CN105016302B - Device and method for automatic gas and liquid separation - Google Patents
Device and method for automatic gas and liquid separation Download PDFInfo
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- CN105016302B CN105016302B CN201510501198.6A CN201510501198A CN105016302B CN 105016302 B CN105016302 B CN 105016302B CN 201510501198 A CN201510501198 A CN 201510501198A CN 105016302 B CN105016302 B CN 105016302B
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Abstract
The invention discloses a device for automatic gas and liquid separation. The device comprises a high-purity chlorine dioxide generating device (1), a residue liquor storing tank (2), a residue liquor pump (3), a waste water treatment tank (4), a circulating pump (5) and a water ejector (6) which are sequentially connected in series. The high-purity chlorine dioxide generating device (1) comprises a chlorine dioxide generator (7), a buffering tank (8) and a special-shaped U-type pipe (9) which are sequentially connected. The invention further discloses a method for carrying out gas and liquid separation by adopting the device for the automatic gas and liquid separation. Chlorine dioxide gas can be efficiently separated, it is unnecessary to increase much investment, modifying can be carried out on the basis of an original generator, the requirement for water treatment and the requirements of customers can be met completely, and the device has great significance in water treatment, and solves the key problem for water treatment enterprises with the special requirements.
Description
Technical field
The present invention relates to technical field of inorganic chemical industry, the device of more particularly to a kind of voluntarily gas-liquid separation and using the dress
Put the method for carrying out voluntarily gas-liquid separation.
Background technology
Chlorine dioxide generator begins to be researched and developed from eighties of last century the eighties in China, and so far 20
History for many years, in water treatment field the important function such as sterilized, sterilization, decolouring are played always.Chlorine dioxide generator is certainly
From research and development, using when always the chlorine dioxide prepared together is extracted out with reacted raffinate using water sprayer
Generator, delivering to processed water body carries out sterilization, sterilization.For this addition method, to the water body without particular/special requirement, affect
It is not too big, but, for process running water, secondary water-supply, containing the water body such as cyanogen, nickeliferous, waste water containing COD, particularly process comprehensive
Conjunction property waste water, gas-liquid is added together, can bring many harm and drawback, and affects the extensive application of chlorine dioxide generator,
The water body for especially processing using high-pure chlorinedioxide generator, can not only affect treatment effect, can also increase processing cost.
At present, also there are the various methods for preparing chlorine dioxide on market, but, there is certain specific aim, adopt
Corresponding construction, application is also variant, for the chlorine dioxide generator of various lots of water treatment field application, does not but have
A kind of method with chlorine dioxide is individually added, therefore, govern to some extent water process it is extensive, deeply enter
OK.To solve this problem, many producers are just developed outside chlorine dioxide generator, increase various separators to solve gas-liquid
Separation problem, it is to avoid raffinate enters water body after reaction, to ensure sterilization, Disinfection Effect, it is to avoid bring pollution.But, this side
Still there is certain defect in method, not only increase equipment investment, increased floor space, and can not thoroughly solve raffinate entrainment
The problem of chlorine dioxide, so that causing the waste and pollution of chlorine dioxide.
The content of the invention
For the shortcoming of above prior art, according to the requirement of water process, the technical problem to be solved in the present invention is to provide
A kind of device of voluntarily gas-liquid separation and the method for carrying out voluntarily gas-liquid separation using the device, not only can efficiently separate out two
Oxidation chlorine body, also, it is not necessary to increase many investments, is transformed on the basis of former generator, can be expired completely
The requirement of sufficient water process and the demand of client, there is highly important meaning to water process, are the water process enterprise of particular/special requirement
Solve key issue.
A kind of device of voluntarily gas-liquid separation, including the high-pure chlorinedioxide generating means, raffinate storage tank being sequentially connected in series, residual
Liquid pump, purification tank for liquid waste, circulating pump and water sprayer, the high-pure chlorinedioxide generating means includes the chlorine dioxide being sequentially connected
Generator, surge tank and special-shaped U-tube.
The device of voluntarily gas-liquid separation of the present invention, wherein passing through between the tail pump and the purification tank for liquid waste
First pipeline is connected, and the water sprayer is connected with the purification tank for liquid waste, and the water sprayer is also by the second pipeline and the height
Pure chlorine dioxide generating means is connected, the chlorine dioxide generator in the high-pure chlorinedioxide generating means and raw material input pipe
Road is connected, and is connected by the 3rd pipeline between the raw material intake line and first pipeline, the raffinate storage tank and institute
State and be connected by the 4th pipeline between the second pipeline.
