CN105019236B - A kind of textile composite antibacterial finishing agent - Google Patents
A kind of textile composite antibacterial finishing agent Download PDFInfo
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- CN105019236B CN105019236B CN201510410022.XA CN201510410022A CN105019236B CN 105019236 B CN105019236 B CN 105019236B CN 201510410022 A CN201510410022 A CN 201510410022A CN 105019236 B CN105019236 B CN 105019236B
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- composite antibacterial
- antibacterial finishing
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Abstract
The present invention relates to a kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Polyhexamethylene guanide 1 5%, glycine betaine 5 10%, nano zine oxide 1 5%, shitosan 1 5%, surfactant 0.5 2%, organic solvent 5 10%, essence 0.1 0.5%.The textile composite antibacterial finishing agent uses various antiseptic Synergistic antimicrobials, makes that product heat resistance of the present invention is high, antibiotic property strong, and safe and reliable, environmental protection can be used for the antibiotic finish of various textiles.
Description
Technical field
The present invention relates to a kind of textile finish, in particular to a kind of textile composite antibacterial finishing agent.
Background technology
Porous textile easily absorbs the excretion such as sweat, metabolism product and sebum of human sweat glands and smegma
Thing, so as to form the nutrient source of microorganism, easily causes the growth and breeding of microorganism.Particularly in moist, nutrition and properly
At a temperature of, microbial reproduction is rapid, and bacterial plaque is generated on fabric, make textile produce go mouldy, it is brittle or even rotten so that
Human body is uncomfortable in dress or application process or produces harmful effect to human body.In addition, bacterium also decomposes human secretion, produce
The smell substances such as ammonia, so as to produce dirty body odour, cause the propagation of disease of skin or infection.
With the improvement of living standards, requirement more and more higher of the people to quality of life, it is especially closely bound up with life
Textile, particularly safely, comfortably, health, cleaning etc. idea formation, make the Final finishings such as the antibacterial of weaving, mould proof, deodorization
Processing is more exposed to the attention of people.
The purpose of textiles antibacterial finishing is to confer to the good antibacterial functions of textile, protects textile not dropped by mould etc.
Solution, and microorganisms spreading is prevented, reduce the cross-infection rate of PE；Meanwhile, can also prevent bacterium constantly numerous on fabric
Environment is taken in the foul smell grown and produce, improvement.
The content of the invention
The present invention provides a kind of textile composite antibacterial finishing agent, and the antibacterial finishing agent is cooperateed with anti-using various antiseptics
Bacterium, makes that product heat resistance of the present invention is high, antibiotic property strong, and safe and reliable, environmental protection, the antibacterial that can be used for various textiles is whole
Reason.
Specifically, a kind of raw material of textile composite antibacterial finishing agent of present invention offer, including following percentage by weight：It is poly-
Hexa-methylene guanidine 1-5%, glycine betaine 5-10%, nano zine oxide 1-5%, shitosan 1-5%, surfactant 0.5-2%, have
Machine solvent 5-10%, essence 0.1-0.5%.
In a specific embodiment of the invention, described a kind of textile composite antibacterial finishing agent, also including poly-
Ethylene glycol 1-2%, hydroxypropyl methyl cellulose 1-3% and aqueous polyurethane 1-3%.Preferably, the polyethylene glycol is poly- second
Glycol 400.
In a specific embodiment of the invention, a kind of described textile composite antibacterial finishing agent, wherein surface
Activating agent is NPE or ethoxylated dodecyl alcohol.
In a specific embodiment of the invention, described a kind of textile composite antibacterial finishing agent, wherein organic
Solvent is ethanol and acetone, and the volume ratio of the two is 1:1.
In a specific embodiment of the invention, a kind of described textile composite antibacterial finishing agent, including it is as follows
The raw material of percentage by weight：Polyhexamethylene guanide 1-5%, glycine betaine 5-10%, nano zine oxide 1-5%, shitosan 1-5%,
Surfactant 0.5-2%, organic solvent 5-10%, essence 0.1-0.5%, polyethylene glycol 1-2%, hydroxypropyl methyl cellulose
1-3%, aqueous polyurethane 1-3%, balance of deionized water.
