CN1049702C - Method for making flame-retardant polyester fibre continuous filament - Google Patents
Method for making flame-retardant polyester fibre continuous filament Download PDFInfo
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- CN1049702C CN1049702C CN96115709A CN96115709A CN1049702C CN 1049702 C CN1049702 C CN 1049702C CN 96115709 A CN96115709 A CN 96115709A CN 96115709 A CN96115709 A CN 96115709A CN 1049702 C CN1049702 C CN 1049702C
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- fire
- retardant
- flame
- polyester
- flame resisting
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Abstract
The present invention belongs to the technical field of flame resisting fiber, particularly to a method for producing flame resisting dacron long threads. A product is obtained by drying and melting polyester chips, extruding out a melting body and spinning the melting body. The present invention is characterized in that the extrusion and the spinning operation are carried out after adding a flame resisting melting body into a polyester melting body, and together mixing the flame resisting melting body and the polyester melting body. The flame resisting melting body is made by drying and melting flame resisting mother particles of which the structural formula is disclosed in the specification. The method uses a novel flame resisting agent, and uses scientific and reasonable preparing technology. Thus, the produced flame resisting dacron long threads have the advantages of softness, elasticity, good flame resistance, long flame resisting period and permanent flame resistance.
Description
The invention belongs to the fire resistance fibre technical field.
Being of wide application of fiber, the fire resistance of fiber has caused people's attention, some countries have also formulated laws and regulations to the fire-retardant requirement of textiles for general use, require curtain, curtain account, old man and the child's of public places such as theater, hospital, hotel clothes all must reach certain flame-retardant standard with textiles, therefore, the fire-retardant of fiber is very important.
At present, brominated organic compound and the antimony oxide of the fire-retardant common employing of macromolecular material is re-dubbed flame-retardant system, this based flame retardant systems, heat endurance is relatively poor, easily in process, decompose, produce corrosive gas, human body is had asphyxiating, and corrosion spinning and other processing of high molecular material equipment.In addition, antimony oxide itself belongs to the non-material that melts, and easily the plate hole of silk or spray silk is squeezed in obstruction in spinning process, changes the shortening of plate cycle thereby make, and reduces production efficiency.Aborning, this based flame retardant at first is mixed in the polyester slice, and by common spinning technique producd fibers, production process is affected, and has also influenced the performance of spinning fibre again.
The object of the present invention is to provide a kind of manufacture method of fire-retardant polyester filament yarn, this method is used BACN, adopts scientific and reasonable preparation technology, makes the fire-retardant polyester filament yarn of manufacturing have superperformance.
Purpose of the present invention can be realized by following scheme:
The manufacture method of described fire-retardant polyester filament yarn, with fusion after the polyester slice drying, with molten mass extrude, spinning obtains product, it is characterized in that in the polyester molten mass, adding fire-retardantly extrude again after melt blended, spinning, fire-retardant melt by structural formula is
The fire-retardant master granule drying after fusion and making.
Above-mentioned fire-retardant master granule is called the SF-FR fire-retardant master granule, produce by Tengzhou City, Shandong textile auxiliary factory, it itself is macromolecule that this fire-retardant master granule has, addition is few, one-component is fire-retardant, do not need synergist, good flame retardation effect, the decomposition temperature height, Heat stability is good, the amount of being fuming is few, nontoxic, non-corrosiveness, good with the macromolecular material compatibility, substantially do not influence characteristics such as the original performance of material, because the chemical constitution of SF-FR fire-retardant master granule is similar to the chemical constitution of polyester and polyamide substantially, make flame-retardant composition and compatibility and spinning rheological characteristic are preferably arranged between the fire-retardant thing, simultaneously also guarantee to be blended into fine back flame-retardant composition and can from fiber, not dissociate out, reached permanent fire-retardant purpose.
Take into account the characteristic of polyester slice and SF-FR fire-retardant master granule, need determine new preparation technology, adjust process, determine reasonable technological parameter.
