CN105037655A - Carbon gold composite floor and preparation method thereof - Google Patents
Carbon gold composite floor and preparation method thereof Download PDFInfo
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- CN105037655A CN105037655A CN201510558512.4A CN201510558512A CN105037655A CN 105037655 A CN105037655 A CN 105037655A CN 201510558512 A CN201510558512 A CN 201510558512A CN 105037655 A CN105037655 A CN 105037655A
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- flyash
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Abstract
The invention discloses a carbon gold composite floor and a preparation method thereof, and relates to a floor. The carbon gold composite floor is prepared from, by weight, 80-100 parts of polyvinyl chloride resin, 400-700 parts of pulverized fuel ash, 50-70 parts of dioctyl phthalate, 8-10 parts of chlorinated polyethylene, 5-8 parts of acrylate, 5-8 parts of composite heat stabilizer TF-500JP, 1-2 parts of stearic acid and 8-12 parts of silane coupling agents. The preparation method comprises the steps that the silane coupling agents are hydrolyzed by water and ethyl alcohol, added with the pulverized fuel ash and then added with the other components for mixing in a closed type high-speed mixing machine, and the mixture is aged for 10-14 h; plasticizing and piece pulling are carried out on a two-roller open mill, and the temperature ranges from 155 DEG C to 165 DEG C; compression molding is carried out on a plate vulcanizing machine; the temperature ranges from 175 DEG C to 180 DEG C, pressure is 12.5 MPa, and therefore the carbon gold composite floor is obtained. The carbon gold composite floor has the advantages of being high in waste utilization rate, low in production cost, good in performance, safe and environmentally friendly.
Description
Technical field
The present invention relates to floor, relate to composite floor board, be specifically related to a kind of carbon gold composite floor board and preparation method thereof.
Technical background
China take coal as the country of main energy sources, and the flyash of the enormous amount that the thermal power generation dominated by coal produces causes environment day by day severe.How flyash is carried out efficiently, the comprehensive utilization of high performance-price ratio, high added value, become the key subjects that modern faces.But the low value-added field such as the utilization of present stage to flyash mostly is and fills out sea, build the road.A small amount of utilization and the application of building field, the utilization ratio of flyash is only up to 40%.
Chinese patent 2008101582818, disclosing a kind of floor tile, is be floor tile prepared by raw material with flyash, but lower by the floor tile flyash addition that the method is obtained, part starting material are as high in costs such as silver suboxide, honey, glutens, and the poor-performing of obtained floor tile.Chinese patent 2013101517684, discloses floor tile prepared by a kind of PVC film, but is weighting agent by the obtained floor tile of the method with calcium carbonate, and is thermo-stabilizer with tribasic lead sulfate, and not only cost is higher, and does not meet environmental requirement.
In order to solve the above-mentioned defect that prior art exists, the invention provides a kind of preparation technology of the floor based on flyash.
Summary of the invention
The object of this invention is to provide a kind of carbon gold composite floor board and preparation method thereof.
The present invention is by the following technical solutions:
A kind of carbon gold composite floor board is that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 80-100 flyash 400-700
Dioctyl phthalate (DOP) 50-70 chlorinatedpolyethylene 8-10
Acrylate 5-8 composite thermal stabilizer TF-500JP5-8
Stearic acid 1-2 silane coupling agent 8-12.
Further, each component of preferred following weight part:
Polyvinyl chloride (PVC) RESINS 90 flyash 550
Dioctyl phthalate (DOP) 60 chlorinatedpolyethylene 9
Acrylate 7 composite thermal stabilizer TF-500JP6
Stearic acid 1.5 silane coupling agent 10.
Further, the preparation method of above-mentioned carbon gold composite floor board, step is:
(1) by after silane coupling agent water and ethanol hydrolysis, add flyash mixing, carry out priming reaction, and then add other each components of above-mentioned weight part, mix in closed high-speed mixer, ageing 10-14 hour;
(2) in two roller mill by mixed material plasticizing, pulling-on piece, temperature is 155-165 DEG C;
(3) by sheet stock compression molding on vulcanizing press; Temperature 175-180 DEG C, pressure 12.5MPa, gets product.
The present invention take flyash as the carbon gold floor of main material production, for the recycling of flyash opens up a new way, silane coupling agent is used to carry out activation treatment to flyash during preparation, after coupling agent hydrolysis, firmly Si-O covalent linkage is formed on the one hand with flyash condensation, firmly be wound around with PVC macromolecular chain on the other hand, flyash and PVC are combined securely, again by adding softening agent, toughner, thermo-stabilizer, properties-correcting agent and lubricant, improve mechanical property and the processing characteristics of carbon gold composite floor board.And existing Coal ash floor many uses linking agent promotes the combination of flyash and other filler, belong to physical property and combine, so ubiquity flyash addition is low, high in cost of production shortcoming.Namely the present invention uses silane coupling agent to carry out activating fly ash, and make to form chemical between flyash with filler and be combined, substantially increase flyash addition, addition reaches as high as 80%, also reduces production cost simultaneously, is conducive to environment protection.
