CN104962372A - Hastelloy sheet strip cold-rolling lubricant composition - Google Patents
Hastelloy sheet strip cold-rolling lubricant composition Download PDFInfo
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- CN104962372A CN104962372A CN201510428659.1A CN201510428659A CN104962372A CN 104962372 A CN104962372 A CN 104962372A CN 201510428659 A CN201510428659 A CN 201510428659A CN 104962372 A CN104962372 A CN 104962372A
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Abstract
The invention discloses a Hastelloy sheet strip cold-rolling lubricant composition which uses HVIS 150 base oil as base oil matched with multiple additives, including an extreme pressure agent, an antiwear additive, an oily agent, a friction improver, an antioxidant, a defoaming agent, a metal passivator, a reinforcing agent and an assistant. The lubricant composition has the advantages of lower viscosity, high heat capacity, high cooling power and high cleaning power, and can reduce the phenomenon of adhesion between the rolled piece and rollers. The lubricant composition can enhance the technical lubricating property, increase the oil film strength in the deformation zone and lower the friction factor. The lubricant composition has the characteristics of stable composition and properties, no corrosiveness for metals and equipment, no toxicity and no irritating odor.
Description
Technical field
The invention belongs to metal working lubricant field, particularly Hastelloy Strip cold-rolling lubricant composition.
Background technology
Hastelloy is corrosion-resistant nickel-based alloy.Mainly contain nickel-copper alloy and the large class of Ni-Cr-Mo two.Hastelloy is the general designation of the commercial grades of the abros that the U.S. or alloy company produce.Its Strip is mainly applicable to the various chemical industry containing oxidation and reductant.Higher molybdenum, chromium content enable alloy anti-chlorine ion corrosion, and W elements further increases solidity to corrosion.Meanwhile, Hastelloy Strip is one of the material of only several humidity chlorine, the corrosion of hypochlorite machine ClO 2 solution.In addition, significant solidity to corrosion is had to chlorate solution such as iron(ic) chloride and the cupric chloride of high density.Therefore be widely used and heat exchanger, corrugated tube, loop expansion pipe, chemical industry equipment, flue gas desulfurization sulphur nitre, paper industry, aerospace application etc.Its characteristic, in oxidation and reduction two environment, has excellent solidity to corrosion to most of corrosive medium, has outstanding resistance to spot corrosion, crevice corrosion and stress crack corrosion.In addition, just bamboo is many than soft steel for its electric conductivity and thermal conductivity, and resistivity and rate of expansion more much higher than soft steel, molten bath poor fluidity, wettability is poor, and penetrance is little, and penetration is shallow, in wet oxygen, sulfurous acid, acetic acid, formic acid and Strong oxdiative salt, also there is excellent solidity to corrosion, general corrosion resistance and resistance to intergranular corrosion.Under its cold-rolled plate and strip is applied to above-mentioned various corrosive conditions envrionment conditions.
Summary of the invention
The technical problem to be solved in the present invention is to provide one, and to have viscosity lower, and thermal capacitance is large, cooling, cleansing power are strong, can reduce the adherent phenomenon of rolled piece and roll; Also can improve technological lubrication performance simultaneously, increase oil film strength in distorted area, reduce frictional coefficient; Composition and stable performance; To metal and equipment corrosion-free; Nontoxicity, the Hastelloy Strip cold-rolling lubricant composition had no irritating odor.
The present invention adopts following technical scheme to solve the problems of the technologies described above:
Hastelloy Strip cold-rolling lubricant composition, adopt oil based on HVIS 150 base oil, coordinate multiple additives, its each component and mass percent thereof are:
Component | Mass percent content |
Base oil | Surplus |
Extreme pressure agent | 4%~6% |
Anti-wear agent | 10%~15% |
Oiliness improver | 3%~5% |
Friction improver | 3%~5% |
Oxidation inhibitor | 0.5%~1% |
Kilfoam | 10ppm~50ppm |
Metal passivator | 1%~1.2% |
Strengthening agent | 1%~1.5% |
Auxiliary agent | 1%~2% |
Extreme pressure agent is triethyl phosphate.
Anti-wear agent is clorafin T302.
Oiliness improver is sulfuration Oleum Gossypii semen.
Friction improver is phosphoric acid ester.
Oxidation inhibitor is 2,6-di-t-butyl mixed phenols of mass ratio 50% and the Phenyl beta naphthylamine compound of 50%.
Kilfoam is dimethyl silicone oil.
Metal passivator is the 124 Triazole derivative of mass ratio 50% and the thiadiazoles derivative compound of 50%.
Strengthening agent is sulphur phosphorus fourth octyl group zinc salt T202.
