CN105017877A - Aqueous environmentally-friendly polyethylene plastic cement paint accelerant and preparation method thereof - Google Patents
Aqueous environmentally-friendly polyethylene plastic cement paint accelerant and preparation method thereof Download PDFInfo
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- CN105017877A CN105017877A CN201510407292.5A CN201510407292A CN105017877A CN 105017877 A CN105017877 A CN 105017877A CN 201510407292 A CN201510407292 A CN 201510407292A CN 105017877 A CN105017877 A CN 105017877A
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- methylcyclohexane
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Abstract
The invention discloses an aqueous environmentally-friendly polyethylene plastic cement paint accelerant. The aqueous environmentally-friendly polyethylene plastic cement paint accelerant consists of the following components in percentage by weight: 22%-27% of solid thermoplastic polyolefine resins, 3%-8% of solid state dammar resins, 5%-10% of butanone, 3%-6% of isopropyl alcohol, 39%-62% of methylcyclohexane and 5%-10% of an emulsifying agent. The aqueous environmentally-friendly polyethylene plastic cement paint accelerant has high product performance, the preparation technology of the aqueous environmentally-friendly polyethylene plastic cement paint accelerant is simple, the price is low, the construction performance is good, the environmental pressure is low, and the aqueous environmentally-friendly polyethylene plastic cement paint accelerant is convenient for large-scale industrial production and has wide market prospects.
Description
Technical field
The present invention relates to a kind of coating promotor, particularly relate to a kind of aqueous, environmental protective polyethylene plastic coating promotor and preparation method thereof.
Background technology
PE plastics because of its environmental and durable plurality of advantages such as light, so be day by day widely used on automobile, engineering plastics, toy, container, other mouldings and packaging film.In order to modify and protect these plastic prods, usually for their last layer paints or art pattern attractive in appearance can be stamped.
At present, plasthetics is due to poorly conductive, and in electrostatic spraying, need to apply one deck conductive primer at whole plastic surface could spray paint.Simultaneously due to the technique of electrostatic spraying, much have the plastic coating that chemicals-resistant daily use chemicals product such as () Liquid soap, liquid detergent, cleansing milk requires and coating surface can be caused when electrostatic spraying coarse, uneven color, weak effect does not reach customer requirement.
Be very difficult at plastics adhered thereto coating and printed patterns, and be wherein the most difficult for the application of PE (polyethylene), these difficult problems are not well solved all the time.Have now a lot of producer import chlorinated polypropylene to do PE promotor, adhesion effect is all undesirable, and because of chloride also not environmentally.
Summary of the invention
The present invention is the defect in order to overcome prior art, object is to provide the direct disposable spray finishing of a kind of energy in the aqueous, environmental protective polyethylene plastic coating promotor of polyethylene (PE) plastic cement, this aqueous, environmental protective polyethylene plastic coating promotor still can obtain wear-resisting and the heat-resisting and erosion of water of excellent sticking power, paint film, easy easy spray when not carrying out flame or corona treatment, save artificial and material resources and time.
The technical solution adopted for the present invention to solve the technical problems is: a kind of aqueous, environmental protective polyethylene plastic coating promotor, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 22% ~ 27%
Solid-state dammar gum 3% ~ 8%
Butanone 5% ~ 10%
Virahol 3% ~ 6%
Methylcyclohexane 39% ~ 62%
Emulsifying agent 5% ~ 10%.
This aqueous, environmental protective polyethylene plastic coating promotor adopt formula rate comparatively to optimize have following several proportioning:
1. solid thermoplastic polyolefin resin 22%, solid-state dammar gum 4%, butanone 5%, Virahol 4%, methylcyclohexane 60%, emulsifying agent 5%.;
2. solid thermoplastic polyolefin resin 25%, solid-state dammar gum 7%, butanone 6%, Virahol 3%, methylcyclohexane 50%, emulsifying agent 9%.
3. solid thermoplastic polyolefin resin 27%, solid-state dammar gum 3%, butanone 7%, Virahol 5%, methylcyclohexane 52%, emulsifying agent 6%.
