CN105038567A - Water-based bamboo and wood cultural relic protective coating and preparation and application methods thereof - Google Patents
Water-based bamboo and wood cultural relic protective coating and preparation and application methods thereof Download PDFInfo
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Abstract
The invention discloses a water-based bamboo and wood cultural relic protective coating. The coating is formed by a first component and a second component in a mass ratio of (1 to 1)-(1 to 2), wherein the first component comprises the following components in parts by weight: 90-120 parts of acrylic polyurethane aqueous dispersion, 0.5-1.5 parts of thickening agent and 5-20 parts of water; the second component comprises the following components in parts by weight: 2-8 parts of propylene glycol monomethyl ether acetate, 0.5-5 parts of dispersing agent, 0.2-0.8 part of defoaming agent, 10-30 parts of water, 2-8 parts of flame retardant, 10-20 parts of mould inhibitor and 4-8 parts of plant mothproofing agent. The invention also discloses preparation and application methods of the water-based bamboo and wood cultural relic protective coating. The water-based bamboo and wood cultural relic protective coating forms a fireproof, waterproof, mouldproof and mothproof coat on the surfaces of bamboo and wood cultural relics and is environment-friendly and does not pollute the cultural relics.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of water-based bamboo wood historical relic's protection coating, the preparation method of this water-based bamboo wood historical relic's protection coating and the application method of this water-based bamboo wood historical relic's protection coating.
Background technology
China is an ancient civilized country with more than 5000 year history.Ancestors leave abundant cultural heritage to us, comprise ancient building, bamboo caving, woodcarving, mural painting, painting and calligraphy, sculpture, inscriptions on precipices, metal and ceramic etc. innumerable, also have the continuous a large amount of historical relics be unearthed to be all the treasure of our people.With regard to bamboo wood historical relic, being not only the treasure of Chinese people, is also the treasure of the people of the world, has very high academic research, value of art appreciation.Bamboo wooden cultural relic belongs to the organic substance that should not preserve, large and easily produce mildew under the condition of improper ventilation in atmospheric moisture, special in In Middle And Lower Reaches of Changjiang River, because distinctive plum rain season, the growth and breeding of very suitable mould and moth, be easy to mildew or produce hole, to such an extent as to grain is rotten by mold corrosion.Such as, Zha Gun Shandong, the Xinjiang gram a large amount of woodenware be unearthed in one, No. two graveyard, have very high historic survey and are worth.Wherein, part implements, by the corrosion of underground water, make wood-cellulose, xylogen etc. wreck.The insectofungicides such as the mothproof usual employing creosote of bamboo wood historical relic, Dieldrin-attapulgite mixture, permethrin process; fire prevention adopts the frie retardant coating process such as vinyl chloride resin, chlorinated rubber, resol and aminoresin, but it is less market to have fire prevention, waterproof, mildew-resistant and mothproof water-based bamboo wood historical relic's protection coating.
Summary of the invention
The object of the embodiment of the present invention is the above-mentioned deficiency overcoming prior art, provides a kind of water-based bamboo wood historical relic's protection coating, improves mildew resistance and the insect resistance of coating.
Another object of the embodiment of the present invention is the above-mentioned deficiency overcoming prior art, and provide the preparation method of a kind of water-based bamboo wood historical relic's protection coating, preparation technology is simple, and the coating prepared can improve mildew resistance and the insect resistance of coating.
An object again of the embodiment of the present invention is the above-mentioned deficiency overcoming prior art, provides the application method of a kind of water-based bamboo wood historical relic's protection coating, this coating is brushed bamboo wood cultural artifact surface and plays protective effect.
In order to realize foregoing invention object, the technical scheme of the embodiment of the present invention is as follows:
A kind of water-based bamboo wood historical relic's protection coating, be that first component of 1:1 ~ 1:2 and second component are formed by mass ratio, described first component comprises following composition according to the mass fraction: crylic acid polyurethane aqueous dispersion body 90 ~ 120 parts, thickening material 0.5 ~ 1.5 part, 5 ~ 20 parts, water; Described second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 2 ~ 8 parts, dispersion agent 0.5 ~ 5 part, defoamer 0.2 ~ 0.8,10 ~ 30 parts, water, fire retardant 2 ~ 8 parts, mould inhibitor 10 ~ 20 parts, plant mothproofing agent 4 ~ 8 parts.
