CN105000811B - Parallel flow heat accumulating type lime kiln production technology based on CO2 accumulation - Google Patents

Parallel flow heat accumulating type lime kiln production technology based on CO2 accumulation Download PDF

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CN105000811B
CN105000811B CN201510444135.1A CN201510444135A CN105000811B CN 105000811 B CN105000811 B CN 105000811B CN 201510444135 A CN201510444135 A CN 201510444135A CN 105000811 B CN105000811 B CN 105000811B
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gas
accumulating type
heat accumulating
kiln
combustion
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CN105000811A (en
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李宝宽
荣文杰
王强
李林敏
孙美佳
童岩鹏
李明
李一明
齐凤升
王芳
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Northeastern University China
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/40Production or processing of lime, e.g. limestone regeneration of lime in pulp and sugar mills

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Abstract

The invention discloses a parallel flow heat accumulating type lime kiln production technology based on CO2 accumulation. The parallel flow heat accumulating type lime kiln production technology includes the steps that limestone raw materials are fed into two kiln chambers of a parallel flow heat accumulating type lime kiln; carrier gas is sprayed into the kiln chambers; combustion supporting gas is fed; in a combustion zone of the current kiln chamber, limestone absorbs the heat generated by fuel combustion to be decomposed to generate quick lime and CO2 gas; the quick lime is discharged after being cooled to 80 DEG C to 100 DEG C; cooling gas, the CO2 gas generated by decomposing the limestone and CO2 gas generated by fuel combustion are mixed to enter the other kiln chamber to preheat limestone; flue gas generated by preheating releases heat to the limestone, then the temperature of the flue gas is reduced, the flue gas is exhausted, and CO2 gas with the volume concentration larger than 95% is generated; the parallel flow heat accumulating type lime kiln starts reversing work. By means of the parallel flow heat accumulating type lime kiln production technology, the high-purity CO2 gas is obtained while the high-quality lime is prepared. Compared with an existing technology, circulation of N2 in a system is avoided, the energy used for heating the N2 is saved, and the flue gas is recycled to achieve the aims of increasing the product added value, saving energy and reducing consumption.

Description

One kind is based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment
Technical field
The present invention relates to limekiln manufacturing technique method, it is based on co particularly to a kind of2The cocurrent heat accumulating type Calx of enrichment Kiln manufacturing technique method.
Background technology
In metallurgical industry, substantial amounts of co can be produced when producing slag making materials quick lime2.In actual production, produce 1 ton of life Calx just produces the co more than 1 ton2, and 1 ton of steel of melting about needs the quick lime of 70 kg.Chinese crude steel yield is about 8.2 within 2014 Hundred million tons, then about need 57,000,000 tons of quick lime, produce the co more than 60,000,000 tons2.It is used mostly limekiln next life generation stone at present Ash, but co in the waste gas that ejects of limekiln2Content very low, if by co2Enrichment recycling, then also need to spend very A part of greatly energy and fund, so most enterprises select directly to discharge, this has resulted in a very serious environmental problem.
Domestic cocurrent heat accumulating type limekiln produces and is used mostly compressed air pulverized coal conveying, combustion-supporting and product cooling at present, Co in the flue gas producing2Concentration low (volumetric concentration 10 ~ 14%) and exhaust gas volumn is big.Due to separating low co after recovered flue gas2Content Waste gas is relatively costly, so flue gas is directly discharged into air by most enterprise, causes serious atmospheric pollution and the wasting of resources.
Content of the invention
The problem existing for existing process method, the present invention provides one kind to be based on co2The cocurrent heat accumulating type Calx of enrichment Kiln manufacturing technique method.