The device of voluntarily gas-liquid separation of the present invention, wherein the raw material intake line is two, respectively first
Raw material input pipe and the second raw material input pipe, the 3rd pipeline is connected with the second raw material input pipe, described high-purity
Air inlet duct is provided with chlorine dioxide generator in chlorine dioxide generating device, is provided with the purification tank for liquid waste
Comprehensive wastewater entrance and wastewater outlet.
The device of voluntarily gas-liquid separation of the present invention, wherein cylindrical structural of the surge tank for sealing two ends,
The middle and upper part of the surge tank is provided with mixture inlet, the mixture inlet occurs by pipeline with the chlorine dioxide
Device is connected, and the top of the surge tank is provided with chlorine dioxide outlet, and bottom is provided with raffinate outlet, the titanium dioxide
Chlorine body outlet is connected with second pipeline, uniform on the inwall on the surge tank top to be staggeredly fixed with multiple horizontal foldings
Stream plate.
The device of voluntarily gas-liquid separation of the present invention, wherein the special-shaped U-tube is transformed on the basis of U-tube
, including the round coil positioned at left side, the horizontal straight tube positioned at bottom and the vertical straight tube positioned at right side, the round coil
The outlet of top and the raffinate be connected, bottom is connected with one end of the horizontal straight tube, the other end of the horizontal straight tube
Be connected with the bottom of the vertical straight tube, the top of the vertical straight tube is connected with residual liquid discharge pipe, the residual liquid discharge pipe with
The raffinate storage tank is connected.
The device of voluntarily gas-liquid separation of the present invention, wherein the input of the air input passageway, first raw material
Pipe and the second raw material input pipe are arranged at the top of the chlorine dioxide generator.
The device of voluntarily gas-liquid separation of the present invention, wherein the transverse baffle is the circle that edge has a breach
Plate, the outline of the cross section of the transverse baffle is made up of a major arc and a straight flange for connecting the major arc two ends,
Multiple horizontal deflection plates are staggeredly fixed on the top of the buffering top tank structure, two straight flanges of the two neighboring horizontal deflection plate
Both sides that are parallel and being arranged on the surge tank axis.
The method that voluntarily gas-liquid separation is carried out using the device of voluntarily gas-liquid separation of the present invention, including following step
Suddenly：
High-pure chlorinedioxide generating means is controlled into temperature by electromagnetic induction heater, negative pressure is controlled by water sprayer,
Raffinate after the chlorine dioxide of reaction generation and reaction, is carried out respectively in the upper and lower parts of high-pure chlorinedioxide generating means
Voluntarily separate, wherein, on the high-pure chlorinedioxide generating means top, pure chlorine dioxide after surge tank separation,
Directly extracted out by water sprayer again and deliver to processed water body, in the high-pure chlorinedioxide generating means bottom, raffinate after reaction
By special-shaped U-tube, raffinate is set voluntarily to flow in raffinate storage tank after separating using pressure reduction change, the raffinate after separation passes through raffinate
It is pumped to head tank or purification tank for liquid waste.
The method of voluntarily gas-liquid separation of the present invention, wherein the high-pure chlorinedioxide generating means reaction temperature control
It is made as 53～60 DEG C.
The method of voluntarily gas-liquid separation of the present invention, wherein the surge tank is based on gas speed ratio, control enters pipeline
Interior gas speed and the gas speed ratio for being passed through surge tank are 72～80：1；The special-shaped U-tube is filled by the high-pure chlorinedioxide
Interior depressimeter is put, the negative pressure of the special-shaped U-tube of control is more than 8KPa.