Further: described mould inhibitor is silver suboxide mould inhibitor.
Further: the shape of described mould inhibitor is volution.
Further: forming described spiral spirochetal diameter is 50 ~ 200nm, and described spiral pitch is 100 ~ 500nm, and screw diameter is 100 ~ 1000nm.
Further: described mould inhibitor is prepared by the following method: step S11: take acetylene as carbon source, with nickel plate for catalyzer, with PCl
3for promotor prepares volution chiral carbon fiber; Step S12: obtain silver-plated volution chiral carbon fiber dust at the electroplate of described volution chiral carbon fiber; Step S13: described silver-plated volution chiral carbon fiber dust is heat-treated, obtains described mould inhibitor after cooling.
Further: described plant mothproofing agent extracts from the mixture of leaf of Cortex cinnamomi camphorae, tarragon and lavandula angustifolia.
Further: described plant mothproofing agent is prepared by the following method: step S21: by fresh described leaf of Cortex cinnamomi camphorae, described tarragon and described lavandula angustifolia drying and dehydrating; Step S22: by the described leaf of Cortex cinnamomi camphorae after dehydration, described tarragon and described lavandula angustifolia in mass ratio 2:2:1 mix and pulverize as mixed slurry; Step S23: by described mixed slurry and dehydrated alcohol mixing, extract at 50 DEG C and obtain mixed solution; Step S24: centrifugal for described mixed solution, filtration are obtained filtrate, and obtain described plant mothproofing agent by concentrated for described filtrate.
Further: described thickening material is selected from least one in Natvosol 250HBR and polyethylene wax; And/or described dispersion agent is selected from least one in BYK190 dispersion agent and TH-904 dispersion agent; And/or described defoamer is selected from least one in BYK022 defoamer and BYK024 defoamer; And/or described fire retardant is pentabromotoluene.
A kind of preparation method of water-based bamboo wood historical relic's protection coating, comprise: step S01: prepare the first component, described first component comprises following composition according to the mass fraction: crylic acid polyurethane aqueous dispersion body 90 ~ 120 parts, thickening material 0.5 ~ 1.5 part, 5 ~ 20 parts, water; Step S02: prepare second component, described second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 2 ~ 8 parts, dispersion agent 0.5 ~ 5 part, defoamer 0.2 ~ 0.8,10 ~ 30 parts, water, fire retardant 2 ~ 8 parts, mould inhibitor 10 ~ 20 parts, plant mothproofing agent 4 ~ 8 parts; Step S03: be that 1:1 ~ 1:2 packs respectively according to mass ratio by described first component and described second component.
And a kind of application method of foregoing water-based bamboo wood historical relic's protection coating, comprising: the first component and second component are mixed, after slaking, is applied on stone cultural artifact.
The beneficial effect of the embodiment of the present invention is as follows:
1, the present invention by adding mildew resistance and the insect resistance of sanitas and plant mothproofing agent raising coating in coating.
2, coating of the present invention also has the characteristic of fire prevention, waterproof.
3, the production technique of coating of the present invention simple, there is preferably workability.
4, coating of the present invention is without the need to hot setting, in advantages such as room temperature choosing drying are rapid.
5, paint brush of the present invention is coated in bamboo wood cultural artifact surface and plays protective effect, has a wide range of applications in bamboo wood historical relic's protection field.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
The invention provides a kind of water-based bamboo wood historical relic's protection coating.This water-based bamboo wood historical relic's protection coating is that first component of 1:1 ~ 1:2 and second component are formed by mass ratio.Wherein, the first component comprises following composition according to the mass fraction: crylic acid polyurethane aqueous dispersion body 90 ~ 120 parts, thickening material 0.5 ~ 1.5 part, 5 ~ 20 parts, water.Wherein, second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 2 ~ 8 parts, dispersion agent 0.5 ~ 5 part, defoamer 0.2 ~ 0.8,10 ~ 30 parts, water, fire retardant 2 ~ 8 parts, mould inhibitor 10 ~ 20 parts, plant mothproofing agent 4 ~ 8 parts.
