CN104997661A - Mild silicone-oil-free shampoo in cation system and preparing method thereof - Google Patents
Mild silicone-oil-free shampoo in cation system and preparing method thereof Download PDFInfo
- Publication number
- CN104997661A CN104997661A CN201510330672.3A CN201510330672A CN104997661A CN 104997661 A CN104997661 A CN 104997661A CN 201510330672 A CN201510330672 A CN 201510330672A CN 104997661 A CN104997661 A CN 104997661A
- Authority
- CN
- China
- Prior art keywords
- extract
- hair
- adopts
- shampoo
- agitated kettle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses mild silicone-oil-free shampoo in a cation system. According to the formula, the shampoo comprises an acrylic acid (acrylate)/steareth-20 methacrylate copolymer, cocamidopropyl glycine betaine, polyquaternium-10, lauroyl amphiprotic disodium oxalate, methyl cocoyl sodium taurate, behenyl trimethyl ammonium chloride, stearamide propyl dimethylamine, glycol distearate, quaternium-27, a scalp protective agent, cation conditioner, preservative, essence, a plant extract, a dandruff removal factor, a coix lacryma-jobi seed extractive, ricinic acid amide propyl ethyl dimethyl ammonio ethyl sulfate, and the balance water. The mild silicone-oil-free shampoo has the advantages that the shampoo does not contain sulfate, oxirane or silicone oil to avoid defects caused by the three materials, is good in biological degradability and has the effects of protecting and smoothing hair.
Description
Technical field
The present invention relates to a kind of shampoo, be specifically related to a kind of gentleness in cationic system without silicone oil shampoo and preparation method thereof.
Background technology
Hair by hair follicle and dryly to form.The overwhelming majority of hair is hair shaft.Hair shaft be made up of three parts, have outward in be respectively hair cuticle, hair cortex and hair medulla.
1, hair cuticle is the extexine of hair, and its effect is protective hair cortex, gives hair with gloss and elasticity, and in certain degree, determines the tone of hair.Hair cuticle generally has the squamous cell overlapping arrangement of 6 ~ 10 layers to form.The gross thickness of hair cuticle layer is generally 3 ~ 4 μm, and area accounts for about 15% of hair total cross section.Observe under scanning electron microscope, can find healthy int hair cuticle flat smooth, arrangement in order.
2, hair cortex is the topmost component part of hair, and it determines elasticity, intensity, tone and the thickness of hair.The area of hair cortex part accounts for about 82% of hair total cross section.
3, hair medulla is the core of hair, little to the characteristics influence of hair.
The main chemical compositions of hair is keratoprotein, accounts for 65 ~ 95% of hair; Also containing lipid, pigment and some trace element etc.Trace element is combined with keratic side chain or fatty acid, is not free state.Keratin is amino acid whose polymer, is made up of tens seed amino acids, and comprises 5 kinds of chemical elements in these aminoacid and be present in keratin chains and the various chemical bonds of interchain play the effect of giving hair intensity and maintaining shape.
Hair physical property: 1. hair is one the most full of elasticity in natural fiber, when the int wet hair of stretching health, it can extend 30%, and recovers the original length after the drying.(because of flexible, hair can be resisted external force and keep the profile sent out, and length is constant) 2. hair rubbing action causes by delivering the special construction that face hair cuticle flakey arranges.The coefficient of friction of hair increases along with sending out the impaired of age and hair.Hair wet friction effect is higher than dry friction effect, and increases with the increase of relative humidity.The rubbing action of hair has directivity, is namely extremely sent out the rubbing action in the direction of point by root of hair compared with little to the direction of root of hair by sending out point.This is also the directivity decision of hair cuticle scale arrangement.3. electrostatic interaction.Hair has the performance of triboelectrification.The hair that friction is dry, during as brush or combing, hair forms electrostatic.This phenomenon is especially easily observed in the weather of drying.Electrostatic be hair mutually repel and can not be smooth arranged together, cause hair to be erect, move swiftly, fluffyly to open.The static electrification of hair is by the control of three factors, and one is the state in the face of delivering, and one is the content of water in sending out, and another is temperature.And hair surface is when being coated with sufficient hair care ingredient as cation form activating agent, generally triboelectrification phenomenon can not be there is.And also seldom there is to have rubbed the phenomenon of electrostatic when hair is comparatively moistening.In addition, the electrical resistance temperature of hair keratin fiber rising and the approximately often high 10 DEG C of resistance that decline decline 5 times.Thus, generally there will not be electrostatic when temperature raises.
