CN105062294B - A kind of water-fast construction wall lining of high-performance - Google Patents
A kind of water-fast construction wall lining of high-performance Download PDFInfo
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- CN105062294B CN105062294B CN201510491399.2A CN201510491399A CN105062294B CN 105062294 B CN105062294 B CN 105062294B CN 201510491399 A CN201510491399 A CN 201510491399A CN 105062294 B CN105062294 B CN 105062294B
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- 238000010276 construction Methods 0.000 title claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 34
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000004078 waterproofing Methods 0.000 claims abstract description 25
- 239000002086 nanomaterial Substances 0.000 claims abstract description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 22
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000013530 defoamer Substances 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 15
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 15
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000003505 terpenes Chemical class 0.000 claims abstract description 15
- 235000007586 terpenes Nutrition 0.000 claims abstract description 15
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 14
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 14
- 239000010440 gypsum Substances 0.000 claims abstract description 14
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 12
- 239000010703 silicon Substances 0.000 claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 10
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 10
- 229920001577 copolymer Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 150000003376 silicon Chemical class 0.000 claims abstract description 10
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910021389 graphene Inorganic materials 0.000 claims description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- 235000010215 titanium dioxide Nutrition 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000011863 silicon-based powder Substances 0.000 claims description 10
- 150000002989 phenols Chemical class 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 5
- JKGITWJSGDFJKO-UHFFFAOYSA-N ethoxy(trihydroxy)silane Chemical class CCO[Si](O)(O)O JKGITWJSGDFJKO-UHFFFAOYSA-N 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical class OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 28
- 239000006210 lotion Substances 0.000 description 6
- -1 MAA methacrylic acids Chemical class 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- SVKDNKCAGJVMMY-UHFFFAOYSA-N triethoxy(tetradecyl)silane Chemical compound CCCCCCCCCCCCCC[Si](OCC)(OCC)OCC SVKDNKCAGJVMMY-UHFFFAOYSA-N 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000255964 Pieridae Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002939 oilproofing Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention discloses a kind of water-fast construction wall lining of high-performance, it is characterised in that including set gradually from the inside to the outside basic unit, tack coat, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；The raw material of the acrylic coating includes terpene resin 20 30 by weight, butyl acetate 30 40, acrylate copolymer emulsion 15 25, acrylic acid solution 10 20, waterproofing agent 0.5 1.5, glass microballoon 20 30, modified Nano material 30 40, titanium dioxide 0.5 1.5, gypsum 20 30, kaolin 5 10, diatomite 20 25, dispersant 13, levelling agent 0.5 0.8, isothiazolinone derivatives 1.5 2.5, ethoxylated alkylphenol ammonium sulfate 0.5 2, propandiol butyl ether 15 20, antioxidant 0.5 1.5, organic silicon defoamer 12, ether modified organic silicon class defoamer 12.
Description
Technical field
The present invention relates to wallboard technical field, more particularly to a kind of water-fast construction wall lining of high-performance.
Background technology
Lining is used to protect and decorative architecture wall, therefore it must have weatherability good enough, stain resistance and resistance to
Freeze thawing, just can guarantee that preferable decorative effect and durability.Lining can make construction wall neat and artistic, so as to reach
Beautifying urban environment and protect building walls effect, but lining currently on the market there are it is water-fast, oil resistivity is poor, make
With short life, this have impact on the beauty of building, also reduce the service life of construction wall.
The content of the invention
The present invention proposes a kind of water-fast construction wall lining of high-performance, and good waterproof performance, mechanical property is good, resistance to ag(e)ing
Can be extremely excellent.