The main film forming substance of the water-based bamboo wood historical relic's protection coating of the embodiment of the present invention is disperseed to form under certain processing condition by crylic acid polyurethane aqueous dispersion body and 1-Methoxy-2-propyl acetate; paint film after solidification has high crosslink density; strong adhesion, high rigidity, the features such as high solids content.By adding mildew resistance and the insect resistance of sanitas and plant mothproofing agent raising coating in coating, also there is the characteristic of fire prevention, waterproof simultaneously.In addition fire retardant uses pentabromotoluene, and preferably adopt the non-expansion type pentabromotoluene that decorative appearance is good, flameproof effect is good, is applicable to the fields such as bamboo wood historical relic's protection.
Particularly, this mould inhibitor is silver suboxide mould inhibitor, prepares by the following method:
Step S11: take acetylene as carbon source, with nickel plate for catalyzer, with PCl
3for promotor prepares volution chiral carbon fiber;
Step S12: obtain silver-plated volution chiral carbon fiber dust at the electroplate of volution chiral carbon fiber;
Step S13: silver-plated volution chiral carbon fiber dust is heat-treated, obtains mould inhibitor after cooling.
Wherein, in step S11, preferably adopt horizontal chamber oven substrate method and prepare volution chiral carbon fiber by chemical gas phase growth methods.Wherein, the processing parameter of chemical gas phase growth methods is: temperature of reaction 650 ~ 700 DEG C, argon flow amount 20 ~ 40mL/min, acetylene gas flow 20 ~ 30mL/min, hydrogen flowing quantity 50 ~ 70mL/min, PCl
3flow 0.03 ~ 0.05mL/min.
In step S12, by the electroplate of magnetron sputtering method at volution chiral carbon fiber.Wherein, sputter gas is Ar gas, and target is Ag target.Particularly, be placed on by Ag target on strong magnetic target, have the nickel plate of volution chiral carbon fiber to be placed in magnetic control sputtering device sample table by long, the time of sputtering is 3 minutes.The processing parameter of sputtering is: vacuum tightness l × l0
-4mbar, sputtering current 100mA, sedimentation rate 10nm/ divides.
In step S13, heat-treat in warm tube furnace in preferably adopting.Process of thermal treatment condition is: be incubated 1 hour at 400 DEG C.
The silver suboxide mould inhibitor obtained by aforesaid method is preferably nano level, and this nano level mould inhibitor is volution, forms spiral spirochetal diameter 50 ~ 200nm, pitch 100 ~ 500nm, screw diameter 100 ~ 1000nm.Spirane structure refers to " mould inhibitor winding forms volution, and the mould inhibitor winding of such as wire forms volution ".Spirochetal diameter refers to " form the diameter of the mould inhibitor spirochete self of spirane structure, the mould inhibitor of such as wire forms volution, and the diameter of this wire mould inhibitor self is spirochetal diameter ".Pitch refers to " axial distances between the adjacent two tooth corresponding points of the screw thread of formation spirane structure ".Screw diameter refers to " forming the external diameter of the screw thread of spirane structure ".By adding nano phase ag_2 o mould inhibitor in coating, the coating after coating application has very strong kill activity to mould.This coating can be brushed and be prevented mildew on surfaces such as bamboo wood historical relics, and reduce the rotten speed of bamboo wood historical relic, this silver suboxide mould inhibitor has better bactericidal property relative to other mould inhibitor, and resisting chloride ion penetration jamming performance.This nano level mould inhibitor is that the strength of coating of spiral-shaped structure to coating has enhancement, and it is more easily dispersed in the coating not easily to reunite, and sterilization effect is also significantly better than micron order.
Particularly, this plant mothproofing agent extracts from the mixture of leaf of Cortex cinnamomi camphorae, tarragon and lavandula angustifolia.This plant mothproofing agent is prepared by the following method:
Step S21: by fresh leaf of Cortex cinnamomi camphorae, tarragon and lavandula angustifolia drying and dehydrating;
Step S22: by the leaf of Cortex cinnamomi camphorae after dehydration, tarragon and lavandula angustifolia in mass ratio 2:2:1 mix and pulverize as mixed slurry;
Step S23: by mixed slurry and dehydrated alcohol mixing, extract at 50 DEG C and obtain mixed solution;
Step S24: mixed solution is centrifugal, filtration obtains filtrate, and obtain described plant mothproofing agent by concentrated for filtrate.