And existing take PVC as the floor of raw material, also not using flyash as stopping composition, this is because existing physical property combines, PVC and flyash cannot be made to carry out good combination, so high-quality floor tile cannot be obtained.
Flyash is as a kind of solid waste; because reserves are huge; contaminate environment; the carbon gold floor that the present invention utilizes flyash filled PVC to make; there is the excellent mechanical property not available for other PVC board, have both the premium propertiess such as good erosion resistance, very strong resistance to deterioration, zero Form aldehyde release, and the present invention is while carrying out utilization of waste material to flyash simultaneously; reduce production cost, and be conducive to environment protection.The flexural strength 35.77MPa of the floor tile obtained according to the inventive method, shock strength 19.21kJ/m
2, in the water of 23 DEG C, soak 24h, absorption percentage is 0.042%, and burst size of methanal is 0.1mg/L.
In sum, the present invention has that salvage value is high, production cost is low, excellent property, the advantage of safety and environmental protection.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
A kind of carbon gold composite floor board is that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 90 flyash 700
Dioctyl phthalate (DOP) 50 chlorinatedpolyethylene 9
Acrylate 5 composite thermal stabilizer TF-500JP6
Stearic acid 1.5 silane coupling agent 12,
Preparation process is:
(1) by after silane coupling agent water and ethanol hydrolysis, add flyash mixing, carry out priming reaction, and then add other each components of above-mentioned weight part, mix in closed high-speed mixer, ageing 12 hours;
(2) in two roller mill by mixed material plasticizing, pulling-on piece, temperature is 155-165 DEG C;
(3) by sheet stock compression molding on vulcanizing press; Temperature 175-180 DEG C, pressure 12.5MPa, gets product.
Embodiment 2
A kind of carbon gold composite floor board is that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 100 flyash 400
Dioctyl phthalate (DOP) 60 chlorinatedpolyethylene 10
Acrylate 8 composite thermal stabilizer TF-500JP5
Stearic acid 2 silane coupling agent 8,
Preparation process is:
(1) by after silane coupling agent water and ethanol hydrolysis, add flyash mixing, carry out priming reaction, and then add other each components of above-mentioned weight part, mix in closed high-speed mixer, ageing 14 hours;
(2) in two roller mill by mixed material plasticizing, pulling-on piece, temperature is 155-165 DEG C;
(3) by sheet stock compression molding on vulcanizing press; Temperature 175-180 DEG C, pressure 12.5MPa, gets product.
Embodiment 3
A kind of carbon gold composite floor board is that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 80 flyash 600
Dioctyl phthalate (DOP) 70 chlorinatedpolyethylene 8
Acrylate 7 composite thermal stabilizer TF-500JP8
Stearic acid 1 silane coupling agent 10,
Preparation process is:
(1) material of above-mentioned weight part is mixed in closed high-speed mixer, ageing 10 hours;
(2) in two roller mill by mixed material plasticizing, pulling-on piece, temperature is 155-165 DEG C;
(3) by sheet stock compression molding on vulcanizing press; Temperature 175-180 DEG C, pressure 12.5MPa, gets product.
Embodiment 4
A kind of carbon gold composite floor board is that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 90 flyash 550
Dioctyl phthalate (DOP) 60 chlorinatedpolyethylene 9
Acrylate 7 composite thermal stabilizer TF-500JP6
Stearic acid 1.5 silane coupling agent 10,
Preparation process is:
(1) material of above-mentioned weight part is mixed in closed high-speed mixer, ageing 10 hours;
(2) in two roller mill by mixed material plasticizing, pulling-on piece, temperature is 155-165 DEG C;
(3) by sheet stock compression molding on vulcanizing press; Temperature 175-180 DEG C, pressure 12.5MPa, gets product.
Claims (3)
1. a carbon gold composite floor board, it is characterized in that, be that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 80-100 flyash 400-700
Dioctyl phthalate (DOP) 50-70 chlorinatedpolyethylene 8-10
Acrylate 5-8 composite thermal stabilizer TF-500JP5-8
Stearic acid 1-2 silane coupling agent 8-12.
2. carbon gold composite floor board according to claim 1, it is characterized in that, be that raw material is prepared from by each component of following weight part:
Polyvinyl chloride (PVC) RESINS 90 flyash 550
Dioctyl phthalate (DOP) 60 chlorinatedpolyethylene 9
Acrylate 7 composite thermal stabilizer TF-500JP6
Stearic acid 1.5 silane coupling agent 10.