The development course of shampoo: hair and scalp clean is then the basis of hair caring.Want to keep the attractive in appearance of hair, first will often have one's hair wash.Hair has coupled sebaceous gland, constantly secretes sebum.Sebum to mix formation sebum film in antiperspirant.Sebum film is also formed and other positions of health, thus causes favorable environment for the procreation of microorganism.If do not washed hair for a long time, not only hair dirt is unfavorable for attractive in appearance, and likely causes the dandruff, and dermatitis is the disease such as alopecia even.
The classification of shampoo: be generally divided into two large classes, namely single washing function floods and Two-in-one shampoo (cleaning function and hair care function).Main with Two-in-one shampoo on current market at home.In Two-in-one shampoo, by using cationic polymeric compound, hair care ingredient as polysiloxanes etc. very dexterously dispersion suspension in as in the anionic surfactant system of abluent.These hair care ingredients in the product can stable existence, and when shampoo contacts with hair, they are just released and are attached to the surface of hair.The ultimate principle of hair care is that hair care ingredient is attached to hair surface, and lubrication delivers layer, reduces frictional force, thus reduces the probability of the hair damage that generation causes because of combing etc.The protecting film that hair care ingredient is formed in addition can slow down the change of the moisture in the hair that brings because humidity change.
Main component in cleaning shampoo is surfactant, is generally anion surfactant.As ammonium lauryl sulfate, sodium lauryl sulphate, Dodecyl Polyoxyethylene Ether ammonium sulfate, Dodecyl Polyoxyethylene Ether sodium sulfate etc.General not containing insoluble hair care ingredient in cleaning shampoo, therefore transparent shape.
Summary of the invention
The object of the present invention is to provide a kind of gentleness in cationic system without silicone oil shampoo.
For achieving the above object, technical scheme of the present invention is: a kind of gentleness in cationic system is without silicone oil shampoo, and by weight percentage, its formula is as follows:
Acrylic acid (ester) class/stereth-20 methacrylate copolymer 1 ~ 6%,
Cocamido propyl betaine 20 ~ 45%,
Polyquaternium-10 0.25 ~ 1.25%,
Lauroyl both sexes base oxalic acid disodium 2.5 ~ 15%,
Sodium methyl cocoyl taurate 1.0 ~ 5%,
Mountain Yu base trimethyl ammonium chloride 0.5 ~ 3%,
Stearamidopropyl dimethylamine 0.5 ~ 3%,
Glycol distearate 1 ~ 3%,
Quaternary ammonium salt-27 0.5 ~ 3%,
Scalp protective agent 0.1 ~ 0.3%,
Cation opsonizing agent 1 ~ 4%,
Antiseptic 0.05 ~ 0.2%,
Essence 0.25 ~ 1.5%,
Plant extraction liquid 0.10 ~ 0.50%,
The anti-dandruff factor 0.01 ~ 0.05%,
Semen Coicis seed extract 0.01 ~ 0.05%,
Ricinoleic acid amide ethyl dimethyl ammonium ethylsulfate 0.5 ~ 3%,
The rest is water.
Wherein the anti-dandruff factor adopts ZPT; antiseptic adopts Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate; scalp protective agent adopts Brassica campestris L (BRASSICA CAMPESTRIS) sterols or cetearyl alcohol, and cation opsonizing agent adopts stearyl trimethyl ammonium chloride or cetearyl alcohol.