The technical scheme is that
One kind is based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, comprises the following steps:
(1) in first combustion period, by raw limestone, before kiln, building stones storehouse is delivered to scale hooper, raw limestone warp Load after scale hooper weighing in truck and be transported to cocurrent heat accumulating type limekiln kiln crown, enter two kiln thoraxes in cocurrent heat accumulating type limekiln Interior;
(2) Fuel lance in a kiln thorax in cocurrent heat accumulating type limekiln is inserted in limestone stock column, and carrier gas carries Fuel is sprayed in kiln thorax by Fuel lance;
(3) pass through combustion fan to be fed combustion-supporting gas by cocurrent heat accumulating type limekiln kiln crown, in the draft of combustion fan Lower combustion-supporting gas is flowed down to combustion zone and is met with fuel, so that fuel is burnt below the spout of Fuel lance;
(4) in the combustion zone of current kiln thorax, limestone absorb fuel combustion produce heat, decompose generate quick lime and co2Gas;
(5) quick lime producing in the combustion zone of current kiln thorax is carried out being cooled to 80 by the cooling gas that cooling blower feeds DEG C ~ 100 DEG C after discharging;
(6) rise to after cooling gas are heated by quick lime at interface channel, the co generating with decomposition of limestone2Gas and The co that fuel combustion produces2Gas mixing enters another kiln thorax by interface channel and rises, and enters preheating zone through combustion zone Limestone is preheated;
(7) after pre- thermogenetic flue gas rejects heat to limestone, temperature reduces and discharges, and by udst separation, produces The co that volumetric concentration is more than 95%2Gas, this co2, as the carrier gas of conveying fuel, another part is as by cold for a part for gas But blower fan feeds the cooling gas of cooling zone, and remaining directly stores or makes dry ice product;
(8) first burnout cycle complete, and in cocurrent heat accumulating type limekiln, various air-flows stop flowing, cocurrent heat accumulating type stone Ash furnace starts commutation work, commutating period 40 s ~ 50s, and quick lime draws off from the kiln thorax bottom in cocurrent heat accumulating type limekiln.
The described combustion-supporting gas of step (3) be oxygen concentration > 95% oxygen-enriched.
The co that volumetric concentration described in described step (7) is more than 95%230% ~ 35% co in gas2Gas directly stores Or make dry ice product.
The co that volumetric concentration described in described step (7) is more than 95%2In gas, 5% ~ 10% as the load conveying fuel Gas.
The co that volumetric concentration described in described step (7) is more than 95%2In gas, 55% ~ 65% conduct is supplied by cooling blower Enter the cooling gas of combustion zone.
Beneficial effect:
The invention provides being based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, this have enrichment co2 The cocurrent heat accumulating type limekiln manufacturing technique method of function also obtains highly purified co while preparing high-quality Calx2Gas Body.Compared with existing process, eliminate n2Circulation in system, saves for heating n2Energy, and by flue gas Recycle and improve added value of product and the target such as energy-saving to reach.
Brief description
Fig. 1 is to adopt in the embodiment of the present invention based on co2The cocurrent heat accumulating type limekiln system structure diagram of enrichment.
Specific embodiment
Below in conjunction with the accompanying drawings the specific embodiment of the present invention is elaborated.
Embodiment 1
It is based on co in the present embodiment2The cocurrent heat accumulating type limekiln system structure of enrichment is as shown in figure 1, employing in system Dust arrester be sack cleaner, fuel be coal dust.Dust concentration≤the 50mg/nm of the flue gas discharged from air vent3.
Using above-mentioned cocurrent heat accumulating type Calx kiln system produce quick lime (cao), 450 tons of the quick lime daily output, daily 80 The individual production cycle, per production cycle coal dust amount 240 kg ~ 270kg, combustion air coefficient of excess 1.1 ~ 1.4.
Based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, comprises the following steps:
(1) in first combustion period, by raw limestone, before kiln, building stones storehouse is delivered to scale hooper, raw limestone warp Load after scale hooper weighing in truck and be transported to cocurrent heat accumulating type limekiln kiln crown, enter two kiln thoraxes in cocurrent heat accumulating type limekiln In (kiln thorax 1 and kiln thorax 2);
Concrete feeding technique: limestone, by underground receiver bin, delivers to wide-angle belt through electric vibrating feeder, by wide-angle Limestone is transported to the monolayer building stones sieve that shakes and is sieved by belt, and wherein rock screen removes and uses it for anything else to refuse bin, qualified Calx Shi Ze passes through to shake and sieves by chute to intermediate belt, then by building stones storehouse before intermediate belt to kiln.The qualified limestone in the front storehouse of kiln, passes through After scale hooper weighs before kiln, send into winch hoister hopper, limestone is delivered to by kiln crown building stones scale hooper by hoist engine, then by one Limestone is sent into the revolving top being located on two kiln cylinders by platform bobbing machine and reversible belt machine, finally by distributing device by Calx Stone sends into kiln.
