CN104964586B - Heat exchanger for reducing butadiene autopolymer and using method thereof - Google Patents

Heat exchanger for reducing butadiene autopolymer and using method thereof Download PDF

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Publication number
CN104964586B
CN104964586B CN201510384096.0A CN201510384096A CN104964586B CN 104964586 B CN104964586 B CN 104964586B CN 201510384096 A CN201510384096 A CN 201510384096A CN 104964586 B CN104964586 B CN 104964586B
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butadiene
autopolymer
chamber
heat exchanger
tubulation
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CN104964586A (en
Inventor
吴新祥
于炳成
薛巍
黄文�
王晓刚
于文涛
李刚
王勇
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XINJIANG LAND FINE PETROCHEMICAL CO Ltd
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XINJIANG LAND FINE PETROCHEMICAL CO Ltd
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Abstract

The invention relates to the technical field of butadiene heat exchange devices and discloses a heat exchanger for reducing butadiene autopolymer and a using method thereof. The heat exchanger for reducing the butadiene autopolymer comprises a shell, a left tube plate and a right tube plate are fixed inside the shell from left to right, a heat exchange chamber is formed in the portion, between the left tube plate and the right tube plate, of the interior of the shell, tube arrays are distributed inside the heat exchange chamber, and a left gland is fixed on the left portion of the shell. According to the heat exchanger, in the heat exchange process, the butadiene autopolymer can be prevented from entering dead spaces, the gathered butadiene autopolymer is effectively prevented from blocking the heat exchanger for reducing the butadiene autopolymer, it is guaranteed that the heat exchanger for reducing the butadiene autopolymer can conduct heat exchange operation, the heat exchanger for reducing the butadiene autopolymer is prevented from damage due to the fact that the heat exchanger for reducing the butadiene autopolymer is burst to fracture by the butadiene autopolymer, the service cycle of the heat exchanger for reducing the butadiene autopolymer is prolonged, and the adverse effects caused to the production of butadiene rubber are reduced, so that the production efficiency of the butadiene rubber is improved.