Wherein quaternary ammonium salt-27 effect is that shampoo can be atomized in water, and the composition be conducive in shampoo can fully disperse.Ricinoleic acid amide ethyl dimethyl ammonium ethylsulfate, as the attached fat composition of shampoo cationic, belongs to the cation of intermediate molecular weight, does not have accumulative effect.
Plant extraction liquid adopts butchers broom (RUSCUS ACULEATUS) root extract, Herba Centellae (CENTELLA ASIATICA) extract, Flos Inulae (CALENDULA OFFICINALIS) flower extract, Fructus Litchi (LITCHI CHINENSIS) berry extract, Fructus Vitis viniferae (VITIS VINIFERA) berry extract, bergamot (CITRUS AURANTIUM BERGAMIA) berry extract, Fructus Mali pumilae (MALUS DOMESTICA) berry extract, Fructus Fragariae Ananssae (FRAGARIA CHILOENSIS) berry extract, A.chinensis Planch. (ACTINIDIA CHINENSIS) berry extract, one or more combination in Punica granatum L. (PUNICA GRANATUM) berry extract.
Another object of the present invention is to provide the preparation method of a kind of gentleness in cationic system without silicone oil shampoo.
To achieve these goals, technical scheme of the present invention is as follows: a kind of gentleness in cationic system is without the preparation method of silicone oil shampoo, comprise the following steps: A, acrylic acid (ester) class/stereth-20 methacrylate copolymer and suitable quantity of water stir in agitated kettle, cocamido propyl betaine are added mix homogeneously in agitated kettle; B, Polyquaternium-10 and suitable quantity of water are added in agitated kettle, stir, be warming up to 70 ~ 75 DEG C, lauroyl both sexes base oxalic acid disodium, sodium methyl cocoyl taurate are added in agitated kettle and continues the homogenizing that stirs; C, agitated kettle is warming up to 80 ~ 82 DEG C, mountain Yu base trimethyl ammonium chloride, stearamidopropyl dimethylamine, glycol distearate, quaternary ammonium salt-27, scalp protective agent, cation opsonizing agent is added in agitated kettle and stirs, be incubated 25 ~ 35 minutes; D, continuation are stirred, be cooled to 39 ~ 41 DEG C, antiseptic, essence, plant extraction liquid, the anti-dandruff factor, Semen Coicis seed extract, ricinoleic acid amide ethyl dimethyl ammonium ethylsulfate are added in agitated kettle and stirs, until material body is even, stop stirring, open vacuum pump, bubble of bleeding, E, be cooled to 35 ~ 38 DEG C of dischargings.
Wherein the anti-dandruff factor adopts ZPT; antiseptic adopts Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate; scalp protective agent adopts Brassica campestris L (BRASSICA CAMPESTRIS) sterols or cetearyl alcohol, and cation opsonizing agent adopts stearyl trimethyl ammonium chloride or cetearyl alcohol.
Plant extraction liquid adopts butchers broom (RUSCUS ACULEATUS) root extract, Herba Centellae (CENTELLA ASIATICA) extract, Flos Inulae (CALENDULA OFFICINALIS) flower extract, Fructus Litchi (LITCHI CHINENSIS) berry extract, Fructus Vitis viniferae (VITIS VINIFERA) berry extract, bergamot (CITRUS AURANTIUM BERGAMIA) berry extract, Fructus Mali pumilae (MALUS DOMESTICA) berry extract, Fructus Fragariae Ananssae (FRAGARIA CHILOENSIS) berry extract, A.chinensis Planch. (ACTINIDIA CHINENSIS) berry extract, one or more combination in Punica granatum L. (PUNICA GRANATUM) berry extract.
Wherein in steps A, suitable quantity of water accounts for 20 ~ 24% of shampoo gross weight, and in step B, suitable quantity of water accounts for 13 ~ 14% of shampoo gross weight.