In a specific embodiment of the invention, a kind of described textile composite antibacterial finishing agent, including it is as follows
The raw material of percentage by weight：Polyhexamethylene guanide 1%, glycine betaine 5%, nano zine oxide 1%, shitosan 1%, surfactant
0.5%, organic solvent 5%, essence 0.1%, polyethylene glycol 1%, hydroxypropyl methyl cellulose 1%, aqueous polyurethane 1% is remaining
It is deionized water to measure.
In a specific embodiment of the invention, a kind of described textile composite antibacterial finishing agent, including it is as follows
The raw material of percentage by weight：Polyhexamethylene guanide 3%, glycine betaine 8%, nano zine oxide 3%, shitosan 4%, surfactant
1%, organic solvent 8%, essence 0.3%, polyethylene glycol 1.5%, hydroxypropyl methyl cellulose 2%, aqueous polyurethane 2% is remaining
It is deionized water to measure.
In a specific embodiment of the invention, a kind of described textile composite antibacterial finishing agent, including it is as follows
The raw material of percentage by weight：Polyhexamethylene guanide 5%, glycine betaine 10%, nano zine oxide 5%, shitosan 5%, surface-active
Agent 2%, organic solvent 10%, essence 0.5%, polyethylene glycol 2%, hydroxypropyl methyl cellulose 3%, aqueous polyurethane 3% is remaining
It is deionized water to measure.
In a specific embodiment of the invention, a kind of described textile composite antibacterial finishing agent, wherein surface
Activating agent is NPE or ethoxylated dodecyl alcohol.
In a specific embodiment of the invention, described a kind of textile composite antibacterial finishing agent, wherein organic
Solvent is ethanol and acetone, and the volume ratio of the two is 1:1.
Textile composite antibacterial finishing agent of the present invention can be prepared by the way of this area routinely mixing.Tool
Body, preparation method of the invention may include steps of：
(1) deionized water, organic solvent, surfactant are sufficiently mixed at room temperature；
(2) temperature is gradually risen to after 60 DEG C, adding polyethylene glycol, hydroxypropyl methyl cellulose and aqueous polyurethane, and
Persistently stir 30min；
(3) be cooled to 40 DEG C adds glycine betaine, polyhexamethylene guanide, nano zine oxide, shitosan to fill under continuous stirring
Divide mixing；
(4) it is kept stirring for, is down to room temperature, adds essence, discharging.
Textile composite antibacterial finishing agent of the invention, application method is that finishing agent is configured into padding liquid, at room temperature,
Fabric is placed in padding liquid, using two leaching two roll process, pick-up is 90%-100%, by preliminary drying, bake, to fabric
Carry out antibiotic finish；Textile composite antibacterial finishing agent of the invention soaks arrangement after also can be used for home textiles washing.
Textile composite antibacterial finishing agent of the invention, using various antiseptic Synergistic antimicrobials, makes product of the present invention heat-resisting
The high, antibiotic property of property is strong, and safe and reliable, environmental protection can be used for the antibiotic finish of various textiles.Without special theory in the present invention
In the case of bright, all percentages are weight percentage.
With reference to specific embodiment, the invention will be further described.
Specific embodiment
Embodiment 1：
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Polyhexamethylene guanide 1% is sweet
Dish alkali 5%, nano zine oxide 1%, shitosan 1%, surfactant 0.5%, organic solvent 5%, essence 0.1%, poly- second two
Alcohol 1%, hydroxypropyl methyl cellulose 1%, aqueous polyurethane 1%, wherein balance of deionized water, organic solvent are ethanol and third
Ketone, the volume ratio of the two is 1:1.
Embodiment 2:
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Polyhexamethylene guanide 3% is sweet
Dish alkali 8%, nano zine oxide 3%, shitosan 4%, surfactant 1%, organic solvent 8%, essence 0.3%, polyethylene glycol
1.5%, hydroxypropyl methyl cellulose 2%, aqueous polyurethane 2%, wherein balance of deionized water, organic solvent are ethanol and third
Ketone, the volume ratio of the two is 1:1.
Embodiment 3：
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Polyhexamethylene guanide 5% is sweet
Dish alkali 10%, nano zine oxide 5%, shitosan 5%, surfactant 2%, organic solvent 10%, essence 0.5%, poly- second two
Alcohol 2%, hydroxypropyl methyl cellulose 3%, aqueous polyurethane 3%, wherein balance of deionized water, organic solvent are ethanol and third
Ketone, the volume ratio of the two is 1:1.