Wherein, in step S21, preferably by three kinds of substance dehydrates to water ratio below 10%.
In step S23, the amount ratio of mixed slurry and dehydrated alcohol is preferably: by 1g mixed slurry and 20mL dehydrated alcohol proportioning.The process extracted can be carried out in constant temperature water bath, and the time of preferably extracting is 1h.
In step S24, by mixed solution in low speed large capacity centrifuge with 3000rmin
-1speed carry out centrifugal.Ethanol in this preparation process reclaims by concentrated mode.
The mothproofing agent utilizing leaf of Cortex cinnamomi camphorae, tarragon and lavandula angustifolia to make of the present invention, not only mothproof effect is good but also environmental protection is pollution-free.Traditional santochlor mothproofing agent is the suspicious carcinogens of the animal carcinogens of generally acknowledging at present and the mankind, studies have reported that santochlor can cause the diseases such as liver, lung, kidney and cataract, and think that it has potential carcinogenesis, and the present invention is prepared by natural plant essential oils and has that have no side effect can not be carcinogenic, the sterilant that insecticidal effect and traditional chemical synthesize is suitable.
Particularly, thickening material in the present invention is selected from least one in Natvosol 250HBR and polyethylene wax, dispersion agent is selected from least one in the TH-904 of BYK190 and the Shandong calm and peaceful water treatment company limited production that German Bi Ke company produces, and defoamer is selected from least one in BYK022 and BYK024 of German Bi Ke company production.Water described in the present invention is preferably deionized water or distilled water.
The invention also discloses the preparation method of a kind of water-based bamboo wood historical relic's protection coating.The method comprises following step:
Step S01: prepare the first component.As previously mentioned, the first component comprises following composition according to the mass fraction: crylic acid polyurethane aqueous dispersion body 90 ~ 120 parts, thickening material 0.5 ~ 1.5 part, 5 ~ 20 parts, water.
Step S02: prepare second component.As previously mentioned, second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 2 ~ 8 parts, dispersion agent 0.5 ~ 5 part, defoamer 0.2 ~ 0.8,10 ~ 30 parts, water, fire retardant 2 ~ 8 parts, mould inhibitor 10 ~ 20 parts, plant mothproofing agent 4 ~ 8 parts.
Step S03: be that 1:1 ~ 1:2 packs respectively according to mass ratio by the first component and second component.
Wherein, in second component, the preparation method of mould inhibitor and plant mothproofing agent is prepared according to previously described method.
In step S01, first according to formula consumption, thickening material and water are mixed.This mixing process can be carried out in agitator, accompanies by 300rmin
-1stirring velocity.Then add the crylic acid polyurethane aqueous dispersion body of formula consumption, mix, this process mixed can disperse 30min by the mode of high speed dispersion, obtains the first component.
In step S02, first dispersion agent, defoamer, 1-Methoxy-2-propyl acetate and water are mixed according to formula ratio, the process of this mixing can be carried out getting the raw materials ready in pot.Then at 1000rmin
-1speed under stir, add pentabromotoluene, mould inhibitor, plant mothproofing agent, can on high speed dispersor by above-mentioned substance low speed disperse, then high speed dispersion.Under the effect of high shear force, sand milling dispersion, until fineness is less than 20 μm, obtains second component.
Due to this coating in use, just by above-mentioned two kinds of components mixing, therefore, after prepare the first component and second component, stored the first component and second component by the mode of separating independent packaging.
The embodiment of the present invention additionally provides the application method of a kind of water-based bamboo wood historical relic's protection coating.The method comprises following process: the first above-mentioned component and second component are mixed, and after slaking, is applied on bamboo wood historical relic.Wherein, the mass ratio of the first component and second component is 1:1 ~ 1:2.After both being mixed by the mode stirred, recurring 10min can use.
With specific embodiment, technical scheme of the present invention is described further below.