3. the preparation method of carbon gold composite floor board according to claim 1, it is characterized in that, step is:
(1) by after silane coupling agent water and ethanol hydrolysis, add flyash mixing, carry out priming reaction, and then add other each components of above-mentioned weight part, mix in closed high-speed mixer, ageing 10-14 hour;
(2) in two roller mill by mixed material plasticizing, pulling-on piece, temperature is 155-165 DEG C;
(3) by sheet stock compression molding on vulcanizing press; Temperature 175-180 DEG C, pressure 12.5MPa, gets product.
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CN201510558512.4A CN105037655A (en) | 2015-09-06 | 2015-09-06 | Carbon gold composite floor and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105971240A (en) * | 2016-06-06 | 2016-09-28 | 江苏洛基木业有限公司 | Floor made of carbide materials or carbon gold materials and production process |
CN107722507A (en) * | 2017-11-10 | 2018-02-23 | 中山市远疆环保科技有限公司 | A kind of high filling fly ash sheet material and preparation method thereof |
CN109401109A (en) * | 2018-08-23 | 2019-03-01 | 安徽建筑大学 | Fly ash enhanced PVC plastic and preparation method thereof |
CN110563382A (en) * | 2019-09-27 | 2019-12-13 | 山西碳金科技有限公司 | fly ash floor and preparation method thereof |
CN110640872A (en) * | 2019-09-27 | 2020-01-03 | 山西碳金科技有限公司 | Fly ash decorative wallboard and preparation method thereof |
CN112920524A (en) * | 2021-01-26 | 2021-06-08 | 湖北理工学院 | Waterproof and anti-icing fly ash/PVC composite board and preparation method and application thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102372880A (en) * | 2010-08-06 | 2012-03-14 | 苏州富通电器塑业有限公司 | Fly ash-highly filled polyvinyl chloride plastic floor |
CN103172952A (en) * | 2013-04-08 | 2013-06-26 | 陕西理工学院 | Preparation method of coal ash-resin composite material suitable for extrusion molding |
CN103254527A (en) * | 2013-05-21 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | Ecological thermal insulation floor |
DE102012003613A1 (en) * | 2012-02-23 | 2013-08-29 | Armstrong DLW GmbH | Flexible poly vinyl chloride-based plastic floor covering comprises ionomer, based on the total weight of floor covering formulation |
-
2015
- 2015-09-06 CN CN201510558512.4A patent/CN105037655A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102372880A (en) * | 2010-08-06 | 2012-03-14 | 苏州富通电器塑业有限公司 | Fly ash-highly filled polyvinyl chloride plastic floor |
DE102012003613A1 (en) * | 2012-02-23 | 2013-08-29 | Armstrong DLW GmbH | Flexible poly vinyl chloride-based plastic floor covering comprises ionomer, based on the total weight of floor covering formulation |
CN103172952A (en) * | 2013-04-08 | 2013-06-26 | 陕西理工学院 | Preparation method of coal ash-resin composite material suitable for extrusion molding |
CN103254527A (en) * | 2013-05-21 | 2013-08-21 | 苏州富通高新材料科技股份有限公司 | Ecological thermal insulation floor |
Non-Patent Citations (4)
Title |
---|
于守武: "《高分子材料改性——原理及技术》", 31 May 2015, 知识产权出版社 * |
吴正直,等: "《粉煤灰综合利用》", 30 June 2013, 中国建材工业出版社 * |
李登新: "《固体废物处理与处置》", 31 July 2014, 中国环境出版社 * |
祝永年,等: "《新型装修材料及其应用》", 31 October 1989, 中国铁道出版社 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105971240A (en) * | 2016-06-06 | 2016-09-28 | 江苏洛基木业有限公司 | Floor made of carbide materials or carbon gold materials and production process |
CN107722507A (en) * | 2017-11-10 | 2018-02-23 | 中山市远疆环保科技有限公司 | A kind of high filling fly ash sheet material and preparation method thereof |
CN109401109A (en) * | 2018-08-23 | 2019-03-01 | 安徽建筑大学 | Fly ash enhanced PVC plastic and preparation method thereof |
CN110563382A (en) * | 2019-09-27 | 2019-12-13 | 山西碳金科技有限公司 | fly ash floor and preparation method thereof |
CN110640872A (en) * | 2019-09-27 | 2020-01-03 | 山西碳金科技有限公司 | Fly ash decorative wallboard and preparation method thereof |
CN112920524A (en) * | 2021-01-26 | 2021-06-08 | 湖北理工学院 | Waterproof and anti-icing fly ash/PVC composite board and preparation method and application thereof |
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Application publication date: 20151111 |