Utilize Semen Coicis seed extract to carry out hair conditioning in the present invention, avoid jag, the same due to scattergram amino acid whose in Semen Coicis seed extract and amino acid whose scattergram in hair, therefore, it is possible to hair conditioning better, avoid jag.The invention has the advantages that not containing sulfate, oxirane and silicone oil, therefore there is not its defect brought, and biological degradability is good, also can reach the effect of hair care and submissive hair simultaneously.
Accompanying drawing explanation
Fig. 1 utilizes tonometer friction testing instrument in the test effect of frictional force pattern.
Fig. 2 is the test effect of carding force pattern.
Fig. 3 is the dry wet carding property comparison diagram of three kinds of samples.
Fig. 4 is the comparison diagram of the foaming degree of three kinds of samples.
Fig. 5 is the test report of inventive samples.
Fig. 6 is the test report of inventive samples.
Detailed description of the invention
Embodiment 1 is the formula of a kind of olive oil nutrition hair-washing dew
Component number material combination Name Weight %
1 citric acid 0.15
2 carbomers 0.35
3 water 61
4 guar hydroxypropyltrimonium chlorides, sodium chloride, fumaric acid 0.5
5 water 13
6 sodium laureth sulfate 15.5
7 lauroyl both sexes base oxalic acid disodiums 7
8 glycol distearates 1
9 polydimethylsiloxane, laureth-23, C12-15 Pareth-3, water 1
10 DMDM hydantoin 0.5
11 essence 0.5
12 Fructus oleae europaeae (OLEA EUROPAEA) fruit oil 0.01
13 pigment 0.42.
Its rule of operation is as follows:
A, in formula table ratio, deionized water is weighed into be uniformly mixed pot start stir;
B, add the raw material that component number is 2,4, No. 5 successively, add in the ratio of formula table and be uniformly mixed in pot, be heated to 75-85 DEG C, stir;
C, add the raw material of No. 6,7,8, component number, continue to stir, this temperature 30 minutes;
D, be uniformly mixed pot and cool 55 DEG C, add component number 1 adjust ph, pH
Value is 5.5-7.5;
E, continue stirring and be cooled to 40 DEG C, add after component number 9,10,11,12,13 stirs, until material body is even, stops stirring, open vacuum pump, bubble of bleeding;
F, be cooled to 35-38 DEG C of discharging in holding vessel, after the inspection of semifinished product is qualified, enter fill room;
G, carry out fill by net content requirement, per half an hour surveys sample fill net content.
Wherein, each component sum of embodiment 1, slightly larger than 100%, is because fraction water wherein can volatilize.
Embodiment 2 be a kind of gentleness in cationic system of the present invention without silicone oil shampoo, its formula is as follows:
Component number material combination Name Weight %
1 water 22
2 acrylic acid (ester) class/stereth-20 methacrylate copolymer 5
3 cocamido propyl betaine 40
4 Polyquaternium-10s 1
5 water 13
6 lauroyl both sexes base oxalic acid disodiums 10
7 sodium methyl cocoyl taurate 2
8 mountain Yu base trimethyl ammonium chlorides 1
9 stearamidopropyl dimethylamine 1
10 glycol distearates 1.5
11 quaternary ammonium salts-27 1
12 Brassica campestris Ls (BRASSICA CAMPESTRIS) sterols or cetearyl alcohol 0.2
13 stearyl trimethyl ammonium chloride or cetearyl alcohol 3
14 Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate 0.18
15 essence 1
16 plant extraction liquid 1(butchers broom (RUSCUS ACULEATUS) root extracts, Herba Centellae (CENTELLA ASIATICA) extract, pantothenylol, water, Flos Inulae (CALENDULA OFFICINALIS) flower extract) 0.01
17 plant extraction liquid 2(Fructus Litchi (LITCHI CHINENSIS) berry extracts, Fructus Vitis viniferae (VITIS VINIFERA) berry extract, bergamot (CITRUS AURANTIUM BERGAMIA) berry extract, Fructus Mali pumilae (MALUS DOMESTICA) berry extract, Fructus Fragariae Ananssae (FRAGARIA CHILOENSIS) berry extract, A.chinensis Planch. (ACTINIDIA CHINENSIS) berry extract, Punica granatum L. (PUNICA GRANATUM) berry extract)
