CN105000872A - High-strength sheet aluminum oxide porous ceramic used for LED lamp heat dissipation and preparation method thereof - Google Patents

Abstract

High-strength sheet aluminum oxide porous ceramic used for LED lamp heat dissipation comprises, by weight, 34-36 parts of alpha-Al2O3 (the particle size is 2 micrometers-8 micrometers), 100-105 parts of deionized water, 0.2-0.3 part of sodium polyacrylate, 2-2.3 parts of methylcellulose, 1.6-1.8 parts of glycerin, 1.3-1.6 parts of tetrapod-like zinc oxide whiskers, 0.6-0.8 part of submicron silica particles, 0.8-1 part of zirconium hydrogen phosphate, 0.4-0.6 part of nanometer pearl powder, 4-5 parts of nano-aluminium hydroxide, 1.2-1.5 parts of nano-copper and 0.9-1.1 parts of PVA adhesion agents. Through using the tetrapod-like zinc oxide whiskers, the properties of strength, abrasion resistance and wave absorption and antistatic and antibacterial properties of the sheet aluminum oxide porous ceramics are improved; through using the submicron silica particles, the zirconium hydrogen phosphate and the nanometer pearl powder, the pore connectivity of the ceramic is improved, heat conduction is improved, and the binding force with metal is increased.

Description

A kind of high strength LED heat transmission tabular alumina porous ceramics and preparation method thereof

Technical field

The present invention relates to porous heat dissipation ceramic field, particularly relate to a kind of high strength LED heat transmission tabular alumina porous ceramics and preparation method thereof.

Background technology

Photodiode (LED) is that a class directly by the luminescent device that electric energy conversion is visible ray and radiating capacity, have powerful market potential, and great power LED can be thought the Main way 1 in lighting source market by industry.Under present level, the power input of 10% ~ 20% can only be converted into luminous energy by great power LED, and all the other 80% ~ 90% are all converted into heat energy.For ensureing that it normally works, need ensure that the working temperature of LED is in allowed band by effective heat dissipation design.Therefore great power LED chip cooling problem has become the obstacle that current LED technology is applied in illuminating engineering.

Scholar is had to use powder metallurgic method to prepare metal/ceramic heat sink compound.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If will there is small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, when can also reduce metal and Ceramic Composite, have scholar to use powder metallurgic method to prepare metal/ceramic heat sink compound because two-phase thermal expansivity does not mate to cause in use.But due to metal and ceramic fusing point difference comparatively large, therefore not easily burn altogether.If by having small-bore, the porous ceramics of clear opening and metal composite, two-phase not only can be avoided to burn altogether, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when can also reduce metal and Ceramic Composite.And prepare the key that this flake porous pottery is this technical development.

Flow casting molding prepares one of big area, the most effective means of thin plate stupalith at present.Replace the casting technology of organic solvent to become the emphasis of research at present due to its hypotoxicity, oligosaprobic feature using water as solvent.Simultaneously freeze-drying in the porous ceramics of controlled, the high through-hole rate of preparation aperture size also tool have great advantage." multilayer low temperature curtain coating legal system is for tabular alumina porous ceramics " literary composition describes the method preparing alumina porous ceramic, and the thermal fatigue of ceramics performance of making is good.But the method can not be even by alumina dispersion, and easily reunite, ceramic structure is uneven, and if this ceramic plate is applied to LED radiator element, also need the problem such as toughness, thermal conductivity, crack resistence, thermotolerance improving pottery.The consistency of this ceramic plate and metal is poor, needs to improve.

Summary of the invention

The object of the present invention is to provide a kind of high strength LED heat transmission tabular alumina porous ceramics, the intensity of this tabular alumina porous ceramics is high, and wear-resisting, wave absorbtion, the performance such as antistatic, antibacterial are good, strengthen with the bonding force of metal.

Technical scheme of the present invention is as follows:

A kind of high strength LED heat transmission tabular alumina porous ceramics, is characterized in that being made up of the raw material of following weight part: α-Al ₂o ₃(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, four acicular type zinc oxide crystal whisker 1.3-1.6, submicron silica gel particle 0.6-0.8, phosphoric acid hydrogen zirconium 0.8-1, nanometer Margarita powder 0.4-0.6, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.

The production method of described high strength LED heat transmission tabular alumina porous ceramics, is characterized in that:

(1) by α-Al ₂o ₃, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add four acicular type zinc oxide crystal whisker, phosphoric acid hydrogen zirconium, submicron silica gel particle, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide, nanometer Margarita powder again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;

(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al ₂o ₃ceramic size;

(3) by Al that (2) step obtains ₂o ₃ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;

(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.