The device difference from prior art of the present invention voluntarily gas-liquid separation is：
Compared with the now separation method of additional separator, the main distinction is the voluntarily gas-liquid separation device and method of the present invention
Former separation method needs to increase by one or two gas-liquid separation equipments, and chlorine dioxide needs two water sprayers to be aspirated,
So, equipment investment is not only increased, increases floor space, equipment installs complicated, and can not thoroughly solve raffinate entrainment
The problem of chlorine dioxide, causes unavoidably the waste and pollution of chlorine dioxide, and has influence on preparation cost.The present invention is
On the basis of high-pure chlorinedioxide generator, do not increase any equipment, only change dependency structure, using gas speed and negative pressure
The change of value, voluntarily carries out gas-liquid separation.The voluntarily gas-liquid separation device, not only separative efficiency is high, separates thorough, separates, returns
Receipts can be carried out simultaneously, also, facility compact, easy to operate, and safety is safe, has both saved equipment investment, and online gas is solved again
Liquid separation problem, is a kind of brand-new voluntarily gas-liquid separation equipment, firmly gets the satisfaction of user, be high-pure chlorinedioxide generator more
Good basis has been established in extensive popularization, application.
The present invention on the basis of former high-pure chlorinedioxide generator, respectively in generator surge tank upper and lower parts,
Using two structures, different parts are acted on, the gas-liquid for solving chlorine dioxide generator well is online, safe efficient point
From, the problem that recycles, the client for particular/special requirement provides new method, be wastewater treatment it is extensive, deeply carried
More excellent product is supplied, the cost of investment and cost for wastewater treatment to reducing wastewater treatment is all highly profitable, and is at water
Reason field opens a new effective way, makes water treatment effect more preferable, can meet the needs in more markets.
Voluntarily gas-liquid separating method of the present invention, as a result of upper and lower two different structures, becomes in different pressure reduction
Under change, gas-liquid separation effect is effectively improved, up to more than 95%, in the method, gas phase is all classified as one to liquid separation rate
System, using a water sprayer, can effectively remove the chlorine dioxide in raffinate, it is to avoid the dirt to surrounding space environment
Dye.
The device of the voluntarily gas-liquid separation of the present invention is described further below in conjunction with the accompanying drawings.
Description of the drawings
Fig. 1 is the structural representation of the voluntarily device of gas-liquid separation of the invention；
Fig. 2 is the structural representation of high-pure chlorinedioxide generating means in the voluntarily device of gas-liquid separation of the invention；
Fig. 3 is the cross-sectional view of the horizontal deflection plate in the voluntarily device of gas-liquid separation of the invention in surge tank.
Specific embodiment
Embodiment 1
As shown in Figure 1-Figure 3, a kind of device of voluntarily gas-liquid separation, fills including the high-pure chlorinedioxide being sequentially connected in series
1, raffinate storage tank 2, tail pump 3, purification tank for liquid waste 4, circulating pump 5 and water sprayer 6 are put, high-pure chlorinedioxide generating means 1 includes
Chlorine dioxide generator 7, surge tank 8 and the special-shaped U-tube 9 being sequentially connected.
On this basis, preferably：It is connected by the first pipeline 201 between tail pump 3 and purification tank for liquid waste 4, water-jet
Device 6 is connected with purification tank for liquid waste 4, and water sprayer 6 is also connected by the second pipeline 202 with high-pure chlorinedioxide generating means 1, high-purity
Chlorine dioxide generator 7 in chlorine dioxide generating device 1 is connected with raw material intake line, raw material intake line and the first pipeline
It is connected by the 3rd pipeline 203 between 201, is connected by the 4th pipeline 204 between raffinate storage tank 2 and the second pipeline 202.
Raw material intake line is two, respectively the first raw material input pipe 102 and the second raw material input pipe 103, the 3rd pipe
Road 203 is connected with the second raw material input pipe 103, arranges on the chlorine dioxide generator 7 of high-pure chlorinedioxide generating means 1
There is air inlet duct 101, comprehensive wastewater entrance 401 and wastewater outlet 402 are provided with purification tank for liquid waste 4.
Surge tank 8 is the cylindrical structural of sealing two ends, and the middle and upper part of surge tank 8 is provided with mixture inlet, mixes
Thing entrance is connected by pipeline with chlorine dioxide generator 7, and the top of surge tank 8 is provided with chlorine dioxide outlet, under
Portion is provided with raffinate outlet, and chlorine dioxide outlet is connected with the second pipeline 202, uniform on the inwall on the top of surge tank 8
Staggeredly it is fixed with multiple transverse baffles 801.
Special-shaped U-tube 9 is transformed on the basis of U-tube, including the round coil 901 positioned at left side, positioned at bottom
Horizontal straight tube 902 and the vertical straight tube 903 positioned at right side, the top of round coil 901 is connected with raffinate outlet, bottom and water
One end of straight pipe 902 is connected, and the other end of horizontal straight tube 902 is connected with the bottom of vertical straight tube 903, vertical straight tube 903
Top be connected with residual liquid discharge pipe, residual liquid discharge pipe is connected with raffinate storage tank 2.
