performance so that parent have better performance.PVD is substantially square Method: it is evaporated in vacuo, sputtering, ion plating (hallow cathode deposition, HCD, hot cathode ion plating, arc ion plating, active reaction ion Plating, RF ion plating, direct-current discharge ion plating).
The material of present phone housing is mostly plastics, but pure plastic housing have the shortcomings that it is easily-deformable, frangible;With mobile phone shell Development, start more and more aluminium alloys and magnesium alloy case occur, Al alloy shell is durable, frivolous, good toughness, and texture is good, Use high-end, atmosphere, value-added content of product can be improved by improving grade.But Al alloys andMg alloys make because part processing technology is restricted Mobile phone shell cannot use all aluminium alloy, and it is oxidizable shorten the working life so that the use scope of Al alloys andMg alloys phone housing More limit to.Androgynous plastic housing is metal alloy and plastics by being integrally formed, at the same have the durable of metal alloy and The not oxidizable advantage of plastic housing, has a vast market foreground, not yet occurs in the market.
Chinese patent (CN201110390023.4) discloses a kind of metal surface treatment process, but just for made of metal The abrasion resistance and hardness of product is optimized, and does not explain to how the metal alloy of nested inside injection molding is handled, has one Fixed limitation.
Summary of the invention
The present invention is by solving alloy because part processing technology is restricted so that mobile phone in the interior injection moulding plastic material of alloy Shell cannot use the problem of full alloy;It is sprayed by alloy surface, and carries out PVD on the basis of spraying to solve alloy Oxidizable inaesthetic defect enhances the corner volume wear-resisting property of shell and realizes beautiful and durable combination.
To achieve the above object, the present invention provides a kind of androgynous plastic housing of PVD spraying, and it is interior that the PVD, which sprays androgynous plastic housing, The metal alloy mobile phone shell of portion's nesting injection molding, the metal alloy mobile phone shell frame carry out PVD processing.The metal alloy mobile phone Shell is more preferably Mg alloy mobile phone cover shell or aluminium alloy mobile phone shell.
A method of it preparing PVD and sprays androgynous plastic housing, comprise the steps of:
(1) metal alloy phone housing frame die cast, the melt temperature are 600 DEG C -850 DEG C, and mold temperature is 250 DEG C -350 DEG C, single product molding cycle is 15-25s;
(2) metal alloy nesting is molded, and first molded aluminum alloy frame is put into mold, is then moulded to mold Glue injection molding, the technique of plastic-injection is 260 DEG C -310 DEG C of melt temperature, mold temperature be 90 DEG C -120 DEG C, molding time be for 15-25s;
(3) primer priming paint is once sprayed;
(4) primary polishing;
(5) secondary spraying primer priming paint;
(6) secondary polishing;
(7) spray-applied primer;
(8) colored paint is sprayed;
(9) spray paint;
(10) CNC processes frame;
(11) PVD processes frame, using sputtering technology, successively carries out product piece installing, vacuumizes 5-15min, pass through high pressure Sputtering technology is bombarded to pass through with oxygen reaction into AL substrate aluminium2O3After be attached to product surface, time 5-15min, plating silicon, Silicon and oxygen generate SiO2After be attached to the product surface time be 5-10min, plate AF liquid medicine, time 5-15min.
Further, once sprayed in the step (3) primer priming paint with a thickness of 35-45 microns, for fill up close The gap thickness that gold and plastic cement combine.
Further, in the step (5) it is secondary spraying primer priming paint with a thickness of 35-45 micron, for fill up conjunction The gap thickness that gold and plastic cement combine.
Further, the priming paint of step (7) spraying is acrylate, with a thickness of 15-25 microns, for increasing Adhesive force.
Further, the colored paint of step (8) spraying is that acrylate adds pigment, with a thickness of 5-15 microns, is used In abundant product colour.
Further, the finishing coat of the step (9) spraying is polyurethane resin, and with a thickness of 20-30 microns, the finishing coat is Protective layer, for increasing wear-resisting and scratch resistant performance.
The present invention has the advantages that
1. by the interior injection moulding plastic material of alloy come solve alloy because part processing technology is restricted so that mobile phone shell not The problem of full alloy can be used;
2. being sprayed by alloy surface, and progress PVD is oxidizable unsightly to solve alloy on the basis of spraying Defect, enhance the corner volume wear-resisting property of shell and realize beautiful and durable combination;
3. mobile phone shell of the invention has preferable appearance, it is able to ascend the added value of mobile phone.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution carry out clear, complete description, it is clear that described embodiments are some of the embodiments of the present invention, rather than Whole embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work premise Under every other embodiment obtained, shall fall within the protection scope of the present invention.
A kind of androgynous plastic housing of PVD spraying, it is the aluminium alloy mobile phone shell that nested inside is molded that the PVD, which sprays androgynous plastic housing, The aluminium alloy mobile phone shell frame carries out PVD processing.
A method of PVD spraying aluminium alloy mobile phone shell is prepared, is comprised the steps of:
((1) metal alloy phone housing frame die cast, the melt temperature are 700 DEG C, and mold temperature is 300 DEG C, Single product molding cycle is 20s;
(2) metal alloy nesting is molded, and first molded aluminum alloy frame is put into mold, is then moulded to mold Glue injection molding, the technique of plastic-injection is 280 DEG C of melt temperature, and mold temperature is 100 DEG C, and molding time is 20s;
(3) primer priming paint is once sprayed;
(4) primary polishing;
(5) secondary spraying primer priming paint;
(6) secondary polishing;
(7) spray-applied primer;
(8) colored paint is sprayed;
(9) spray paint;
(10) CNC processes frame;
(11) PVD processes frame, using sputtering technology, successively carries out product piece installing, vacuumizes 10min, is banged by high pressure Sputtering technology is hit to pass through with oxygen reaction into AL substrate aluminium2O3After be attached to product surface, time 10min, plating silicon, silicon and Oxygen generates SiO2After be attached to the product surface time be 5-10min, plate AF liquid medicine, time 10min.
Once sprayed in the step (3) primer priming paint with a thickness of 40 microns, combined for filling up alloy and plastic cement Gap thickness.
In the step (5) secondary spraying primer priming paint with a thickness of 40 microns, combined for filling up alloy and plastic cement Gap thickness.
Once sprayed in the step (3) primer priming paint with a thickness of 40 microns, combined for filling up alloy and plastic cement Gap thickness.
In the step (5) secondary spraying primer priming paint with a thickness of 40 microns, combined for filling up alloy and plastic cement Gap thickness.
The priming paint of step (7) spraying is acrylate, with a thickness of 20 microns, for increasing adhesive force.
The colored paint of step (8) spraying is that acrylate adds pigment, with a thickness of 10 microns, for enriching product face Color.
The finishing coat of step (9) spraying is polyurethane resin, and with a thickness of 25 microns, the finishing coat is protective layer, is used for Increase wear-resisting and scratch resistant performance.
The androgynous mobile phone shell of present embodiment production is measured through experiment: 1. hundred lattice are tested: KSA-1514 gummed paper glues 3 times and falls paint < 2/3;2. wear-resisting test: RCA >=30 time (counterweight 275g);3. hardness test: 2 no markings of 1000gf/F pencil;4. alcohol Test: 500gf/250 times;5. boiling test: 80 ° 30 minutes without cracking.It can be seen that PVD of the invention sprays androgynous plastic housing It is with good performance.
Present embodiment is by solving aluminium alloy because part processing technology is restricted in the interior injection moulding plastic material of aluminium alloy Prevent the problem of mobile phone shell is from using all aluminium alloy;By being sprayed in aluminum alloy surface, and on the basis of spraying into Row PVD solves the oxidizable inaesthetic defect of aluminium alloy, enhances the corner volume wear-resisting property of shell and realizes beautiful and durable Combination;Mobile phone shell of the invention also has preferable appearance, is able to ascend the added value of mobile phone.