In the manufacture method of the present invention, used polyester slice is the PET polyester slice, and main component is an ethylene glycol terephthalate.
In the manufacture method of the present invention, the percentage by weight that the addition of fire-retardant melt is controlled at polyester slice and fire-retardant master granule is: polyester slice 90～94% fire-retardant master granules 10～6%, to guarantee spinning quality and to have suitable melt viscosity to be convenient to spinning, can guarantee fire resistance again.
In the manufacture method of the present invention, the baking temperature of fire-retardant master granule is 130～150 ℃, and be 4～6 hours drying time, and effect is better.
In the manufacture method of the present invention, the best melt temperature of fire-retardant master granule is 265～286 ℃.
Manufacture method of the present invention is the improvement of carrying out on original fibre manufacture, has the following advantages:
(1) flame retardant performance is good, addition is few, one-component is fire-retardant, do not need that synergist, good flame retardation effect, decomposition temperature height, Heat stability is good, the amount of being fuming are few, nontoxic, non-corrosiveness, no asphyxia, good with the macromolecular material compatibility, do not influence the original performance and the production requirement of material substantially.
(2) determine production technology according to material performance, scientific and reasonable, implement easily, be convenient to grasp.
(3) the fire-retardant polyester filament yarn performance of this method manufacturing is good, and all indexs all meet standard-required, the fiber softening high resilience, and fire resistance is good, and the fire-retardant effect phase is long, can reach permanent fire-retardant.
The invention will be further described below in conjunction with drawings and Examples.
The block flow diagram of Fig. 1, manufacture method of the present invention.
Embodiment 1, production procedure are as shown in Figure 1, and be raw materials used and technological parameter is as follows:
The ethylene glycol terephthalate section is respectively with the percentage by weight of SF-FR fire-retardant master granule:
92％，8％。
The baking temperature of ethylene glycol terephthalate section is: 165～175 ℃
Be drying time: 4 hours
Melt temperature is: 280～290 ℃
The baking temperature of SF-FR fire-retardant master granule is: 135～145 ℃
Time is: 5 hours
Melt temperature is: 270～280 ℃
This batch product department after testing detects, and the results are shown in Table 1:
Table 1:
| Sequence number | Project name | Standard-required | Unit | Assay | The standard foundation |
| 1 | Line density | 60±1.8 | dtex | 59.0 | GB/T14460-93 |
| 2 | Line density CV value (%) | ≤1.40 | 0.64 | GB/T14460-93 | |
| 3 | Fracture strength | ≥3.00 | CN/dtex | 3.20 | GB/T14460-93 |
| 4 | Fracture strength CV value (%) | ≤8.00 | 3.74 | GB/T14460-93 | |
| 5 | Elongation at break (%) | 20±7.0 | 14.8 | GB/T14460-93 | |
| 6 | Elongation at break CV value (%) | ≤12.0 | 9.64 | GB/T14460-93 | |
| 7 | Crimp shrinkage rate (%) | 15±7 | 10.2 | GB/T14460-93 | |
| 8 | Crimp shrinkage rate CV (%) | ≤14.0 | 6.07 | GB/T14460-93 | |
| 9 | Curling stability (%) | ≥55.0 | 78.3 | GB/T14460-93 | |
| 10 | Boiling water shrinkage (%) | 2±0.8 | 1.6 | GB/T14460-93 | |
| 11 | Dyeing uniformity | 4 | Level | 4～5 | GB/T14460-93 |
| 12 | Oxygen index (OI) | 30.5 | GB5454 |
Embodiment 2～4 production procedures are with embodiment 1, and raw materials used technological parameter sees Table 2.