Description

Reduce the heat exchanger and its using method of butadiene autopolymer
Technical field
The present invention relates to butadiene technical field of heat exchange devices, it is a kind of heat exchanger of reduction butadiene autopolymer and its makes Use method.
Background technology
In the production process of butadiene rubber, because butadiene has the characteristic of autohemagglutination, therefore, butadiene is easily in container Middle generation autopolymer.Polymerization inhibitor can not be used in the butadiene extraction line of butadiene refined unit, so, butadiene extraction line In heat exchanger be also easy to produce butadiene autopolymer, because there is dead angle, butadiene autopolymer in the upper left quarter in exchanger head Easily in dead angle aggregation, when butadiene autopolymer is assembled and reaches a certain amount of, autopolymer can block heat exchanger, cause extraction not Freely, heat exchanger can be caused when serious to be split up by butadiene autopolymer, causes the damage of heat exchanger, shorten heat exchanger uses week Phase, the production to butadiene rubber has undesirable effect, so as to reduce the production efficiency of butadiene rubber.
The content of the invention
The invention provides a kind of heat exchanger and its using method for reducing butadiene autopolymer, overcomes above-mentioned existing skill The deficiency of art, its can effectively solving is existing and butadiene heat-exchanger rig is present in actual use butadiene autopolymer hold The problem easily assembled in heat exchanger.
One of technical scheme is realized by following measures:A kind of heat exchange for reducing butadiene autopolymer Device, including housing, from a left side, the right side is fixed with left tube sheet and right tube plate in housing, in the housing between left tube sheet and right tube plate Heat Room is formed, tubulation is distributed with heat exchange interior, in the left part of housing left end socket is fixed with, in the right part of housing the right side is fixed with End socket, between left end socket and left tube sheet left chamber is formed, and is fixed with left chamber and for left chamber to be divided into upper chamber and lower chambers Baffle plate, have butadiene import in housing upper corresponding with upper chamber, in butadiene import to be fixed with and be divided into upper chamber The playpipe of chamber and exocoel, inner cavity chamber communicates with the left end of the tubulation above baffle plate, the tubulation above exocoel and baffle plate It is not communicated with, right chamber room is formed between right end socket and right tube plate, under the baffle the left end of square tubulation is communicated with lower chambers, tubulation Right-hand member communicate with right chamber room, have the heat transferring medium import that communicates with Heat Room in the housing upper near left tube sheet, close The heat transferring medium outlet communicated with Heat Room is arranged at right tube plate bottom, has in lower housing portion corresponding with lower chambers and is communicated with lower chambers Butadiene outlet.
The further optimization and/or improvements to one of foregoing invention technical scheme are presented herein below:
The outlet of above-mentioned playpipe is in left narrow right wide horn-like.
The two of technical scheme are realized by following measures:A kind of heat exchange for reducing butadiene autopolymer The using method of device, is carried out as follows:When butadiene is in playpipe, in tubulation, in right chamber room and at the one of lower chambers During autopolymer formed above, butadiene is sequentially sent into butadiene import, playpipe, inner cavity chamber, tubulation, right chamber above baffle plate Tubulation and lower chambers below room, baffle plate, finally, butadiene and autopolymer are discharged by butadiene outlet, wherein, butadiene Pressure is 0.37MPa to 0.38MPa, and the temperature of butadiene is 40 DEG C to 42 DEG C, the flow of butadiene be 5 cubic metres per hour extremely 14 cubic metres per hour.
The present invention is prevented from butadiene autopolymer and enters dead angle in heat transfer process, effectively prevents the butadiene assembled Autopolymer blocking reduces the heat exchanger of butadiene autopolymer, it is ensured that reducing the heat exchanger of butadiene autopolymer can carry out heat exchange behaviour Make, prevent the heat exchanger for reducing butadiene autopolymer to be split up by butadiene autopolymer and cause to reduce the heat exchange of butadiene autopolymer The damage of device, extends the usage cycles of the heat exchanger for reducing butadiene autopolymer, reduces the production to butadiene rubber and causes Harmful effect, so as to improve the production efficiency of butadiene rubber.
Description of the drawings
Accompanying drawing 1 is the main structure diagram of the embodiment of the present invention 1.
Coding in accompanying drawing is respectively:1 is housing, and 2 is left tube sheet, and 3 is right tube plate, and 4 is Heat Room, and 5 is tubulation, and 6 are Left end socket, 7 is right end socket, and 8 is exocoel, and 9 is lower chambers, and 10 is baffle plate, and 11 is right chamber room, and 12 is heat transferring medium import, 13 For heat transferring medium outlet, 14 is butadiene import, and 15 are butadiene outlet, and 16 is playpipe, and 17 is inner cavity chamber.
Specific embodiment
The present invention is not limited by following embodiments, can technology according to the present invention scheme and actual conditions determining specifically Embodiment.