0.02
18 ZPTs 0.01
19 Semen Coiciss (COIX LACRYMA-JOBI) seed extract 0.01
20 ricinoleic acid amide ethyl dimethyl ammonium ethylsulfate 2
Its rule of operation
A, in formula table ratio, component number 1, No. 2 raw materials are dropped into and is uniformly mixed pot and starts to stir;
B, add the raw material that component number is No. 3, add in the ratio of formula table and be uniformly mixed in pot, stir;
C, add the raw material of the numbering 4,5 of component mix homogeneously, stir.Heat to 70-75 degree, then add component number 6, No. 7 raw materials, continue to stir, homogenizing 3 times;
D, be uniformly mixed pot and heat to 80-82 DEG C, add component number 8,9,10,11,12, No. 13 raw materials, stir, this temperature 30 minutes;
E, continue stirring and be cooled to 40 DEG C, add after component number 14,15,16,17,18,19, No. 20 raw materials stir, until material body is even, stops stirring, open vacuum pump, bubble of bleeding;
F, be cooled to 35-38 DEG C of discharging in holding vessel, after the inspection of semifinished product is qualified, enter fill room;
G, carry out fill by net content requirement, per half an hour surveys sample fill net content.
The production equipment wherein used comprises:
1, vacuum emulsification pot 300kg/500kg
2, oil phase pot, aqueous phase pot
2, storage tank, storage vat
4, shampoo filling machine, air compressor machine
5, Imaje ink jet numbering machine.
In this embodiment, each component sum, also slightly larger than 100%, is because part water can be evaporated.
Shampoo embodiment 1 made is as sample 1, and the shampoo made by embodiment 2 i.e. formula according to the present invention, as sample 2, using another commercially available shampoo as sample 3, is tested.
Fig. 1 utilizes tonometer friction testing instrument in the test effect of frictional force pattern.
Fig. 2 is the test effect of carding force pattern.
Fig. 3 is the dry wet carding property comparison diagram of three kinds of samples.Evaluate its dry & with remaining carding force in test to wet carding property, the lower then cardability of numerical value is better.Test display is for wet cardability, and No. 1 sample behaves oneself best, and is better than No. 2 and No. 3 samples, and No. 2, No. 3 samples do not have significant difference; But for dry cardability, No. 2 samples then show even better, No. 1 and No. 3 comparing class seemingly, all not as No. 2 samples.Visible shampoo of the present invention has better effect in dry cardability.
Fig. 4 is the comparison diagram of the foaming degree of three kinds of samples.From foaming and foaming abundancy degree, No. 2 samples behave oneself best, and are secondly No. 1, and No. 3 comparatively speaking more obviously not as 1, No. 2 sample.
Fig. 5 and Fig. 6 is the test report of inventive samples.Visible, shampoo of the present invention does not have irritative response.
Above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that the present invention specifically implements to be confined to these explanations above-mentioned.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (6)
1. the gentleness in cationic system, without a silicone oil shampoo, is characterized in that by weight percentage, and its formula is as follows:
Acrylic acid (ester) class/stereth-20 methacrylate copolymer 1 ~ 6%,
Cocamido propyl betaine 20 ~ 45%,
Polyquaternium-10 0.25 ~ 1.25%,
Lauroyl both sexes base oxalic acid disodium 2.5 ~ 15%,
Sodium methyl cocoyl taurate 1.0 ~ 5%,
Mountain Yu base trimethyl ammonium chloride 0.5 ~ 3%,
Stearamidopropyl dimethylamine 0.5 ~ 3%,
Glycol distearate 1 ~ 3%,
Quaternary ammonium salt-27 0.5 ~ 3%,
Scalp protective agent 0.1 ~ 0.3%,
Cation opsonizing agent 1 ~ 4%,
Antiseptic 0.05 ~ 0.2%,
Essence 0.25 ~ 1.5%,
Plant extraction liquid 0.10 ~ 0.50%,
The anti-dandruff factor 0.01 ~ 0.05%,
Semen Coicis seed extract 0.01 ~ 0.05%,
Ricinoleic acid amide ethyl dimethyl ammonium ethylsulfate 0.5 ~ 3%,
The rest is water.