Claims (6)

1. a kind of method for preparing PVD and spraying androgynous plastic housing, it is characterised in that comprise the steps of:
(1) metal alloy phone housing frame die cast, melt temperature are 600 DEG C -850 DEG C, and mold temperature is 250 DEG C -350 DEG C, single product molding cycle is 15-25s;
(2) metal alloy nesting is molded, and first molded aluminum alloy frame is put into mold, then carries out plastic cement note to mold Modeling, the technique of plastic-injection is 260 DEG C -310 DEG C of melt temperature, and mold temperature is 90 DEG C -120 DEG C, molding time 15- 25s;
(3) primer priming paint is once sprayed;
(4) primary polishing;
(5) secondary spraying primer priming paint;
(6) secondary polishing;
(7) spray-applied primer;
(8) colored paint is sprayed;
(9) spray paint;
(10) CNC processes frame;
(11) PVD processes frame: using sputtering technology, successively carries out product piece installing, vacuumize 5-15min, pass through high velocity bombardment Substrate aluminium is attached to product surface, time 5-15min after reacting with oxygen into AL2O3 by sputtering technology, plate silicon, silicon and Oxygen generates SiO2After be attached to the product surface time be 5-10min, plate AF liquid medicine, time 5-15min.
2. a kind of method for preparing PVD and spraying androgynous plastic housing as described in claim 1, it is characterised in that: in the step (3) Primary spraying primer priming paint with a thickness of 35-45 microns.
3. a kind of method for preparing PVD and spraying androgynous plastic housing as described in claim 1, it is characterised in that: in the step (5) It is secondary spraying primer priming paint with a thickness of 35-45 microns.
4. a kind of method for preparing PVD and spraying androgynous plastic housing as described in claim 1, it is characterised in that: step (7) spray The priming paint of painting is acrylate, with a thickness of 15-25 microns.
5. a kind of method for preparing PVD and spraying androgynous plastic housing as described in claim 1, it is characterised in that: step (8) spray The colored paint of painting is that acrylate adds pigment, with a thickness of 5-15 microns.
6. a kind of method for preparing PVD and spraying androgynous plastic housing as described in claim 1, it is characterised in that: step (9) spray The finishing coat of painting is polyurethane resin, with a thickness of 20-30 microns.
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CN105337985A (en) * 2015-11-19 2016-02-17 北京师范大学 Attack detection method and system
CN106534740B (en) * 2016-11-30 2019-07-09 江苏蔚联机械股份有限公司 A kind of television set pedestal processing method
CN106807609A (en) * 2017-01-13 2017-06-09 广东龙昕科技有限公司 A kind of preparation technology of shells ceramic structure
CN106893978B (en) * 2017-02-07 2018-12-18 深圳市联懋塑胶有限公司 A kind of technique that plastic surface imitates metal-back processing
CN107299260A (en) * 2017-07-12 2017-10-27 合肥展游软件开发有限公司 A kind of phone housing and its preparation technology
CN108515315A (en) * 2018-03-14 2018-09-11 东莞市鑫濠信精密工业有限公司 Mobile phone center manufacture craft
CN108810213A (en) * 2018-08-28 2018-11-13 深圳市旺鑫精密工业有限公司 Androgynous plastic housing of a kind of PVD spraying and preparation method thereof

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CN103722668A (en) * 2013-12-25 2014-04-16 浙江师范大学 Metal-plastic composite mobile phone shell and forming method thereof

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CN103722668A (en) * 2013-12-25 2014-04-16 浙江师范大学 Metal-plastic composite mobile phone shell and forming method thereof

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