In the present invention, for the ease of description, the description of the relative position relation of each part of embodiment 1 is according to explanation The Butut mode of book accompanying drawing 1 being described, such as:The position relationship of forward and backward, upper and lower, left and right etc. is attached according to specification The Butut direction of Fig. 1 is determining.
With reference to embodiment and accompanying drawing, the invention will be further described:
Embodiment 1:As shown in Figure 1, the heat exchanger of the reduction butadiene autopolymer includes housing 1, from a left side in housing 1 And the right side is fixed with left tube sheet 2 and right tube plate 3, Heat Room 4 is formed in the housing 1 between left tube sheet 2 and right tube plate 3, in heat exchange Tubulation 5 is distributed with room 4, in the left part of housing 1 left end socket 6 is fixed with, right end socket 7 is fixed with the right part of housing 1, in left envelope Left chamber is formed between 6 and left tube sheet 2, the baffle plate 10 that left chamber is divided into upper chamber and lower chambers 9 is fixed with left chamber, There is butadiene import 14 on the top of housing 1 corresponding with upper chamber, be fixed with butadiene import 14 and upper chamber is divided into into inner chamber The playpipe 16 of room 17 and exocoel 8, the left end of the tubulation 5 of the top of inner cavity chamber 17 and baffle plate 10 is communicated, exocoel 8 and baffle plate 10 The tubulation 5 of top is not communicated with, and right chamber room 11, a left side for the tubulation 5 below baffle plate 10 are formed between right end socket 7 and right tube plate 3 End communicates with lower chambers 9, and the right-hand member of tubulation 5 is communicated with right chamber room 11, has and Heat Room 4 on the top of housing 1 near left tube sheet 2 The heat transferring medium import 12 for communicating, is having the heat transferring medium communicated with Heat Room 4 to export 13, near the bottom of right tube plate 3 The butadiene outlet 15 communicated with lower chambers 9 is arranged at the corresponding bottom of housing 1 of chamber 9.Heat transferring medium can be entered by heat transferring medium Mouth 12 enters Heat Room 4, and heat transferring medium discharges Heat Rooms 4 by heat transferring medium outlet 13.The setting of playpipe 16 is prevented from Butadiene autopolymer enters the lower left corner of exocoel 8(Dead angle), prevent butadiene autopolymer from assembling at dead angle, i.e., effectively prevent The butadiene autopolymer blocking of aggregation reduces the heat exchanger of butadiene autopolymer, it is ensured that reduce the heat exchanger energy of butadiene autopolymer It is enough persistently to carry out heat exchange operation, prevent the heat exchanger for reducing butadiene autopolymer to be split up by butadiene autopolymer and cause to reduce fourth The damage of the heat exchanger of diene autopolymer, extends the usage cycles of the heat exchanger for reducing butadiene autopolymer, reduces to suitable The production of buna has undesirable effect, so as to improve the production efficiency of butadiene rubber.When butadiene is in playpipe 16, row In pipe 5, in right chamber room 11 and when lower chambers 9 form autopolymer, by injecting butadiene to playpipe 16, by butadiene autopolymer Going out in time reduces the heat exchanger of butadiene autopolymer, and being effectively prevented butadiene autopolymer is reducing butadiene autopolymer Aggregation in heat exchanger.
The heat exchanger of above-mentioned reduction butadiene autopolymer can be made further optimization and/or improvements according to actual needs:
As needed, the outlet of playpipe 16 is in left narrow right wide horn-like.Trumpet-shaped playpipe 16 can be to baffle plate The all of tubulation 5 in 10 tops is rinsed, and effectively further prevents the aggregation of butadiene autopolymer.
Embodiment 2:As shown in Figure 1, the using method of the heat exchanger of the reduction butadiene autopolymer, enters as follows OK:When butadiene is in the playpipe 16, in tubulation 5, in right chamber room 11 and during autopolymer formed above at the one of lower chambers 9, will Butadiene sequentially sends into butadiene import 14, playpipe 16, inner cavity chamber 17, tubulation 5, the right chamber room 11, baffle plate of the top of baffle plate 10 The tubulation 5 and lower chambers 9 of 10 lower sections, finally, butadiene and autopolymer are discharged by butadiene outlet 15, wherein, butadiene Pressure is 0.37MPa to 0.38MPa, and the temperature of butadiene is 40 DEG C to 42 DEG C, the flow of butadiene be 5 cubic metres per hour extremely 14 cubic metres per hour.
In sum, the present invention is prevented from butadiene autopolymer and enters dead angle in heat transfer process, effectively prevents aggregation Butadiene autopolymer blocking reduce butadiene autopolymer heat exchanger, it is ensured that reduce butadiene autopolymer heat exchanger can enter Row heat exchange operation, prevents the heat exchanger for reducing butadiene autopolymer to be split up by butadiene autopolymer and cause to reduce butadiene autohemagglutination The damage of the heat exchanger of thing, extends the usage cycles of the heat exchanger for reducing butadiene autopolymer, reduces to butadiene rubber Production has undesirable effect, so as to improve the production efficiency of butadiene rubber.
Above technical characteristic constitutes embodiments of the invention, and it has stronger adaptability and implementation result, can basis It is actually needed the non-essential technical characteristic of increase and decrease to meet the demand of different situations.