2. as claimed in claim 1 gentle without silicone oil shampoo; it is characterized in that the anti-dandruff factor adopts ZPT; antiseptic adopts Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate; scalp protective agent adopts campesterol class or cetearyl alcohol, and cation opsonizing agent adopts stearyl trimethyl ammonium chloride or cetearyl alcohol.
3. as claimed in claim 1 gentle without silicone oil shampoo, it is characterized in that plant extraction liquid adopts one or more the combination in butchers broom root extract, Herba Centellae extract, Flos Inulae flower extract, litchi extract, uva extract, bergamot berry extract, Apples extract, Fructus Fragariae Ananssae berry extract, A.chinensis Planch. berry extract, Punica granatum L. extract.
4. the gentleness in cationic system is without the preparation method of silicone oil shampoo, comprise the following steps: A, acrylic acid (ester) class/stereth-20 methacrylate copolymer and suitable quantity of water stir in agitated kettle, cocamido propyl betaine are added mix homogeneously in agitated kettle; B, Polyquaternium-10 and suitable quantity of water are added in agitated kettle, stir, be warming up to 70 ~ 75 DEG C, lauroyl both sexes base oxalic acid disodium, sodium methyl cocoyl taurate are added in agitated kettle and continues the homogenizing that stirs; C, agitated kettle is warming up to 80 ~ 82 DEG C, mountain Yu base trimethyl ammonium chloride, stearamidopropyl dimethylamine, glycol distearate, quaternary ammonium salt-27, scalp protective agent, cation opsonizing agent is added in agitated kettle and stirs, be incubated 25 ~ 35 minutes; D, continuation are stirred, be cooled to 39 ~ 41 DEG C, antiseptic, essence, plant extraction liquid, the anti-dandruff factor, Semen Coicis seed extract, ricinoleic acid amide ethyl dimethyl ammonium ethylsulfate are added in agitated kettle and stirs, until material body is even, stop stirring, open vacuum pump, bubble of bleeding, E, be cooled to 35 ~ 38 DEG C of dischargings.
5. preparation method as claimed in claim 4; it is characterized in that the anti-dandruff factor adopts ZPT; antiseptic adopts Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate; scalp protective agent adopts campesterol class or cetearyl alcohol, and cation opsonizing agent adopts stearyl trimethyl ammonium chloride or cetearyl alcohol.