The water-fast construction wall lining of a kind of high-performance proposed by the present invention, including set gradually from the inside to the outside basic unit,
Tack coat, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；
The raw material of the acrylic coating includes by weight：20-30 parts of terpene resin, 30-40 parts of butyl acetate, propylene
15-25 parts of acid esters copolymer emulsion, 10-20 parts of acrylic acid solution, 0.5-1.5 parts of waterproofing agent, 20-30 parts of glass microballoon, modification are received
30-40 parts of material of rice, 0.5-1.5 parts of titanium dioxide, 20-30 parts of gypsum, 5-10 parts of kaolin, 20-25 parts of diatomite, dispersant 1-
3 parts, 0.5-0.8 parts of levelling agent, 1.5-2.5 parts of isothiazolinone derivatives, 0.5-2 parts of ethoxylated alkylphenol ammonium sulfate, third
15-20 parts of glycol butyl ether, 2,6- 0.5-1.5 parts of di-tert-butyl-4-methy phenols, 1-2 parts of organic silicon defoamer, ether, which is modified, to be had
1-2 parts of machine silicon class defoamer.
Preferably, the waterproofing agent is prepared using following technique：By weight by 10-20 parts of water, 1-3 parts of dodecyl sulphurs
Sour sodium, 10-15 part polyvinyl alcohol, 0.5-1 parts of gamma-aminopropyl-triethoxy-silanes, 0.5-1 parts of γ-glycidyl ether oxygen propyls
Trimethoxy silane and 1-2 parts of aluminum sulfate are sent into blender and are stirred evenly, and whipping temp is 80-90 DEG C, then adds 1-2 parts
Myristyl triethoxysilane stirs evenly, and it is 5-6 to add sodium acid carbonate regulation system pH value, obtains waterproofing agent.
Preferably, the function monomer is MAA methacrylic acids and/or acrylamide.
Preferably, modified Nano material is prepared using following technique：By weight by 100 parts of deionized waters, 5-10 parts of stones
Black alkene, 20-50 part clay, 50-80 parts of silicon powders, 20-40 parts of ethyl orthosilicates are added in reaction kettle, by the temperature of reaction kettle
50-60 DEG C is risen to, then adds 50-80 parts of nano-titanium dioxide stirrings, mixing speed 400-500r/min, mixing time is
1-3h, adds 1-5 parts of monoalkoxytitanates and stirs evenly, open vacuum pump, the pressure in reaction kettle is controlled in 10-
20kPa, constant temperature stirring 40-50min, cools down, and filtering, dry, pulverize, and the modified Nano material that particle diameter is 1-20nm is obtained by filtration
Material.
Preferably, the graphene by single-layer graphene, bilayer graphene and multi-layer graphene one or more
Composition.
Preferably, the particle diameter of the silicon powder is 100-200 microns.
Preferably, the particle diameter of the nano-titanium dioxide is 5-35nm.
Preferably, the weight ratio of terpene resin, butyl acetate, acrylate copolymer emulsion and acrylic acid solution is 24-26：
32-35：20-24：12-14.
Preferably, glass microballoon, modified Nano material, titanium dioxide, gypsum, kaolin and diatomaceous weight ratio are 24-
26：32-36：0.8-1：24-26：6-8：22-24.
Preferably, the raw material of the acrylic coating includes by weight：24-26 parts of terpene resin, butyl acetate 32-35
Part, 20-24 parts of acrylate copolymer emulsion, 12-14 parts of acrylic acid solution, 1-1.4 parts of waterproofing agent, 24-26 parts of glass microballoon, changes
32-36 parts of nano material of property, 0.8-1 parts of titanium dioxide, 24-26 parts of gypsum, 6-8 parts of kaolin, 22-24 parts of diatomite, dispersant
2-2.6 parts, 0.6-0.75 parts of levelling agent, 2-2.3 parts of isothiazolinone derivatives, 0.8-1 parts of ethoxylated alkylphenol ammonium sulfate,
16-18 parts of propandiol butyl ether, 2,6- 1-1.3 parts of di-tert-butyl-4-methy phenols, 1.2-1.6 parts of organic silicon defoamer, ether changes
1.4-1.8 parts of organic silicon defoamer of property.
Acrylic coating of the present invention is prepared using following technique：By waterproofing agent, glass microballoon, modified Nano material,
Titanium dioxide, gypsum, kaolin, diatomite, dispersant, levelling agent, isothiazolinone derivatives, ethoxylated alkylphenol sulfuric acid
Ammonium, propandiol butyl ether, 2,6 di tert butyl 4 methyl phenol, organic silicon defoamer, ether modified organic silicon class defoamer add
Stirred evenly in skin grinder, add acrylate copolymer emulsion, acrylic acid solution grinding uniformly, milling time 2-4h, connects
Addition terpene resin, butyl acetate continuation agitation grinding 20-50min, sieving obtains acrylic coating.
