CN105063492A - Hot-rolled steel for car friction plate and preparation method of hot-rolled steel - Google Patents
Hot-rolled steel for car friction plate and preparation method of hot-rolled steel Download PDFInfo
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Abstract
The invention discloses hot-rolled steel for a car friction plate. The hot-rolled steel comprises the following chemical compositions by mass percent: 0.45-0.75 percent of C, 0.10-0.30 percent of Si, 0.60-1.20 percent of Mn, less than or equal to 0.015 percent of P, less than or equal to 0.005 percent of S, less than or equal to 0.006 percent of N, 0.05-0.50 percent of Cr, 0.015-0.050 percent of Als, less than or equal to 0.005 percent of Ti, 0.01-0.03 percent of V and the balance of Fe and inevitable impurities. The invention further discloses a preparation method of the hot-rolled steel for the car friction plate. The hardness of the hot-rolled steel is controlled within 18-25 HRC, the hardness of the steel annealed at 600-850 DEG C is still kept at 14-18 HRC, and the hot-rolled steel has favorable cold working forming performance and does not crack in the blanking and forming process.
Description
Technical field
The present invention relates to hot rolled strip manufacturing technology, refer to hot-strip of a kind of automobile friction and preparation method thereof particularly.
Background technology
Automobile friction is the important spare part of automobile brake system, is one of automobile easily worn part.Existing manufacturing procedure comprises stamping-out steel disc, comparatively flat, mill, on the base steel ground, then sinters one deck cupric friction materials make.The Working environment of automobile friction and complete processing require that base steel has good hardenability, wear resistance, higher intensity etc., especially require that base steel still has the hardness of 14 ~ 18HRC after the sintering of 600 ~ 800 DEG C.In addition, automobile friction to the thickness and precision of steel band and surface requirements also higher, thickness and precision require reach ± 0.03mm, surface roughness requirements is less than 0.3um.In order to meet this requirement, current automobile friction base steel used material adopts cold rolling 40Mn, 50Mn or 65Mn steel band usually.Although cold-rolled steel strip can meet friction plate to thickness and precision and surperficial requirement, after sintering, its hardness, lower than 14HRC, does not meet the requirement of existing technique, and the cost of cold-rolled steel strip is higher.Based on this, meet existing complete processing in the urgent need to one at present and require and lower-cost material.Current also paid pilot production hot rolling 65Mn material substitution cold rolling material, but hot-finished material its hardness decline after oversintering annealing is larger and uneven, does not meet existing processing requirement.
Authorization Notice No. is that the Chinese invention patent of CN101773930B discloses a kind of method of producing 65Mn hot-rolled steel sheet, the chemical composition that refining process carries out the molten steel after Alloying Treatment is: C:0.62 ~ 0.70%, Si:0.17 ~ 0.37%, Mn:0.90 ~ 1.20%, P≤0.035%, S≤0.035%, Cr≤0.25%, Ni≤0.25%, all the other are Fe and inevitable impurity; Describe a kind of method adopting bar strip continuous casting and rolling flow path to produce 65Mn hot-rolled steel sheet, the hardness of hot-rolled product is 19 ~ 30HRC.But because in steel, nothing is stablized and resistant to elevated temperatures carbide, material is after high temperature annealing, and the decline of its product hardness is larger and uneven, does not meet existing processing requirement.If the hardness before existing hot-rolled steel sheet annealing is increased to more than 30HRC further, then in punching course, easily there is the phenomenons such as cracking.In addition, the roughness Ra of hot rolled strip, all at more than 1.0um, does not meet the requirement that existing processing requirement steel substrate surface roughness is less than 0.30um.
Therefore, provide that a kind of Financial cost is low, after oversintering annealing, product hardness less, the hot-strip with the automobile friction of good cold-forming ability and preparation method thereof that declines seems very necessary.
Summary of the invention
The object of the invention is to the weak point overcoming above-mentioned existing background technology, hot-strip of a kind of automobile friction and preparation method thereof is provided.
The object of the invention is to be reached by following measure: a kind of hot-strip of automobile friction, in steel, chemical composition and mass percent are: C:0.45 ~ 0.75%, Si:0.10 ~ 0.30%, Mn:0.60 ~ 1.20%, P≤0.015%, S≤0.005%, N≤0.006%, Cr:0.05 ~ 0.50%, Als:0.015 ~ 0.050%, Ti≤0.005%, V:0.01 ~ 0.03%, all the other are Fe and inevitable impurity; The Hardness Control of hot-rolled product is at 18 ~ 25HRC, and after the annealing temperature of 600 ~ 850 DEG C, the hardness of steel still remains on 14 ~ 18HRC.