(2) Fuel lance in a kiln thorax (kiln thorax 1) in cocurrent heat accumulating type limekiln is inserted in limestone stock column, carries Airborne fuel is sprayed in kiln thorax by Fuel lance;
(3) by combustion fan using oxygen concentration > 95% oxygen-enriched as combustion-supporting gas by cocurrent heat accumulating type limekiln kiln crown Feed, under the draft of combustion fan, combustion-supporting gas is flowed down to combustion zone and met with fuel, makes fuel in Fuel lance Burn below spout;
(4) in the combustion zone of current kiln thorax (kiln thorax 1), limestone absorbs the heat that fuel combustion produces, and decomposes and generates life Calx and co2Gas;
(5) quick lime producing in the combustion zone of current kiln thorax (kiln thorax 1) is carried out by the cooling gas that cooling blower feeds Discharging after being cooled to 80 DEG C ~ 100 DEG C;
During kiln thorax 1 calcining, coal dust sprays in kiln thorax 1 by fuel nozzle, co2Combustion-supporting gas (carrier gas of conveying fuel) is from kiln crown Spray into, the bottom of two kiln thoraxes is passed through co2Cooling gas (is fed the cooling gas of combustion zone) by cooling blower, co2Cooling gas is by temperature Spend the high temperature cao for 1000 DEG C ~ 1150 DEG C and be cooled to 80 DEG C ~ 100 DEG C.
(6) rise to after cooling gas are heated by quick lime at interface channel, the co generating with decomposition of limestone2Gas and The co that fuel combustion produces2Gas mixing enters another kiln thorax (kiln thorax 2) by interface channel and rises, and enters through combustion zone Preheating zone preheats to limestone;
(7) after pre- thermogenetic flue gas rejects heat to limestone, temperature reduces and discharges, and by udst separation, produces The co that volumetric concentration is more than 95%2Gas, this co2The 5% of gas is fed by cooling blower as the carrier gas of conveying fuel, 65% conduct The cooling gas of cooling zone, remaining 30% direct stores or makes dry ice product;
(8) first burnout cycle complete, and in cocurrent heat accumulating type limekiln, various air-flows stop flowing, cocurrent heat accumulating type stone Ash furnace starts commutation work, commutating period 45s, and quick lime draws off from the kiln thorax bottom in cocurrent heat accumulating type limekiln.
Commutation work: combustion air change-over valve changes position, combustion air release valve is opened, cooling air relief valve Door is opened, and discharge shutter is opened.
Former day 450 tons of Calx the daily discharge in cocurrent heat accumulating type limekiln co2Measure as 385 ~ 415 tons, through side of the present invention After method, the exhaust gas volumn of the recycling of the part of air inlet compressor is 231 ~ 270 tons, 164 ~ 184 tons of the exhaust gas volumn of storage, Reduce fume emission, decrease environmental pollution.
Embodiment 2
It is based on co in the present embodiment2The cocurrent heat accumulating type limekiln system structure of enrichment is as shown in figure 1, employing in system Dust arrester be sack cleaner, fuel be coal dust.Dust concentration≤the 50mg/nm of the flue gas discharged from air vent3.
Using above-mentioned cocurrent heat accumulating type Calx kiln system produce quick lime (cao), 500 tons of the quick lime daily output, daily 80 The individual production cycle, per production cycle coal dust amount 265kg ~ 300kg, combustion air coefficient of excess 1.1 ~ 1.4.
Based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, comprises the following steps:
(1) in first combustion period, by raw limestone, before kiln, building stones storehouse is delivered to scale hooper, raw limestone warp Load after scale hooper weighing in truck and be transported to cocurrent heat accumulating type limekiln kiln crown, enter two kiln thoraxes in cocurrent heat accumulating type limekiln In (kiln thorax 1 and kiln thorax 2);
(2) Fuel lance in a kiln thorax (kiln thorax 1) in cocurrent heat accumulating type limekiln is inserted in limestone stock column, carries Airborne fuel is sprayed in kiln thorax by Fuel lance;
(3) pass through combustion fan to be fed combustion-supporting gas by cocurrent heat accumulating type limekiln kiln crown, in the draft of combustion fan Lower combustion-supporting gas is flowed down to combustion zone and is met with fuel, so that fuel is burnt below the spout of Fuel lance;Described combustion-supporting Gas be oxygen concentration > 95% oxygen-enriched;
(4) in the combustion zone of current kiln thorax (kiln thorax 1), limestone absorbs the heat that fuel combustion produces, and decomposes and generates life Calx and co2Gas;
(5) quick lime producing in the combustion zone of current kiln thorax (kiln thorax 1) is carried out by the cooling gas that cooling blower feeds Discharging after being cooled to 80 DEG C ~ 100 DEG C;
During kiln thorax 1 calcining, coal dust sprays in kiln thorax 1 by fuel nozzle, co2Combustion-supporting gas (carrier gas of conveying fuel) is from kiln crown Spray into, the bottom of two kiln thoraxes is passed through co2Cooling gas (is fed the cooling gas of combustion zone) by cooling blower, co2Cooling gas is by temperature Spend the high temperature cao for 1000 DEG C ~ 1150 DEG C and be cooled to 80 DEG C ~ 100 DEG C.