Embodiment 1
This water-based bamboo wood historical relic's protection coating is prepared according to method of the present invention.Water-based bamboo wood historical relic's protection coating first component of embodiment 1 and second component are that 1:2 is formed according to quality proportioning.Wherein, the first components in mass portion number meter comprise with composition: crylic acid polyurethane aqueous dispersion body 100 parts, thickening material 1 part, distilled water 10 parts.Second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 4 parts, dispersion agent 3 parts, defoamer 0.6 part, distilled water 15 parts, fire retardant 2 parts, mould inhibitor 10 parts, plant mothproofing agent 4 parts.
The water-based bamboo of embodiment 1 wood historical relic's protection coating is carried out performance test, specific as follows:
Mildew resistance: the mortality ratio of mould 15d is close or reach 100%;
Insect resistance: the mortality ratio of the moth-eaten 17d of casting skin hair is close or reach 100%;
Water tolerance: pass through for 245 hours;
Fire line: wooden stick vertical combustion records rate of weight loss 0.91%, charing height 9.5cm.
Embodiment 2
This water-based bamboo wood historical relic's protection coating is prepared according to method of the present invention.Water-based bamboo wood historical relic's protection coating first component of embodiment 2 and second component are that 1:1 is formed according to quality proportioning.Wherein, the first components in mass portion number meter comprise with composition: crylic acid polyurethane aqueous dispersion body 110 parts, thickening material 1 part, distilled water 10 parts.Second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 4 parts, dispersion agent 3 parts, defoamer 0.6 part, distilled water 15 parts, fire retardant 5 parts, mould inhibitor 15 parts, plant mothproofing agent 6 parts.
The water-based bamboo of embodiment 2 wood historical relic's protection coating is carried out performance test, specific as follows:
Mildew resistance: the mortality ratio of mould 13d is close or reach 100%;
Insect resistance: the mortality ratio of the moth-eaten 14d of casting skin hair is close or reach 100%;
Water tolerance: pass through for 279 hours;
Fire line: wooden stick vertical combustion records rate of weight loss 0.87%, charing height 9.1cm.
Embodiment 3
This water-based bamboo wood historical relic's protection coating is prepared according to method of the present invention.Water-based bamboo wood historical relic's protection coating first component of embodiment 3 and second component are that 1:1.5 is formed according to quality proportioning.Wherein, the first components in mass portion number meter comprise with composition: crylic acid polyurethane aqueous dispersion body 120 parts, thickening material 1 part, distilled water 10 parts.Second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 4 parts, dispersion agent 3 parts, defoamer 0.6 part, distilled water 15 parts, fire retardant 8 parts, mould inhibitor 20 parts, plant mothproofing agent 8 parts.
The water-based bamboo of embodiment 3 wood historical relic's protection coating is carried out performance test, specific as follows:
Mildew resistance: the mortality ratio of mould 12d is close or reach 100%;
Insect resistance: the mortality ratio of the moth-eaten 13d of casting skin hair is close or reach 100%;
Water tolerance: pass through for 292 hours;
Fire line: wooden stick vertical combustion records rate of weight loss 0.83%, charing height 8.5cm.
Can find coating lacquer film thickness of the present invention more than 100 μm by above-described embodiment, the mortality ratio of mould 13d is close or reach 100%, and the mortality ratio of the moth-eaten 15d of casting skin hair is close or reach 100%, has obvious lethal effect to moth; Water tolerance is greater than 240h and passes through, and wooden stick vertical combustion records that rate of weight loss is less than 1%, charing is highly less than 10cm.
Water-based bamboo wood historical relic's protection coating of the present invention by adding nano phase ag_2 o mould inhibitor, plant mothproofing agent in water-proof fire-proof paint; formed at bamboo wood cultural artifact surface after coating application and there is fire prevention, waterproof, mildew-resistant and mothproof coating; that a kind of environmental protection is to environment and the free of contamination historical relic's protection coating of historical relic; it is widely used, such as, in fields such as silk, the historical relic's protections of paper painting and calligraphy in fields such as bamboo wood historical relic historical relic's protections.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. a water-based bamboo wood historical relic's protection coating, it is characterized in that: be that first component of 1:1 ~ 1:2 and second component are formed by mass ratio, described first component comprises following composition according to the mass fraction: crylic acid polyurethane aqueous dispersion body 90 ~ 120 parts, thickening material 0.5 ~ 1.5 part, 5 ~ 20 parts, water; Described second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 2 ~ 8 parts, dispersion agent 0.5 ~ 5 part, defoamer 0.2 ~ 0.8,10 ~ 30 parts, water, fire retardant 2 ~ 8 parts, mould inhibitor 10 ~ 20 parts, plant mothproofing agent 4 ~ 8 parts.