Transverse baffle 801 is the plectane that edge has a breach, and the outline of the cross section of transverse baffle 801 is by one
The straight flange 803 at individual major arc 802 and the two ends of connection major arc 802 is constituted, and multiple horizontal deflection plates 801 are staggeredly fixed on surge tank 8
The top of inwall, two straight flanges 803 of two neighboring horizontal deflection plate 801 are parallel and are arranged on the both sides of the axis of surge tank 8.
More specifically structure, raffinate storage tank 2 includes raffinate entrance, chlorine dioxide outlet, raffinate outlet, raffinate entrance
It is connected with the raffinate outlet of special-shaped U-tube 9, chlorine dioxide outlet is connected with the 4th pipeline 204, and raffinate is exported and raffinate
Pump intake is connected；The purification tank for liquid waste 4 is specifically provided with raffinate inlet, comprehensive wastewater entrance 401, wastewater outlet 402, circulation
Water out, the raffinate inlet is connected with the outlet of tail pump 3, and circulating water outlet is connected with the entrance of circulating pump, the waste water
Processing pond 4 is connected by wastewater disposal basin water pipe with the outlet of water sprayer 6.
Embodiment 2
A kind of method that voluntarily device of gas-liquid separation carries out voluntarily gas-liquid separation in employing embodiment 1, including following step
Suddenly：
High-pure chlorinedioxide generating means 1 is controlled into temperature by electromagnetic induction heater, it is negative by the control of water sprayer 6
Pressure, reacts raffinate after the chlorine dioxide and reaction for producing, respectively in the upper and lower parts of high-pure chlorinedioxide generating means 1
Voluntarily separated, wherein, on the top of high-pure chlorinedioxide generating means 1, pure chlorine dioxide is separated through surge tank 8
Afterwards, then directly extracted out by water sprayer 6 and deliver to processed water body, in the bottom of high-pure chlorinedioxide generating means 1, raffinate after reaction
By special-shaped U-tube 9, raffinate is set voluntarily to flow in raffinate storage tank 2 after separating using pressure reduction change, the raffinate after separation is by residual
Liquid pump 3 delivers to high-pure chlorinedioxide generating means 1 or purification tank for liquid waste 4.
The reaction temperature of high-pure chlorinedioxide generating means 1 is controlled to 53～60 DEG C.Surge tank 8 by gas speed than based on, control into
It is 72～80 to enter gas speed and the fast ratio of gas for being passed through surge tank 8 in pipeline：1.Special-shaped U-tube 9 is filled by high-pure chlorinedioxide
Depressimeter in 1 is put, the negative pressure of the special-shaped U-tube 9 of control is more than 8KPa.
Embodiment 3
The method that a kind of device described in employing embodiment 1 carries out voluntarily gas-liquid separation, comprises the steps：
High-pure chlorinedioxide generating means 1 is controlled into 56 DEG C by electromagnetic induction heater, the high-purity dioxy for producing is reacted
Change chlorine, by the surge tank 8 on the top of high-pure chlorinedioxide generating means 1, in gas speed than being 76：Under 1, pure chlorine dioxide gas is obtained
Body, together Jing water sprayers 6 deliver to processed water body with the chlorine dioxide of raffinate storage tank 2；The raffinate produced after reaction, leads to
The special-shaped U-tube 9 of the bottom of chlorine dioxide generating device 1 is crossed, the negative pressure in control pipe is ＞ 9,5KPa, by the raffinate isolated,
Raffinate storage tank 2 is voluntarily flowed into, the feed(raw material)inlet of purification tank for liquid waste 4 or chlorine dioxide generating device 1 is delivered to by tail pump 3, entered
Row is reclaimed or comprehensively utilized.
Separator takes a sample test result：Liquid separation rate is more than 95.5%.