Preferably, in steel, chemical composition and mass percent are: C:0.66 ~ 0.75%, Si:0.20 ~ 0.30%, Mn:0.90 ~ 1.20%, P≤0.007%, S≤0.005%, N≤0.006%, Cr:0.05 ~ 0.30%, Als:0.015 ~ 0.030%, Ti≤0.003%, V:0.01 ~ 0.025%, all the other are Fe and inevitable impurity.
Further, in steel, chemical composition and mass percent are: C:0.68%, Si:0.20%, Mn:1.10%, P:0.007%, S:0.005%, N:0.003%, Cr:0.05%, Als:0.015%, Ti:0.002%, V:0.025%, all the other are Fe and inevitable impurity.
Main chemical elements and the percentage composition effect in the present invention thereof of the present invention's selection are as follows:
C: carbon is main in steel plays solution strengthening effect, and improve hardness and the hardenability of steel, carbon content is too low, and after heat treatment hardness is too low, and steel is too soft.Carbon content is too high, and steel hardness is too high, and the course of processing easily occurs problems of crack, and processing characteristics is poor.Therefore carbon content is 0.45 ~ 0.75%, and preferably, C content is chosen as 0.66% ~ 0.75%.
Si:Si plays solution strengthening effect in steel, and content is too low, and strengthening effect is too little, and minimum Si content is 0.10%, Si too high levels, easily forms Fe at product surface
2siO
4, cause surface imperfection, therefore most high Si content is 0.30%.
Mn:Mn plays solution strengthening effect in steel, improve hardness and the hardening capacity of steel, Mn content is too low, strengthening effect is too little, therefore minimum Mn content is 0.60%, Mn too high levels easily causes central segregation of slab in casting process, reduces the use properties of material, and therefore most high Mn content is 1.20%.
P:P is the impurity element in steel, is easy at Grain Boundary Segregation, affects the toughness of product, and therefore its content is more low better.According to working control level, should control below 0.015%.
S:S is the impurity element in steel, easily produces segregation at crystal boundary, reduces the toughness of steel, fully should remove, should ensure that its value is lower than 0.005% during steel-making.
N:N is the impurity element in steel, reduces the toughness of steel, and be easy to Al, Ti and form AlN and TiN, too high levels, easily form thick TiN, therefore reduce its content, its value should lower than 0.006% as far as possible.
Cr:Cr can improve the hardening capacity of steel, be conducive to the hardness and the wear resistance that improve steel, stable carbide is formed in steel, in tempering and annealing process, play the effect of stable steel hardness, in the present invention, Schwellenwert is 0.05%, but Cr too high levels easily causes steel much higher hard, toughness declines, and therefore maximum is 0.50%.
V:V can improve the hardening capacity of steel, is combined to be formed to stablize MC carbide with C, improves hardness and the wear resistance of steel, in tempering and annealing process, play the effect of stable steel performance, therefore its minimum content is 0.01%, consider cost factor, the highest V content is 0.03%.
The N of Ti:Ti easily in steel is combined, and forms thick TiN, produces strand crackle, and reduce quality product, therefore, in steel, Ti should control at lower level, and the present invention controls below 0.005%.
Al:Al is combined with O in steel, mainly plays the effect of deoxidation, and therefore minimum content is that 0.015%, Al too high levels easily forms continuous casting and produces difficulty, and therefore most high-content is 0.050%.
Steel of the present invention is except containing except above-mentioned chemical composition, and all the other are Fe and inevitable impurity.
The preparation method of the hot-strip of above-mentioned automobile friction, comprises the steps:
1) smelting, refining, vacuum-treat and continuous casting: during continuous-casting steel pouring, the superheating temperature of molten steel controls to be 15 ~ 25 DEG C, and it is 50 ~ 90mm that thickness of strand controls;
2) heat: heating steps 1) strand of gained, it is 900 ~ 1100 DEG C that strand charging temperature controls, and it is 1150 ~ 1250 DEG C that tapping temperature controls, and it is 20 ~ 50min that strand time inside furnace controls;
3) controlled rolling: to step 2) in the strand of gained carry out roughing and finish rolling, the draft of the first passage of finish rolling, the second passage and the 3rd passage all controls 30 ~ 50%, finish rolling end percentage pass reduction≤15%, and finishing temperature control is 860 ~ 900 DEG C;
4) control cold: to step 3) in the steel plate of gained carry out control deepfreeze, adopt section cooling, rate of cooling control is 3 ~ 35 DEG C/s;
5) batch: to step 4) in the steel plate of gained batch process, oiler temperature control is 620 ~ 660 DEG C;
6) slow cooling: to step 5) in the coil of strip of gained carry out slow cooling process, slow cooling time controling is 24 ~ 72h;
7) pickling: to step 6) in the coil of strip of gained carry out pickling;
8) smooth and oiling: to step 7) in the coil of strip of gained carry out smooth process, smooth elongation control is 1 ~ 5%, and leveling roll roughness Ra≤0.8um, namely obtains the hot-strip of automobile friction.