2. water-based bamboo wood historical relic's protection coating as claimed in claim 1, is characterized in that: described mould inhibitor is silver suboxide mould inhibitor.
3. water-based bamboo wood historical relic's protection coating as claimed in claim 1, is characterized in that: the shape of described mould inhibitor is volution.
4. water-based bamboo wood historical relic's protection coating as claimed in claim 3, is characterized in that: forming described spiral spirochetal diameter is 50 ~ 200nm, and described spiral pitch is 100 ~ 500nm, and screw diameter is 100 ~ 1000nm.
5. the water-based bamboo wood historical relic's protection coating as described in any one of Claims 1 to 4, is characterized in that: described mould inhibitor is prepared by the following method:
Step S11: take acetylene as carbon source, with nickel plate for catalyzer, with PCl
3for promotor prepares volution chiral carbon fiber;
Step S12: obtain silver-plated volution chiral carbon fiber dust at the electroplate of described volution chiral carbon fiber;
Step S13: described silver-plated volution chiral carbon fiber dust is heat-treated, obtains described mould inhibitor after cooling.
6. water-based bamboo wood historical relic's protection coating as claimed in claim 1, is characterized in that: described plant mothproofing agent extracts from the mixture of leaf of Cortex cinnamomi camphorae, tarragon and lavandula angustifolia.
7. water-based bamboo wood historical relic's protection coating as claimed in claim 6, is characterized in that: described plant mothproofing agent is prepared by the following method:
Step S21: by fresh described leaf of Cortex cinnamomi camphorae, described tarragon and described lavandula angustifolia drying and dehydrating;
Step S22: by the described leaf of Cortex cinnamomi camphorae after dehydration, described tarragon and described lavandula angustifolia in mass ratio 2:2:1 mix and pulverize as mixed slurry;
Step S23: by described mixed slurry and dehydrated alcohol mixing, extract at 50 DEG C and obtain mixed solution;
Step S24: centrifugal for described mixed solution, filtration are obtained filtrate, and obtain described plant mothproofing agent by concentrated for described filtrate.
8. water-based bamboo wood historical relic's protection coating as claimed in claim 1, is characterized in that: described thickening material is selected from least one in Natvosol 250HBR and polyethylene wax; And/or described dispersion agent is selected from least one in BYK190 dispersion agent and TH-904 dispersion agent; And/or described defoamer is selected from least one in BYK022 defoamer and BYK024 defoamer; And/or described fire retardant is pentabromotoluene.
9. a preparation method for water-based bamboo wood historical relic's protection coating, is characterized in that, comprising:
Step S01: prepare the first component, described first component comprises following composition according to the mass fraction: crylic acid polyurethane aqueous dispersion body 90 ~ 120 parts, thickening material 0.5 ~ 1.5 part, 5 ~ 20 parts, water;
Step S02: prepare second component, described second component comprises following composition according to the mass fraction: 1-Methoxy-2-propyl acetate 2 ~ 8 parts, dispersion agent 0.5 ~ 5 part, defoamer 0.2 ~ 0.8,10 ~ 30 parts, water, fire retardant 2 ~ 8 parts, mould inhibitor 10 ~ 20 parts, plant mothproofing agent 4 ~ 8 parts;
Step S03: be that 1:1 ~ 1:2 packs respectively according to mass ratio by described first component and described second component.
10. an application method for the water-based bamboo wood historical relic's protection coating as described in any one of claim 1 ~ 8, is characterized in that, comprising: the first component and second component are mixed, and after slaking, is applied on bamboo wood historical relic.
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Application publication date: 20151111 |