(6) rise to after cooling gas are heated by quick lime at interface channel, the co generating with decomposition of limestone2Gas and The co that fuel combustion produces2Gas mixing enters another kiln thorax (kiln thorax 2) by interface channel and rises, and enters through combustion zone Preheating zone preheats to limestone;
(7) after pre- thermogenetic flue gas rejects heat to limestone, temperature reduces and discharges, and by udst separation, produces The co that volumetric concentration is more than 95%2Gas, this co2The 10% of gas is supplied by cooling blower as the carrier gas of conveying fuel, 55% conduct Enter the cooling gas of cooling zone, remaining 35% direct stores or make dry ice product;
(8) first burnout cycle complete, and in cocurrent heat accumulating type limekiln, various air-flows stop flowing, cocurrent heat accumulating type stone Ash furnace starts commutation work, commutating period 50s, and quick lime draws off from the kiln thorax bottom in cocurrent heat accumulating type limekiln.
Commutation work: combustion air change-over valve changes position, combustion air release valve is opened, cooling air relief valve Door is opened, and discharge shutter is opened.
Former day 500 tons of Calx the daily discharge in cocurrent heat accumulating type limekiln co2Measure as 425 ~ 460 tons, through side of the present invention After method, the exhaust gas volumn of the recycling of the part of air inlet compressor is 255 ~ 276 tons, 170 ~ 184 tons of the exhaust gas volumn of storage, Reduce fume emission, decrease environmental pollution.
Embodiment 3
It is based on co in the present embodiment2The cocurrent heat accumulating type limekiln system structure of enrichment is as shown in figure 1, employing in system Dust arrester be sack cleaner, fuel be coal dust.Dust concentration≤the 50mg/nm of the flue gas discharged from air vent3.
Using above-mentioned cocurrent heat accumulating type Calx kiln system produce quick lime (cao), 550 tons of the quick lime daily output, daily 80 The individual production cycle, per production cycle coal dust amount 290 kg ~ 330kg, combustion air coefficient of excess 1.1 ~ 1.4.
Based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, comprises the following steps:
(1) in first combustion period, by raw limestone, before kiln, building stones storehouse is delivered to scale hooper, raw limestone warp Load after scale hooper weighing in truck and be transported to cocurrent heat accumulating type limekiln kiln crown, enter two kiln thoraxes in cocurrent heat accumulating type limekiln In (kiln thorax 1 and kiln thorax 2);
(2) Fuel lance in a kiln thorax (kiln thorax 1) in cocurrent heat accumulating type limekiln is inserted in limestone stock column, carries Airborne fuel is sprayed in kiln thorax by Fuel lance;
(3) pass through combustion fan to be fed combustion-supporting gas by cocurrent heat accumulating type limekiln kiln crown, in the draft of combustion fan Lower combustion-supporting gas is flowed down to combustion zone and is met with fuel, so that fuel is burnt below the spout of Fuel lance;Described combustion-supporting Gas be oxygen concentration > 95% oxygen-enriched;
(4) in the combustion zone of current kiln thorax (kiln thorax 1), limestone absorbs the heat that fuel combustion produces, and decomposes and generates life Calx and co2Gas;
(5) quick lime producing in the combustion zone of current kiln thorax (kiln thorax 1) is carried out by the cooling gas that cooling blower feeds Discharging after being cooled to 80 DEG C ~ 100 DEG C;
During kiln thorax 1 calcining, coal dust sprays in kiln thorax 1 by fuel nozzle, co2Combustion-supporting gas (carrier gas of conveying fuel) is from kiln crown Spray into, the bottom of two kiln thoraxes is passed through co2Cooling gas (is fed the cooling gas of combustion zone) by cooling blower, co2Cooling gas is by temperature Spend the high temperature cao for 1000 DEG C ~ 1150 DEG C and be cooled to 80 DEG C ~ 100 DEG C.