Beneficial effect of the present invention

Tabular alumina porous ceramics interlayer duct of the present invention is communicated with, and transition is good, and thermal fatigue property is good; By using nano-aluminum hydroxide, improve the phenomenon that alumina particle is easily reunited; By using Nanometer Copper, improve pottery and the consistency of metal, because two-phase thermal expansivity does not mate the Cracking Failure problem caused in use when reducing metal and Ceramic Composite; By using four acicular type zinc oxide crystal whisker, improve the intensity of pottery, wear-resisting, inhale ripple, the performance such as antistatic, antibacterial; By using submicron silica gel particle, phosphoric acid hydrogen zirconium, nanometer Margarita powder, improve the pore connectivity of pottery, thermal conductivity is improved, and strengthens with the bonding force of metal.

Embodiment

A kind of high strength LED heat transmission tabular alumina porous ceramics, is made up of the raw material of following weight part (kilogram): α-Al ₂o ₃(particle diameter is 2-8 μm) 35, deionized water 104, sodium polyacrylate 0.3, methylcellulose gum 2.2, glycerol 1.7, four acicular type zinc oxide crystal whisker 1.5, submicron silica gel particle 0.7, phosphoric acid hydrogen zirconium 0.9, nanometer Margarita powder 0.5, nano-aluminum hydroxide 4.5, Nanometer Copper 1.4, PVA binding agent 1.

The production method of described high strength LED heat transmission tabular alumina porous ceramics, is characterized in that:

(1) by α-Al ₂o ₃, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5.5h, add four acicular type zinc oxide crystal whisker, phosphoric acid hydrogen zirconium, submicron silica gel particle, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide, nanometer Margarita powder again, ball milling 0.8h, leaves standstill 50min, obtains slurry;

(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 21h, then add other remaining component, continue ball milling 2h, then carry out froth in vacuum 6min, obtain Al ₂o ₃ceramic size;

(3) by Al that (2) step obtains ₂o ₃ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;

(4) by after multilayer cast sheet lyophilize 24h, sinter at 1650 DEG C, insulation 2.5h, then be chilled to room temperature with stove, to obtain final product.

Experimental data: by sample after 300 slow cooling (25 DEG C), 200 chillings (25 DEG C) and 195 chillings (– 20 DEG C), the cycle index that sample crackle occurs is 717 times, finds out that the thermal fatigue property of this sample is fine.

Claims (2)

1. a high strength LED heat transmission tabular alumina porous ceramics, is characterized in that being made up of the raw material of following weight part: α-Al ₂o ₃(particle diameter is 2-8 μm) 34-36, deionized water 100-105, sodium polyacrylate 0.2-0.3, methylcellulose gum 2-2.3, glycerol 1.6-1.8, four acicular type zinc oxide crystal whisker 1.3-1.6, submicron silica gel particle 0.6-0.8, phosphoric acid hydrogen zirconium 0.8-1, nanometer Margarita powder 0.4-0.6, nano-aluminum hydroxide 4-5, Nanometer Copper 1.2-1.5, PVA binding agent 0.9-1.1.

2. the production method of high strength LED heat transmission tabular alumina porous ceramics according to claim 1, is characterized in that:

(1) by α-Al ₂o ₃, deionized water, sodium polyacrylate mixes, and obtains suspension, by suspension ball milling 5-5.5h, add four acicular type zinc oxide crystal whisker, phosphoric acid hydrogen zirconium, submicron silica gel particle, mix, then add PVA binding agent, mix, add nano-aluminum hydroxide, nanometer Margarita powder again, ball milling 0.5-1h, leaves standstill 40-60min, obtains slurry;

(2) slurry that (1) step obtains is added methylcellulose gum and glycerol, continue ball milling 20-22h, then add other remaining component, continue ball milling 2-2.5h, then carry out froth in vacuum 5-6min, obtain Al ₂o ₃ceramic size;

(3) by Al that (2) step obtains ₂o ₃ceramic size is flow casting molding on the low-temperature receiver of-45 DEG C at pre-freezing temperature, and control scraper gap is 1mm, after cast layer crystallization, and repetitive operation, every layer thickness controls, for 1mm, to obtain multilayer cast sheet;

(4) by after multilayer cast sheet lyophilize 23-24h, sinter at 1600-1650 DEG C, insulation 2-2.5h, then be chilled to room temperature with stove, to obtain final product.