Reference examples 1
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Glycine betaine 10%, poly- six methylene
Base guanidine 4%, shitosan 4%, surfactant 1%, organic solvent 8%, essence 0.3%, polyethylene glycol 1.5%, hydroxypropyl first
Base cellulose 2%, aqueous polyurethane 2%, wherein balance of deionized water, organic solvent are ethanol and acetone, the volume of the two
Than being 1:1.
Reference examples 2
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Glycine betaine 10%, it is nano oxidized
Zinc 4%, shitosan 4%, surfactant 1%, organic solvent 8%, essence 0.3%, polyethylene glycol 1.5%, hydroxypropyl methyl
Cellulose 2%, aqueous polyurethane 2%, wherein balance of deionized water, organic solvent are ethanol and acetone, the volume ratio of the two
It is 1:1.
Reference examples 3
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Polyhexamethylene guanide 7%, receives
Rice zinc oxide 7%, shitosan 4%, surfactant 1%, organic solvent 8%, essence 0.3%, polyethylene glycol 1.5%, hydroxypropyl
Ylmethyl cellulose 2%, aqueous polyurethane 2%, balance of deionized water, wherein organic solvent be ethanol and acetone, the two
Volume ratio is 1:1.
Reference examples 4：
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Glycine betaine 8%, poly- six methylene
Base guanidine 3%, nano zine oxide 3%, shitosan 4%, surfactant 1%, organic solvent 8%, essence 0.3%, polyethylene glycol
1.5%, aqueous polyurethane 4%, wherein balance of deionized water, organic solvent are ethanol and acetone, and the volume ratio of the two is 1:
1。
Reference examples 5：
A kind of textile composite antibacterial finishing agent, including following percentage by weight raw material：Glycine betaine 8%, poly- six methylene
Base guanidine 3%, nano zine oxide 3%, shitosan 4%, surfactant 1%, organic solvent 8%, essence 0.3%, polyethylene glycol
1.5%, hydroxypropyl methyl cellulose 4%, wherein balance of deionized water, organic solvent are ethanol and acetone, the volume of the two
Than being 1:1.
Embodiment 4：Effect experiment
Same pieces of cloth are carried out the treatment of Escherichia coli, Pseudomonas aeruginosa and staphylococcus aureus respectively, is then put respectively
Enter in the textile composite antibacterial finishing agent prepared by the formula of the embodiment of the present invention 2, reference examples 1-5, the time is 10 minutes, system
Sterilizing rate of each formula to Escherichia coli, Pseudomonas aeruginosa and staphylococcus aureus in pieces of cloth is counted, and is recorded in table 1；
The bactericidal effect of the textile composite antibacterial finishing agent of the present invention of table 1
| Escherichia coli | Pseudomonas aeruginosa | Staphylococcus aureus | |
| Embodiment 1 | 100% | 100% | 99.9% |
| Reference examples 1 | 92.0% | 91.5% | 91.1% |
| Reference examples 2 | 93.6% | 92.8% | 92.5% |
| Reference examples 3 | 91.4% | 90.3% | 90.8% |
| Reference examples 4 | 93.0% | 92.5% | 92.1% |
| Reference examples 5 | 93.5% | 92.7% | 93.8% |
Can be drawn by the result of table 1, each component of finishing agent of the present invention is mutually cooperateed with, and antibacterial action is played jointly,
Reference examples 1-5 omits nano zine oxide, polyhexamethylene guanide, glycine betaine, hydroxypropyl methyl cellulose or aqueous poly- ammonia respectively
After ester, antibacterial effect can all decline.
Claims (4)
1. a kind of raw material of textile composite antibacterial finishing agent, including following percentage by weight：Polyhexamethylene guanide 1-5% is sweet
Dish alkali 5-10%, nano zine oxide 1-5%, shitosan 1-5%, surfactant 0.5-2%, organic solvent 5-10%, essence
0.1-0.5%, polyethylene glycol 1-2%, hydroxypropyl methyl cellulose 1-3%, aqueous polyurethane 1-3%, balance of deionized water；
Wherein organic solvent is ethanol and acetone, and the volume ratio of the two is 1:1；Wherein surfactant be NPE or
Person's ethoxylated dodecyl alcohol.