In the present invention, terpene resin is some thermoplastic block copolymers, and inoxidizability and heat endurance are good, compatibility and
Dissolubility is excellent, and with butyl acetate, acrylate copolymer emulsion and acrylic acid solution collective effect, inside is contained substantial amounts of living
Property Interaction of substituents, product good waterproof performance, Mechanical Properties of Products is high, and ageing-resistant performance is extremely excellent, ethoxylated alkyl
Phenol ammonium sulfate is resistance to oil stains good, and water resistance is excellent, and isothiazolinone derivatives antibiotic property is good, ethoxylated alkylphenol sulfuric acid
Ammonium, isothiazolinone derivatives complex role, product antibacterial, Waterproofing/oilproofing performance further enhance, and security is good, resistance to ag(e)ing
Further enhance；Modified Nano material has distinctive skin effect and the tunnel-effect of macroscopic quantum, with glass microballoon, titanium white
Powder, gypsum, kaolin and diatomite complex role, on the basis of each excellent properties of each component are ensured, can form one layer surely
Fixed gas membrane, both waterproof, oil-stain-preventing, mechanical property is good, and passes through gas, tool can respiratory, with relatively low cost
Obtain optimal comprehensive performance；And in the waterproofing agent added, its internal polyvinyl alcohol has wetting action, while is conducive to carry
The stability of high waterproofing agent, gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl trimethoxy silicane and 14
Alkyl triethoxysilane cooperatively forms compound system, and acts synergistically with polyvinyl alcohol, you can it is excellent to ensure that product has
Different water resistance, and there is splendid permeability and weatherability, waterproofing agent and terpene resin, butyl acetate, acrylic ester copolymer
Lotion and the compatibility of acrylic acid solution are good, and comprehensive function, article water resistance can further enhance, and good weatherability, ageing-resistant
Performance further enhances.
Embodiment
Embodiment 1
A kind of water-fast construction wall lining of high-performance, including set gradually from the inside to the outside basic unit, tack coat, fire prevention
Layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；
The raw material of the acrylic coating includes by weight：20 parts of terpene resin, 40 parts of butyl acetate, acrylate is common
Poly- 15 parts of lotion, 20 parts of acrylic acid solution, 0.5 part of waterproofing agent, 30 parts of glass microballoon, 30 parts of modified Nano material, titanium dioxide 1.5
Part, 20 parts of gypsum, 10 parts of kaolin, 20 parts of diatomite, 3 parts of dispersant, 0.5 part of levelling agent, isothiazolinone derivatives 2.5
Part, 0.5 part of ethoxylated alkylphenol ammonium sulfate, 20 parts of propandiol butyl ether, 2,6- 0.5 part of di-tert-butyl-4-methy phenols are organic
2 parts of silicon class defoamer, 1 part of ether modified organic silicon class defoamer.
Embodiment 2
A kind of water-fast construction wall lining of high-performance, including set gradually from the inside to the outside basic unit, tack coat, fire prevention
Layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；
The raw material of the acrylic coating includes by weight：30 parts of terpene resin, 30 parts of butyl acetate, acrylate is common
Poly- 25 parts of lotion, 10 parts of acrylic acid solution, 1.5 parts of waterproofing agent, 20 parts of glass microballoon, 40 parts of modified Nano material, titanium dioxide 0.5
Part, 30 parts of gypsum, 5 parts of kaolin, 25 parts of diatomite, 1 part of dispersant, 0.8 part of levelling agent, 1.5 parts of isothiazolinone derivatives,
2 parts of ethoxylated alkylphenol ammonium sulfate, 15 parts of propandiol butyl ether, 2,6- 1.5 parts of di-tert-butyl-4-methy phenols, organic silicon
1 part of defoamer, 2 parts of ether modified organic silicon class defoamer.