4. solid thermoplastic polyolefin resin 23%, solid-state dammar gum 5%, butanone 8%, Virahol 6%, methylcyclohexane 51%, emulsifying agent 7%.
5. solid thermoplastic polyolefin resin 24%, solid-state dammar gum 6%, butanone 9%, Virahol 4%, methylcyclohexane 49%, emulsifying agent 8%.
6. solid thermoplastic polyolefin resin 26%, solid-state dammar gum 8%, butanone 10%, Virahol 3%, methylcyclohexane 43%, emulsifying agent 10%.
Thermoplastic polyolefin resin is that a class is with fastest developing speed, kind maximum, the thermoplastic resin that output is maximum, and feature is: 1, have obvious mechanical relaxation phenomenon; 2, under external force, the ability of deformation is comparatively large, namely when rate of straining is little, can have sizable tension set; 3, shock resistance is good.Dammar gum originates in a kind of Dipterocarpaceae plant secretion thing be with in South East Asia one, outward appearance is transparent yellowishly strengthens body to amber grain, be usually used in the glazing wet goods aspect of ink, foodstuff additive, makeup, medical treatment and oil painting and Tan Peila drawing, the sticking power of product, mobility, luminance brightness etc. can be increased.Butanone is colourless transparent liquid, has similar acetone smell, volatile, can be miscible with ethanol, ether, benzene, chloroform, oils.Virahol is as organic raw material and solvent, miscible with water, ethanol, ether, chloroform, can melt the gas chromatography such as alkaloid, rubber and some inorganics.Methylcyclohexane is used as rubber, coating, clear lacquer solvent, fat extracting solvent etc.Emulsifying agent to improve the various surface tension formed between phase in emulsion, makes it the material forming uniform and stable dispersion system or emulsion.
Further scheme as to preceding solution: aforesaid solid thermoplastic polyolefin resin be solid thermoplastic polyvinyl chloride (PVC) RESINS, solid thermoplastic polyvinyl resin, solid thermoplastic acrylic resin, solid thermoplastic polystyrene resin more than one.
In addition, the invention still further relates to the preparation method of aqueous, environmental protective polyethylene plastic coating promotor, the step of this preparation method is:
(1) mixing liquid of butanone, Virahol and methylcyclohexane is added in dispersion cup, stir;
(2) in dispersion cup, solid thermoplastic polyolefin resin, solid-state dammar gum is added at leisure again, dispersing and dissolving 40 minutes;
(3) add emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
In sum, aqueous, environmental protective polyethylene plastic coating promotor product performance of the present invention are excellent, and the preparation technology of product is simple, cheap, workability and environmental stress is little, are convenient to large-scale industrial and produce, have wide market outlook.
Embodiment
Embodiment 1
A kind of aqueous, environmental protective polyethylene plastic coating promotor described by the embodiment of the present invention 1, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 22%
Solid-state dammar gum 4%
Butanone 5%
Virahol 4%
Methylcyclohexane 60%
Emulsifying agent 5%.
Aforesaid solid thermoplastic polyolefin resin is solid thermoplastic polyvinyl chloride (PVC) RESINS.
First be 5% butanone by mass percent, the mixing liquid of 4% Virahol and 60% methylcyclohexane adds in dispersion cup, stir; And then in dispersion cup, add 22% solid thermoplastic polyvinyl chloride (PVC) RESINS, 4% solid-state dammar gum at leisure, dispersing and dissolving 40 minutes; Finally add 5% emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
Embodiment 2
A kind of aqueous, environmental protective polyethylene plastic coating promotor described by the embodiment of the present invention 2, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 25%
Solid-state dammar gum 7%
Butanone 6%
Virahol 3%
Methylcyclohexane 50%
Emulsifying agent 9%.
Aforesaid solid thermoplastic polyolefin resin is solid thermoplastic polyvinyl resin.