Preferably, step 1) in, the superheating temperature of molten steel controls to be 15 ~ 20 DEG C, and it is 50 ~ 70mm that thickness of strand controls.
Further, step 2) in, it is 25 ~ 30min that strand time inside furnace controls.
Again further, step 3) in, finishing temperature control is 860 ~ 880 DEG C.
Again further, step 4) in, it is 10 ~ 25 DEG C/s that rate of cooling controls.
Further, step 5) in, oiler temperature control is 620 ~ 640 DEG C.
Again further, step 8) in, smooth unit elongation controls by 1.5% ~ 4.0%.
The invention has the advantages that:
One, by the chemical composition in control steel and hot rolling technology, laminar flow cooling technology, coiling temperature etc., make in steel, to form stable carbide, make the Hardness Control of hot-strip at 18 ~ 25HRC, and there is good cold-formed performance, after the annealing temperature of 600 ~ 850 DEG C, the hardness of steel still remains on 14 ~ 18HRC, meets the fabrication process condition of existing automobile friction;
Its two, the present invention is in stamping-out moulding process, and steel do not ftracture, and substantially increases lumber recovery and the use properties of steel.
Embodiment
Describe performance of the present invention in detail below in conjunction with embodiment, but they do not form limitation of the invention, only for example.Simultaneously by illustrating that advantage of the present invention will become clearly and easy understand.
Table 1 is embodiment 1 ~ 6 is chemical composition and weight percent in the hot-strip of automobile friction, and comparative example 1 ~ 3 is chemical composition and weight percent in comparative steel, and all the other are Fe and inevitable impurity.
The chemical composition of table 1 various embodiments of the present invention and comparative example and weight percent (wt%)
The slab described chemical composition obtained after smelting, refining, vacuum-treat and continuous casting is cold through heating, controlled rolling, control, batch, slow cooling, pickling and smooth after namely obtain the hot-strip of automobile friction.Concrete main technologic parameters is as following table:
The main technologic parameters list (one) of table 2 various embodiments of the present invention
The main technologic parameters list (two) of table 3 various embodiments of the present invention
Above-described embodiment performance perameter is as shown in the table:
The results of property list of table 4 various embodiments of the present invention and comparative example
As can be seen from Table 4: the embodiment of the present invention 1 ~ 6 product Steel Properties is good, the Hardness Control of hot-strip is at 18 ~ 25HRC, after sintering annealing, steel performance is good, after the temperature sintering annealing of 600 ~ 850 DEG C, the hardness of steel still remains on 14 ~ 18HRC, in stamping-out moulding process, hot-strip does not ftracture.
Other is prior art without the part described in detail.
Claims (10)
1. the hot-strip of an automobile friction, it is characterized in that: in steel, chemical composition and mass percent are: C:0.45 ~ 0.75%, Si:0.10 ~ 0.30%, Mn:0.60 ~ 1.20%, P≤0.015%, S≤0.005%, N≤0.006%, Cr:0.05 ~ 0.50%, Als:0.015 ~ 0.050%, Ti≤0.005%, V:0.01 ~ 0.03%, all the other are Fe and inevitable impurity; The Hardness Control of hot-rolled product is at 18 ~ 25HRC, and after the annealing temperature of 600 ~ 850 DEG C, the hardness of steel still remains on 14 ~ 18HRC.
2. the hot-strip of automobile friction according to claim 1, it is characterized in that: in steel, chemical composition and mass percent are:: C:0.66 ~ 0.75%, Si:0.20 ~ 0.30%, Mn:0.90 ~ 1.20%, P≤0.007%, S≤0.005%, N≤0.006%, Cr:0.05 ~ 0.30%, Als:0.015 ~ 0.030%, Ti≤0.003%, V:0.01 ~ 0.025%, all the other are Fe and inevitable impurity.
3. the hot-strip of automobile friction according to claim 1, it is characterized in that: in steel, chemical composition and mass percent are:: C:0.68%, Si:0.20%, Mn:1.10%, P:0.007%, S:0.005%, N:0.003%, Cr:0.05%, Als:0.015%, Ti:0.002%, V:0.025%, all the other are Fe and inevitable impurity.