6. preparation method as claimed in claim 4, is characterized in that plant extraction liquid adopts one or more the combination in butchers broom root extract, Herba Centellae extract, Flos Inulae flower extract, litchi extract, uva extract, bergamot berry extract, Apples extract, Fructus Fragariae Ananssae berry extract, A.chinensis Planch. berry extract, Punica granatum L. extract.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510330672.3A CN104997661A (en) | 2015-06-15 | 2015-06-15 | Mild silicone-oil-free shampoo in cation system and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510330672.3A CN104997661A (en) | 2015-06-15 | 2015-06-15 | Mild silicone-oil-free shampoo in cation system and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104997661A true CN104997661A (en) | 2015-10-28 |
Family
ID=54370715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510330672.3A Pending CN104997661A (en) | 2015-06-15 | 2015-06-15 | Mild silicone-oil-free shampoo in cation system and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104997661A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105380831A (en) * | 2015-12-15 | 2016-03-09 | 广州温雅日用化妆品有限公司 | Mild nursing hair oil treatment and care composition containing no silicone oil and preparation method of mild nursing hair oil treatment and care composition |
| CN105963165A (en) * | 2016-04-08 | 2016-09-28 | 东莞市长欣家化有限公司 | Shampoo prepared from wheat germ |
| CN106074252A (en) * | 2016-06-24 | 2016-11-09 | 杭州兰茜化妆品有限公司 | Shampoo |
| KR20180016144A (en) * | 2016-08-05 | 2018-02-14 | 애경산업(주) | Hair cleansing composition having improved conditioning |
| CN108670910A (en) * | 2018-08-13 | 2018-10-19 | 花安堂生物科技集团有限公司 | A kind of profit hair composition and preparation method thereof |
| WO2019038309A1 (en) | 2017-08-25 | 2019-02-28 | Unilever Plc | Personal cleansing composition |
| WO2019038308A1 (en) | 2017-08-25 | 2019-02-28 | Unilever Plc | Personal cleansing composition |
| CN113768825A (en) * | 2021-08-26 | 2021-12-10 | 河南天源海汇药物研究有限公司 | Formula and process of sweet wormwood herb shampoo |
| CN114159327A (en) * | 2021-12-10 | 2022-03-11 | 福建省梦娇兰日用化学品有限公司 | Mild hair-care type infant shampoo and preparation method thereof |
| CN115300405A (en) * | 2022-08-11 | 2022-11-08 | 清远天赐高新材料有限公司 | Hair composition with color protection effect and preparation method and application thereof |
-
2015
- 2015-06-15 CN CN201510330672.3A patent/CN104997661A/en active Pending
Non-Patent Citations (3)
| Title |
|---|
| 佚名: "《化妆品便利信息网：http://www.cosdna.com/chs/cosmetic_9f3a164415.html》", 7 November 2014 * |
| 佚名: "《国产非特殊用途化妆品备案信息服务平台，http://125.35.6.80:8080/ftban/itownet/hzp_ba/fw/pz.jsp?processid=20141104091954fu959&nin=20141104091954fu959》", 30 November 2014 * |
| 媚兰S7洗护咨询: "《https://mp.weixin.qq.com/s?src=3×tamp=1539239157&ver=1&signature=NHH3kaT3*vSvSSp*op0xgK5kiOIH7HyUFxKMZN1jADOQsqOngqWcU6ENdWHAuYcMgwFbfrqMsh0Ge4d0*zNhVeZa83s5cx5N-LEqaKZiohhsyqRQytp56ZU1AnFyXKDHO7qud*jX2**p4AnwV1vUUA==》", 13 February 2015 * |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105380831B (en) * | 2015-12-15 | 2018-09-21 | 广州温雅日用化妆品有限公司 | No mild Tiao Li treatment oil Haircare composition of silicone oil and preparation method thereof |
| CN105380831A (en) * | 2015-12-15 | 2016-03-09 | 广州温雅日用化妆品有限公司 | Mild nursing hair oil treatment and care composition containing no silicone oil and preparation method of mild nursing hair oil treatment and care composition |
| CN105963165A (en) * | 2016-04-08 | 2016-09-28 | 东莞市长欣家化有限公司 | Shampoo prepared from wheat germ |
| CN106074252B (en) * | 2016-06-24 | 2019-04-02 | 杭州兰茜化妆品有限公司 | Shampoo |
| CN106074252A (en) * | 2016-06-24 | 2016-11-09 | 杭州兰茜化妆品有限公司 | Shampoo |
| KR20180016144A (en) * | 2016-08-05 | 2018-02-14 | 애경산업(주) | Hair cleansing composition having improved conditioning |