(6) rise to after cooling gas are heated by quick lime at interface channel, the co generating with decomposition of limestone2Gas and The co that fuel combustion produces2Gas mixing enters another kiln thorax (kiln thorax 2) by interface channel and rises, and enters through combustion zone Preheating zone preheats to limestone;
(7) after pre- thermogenetic flue gas rejects heat to limestone, temperature reduces and discharges, and by udst separation, produces The co that volumetric concentration is more than 95%2Gas, this co2The 8% of gas is fed by cooling blower as the carrier gas of conveying fuel, 60% conduct The cooling gas of cooling zone, remaining 32% direct stores or makes dry ice product;
(8) first burnout cycle complete, and in cocurrent heat accumulating type limekiln, various air-flows stop flowing, cocurrent heat accumulating type stone Ash furnace starts commutation work, commutating period 40 s, and quick lime draws off from the kiln thorax bottom in cocurrent heat accumulating type limekiln.
Commutation work: combustion air change-over valve changes position, combustion air release valve is opened, cooling air relief valve Door is opened, and discharge shutter is opened.
Former day 450 tons of Calx the daily discharge in cocurrent heat accumulating type limekiln co2Measure as 470 ~ 510 tons, through side of the present invention After method, the exhaust gas volumn of the recycling of the part of air inlet compressor is 282 ~ 306 tons, 188 ~ 204 tons of the exhaust gas volumn of storage, Reduce fume emission, decrease environmental pollution.

Claims (5)

1. one kind is based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment is it is characterised in that comprise the following steps:
(1) in first combustion period, by raw limestone, before kiln, building stones storehouse is delivered to scale hooper, and raw limestone is through weighing Load after bucket weighing in truck and be transported to cocurrent heat accumulating type limekiln kiln crown, enter in two kiln thoraxes in cocurrent heat accumulating type limekiln;
(2) Fuel lance in a kiln thorax in cocurrent heat accumulating type limekiln is inserted in limestone stock column, and carrier gas carries fuel Sprayed in kiln thorax by Fuel lance;
(3) pass through combustion fan to be fed combustion-supporting gas by cocurrent heat accumulating type limekiln kiln crown, help under the draft of combustion fan Combustion gas body is flowed down to combustion zone and is met with fuel, so that fuel is burnt below the spout of Fuel lance;
(4) in the combustion zone of current kiln thorax, limestone absorbs the heat that fuel combustion produces, and decomposes and generates quick lime and co2Gas Body;
(5) quick lime producing in the combustion zone of current kiln thorax by the cooling gas that cooling blower feeds carry out being cooled to 80 DEG C ~ Discharging after 100 DEG C;
(6) rise to after cooling gas are heated by quick lime at interface channel, the co generating with decomposition of limestone2Gas and fuel The co that burning produces2Gas mixing enters another kiln thorax by interface channel and rises, and enters preheating zone to stone through combustion zone Lime stone is preheated;
(7) after pre- thermogenetic flue gas rejects heat to limestone, temperature reduces and discharges, and by udst separation, produces volume The co that concentration is more than 95%2Gas, this co2, as the carrier gas of conveying fuel, another part is as by cooling wind for a part for gas Machine feeds the cooling gas of cooling zone, and remaining directly stores or makes dry ice product;
(8) first burnout cycle complete, and in cocurrent heat accumulating type limekiln, various air-flows stop flowing, cocurrent heat accumulating type limekiln Start commutation work, commutating period 40 s ~ 50s, quick lime draws off from the kiln thorax bottom in cocurrent heat accumulating type limekiln.
2. according to claim 1 based on co2Enrichment cocurrent heat accumulating type limekiln manufacturing technique method it is characterised in that The described combustion-supporting gas of step (3) be oxygen concentration > 95% oxygen-enriched.
3. according to claim 1 based on co2Enrichment cocurrent heat accumulating type limekiln manufacturing technique method it is characterised in that The co that volumetric concentration described in described step (7) is more than 95%230% ~ 35% co in gas2Gas directly stores or makes dry Ice product.
4. according to claim 1 or 3 based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, its feature exists In the co that the volumetric concentration described in described step (7) is more than 95%2In gas, 5% ~ 10% as the carrier gas conveying fuel.
5. according to claim 1 or 3 based on co2The cocurrent heat accumulating type limekiln manufacturing technique method of enrichment, its feature exists In the co that the volumetric concentration described in described step (7) is more than 95%2In gas, 55% ~ 65% feeds cooling as by cooling blower The cooling gas of band.
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