Embodiment 4
The method that a kind of device described in employing embodiment 1 carries out voluntarily gas-liquid separation, comprises the steps：
Chlorine dioxide generating device 1 is controlled into 53 DEG C by electromagnetic induction heater, the high-pure chlorinedioxide for producing is reacted,
By the surge tank 8 on the top of chlorine dioxide generating device 1, in gas speed than being 72：Under 1, pure chlorine dioxide is obtained, with raffinate
Together Jing water sprayers 6 deliver to processed water body to the chlorine dioxide of storage tank 2；The raffinate produced after reaction, by titanium dioxide
The special-shaped U-tube 9 of the bottom of chlorine generating means 1, the negative pressure in control pipe is ＞ 8KPa, and the raffinate isolated voluntarily is flowed into residual
Liquid storage tank 2, by tail pump 3 feed(raw material)inlet of purification tank for liquid waste 4 or chlorine dioxide generating device 1 is delivered to, and is reclaimed or comprehensive
Close and utilize.
Separator takes a sample test result：Liquid separation rate is more than 95.2%.
Embodiment 5
The method that a kind of device described in employing embodiment 1 carries out voluntarily gas-liquid separation, comprises the steps：
Chlorine dioxide generating device 1 is controlled into 60 DEG C by electromagnetic induction heater, the high-pure chlorinedioxide for producing is reacted,
By the surge tank 8 on the top of chlorine dioxide generating device 1, in gas speed than being 80：Under 1, pure chlorine dioxide is obtained, with raffinate
Together Jing water sprayers 6 deliver to processed water body to the chlorine dioxide of storage tank 2；The raffinate produced after reaction, by sending out dioxy
Change the special-shaped U-tube 9 of the bottom of chlorine generating means 1, the negative pressure in control pipe is ＞ 10KPa, and the raffinate isolated voluntarily is flowed into
Raffinate storage tank 2, by tail pump 3 feed(raw material)inlet of purification tank for liquid waste 4 or chlorine dioxide generating device 1 is delivered to, reclaimed or
Comprehensive utilization.
Separator takes a sample test result：Liquid separation rate is more than 95.8%.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention
Enclose and be defined, on the premise of without departing from design spirit of the present invention, technical side of the those of ordinary skill in the art to the present invention
Various modifications and improvement that case is made, all should fall in the protection domain of claims of the present invention determination.
Claims (8)
1. a kind of device of voluntarily gas-liquid separation, it is characterised in that：Including the high-pure chlorinedioxide generating means being sequentially connected in series
(1), raffinate storage tank (2), tail pump (3), purification tank for liquid waste (4), circulating pump (5) and water sprayer (6), the high-pure chlorinedioxide
Generating means (1) includes the chlorine dioxide generator (7), surge tank (8) being sequentially connected and special-shaped U-tube (9)；
The surge tank (8) is the cylindrical structural of sealing two ends, the middle and upper part of the surge tank (8) is provided with mixture and enters
Mouthful, the mixture inlet is connected with the chlorine dioxide generator (7) by pipeline, is set on the top of the surge tank (8)
Chlorine dioxide outlet is equipped with, bottom is provided with raffinate outlet, the chlorine dioxide outlet and the second pipeline (202) phase
Even, it is uniform on the inwall on the surge tank (8) top to be staggeredly fixed with multiple transverse baffles (801)；
The special-shaped U-tube (9) is transformed on the basis of U-tube, including the round coil (901) positioned at left side, is located at
The horizontal straight tube (902) of bottom and the vertical straight tube (903) positioned at right side, the top of the round coil (901) is residual with described
Liquid outlet is connected, and bottom is connected with the one end of the horizontal straight tube (902), the other end of the horizontal straight tube (902) and institute
The bottom for stating vertical straight tube (903) is connected, and the top of the vertical straight tube (903) is connected with residual liquid discharge pipe, the raffinate row
Put pipe to be connected with the raffinate storage tank (2).
2. the device of voluntarily gas-liquid separation according to claim 1, it is characterised in that：The tail pump (3) is useless with described
It is connected by the first pipeline (201) between water treating pond (4), the water sprayer (6) is connected with the purification tank for liquid waste (4), institute
State water sprayer (6) to be also connected with the high-pure chlorinedioxide generating means (1) by the second pipeline (202), high-purity dioxy
The chlorine dioxide generator (7) changed in chlorine generating means (1) is connected with raw material intake line, the raw material intake line with it is described
Be connected by the 3rd pipeline (203) between first pipeline (201), the raffinate storage tank (2) and second pipeline (202) it
Between by the 4th pipeline (204) be connected.