Embodiment 3
A kind of water-fast construction wall lining of high-performance, including set gradually from the inside to the outside basic unit, tack coat, fire prevention
Layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；
The raw material of the acrylic coating includes by weight：24 parts of terpene resin, 35 parts of butyl acetate, acrylate is common
Poly- 20 parts of lotion, 14 parts of acrylic acid solution, 1 part of waterproofing agent, 26 parts of glass microballoon, 32 parts of modified Nano material, 1 part of titanium dioxide,
24 parts of gypsum, 8 parts of kaolin, 22 parts of diatomite, 2.6 parts of dispersant, 0.6 part of levelling agent, 2.3 parts of isothiazolinone derivatives,
0.8 part of ethoxylated alkylphenol ammonium sulfate, 18 parts of propandiol butyl ether, 2,6- 1 part of di-tert-butyl-4-methy phenols, organic silicon
1.6 parts of defoamer, 1.4 parts of ether modified organic silicon class defoamer.
The waterproofing agent is prepared using following technique：20 parts of water, 1 part of dodecyl sodium sulfate, 15 parts are gathered by weight
Vinyl alcohol, 0.5 part of gamma-aminopropyl-triethoxy-silane, 1 part of γ-glycidyl ether oxygen propyl trimethoxy silicane and 1 part of sulfuric acid
Aluminium is sent into blender and is stirred evenly, and whipping temp is 90 DEG C, and it is equal then to add 1 part of myristyl triethoxysilane stirring
Even, it is 6 to add sodium acid carbonate regulation system pH value, obtains waterproofing agent.The function monomer is MAA methacrylic acids.
Modified Nano material is prepared using following technique：100 parts of deionized waters, 5 parts of graphenes, 50 parts are glued by weight
Soil, 50 parts of silicon powders, 40 parts of ethyl orthosilicates are added in reaction kettle, and the temperature of reaction kettle is risen to 50 DEG C, then adds 80
Part nano-titanium dioxide stirring, mixing speed 400r/min, mixing time 3h, add 1 part of monoalkoxytitanates stirring
Uniformly, vacuum pump is opened, the pressure control in reaction kettle is stirred into 40min in 20kPa, constant temperature, cools down, filters, dry, powder
It is broken, the modified Nano material that particle diameter is 1-20nm is obtained by filtration.The graphene is by single-layer graphene, bilayer graphene and multilayer
Graphene forms.The particle diameter of the silicon powder is 100-200 microns.The particle diameter of the nano-titanium dioxide is 5-35nm.
Embodiment 4
A kind of water-fast construction wall lining of high-performance, including set gradually from the inside to the outside basic unit, tack coat, fire prevention
Layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；
The raw material of the acrylic coating includes by weight：26 parts of terpene resin, 32 parts of butyl acetate, acrylate is common
Poly- 24 parts of lotion, 12 parts of acrylic acid solution, 1.4 parts of waterproofing agent, 24 parts of glass microballoon, 36 parts of modified Nano material, titanium dioxide 0.8
Part, 26 parts of gypsum, 6 parts of kaolin, 24 parts of diatomite, 2 parts of dispersant, 0.75 part of levelling agent, 2 parts of isothiazolinone derivatives,
1 part of ethoxylated alkylphenol ammonium sulfate, 16 parts of propandiol butyl ether, 2,6- 1.3 parts of di-tert-butyl-4-methy phenols, organic silicon
1.2 parts of defoamer, 1.8 parts of ether modified organic silicon class defoamer.
The waterproofing agent is prepared using following technique：10 parts of water, 3 parts of dodecyl sodium sulfates, 10 parts are gathered by weight
Vinyl alcohol, 1 part of gamma-aminopropyl-triethoxy-silane, 0.5 part of γ-glycidyl ether oxygen propyl trimethoxy silicane and 2 parts of sulfuric acid
Aluminium is sent into blender and is stirred evenly, and whipping temp is 80 DEG C, and it is equal then to add 2 parts of myristyl triethoxysilane stirrings
Even, it is 5 to add sodium acid carbonate regulation system pH value, obtains waterproofing agent.The function monomer is acrylamide.