Table 2:
| Embodiment | Raw material | Consumption (%) | Baking temperature (℃) | Drying time (h) | Melt temperature (℃) |
| Embodiment 2 | PET BET section | 94 | 160～170 | 5 | 280～290 |
| The SF-FR fire-retardant master granule | 6 | 130～140 | 6 | 265～270 | |
| Embodiment 3 | PET DET section | 93 | 165～180 | 4 | 280～290 |
| The SF-FR fire-retardant master granule | 7 | 140～150 | 4 | 270～285 | |
| Embodiment 4 | PET DET section | 91 | 168～175 | 5 | 280～290 |
| The SF-FR fire-retardant master granule | 9 | 135～140 | 6 | 270～280 |
Claims (1)
1, a kind of manufacture method of fire-retardant polyester filament yarn, with fusion after the polyester slice drying, with molten mass extrude, spinning obtains product, it is characterized in that in the polyester molten mass, adding fire-retardantly extrude again after melt blended, spinning, fire-retardant
The fire-retardant master granule drying after fusion and making;
The composition of polyester slice is an ethylene glycol terephthalate;
The percentage by weight that the addition of fire-retardant melt is controlled at polyester slice and fire-retardant master granule is: polyester slice 90～94% fire-retardant master granules 10～6%;
The baking temperature of fire-retardant master granule is 130～150 ℃;
Be 4～6 hours the drying time of fire-retardant master granule;
The melt temperature of fire-retardant master granule is 265～286 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96115709A CN1049702C (en) | 1996-03-15 | 1996-03-15 | Method for making flame-retardant polyester fibre continuous filament |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96115709A CN1049702C (en) | 1996-03-15 | 1996-03-15 | Method for making flame-retardant polyester fibre continuous filament |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1160092A CN1160092A (en) | 1997-09-24 |
| CN1049702C true CN1049702C (en) | 2000-02-23 |
Family
ID=5122935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96115709A Expired - Fee Related CN1049702C (en) | 1996-03-15 | 1996-03-15 | Method for making flame-retardant polyester fibre continuous filament |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1049702C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101265620B (en) * | 2008-04-30 | 2010-11-24 | 浙江尤夫高新纤维股份有限公司 | Blending fire retardant -type terylene industrial filament and its manufacturing technique |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101265660B (en) * | 2008-05-05 | 2011-10-05 | 浙江尤夫高新纤维股份有限公司 | Fire retardant-type terylene industrial filament and its manufacturing technique |
| CN101787579B (en) * | 2010-02-05 | 2011-08-31 | 广州市悦诚安纤维制品有限公司 | Flame-retarding polyester fiber, preparation method and device thereof |
| CN105624817A (en) * | 2014-11-06 | 2016-06-01 | 上海市小荷展示器材科技有限公司 | Odorless eco-friendly fireproof display cloth |
| CN110699774A (en) * | 2018-07-09 | 2020-01-17 | 上海泉冰新材料科技有限公司 | Flame-retardant polyester chemical fiber |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49118914A (en) * | 1973-03-30 | 1974-11-13 | ||
| US3987008A (en) * | 1971-12-17 | 1976-10-19 | Celanese Corporation | Flame retardant polyester |
| CN1157347A (en) * | 1995-10-11 | 1997-08-20 | 赫彻斯特特维拉有限公司及两合公司 | Phosphorated modified polyester fibre non-combustible fabric and producing gas bag using the same and its use |
-
1996
- 1996-03-15 CN CN96115709A patent/CN1049702C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3987008A (en) * | 1971-12-17 | 1976-10-19 | Celanese Corporation | Flame retardant polyester |
| JPS49118914A (en) * | 1973-03-30 | 1974-11-13 | ||
| CN1157347A (en) * | 1995-10-11 | 1997-08-20 | 赫彻斯特特维拉有限公司及两合公司 | Phosphorated modified polyester fibre non-combustible fabric and producing gas bag using the same and its use |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101265620B (en) * | 2008-04-30 | 2010-11-24 | 浙江尤夫高新纤维股份有限公司 | Blending fire retardant -type terylene industrial filament and its manufacturing technique |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1160092A (en) | 1997-09-24 |
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