2. a kind of raw material of textile composite antibacterial finishing agent according to claim 1, including following percentage by weight：It is poly-
Hexa-methylene guanidine 1%, glycine betaine 5%, nano zine oxide 1%, shitosan 1%, surfactant 0.5%, organic solvent 5%,
Essence 0.1%, polyethylene glycol 1%, hydroxypropyl methyl cellulose 1%, aqueous polyurethane 1%, balance of deionized water.
3. a kind of raw material of textile composite antibacterial finishing agent according to claim 1, including following percentage by weight：It is poly-
Hexa-methylene guanidine 3%, glycine betaine 8%, nano zine oxide 3%, shitosan 4%, surfactant 1%, organic solvent 8% is fragrant
Essence 0.3%, polyethylene glycol 1.5%, hydroxypropyl methyl cellulose 2%, aqueous polyurethane 2%, balance of deionized water.
4. a kind of raw material of textile composite antibacterial finishing agent according to claim 1, including following percentage by weight：It is poly-
Hexa-methylene guanidine 5%, glycine betaine 10%, nano zine oxide 5%, shitosan 5%, surfactant 2%, organic solvent 10%,
Essence 0.5%, polyethylene glycol 2%, hydroxypropyl methyl cellulose 3%, aqueous polyurethane 3%, balance of deionized water.
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| CN201510410022.XA CN105019236B (en) | 2015-07-13 | 2015-07-13 | A kind of textile composite antibacterial finishing agent |
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|---|---|---|---|
| CN201510410022.XA CN105019236B (en) | 2015-07-13 | 2015-07-13 | A kind of textile composite antibacterial finishing agent |
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| CN105019236A CN105019236A (en) | 2015-11-04 |
| CN105019236B true CN105019236B (en) | 2017-06-23 |
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| CN105350315A (en) * | 2015-12-16 | 2016-02-24 | 常熟绣珀纤维有限公司 | Method for preparing ultrahigh molecular weight polyethylene fine fiber |
| CN105506990A (en) * | 2015-12-16 | 2016-04-20 | 常熟市华博毛纺织有限公司 | Garment material finishing process |
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| CN105625032A (en) * | 2016-03-21 | 2016-06-01 | 卢洁 | Ultraviolet-proof polyester-cotton fabric and preparation method thereof |
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| CN105755809A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Antibacterial finishing agent for textile fabric and preparation method of antibacterial finishing agent |
| CN105755818A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Antibacterial finishing agent for textile fabric and preparation method of antibacterial finishing agent |
| CN105734952A (en) * | 2016-05-13 | 2016-07-06 | 盐城工学院 | Textile finishing auxiliary agent and treatment method of textile |
| CN106894227A (en) * | 2017-02-17 | 2017-06-27 | 南京凯创协同纳米技术有限公司 | Antibacterial nonwoven cloth and preparation method thereof |
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| CN107604645A (en) * | 2017-09-20 | 2018-01-19 | 安徽锦翔纺织服饰有限公司 | A kind of comfortable composite material of antibacterial |
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| CN112442898A (en) * | 2020-11-25 | 2021-03-05 | 浙江天天向上无纺布科技有限公司 | Antibacterial cleaning cloth and preparation method thereof |
| CN114668021B (en) * | 2021-04-08 | 2023-10-27 | 上海涂固安高科技有限公司 | Food-grade multifunctional nano-composite and preparation and application thereof |
| CN113622188A (en) * | 2021-08-12 | 2021-11-09 | 杭州纵纬针纺有限公司 | Deodorizing knitted fabric and manufacturing method thereof |
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| WO2002022941A1 (en) * | 2000-09-14 | 2002-03-21 | Ciba Specialty Chemicals Holding Inc. | Process for the antimicrobial treatment of fiber materials |
| CN103668973A (en) * | 2012-09-21 | 2014-03-26 | 青岛道合生物科技有限公司 | Soft antibacterial finishing agent special for textiles |
| CN103255679B (en) * | 2013-05-06 | 2015-11-25 | 金红叶纸业集团有限公司 | Antibacterial mixed liquor, anti-bacteria paper and antibacterial paper production technique |
| CN103520029B (en) * | 2013-09-22 | 2016-03-02 | 天津市中科健新材料技术有限公司 | The dry towel manufacture method of a kind of sterilization |
| CN103668978B (en) * | 2013-11-27 | 2015-12-30 | 江苏中新资源集团有限公司 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
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