Modified Nano material is prepared using following technique：By weight by 100 parts of deionized waters, 10 parts of graphenes, 20 parts
Clay, 80 parts of silicon powders, 20 parts of ethyl orthosilicates are added in reaction kettle, and the temperature of reaction kettle is risen to 60 DEG C, is then added
50 parts of nano-titanium dioxide stirrings, mixing speed 500r/min, mixing time 1h, add 5 parts of monoalkoxytitanates and stir
Mix uniformly, open vacuum pump, the pressure control in reaction kettle is stirred into 50min in 10kPa, constant temperature, cools down, filters, dry, powder
It is broken, the modified Nano material that particle diameter is 1-20nm is obtained by filtration.The graphene is made of single-layer graphene and multi-layer graphene.
The particle diameter of the silicon powder is 100-200 microns.The particle diameter of the nano-titanium dioxide is 5-35nm.
Embodiment 5
A kind of water-fast construction wall lining of high-performance, including set gradually from the inside to the outside basic unit, tack coat, fire prevention
Layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；
The raw material of the acrylic coating includes by weight：25 parts of terpene resin, 34 parts of butyl acetate, acrylate is common
Poly- 21 parts of lotion, 13.4 parts of acrylic acid solution, 1.2 parts of waterproofing agent, 25 parts of glass microballoon, 34 parts of modified Nano material, titanium dioxide
0.9 part, 25 parts of gypsum, 7.2 parts of kaolin, 23 parts of diatomite, 2.2 parts of dispersant, 0.68 part of levelling agent, isothiazolinone derivative
2.1 parts of thing, 0.94 part of ethoxylated alkylphenol ammonium sulfate, 17.2 parts of propandiol butyl ether, 2,6- di-tert-butyl-4-methy phenols
1.2 parts, 1.4 parts of organic silicon defoamer, 1.6 parts of ether modified organic silicon class defoamer.
The waterproofing agent is prepared using following technique：By weight by 16 parts of water, 2.4 parts of dodecyl sodium sulfates, 12 parts
Polyvinyl alcohol, 0.8 part of gamma-aminopropyl-triethoxy-silane, 0.7 part of γ-glycidyl ether oxygen propyl trimethoxy silicane and 1.6
Part aluminum sulfate, which is sent into blender, to stir evenly, and whipping temp is 82 DEG C, then adds 1.4 parts of myristyl triethoxysilanes
Stir evenly, it is 5.2 to add sodium acid carbonate regulation system pH value, obtains waterproofing agent.The function monomer is MAA methacrylic acids
And acrylamide.
Modified Nano material is prepared using following technique：100 parts of deionized waters, 8 parts of graphenes, 45 parts are glued by weight
Soil, 62 parts of silicon powders, 32 parts of ethyl orthosilicates are added in reaction kettle, and the temperature of reaction kettle is risen to 52 DEG C, then adds 64
Part nano-titanium dioxide stirring, mixing speed 420r/min, mixing time 2.5h, add 3.4 parts of monoalkoxytitanates
Stir evenly, open vacuum pump, the pressure control in reaction kettle is stirred into 46min in 16kPa, constant temperature, cools down, filters, it is dry,
Crush, the modified Nano material that particle diameter is 1-20nm is obtained by filtration.The graphene is by single-layer graphene, bilayer graphene and more
Layer graphene forms.The particle diameter of the silicon powder is 100-200 microns.The particle diameter of the nano-titanium dioxide is 5-35nm.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
- A kind of 1. water-fast construction wall lining of high-performance, it is characterised in that including set gradually from the inside to the outside basic unit, bonding Layer, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn；The waterproof layer is made of acrylic coating；The raw material of the acrylic coating includes by weight：20-30 parts of terpene resin, 30-40 parts of butyl acetate, acrylate 15-25 parts of copolymer emulsion, 10-20 parts of acrylic acid solution, 0.5-1.5 parts of waterproofing agent, 20-30 parts of glass microballoon, modified Nano material 30-40 parts of material, 0.5-1.5 parts of