3. the device of voluntarily gas-liquid separation according to claim 2, it is characterised in that：The raw material intake line is two
Bar, respectively the first raw material input pipe (102) and the second raw material input pipe (103), the 3rd pipeline (203) and described second
Raw material input pipe (103) is connected, and arranges on the chlorine dioxide generator (7) of the high-pure chlorinedioxide generating means (1)
There is air inlet duct (101), comprehensive wastewater entrance (401) and wastewater outlet are provided with the purification tank for liquid waste (4)
(402)。
4. the device of voluntarily gas-liquid separation according to claim 1, it is characterised in that：The transverse baffle (801) is
Edge has the plectane of a breach, and the outline of the cross section of the transverse baffle (801) is by a major arc (802) and one
The straight flange (803) for connecting the major arc (802) two ends is constituted, and multiple transverse baffles (801) are staggeredly fixed on described slow
Rush the top of tank (8) inwall, two straight flanges (803) of the two neighboring transverse baffle (801) are parallel and are arranged on described
The both sides of the axis of surge tank (8).
5. the side of voluntarily gas-liquid separation is carried out using the device of the voluntarily gas-liquid separation described in any one in claim 1-4
Method, it is characterised in that：Comprise the steps：
High-pure chlorinedioxide generating means (1) is controlled into temperature by electromagnetic induction heater, it is negative by water sprayer (6) control
Pressure, reacts raffinate after the chlorine dioxide and reaction for producing, respectively in the upper and lower part of high-pure chlorinedioxide generating means (1)
Position is voluntarily separated, wherein, on high-pure chlorinedioxide generating means (1) top, pure chlorine dioxide is through buffering
After tank (8) is separated, then directly processed water body is delivered in extraction by water sprayer (6), in the high-pure chlorinedioxide generating means
(1) bottom, raffinate makes raffinate voluntarily flow into raffinate storage tank after separating by special-shaped U-tube (9) using pressure reduction change after reaction
(2) in, the raffinate after separation delivers to high-pure chlorinedioxide generating means (1) or purification tank for liquid waste (4) by tail pump (3).
6. the method for voluntarily gas-liquid separation according to claim 5, it is characterised in that：The high-pure chlorinedioxide is filled
Put (1) reaction temperature and be controlled to 53～60 DEG C.
7. the method for voluntarily gas-liquid separation according to claim 6, it is characterised in that：The surge tank (8) is compared by gas speed
Meter, gas speed and the fast ratio of gas for being passed through surge tank (8) in pipeline of controlling is 72～80：1.
8. the method for voluntarily gas-liquid separation according to claim 7, it is characterised in that：The special-shaped U-tube (9) is by described
The interior depressimeter of high-pure chlorinedioxide generating means (1), the negative pressure of the special-shaped U-tube (9) of control is more than 8KPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510501198.6A CN105016302B (en) | 2015-08-14 | 2015-08-14 | Device and method for automatic gas and liquid separation |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510501198.6A CN105016302B (en) | 2015-08-14 | 2015-08-14 | Device and method for automatic gas and liquid separation |
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| CN105016302A CN105016302A (en) | 2015-11-04 |
| CN105016302B true CN105016302B (en) | 2017-05-10 |
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| CN201510501198.6A Active CN105016302B (en) | 2015-08-14 | 2015-08-14 | Device and method for automatic gas and liquid separation |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106145045A (en) * | 2016-08-02 | 2016-11-23 | 四川拓璞环保科技有限公司 | A kind of chlorine dioxide generating device |
| CN108100998A (en) * | 2018-01-17 | 2018-06-01 | 济南科林沃德环境科技有限公司 | A kind of pure chlorine dioxide generating means |
| CN108147366A (en) * | 2018-01-17 | 2018-06-12 | 济南科林沃德环境科技有限公司 | The sterilant gas retracting device that a kind of chlorine dioxide generator generates |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007065103A2 (en) * | 2005-11-29 | 2007-06-07 | University Of Florida Research Foundation, Inc. | On-demand portable chlorine dioxide generator |
| CN203187400U (en) * | 2013-03-21 | 2013-09-11 | 山东山大华特科技股份有限公司 | Device for purifying chlorine dioxide |
| CN204237610U (en) * | 2014-11-17 | 2015-04-01 | 深圳中科欧泰华环保科技有限公司 | A kind of device of gas-liquid separation |
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