First be 6% butanone by mass percent, the mixing liquid of 3% Virahol and 50% methylcyclohexane adds in dispersion cup, stir; And then in dispersion cup, add 25% solid thermoplastic polyvinyl resin, 7% solid-state dammar gum at leisure, dispersing and dissolving 40 minutes; Finally add 9% emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
Embodiment 3
A kind of aqueous, environmental protective polyethylene plastic coating promotor described by the embodiment of the present invention 3, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 27%
Solid-state dammar gum 3%
Butanone 7%
Virahol 5%
Methylcyclohexane 52%
Emulsifying agent 6%.
Aforesaid solid thermoplastic polyolefin resin is solid thermoplastic acrylic resin.
First be 7% butanone by mass percent, the mixing liquid of 5% Virahol and 52% methylcyclohexane adds in dispersion cup, stir; And then in dispersion cup, add 27% solid thermoplastic acrylic resin, 3% solid-state dammar gum at leisure, dispersing and dissolving 40 minutes; Finally add 6% emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
Embodiment 4
A kind of aqueous, environmental protective polyethylene plastic coating promotor described by the embodiment of the present invention 4, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 23%
Solid-state dammar gum 5%
Butanone 8%
Virahol 6%
Methylcyclohexane 51%
Emulsifying agent 7%.
Aforesaid solid thermoplastic polyolefin resin is solid thermoplastic polystyrene resin.
First be 8% butanone by mass percent, the mixing liquid of 6% Virahol and 51% methylcyclohexane adds in dispersion cup, stir; And then in dispersion cup, add 23% solid thermoplastic polystyrene resin, 5% solid-state dammar gum at leisure, dispersing and dissolving 40 minutes; Finally add 7% emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
Embodiment 5
A kind of aqueous, environmental protective polyethylene plastic coating promotor described by the embodiment of the present invention 5, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 24%
Solid-state dammar gum 6%
Butanone 9%
Virahol 4%
Methylcyclohexane 49%
Emulsifying agent 8%.
Aforesaid solid thermoplastic polyolefin resin is the mixture of solid thermoplastic polyvinyl chloride (PVC) RESINS and solid thermoplastic polyvinyl resin.
First be 9% butanone by mass percent, the mixing liquid of 4% Virahol and 49% methylcyclohexane adds in dispersion cup, stir; And then in dispersion cup, add mixture, the 6% solid-state dammar gum of 24% solid thermoplastic polyvinyl chloride (PVC) RESINS and solid thermoplastic polyvinyl resin at leisure, dispersing and dissolving 40 minutes; Finally add 8% emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
Embodiment 6
A kind of aqueous, environmental protective polyethylene plastic coating promotor described by the embodiment of the present invention 6, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 26%
Solid-state dammar gum 8%
Butanone 10%
Virahol 3%
Methylcyclohexane 43%
Emulsifying agent 10%.
Aforesaid solid thermoplastic polyolefin resin is the mixture of solid thermoplastic acrylic resin and solid thermoplastic polystyrene resin.
First be 10% butanone by mass percent, the mixing liquid of 3% Virahol and 43% methylcyclohexane adds in dispersion cup, stir; And then in dispersion cup, add mixture, the 8% solid-state dammar gum of 26% solid thermoplastic acrylic resin and solid thermoplastic polystyrene resin at leisure, dispersing and dissolving 40 minutes; Finally add 10% emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
When aqueous, environmental protective polyethylene plastic coating promotor in the various embodiments described above uses, can spray with after methylcyclohexane mix and blend, the blending ratio of aqueous, environmental protective polyethylene plastic coating promotor and methylcyclohexane is 1:1-4.
The above is only preferred embodiment of the present invention, not does any pro forma restriction to technology contents of the present invention.Every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.
Claims (9)
1. an aqueous, environmental protective polyethylene plastic coating promotor, is characterized in that, is made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 22% ~ 27%
Solid-state dammar gum 3% ~ 8%
Butanone 5% ~ 10%
Virahol 3% ~ 6%
Methylcyclohexane 39% ~ 62%
Emulsifying agent 5% ~ 10%.
2. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, is characterized in that, be made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 22%
Solid-state dammar gum 4%
Butanone 5%
Virahol 4%
Methylcyclohexane 60%
Emulsifying agent 5%.
3. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, is characterized in that, be made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 25%
Solid-state dammar gum 7%
Butanone 6%
Virahol 3%
Methylcyclohexane 50%
Emulsifying agent 9%.
4. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, is characterized in that, be made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 27%
Solid-state dammar gum 3%
Butanone 7%
Virahol 5%
Methylcyclohexane 52%
Emulsifying agent 6%.
5. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, is characterized in that, be made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 23%
Solid-state dammar gum 5%
Butanone 8%
Virahol 6%
Methylcyclohexane 51%
Emulsifying agent 7%.
6. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, is characterized in that, be made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 24%
Solid-state dammar gum 6%
Butanone 9%
Virahol 4%
Methylcyclohexane 49%
Emulsifying agent 8%.
7. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, is characterized in that, be made up of the composition of following mass percent:
Solid thermoplastic polyolefin resin 26%
Solid-state dammar gum 8%
Butanone 10%
Virahol 3%
Methylcyclohexane 43%
Emulsifying agent 10%.
8. a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1 to 7 any one, it is characterized in that, described solid thermoplastic polyolefin resin be solid thermoplastic polyvinyl chloride (PVC) RESINS, solid thermoplastic polyvinyl resin, solid thermoplastic acrylic resin, solid thermoplastic polystyrene resin more than one.
9. the preparation method of a kind of aqueous, environmental protective polyethylene plastic coating promotor according to claim 1, it is characterized in that, the step of this preparation method is:
(1) mixing liquid of butanone, Virahol and methylcyclohexane is added in dispersion cup, stir;
(2) in dispersion cup, solid thermoplastic polyolefin resin, solid-state dammar gum is added at leisure again, dispersing and dissolving 40 minutes;
(3) add emulsifying agent, temperature is raised to 70 degree, disperse 10 minutes, namely obtain aqueous, environmental protective polyethylene plastic coating promotor.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105541952A (en) * | 2016-03-01 | 2016-05-04 | 重庆文理学院 | Water-based dammar resin as well as preparation method and application thereof |
CN109294319A (en) * | 2018-08-24 | 2019-02-01 | 苏新锋 | A kind of aqueous, environmental protective polyethylene plastic coating promotor and preparation method thereof |
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US20040059026A1 (en) * | 2000-10-13 | 2004-03-25 | Elisabeth Clamer | Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing |
CN101397471A (en) * | 2007-09-27 | 2009-04-01 | 比亚迪股份有限公司 | Priming lacquer coating composition for polypropylene substrate and method for preparing thereof |
CN102618130A (en) * | 2012-03-26 | 2012-08-01 | 江门市苏比化工有限公司 | Chlorine-free environment-friendly polyethylene plastic coating accelerator |
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2015
- 2015-07-13 CN CN201510407292.5A patent/CN105017877A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20040059026A1 (en) * | 2000-10-13 | 2004-03-25 | Elisabeth Clamer | Noble metal preparation and use thereof for production of noble metal decorations by means of direct and indirect printing |
CN101397471A (en) * | 2007-09-27 | 2009-04-01 | 比亚迪股份有限公司 | Priming lacquer coating composition for polypropylene substrate and method for preparing thereof |
CN102618130A (en) * | 2012-03-26 | 2012-08-01 | 江门市苏比化工有限公司 | Chlorine-free environment-friendly polyethylene plastic coating accelerator |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105541952A (en) * | 2016-03-01 | 2016-05-04 | 重庆文理学院 | Water-based dammar resin as well as preparation method and application thereof |
CN105541952B (en) * | 2016-03-01 | 2017-11-14 | 重庆文理学院 | A kind of water-based gum dammar and preparation method thereof, application |
CN109294319A (en) * | 2018-08-24 | 2019-02-01 | 苏新锋 | A kind of aqueous, environmental protective polyethylene plastic coating promotor and preparation method thereof |
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Application publication date: 20151104 |