titanium dioxide, 20-30 parts of gypsum, 5-10 parts of kaolin, 20-25 parts of diatomite, 1-3 parts of dispersant, 0.5-0.8 parts of levelling agent, 1.5-2.5 parts of isothiazolinone derivatives, 0.5-2 parts of ethoxylated alkylphenol ammonium sulfate, propane diols 15-20 parts of butyl ether, 2,6- 0.5-1.5 parts of di-tert-butyl-4-methy phenols, 1-2 parts of organic silicon defoamer, ether modified organic silicon 1-2 parts of class defoamer；The waterproofing agent is prepared using following technique：By weight by 10-20 parts of water, 1-3 parts of dodecyl sodium sulfates, 10-15 Part polyvinyl alcohol, 0.5-1 parts of gamma-aminopropyl-triethoxy-silanes, 0.5-1 parts of γ-glycidyl ether oxygen propyl trimethoxy silicon Alkane and 1-2 parts of aluminum sulfate are sent into blender and are stirred evenly, and whipping temp is 80-90 DEG C, then adds 1-2 parts of myristyls three Ethoxysilane stirs evenly, and it is 5-6 to add sodium acid carbonate regulation system pH value, obtains waterproofing agent；Modified Nano material is prepared using following technique：By weight by 100 parts of deionized waters, 5-10 parts of graphenes, 20-50 parts Clay, 50-80 part silicon powder, 20-40 parts of ethyl orthosilicates are added in reaction kettle, and the temperature of reaction kettle is risen to 50-60 DEG C, Then 50-80 parts of nano-titanium dioxide stirrings are added, mixing speed 400-500r/min, mixing time 1-3h, add 1-5 Part monoalkoxytitanates stir evenly, and open vacuum pump, by the pressure control in reaction kettle in 10-20kPa, constant temperature stirring 40-50min, cools down, and filtering, dry, pulverize, and the modified Nano material that particle diameter is 1-20nm is obtained by filtration.
- 2. the water-fast construction wall lining of high-performance according to claim 1, it is characterised in that the graphene is by individual layer One or more kinds of compositions of graphene, bilayer graphene and multi-layer graphene.
- 3. the water-fast construction wall lining of high-performance according to claim 1, it is characterised in that the particle diameter of the silicon powder For 100-200 microns.
- 4. the water-fast construction wall lining of high-performance according to claim 1, it is characterised in that the nano-titanium dioxide Particle diameter be 5-35nm.
- 5. according to the water-fast construction wall lining of claim 1-4 any one of them high-performance, it is characterised in that terpenes tree Fat, butyl acetate, the weight ratio of acrylate copolymer emulsion and acrylic acid solution are 24-26：32-35：20-24：12-14.
- 6. according to the water-fast construction wall lining of claim 1-4 any one of them high-performance, it is characterised in that glass is micro- Pearl, modified Nano material, titanium dioxide, gypsum, kaolin and diatomaceous weight ratio are 24-26：32-36：0.8-1：24-26： 6-8：22-24.
- 7. according to the water-fast construction wall lining of claim 1-4 any one of them high-performance, it is characterised in that the propylene The raw material of sour coating includes by weight：24-26 parts of terpene resin, 32-35 parts of butyl acetate, acrylate copolymer emulsion 20- 24 parts, 12-14 parts of acrylic acid solution, 1-1.4 parts of waterproofing agent, 24-26 parts of glass microballoon, 32-36 parts of modified Nano material, titanium white 0.8-1 parts of powder, 24-26 parts of gypsum, 6-8 parts of kaolin, 22-24 parts of diatomite, 2-2.6 parts of dispersant, levelling agent 0.6-0.75 Part, 2-2.3 parts of isothiazolinone derivatives, 0.8-1 parts of ethoxylated alkylphenol ammonium sulfate, 16-18 parts of propandiol butyl ether, 2,6- 1-1.3 parts of di-tert-butyl-4-methy phenol, 1.2-1.6 parts of organic silicon defoamer, ether modified organic silicon class defoamer 1.4- 1.8 part.
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| CN109160797B (en) * | 2018-10-30 | 2020-11-06 | 梦牌新材料（宁国）有限公司 | High-strength anti-crack gypsum board and preparation method thereof |
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