4. a preparation method for the hot-strip of automobile friction according to claim 1, is characterized in that: comprise the steps:
1) smelting, refining, vacuum-treat and continuous casting: during continuous-casting steel pouring, the superheating temperature of molten steel controls to be 15 ~ 25 DEG C, and it is 50 ~ 90mm that thickness of strand controls;
2) heat: heating steps 1) strand of gained, it is 900 ~ 1100 DEG C that strand charging temperature controls, and it is 1150 ~ 1250 DEG C that tapping temperature controls, and it is 20 ~ 50min that strand time inside furnace controls;
3) controlled rolling: to step 2) in the strand of gained carry out roughing and finish rolling, the draft of the first passage of finish rolling, the second passage and the 3rd passage all controls 30 ~ 50%, finish rolling end percentage pass reduction≤15%, and finishing temperature control is 860 ~ 900 DEG C;
4) control cold: to step 3) in the steel plate of gained carry out control deepfreeze, adopt section cooling, rate of cooling control is 3 ~ 35 DEG C/s;
5) batch: to step 4) in the steel plate of gained batch process, oiler temperature control is 620 ~ 660 DEG C;
6) slow cooling: to step 5) in the coil of strip of gained carry out slow cooling process, slow cooling time controling is 24 ~ 72h;
7) pickling: to step 6) in the coil of strip of gained carry out pickling;
8) smooth and oiling: to step 7) in the coil of strip of gained carry out smooth process, smooth elongation control is 1 ~ 5%, and leveling roll roughness Ra≤0.8um, namely obtains the hot-strip of automobile friction.
5. the preparation method of automobile friction hot rolling high carbon steel according to claim 4, is characterized in that: described step 1) in, the superheating temperature of molten steel controls to be 15 ~ 20 DEG C, and it is 50 ~ 70mm that thickness of strand controls.
6. the preparation method of automobile friction hot rolling high carbon steel according to claim 4, is characterized in that: described step 2) in, it is 25 ~ 30min that strand time inside furnace controls.
7. the preparation method of automobile friction hot rolling high carbon steel according to claim 4, is characterized in that: described step 3) in, finishing temperature control is 860 ~ 880 DEG C.
8. the preparation method of automobile friction hot rolling high carbon steel according to claim 4, is characterized in that: described step 4) in, it is 10 ~ 25 DEG C/s that rate of cooling controls.
9. the preparation method of automobile friction hot rolling high carbon steel according to claim 4, is characterized in that: described step 5) in, oiler temperature control is 620 ~ 640 DEG C.
10. the preparation method of automobile friction hot rolling high carbon steel according to claim 4, is characterized in that: described step 8) in, smooth unit elongation controls by 1.5% ~ 4.0%.
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| CN106591724A (en) * | 2016-12-15 | 2017-04-26 | 武汉钢铁股份有限公司 | Hot-rolled annealed steel plate for cold forming and production method thereof |
| CN106676405A (en) * | 2016-12-09 | 2017-05-17 | 天长市天龙泵阀成套设备厂 | High-strength alloy steel |
| CN107641758A (en) * | 2017-09-18 | 2018-01-30 | 武汉钢铁有限公司 | The manufacture method of the excellent alloy tool steel of fatigue behaviour and its hot rolled plate |
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| CN106676405A (en) * | 2016-12-09 | 2017-05-17 | 天长市天龙泵阀成套设备厂 | High-strength alloy steel |
| CN106591724A (en) * | 2016-12-15 | 2017-04-26 | 武汉钢铁股份有限公司 | Hot-rolled annealed steel plate for cold forming and production method thereof |
| CN107641758A (en) * | 2017-09-18 | 2018-01-30 | 武汉钢铁有限公司 | The manufacture method of the excellent alloy tool steel of fatigue behaviour and its hot rolled plate |
| CN107641758B (en) * | 2017-09-18 | 2019-07-09 | 武汉钢铁有限公司 | The manufacturing method of the excellent alloy tool steel of fatigue behaviour and its hot rolled plate |
| CN109023115A (en) * | 2018-09-29 | 2018-12-18 | 武汉钢铁有限公司 | A kind of hot rolling template pulling-on piece steel and its manufacturing method |
| CN110899329A (en) * | 2019-10-25 | 2020-03-24 | 邯郸钢铁集团有限责任公司 | Method for producing brake pad back steel based on CSP continuous casting and rolling production line |
| CN110899329B (en) * | 2019-10-25 | 2021-08-20 | 邯郸钢铁集团有限责任公司 | Method for producing brake pad back steel based on CSP continuous casting and rolling production line |
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| CN111172455B (en) * | 2019-12-31 | 2021-07-20 | 河钢股份有限公司承德分公司 | Carbon steel 45Mn hot-rolled pickled plate and production method thereof |
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| CN113751499A (en) * | 2021-08-02 | 2021-12-07 | 浙江中箭工模具有限公司 | Wear-resistant high-speed steel hot rolling process |
| CN113751499B (en) * | 2021-08-02 | 2024-01-05 | 浙江中箭工模具有限公司 | Wear-resistant high-speed steel hot rolling process |
| CN114411057A (en) * | 2021-12-30 | 2022-04-29 | 钢铁研究总院 | High-strength steel for core plate capable of sintering friction layer |
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| CN115418552B (en) * | 2022-08-25 | 2023-09-22 | 齐齐哈尔英格机械有限公司 | Preparation method of nitrocarburizing low alloy steel machine tool friction plate |
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