| KR102601554B1 (en) * | 2016-08-05 | 2023-11-14 | 애경산업(주) | Hair cleansing composition having improved conditioning |
| US11779528B2 (en) | 2017-08-25 | 2023-10-10 | Conopco, Inc. | Personal cleansing composition |
| US11931442B2 (en) | 2017-08-25 | 2024-03-19 | Conopco, Inc. | Personal cleansing composition |
| WO2019038309A1 (en) | 2017-08-25 | 2019-02-28 | Unilever Plc | Personal cleansing composition |
| WO2019038308A1 (en) | 2017-08-25 | 2019-02-28 | Unilever Plc | Personal cleansing composition |
| CN111225655A (en) * | 2017-08-25 | 2020-06-02 | 荷兰联合利华有限公司 | Personal cleansing compositions |
| CN108670910B (en) * | 2018-08-13 | 2020-09-04 | 花安堂生物科技集团有限公司 | Hair-moistening composition and preparation method thereof |
| CN108670910A (en) * | 2018-08-13 | 2018-10-19 | 花安堂生物科技集团有限公司 | A kind of profit hair composition and preparation method thereof |
| CN113768825A (en) * | 2021-08-26 | 2021-12-10 | 河南天源海汇药物研究有限公司 | Formula and process of sweet wormwood herb shampoo |
| CN114159327A (en) * | 2021-12-10 | 2022-03-11 | 福建省梦娇兰日用化学品有限公司 | Mild hair-care type infant shampoo and preparation method thereof |
| CN115300405A (en) * | 2022-08-11 | 2022-11-08 | 清远天赐高新材料有限公司 | Hair composition with color protection effect and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104997661A (en) | Mild silicone-oil-free shampoo in cation system and preparing method thereof | |
| CN101039654B (en) | Hair care formulations comprising aminofunctional polyoganosiloxane | |
| CN104487139B (en) | Conditioning composition additive for providing immediate and long lasting benefits to keratin substrates | |
| CN104856895B (en) | A kind of without silicon shampoo and preparation method thereof | |
| DE102015204987A1 (en) | Hair shampoo with improved care performance containing silicones | |
| CN109498494A (en) | A kind of salubrious oil-control is without silicone oil shampoo and preparation method thereof | |
| CN104224575A (en) | Transparent silicone-oil-free hairdressing composition and preparation method thereof | |
| EP1667640A1 (en) | Skin and hair care preparation containing a combination of protein hydrolysates | |
| CN108186385A (en) | A kind of hair scalp cleaning compositions | |
| CN110123721B (en) | Shampoo composition for improving oily scalp | |
| CN106361660A (en) | Sulfate-anionic-surfactant-free silicone-oil-free shampoo composition | |
| CN108125870B (en) | Scalp nourishing composition, preparation method and application thereof, and scalp nourishing shampoo | |
| CN108785198A (en) | Strengthen the hair composition, leaves shampoo and preparation method thereof | |
| CN108685734A (en) | A kind of no sulfate is without the low mild plant herbal shampoo of stimulation of silicon | |
| CN109288725A (en) | A kind of transparent amino acid pattern is without silicone oil shampoo | |
| CN102552056A (en) | Shampoo composition | |
| CN106572955A (en) | Non-petrochemically derived cationic emulsifiers and related compositions and methods | |
| CN108904311A (en) | A kind of no silicone oil shampoo | |
| US20180369113A1 (en) | Personal care formulations comprising carmin protein | |
| CN112891252A (en) | Mild itching-relieving bath composition and preparation method thereof | |
| WO2015086005A1 (en) | Cosmetic composition containing a combination of oligopeptides and ceramides | |
| CN113891908B (en) | Aqueous dispersions of precrosslinked organopolysiloxanes | |
| CN107375028A (en) | A kind of non-stimulated no silicon shampoo and preparation method thereof | |
| JP7294642B2 (en) | hair cosmetics | |
| CN109010137A (en) | A kind of salubrious humidity-preserving type is without silicone oil shampoo |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151028 |
|
| RJ01 | Rejection of invention patent application after publication |