Claims (3)

1. a kind of heat exchanger for reducing butadiene autopolymer, it is characterised in that including housing, from left and the right side is fixed with housing Left tube sheet and right tube plate, in the housing between left tube sheet and right tube plate Heat Room is formed, and tubulation is distributed with heat exchange interior, The left part of housing is fixed with left end socket, and in the right part of housing right end socket is fixed with, and between left end socket and left tube sheet left chamber is formed Room, the baffle plate that left chamber is divided into upper chamber and lower chambers is fixed with left chamber, is had in housing upper corresponding with upper chamber Butadiene import, the playpipe that upper chamber is divided into inner cavity chamber and exocoel, inner cavity chamber and baffle plate are fixed with butadiene import The left end of the tubulation of top is communicated, and exocoel is not communicated with the tubulation above baffle plate, forms right between right end socket and right tube plate Chamber, under the baffle the left end of square tubulation communicate with lower chambers, the right-hand member of tubulation is communicated with right chamber room, in close left tube sheet Housing upper has the heat transferring medium import communicated with Heat Room, there is the heat transferring medium communicated with Heat Room in close right tube plate bottom Outlet, there is the butadiene outlet communicated with lower chambers in lower housing portion corresponding with lower chambers.
2. it is according to claim 1 reduce butadiene autopolymer heat exchanger, it is characterised in that the outlet of playpipe in a left side It is narrow right wide horn-like.
3. it is a kind of it is according to claim 1 and 2 reduce butadiene autopolymer heat exchanger using method, it is characterised in that Carry out as follows:When butadiene autopolymer formed above in playpipe, in tubulation, in right chamber room and at the one of lower chambers When, butadiene is sequentially sent into butadiene import, playpipe, inner cavity chamber, the tubulation above baffle plate, right chamber room, below baffle plate Tubulation and lower chambers, finally, butadiene and autopolymer are discharged by butadiene outlet, wherein, the pressure of butadiene is 0.37MPa To 0.38MPa, the temperature of butadiene is 40 DEG C to 42 DEG C, and the flow of butadiene is 5 cubic metres every little to 14 cubic metres per hour When.
CN201510384096.0A 2015-07-03 2015-07-03 Heat exchanger for reducing butadiene autopolymer and using method thereof Active CN104964586B (en)

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Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59112197A (en) * 1982-12-20 1984-06-28 Hitachi Ltd Heat exchanger
FR2653544B1 (en) * 1989-10-24 1992-02-14 Gaz De France STEAM PUMP WITH AIR EXCHANGER-COUNTER-CURRENT COMBUSTION PRODUCTS WITHOUT INTERMEDIATE FLUID.
MY121525A (en) * 1999-03-11 2006-01-28 Nippon Catalytic Chem Ind Shell-and tube heat exchanger and method for inhibiting polymerization in the shell-and-tube heat exchanger
KR20090115595A (en) * 2008-05-02 2009-11-05 지엠대우오토앤테크놀로지주식회사 Fuel injector Fin rereneration And equipped with type EGR Cooler
CN102645113B (en) * 2011-02-16 2013-07-31 俞天翔 Vibratory spiral fluidized horizontal shell-and-tube heat exchanger
CN202013125U (en) * 2011-04-13 2011-10-19 张文强 Novel fluid impact rotary-type heat exchanger
CN204806938U (en) * 2015-07-03 2015-11-25 新疆蓝德精细石油化工股份有限公司 Reduce heat exchanger of butadiene autopolymer

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