Auxiliary agent is sulphur phosphoric acid nitrogen containing derivative T305.
Remarkable advantage of the present invention is: have viscosity lower, and thermal capacitance is large, cooling, cleansing power are strong, can reduce the adherent phenomenon of rolled piece and roll; Also can improve technological lubrication performance simultaneously, increase oil film strength in distorted area, reduce frictional coefficient; Composition and stable performance; To metal and equipment corrosion-free; Nontoxicity, has no irritating odor.
Embodiment
Embodiment 1:
Each component is in harmonious proportion by following mass percent and forms:
Component | Mass percent content |
HVIS 150 base oil | Surplus |
Triethyl phosphate | 4% |
Clorafin (T302) | 10% |
Sulfuration Oleum Gossypii semen | 3% |
Phosphoric acid ester | 3% |
2,6-di-t-butyl mixed phenols of mass ratio 50% and the Phenyl beta naphthylamine compound of 50% | 0.5% |
Dimethyl silicone oil | 10ppm |
The 124 Triazole derivative of mass ratio 50% and the thiadiazoles derivative compound of 50% | 1% |
Sulphur phosphorus fourth octyl group zinc salt (T202) | 1% |
Sulphur phosphoric acid nitrogen containing derivative (T305) | 1% |
The summation of each constituent mass relative content is 100% above.
Embodiment 2:
Each component is in harmonious proportion by following mass percent and forms:
Component | Mass percent content |
HVIS 150 base oil | Surplus |
Triethyl phosphate | 5% |
Clorafin (T302) | 13% |
Sulfuration Oleum Gossypii semen | 4% |
Phosphoric acid ester | 4% |
2,6-di-t-butyl mixed phenols of mass ratio 50% and the Phenyl beta naphthylamine compound of 50% | 0.8% |
Dimethyl silicone oil | 30ppm |
The 124 Triazole derivative of mass ratio 50% and the thiadiazoles derivative compound of 50% | 1.1% |
Sulphur phosphorus fourth octyl group zinc salt (T202) | 1.3% |
Sulphur phosphoric acid nitrogen containing derivative (T305) | 1.5% |
The summation of each constituent mass relative content is 100% above.
Embodiment 3:
Each component is in harmonious proportion by following mass percent and forms:
Component | Mass percent content |
HVIS 150 base oil | Surplus |
Triethyl phosphate | 6% |
Clorafin (T302) | 15% |
Sulfuration Oleum Gossypii semen | 5% |
Phosphoric acid ester | 5% |
2,6-di-t-butyl mixed phenols of mass ratio 50% and the Phenyl beta naphthylamine compound of 50% | 1% |
Dimethyl silicone oil | 50ppm |
The 124 Triazole derivative of mass ratio 50% and the thiadiazoles derivative compound of 50% | 1.2% |
Sulphur phosphorus fourth octyl group zinc salt (T202) | 1.5% |
Sulphur phosphoric acid nitrogen containing derivative (T305) | 2% |
The summation of each constituent mass relative content is 100% above.
The main physical and chemical index of embodiment 3 product:
Project | Quality index |
Kinematic viscosity (40 DEG C)/mm 2/s | 33.5 |
Viscosity index | 97 |
Flash-point (opening)/DEG C | 207 |
Pour point/DEG C | -18 |
Vaporization losses/% (Angelika Noack method, 250 DEG C, 1h) | 13 |
Mechanical impurity/% | Nothing |
Moisture/% | Vestige |
Corrosion test (copper sheet, 100 DEG C, 3h), level | 1 |
Acid number/mgKOH/g | 0.11 |
Supporting capacity P B/N | 922 |
Claims (10)
1. Hastelloy Strip cold-rolling lubricant composition, is characterized in that: adopt oil based on HVIS 150 base oil, coordinate multiple additives, its each component and mass percent thereof are:
Base oil surplus,
Extreme pressure agent 4% ~ 6%,
Anti-wear agent 10% ~ 15%,
Oiliness improver 3% ~ 5%,
Friction improver 3% ~ 5%,
Oxidation inhibitor 0.5% ~ 1%,
Kilfoam 10ppm ~ 50ppm,
Metal passivator 1% ~ 1.2%,
Strengthening agent 1% ~ 1.5%,
Auxiliary agent 1% ~ 2%.
2. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, extreme pressure agent is triethyl phosphate.
3. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, anti-wear agent is clorafin T302.
4. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, oiliness improver is sulfuration Oleum Gossypii semen.
5. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, friction improver is phosphoric acid ester.
6. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, oxidation inhibitor is 2,6-di-t-butyl mixed phenols of mass ratio 50% and the Phenyl beta naphthylamine compound of 50%.
7. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, kilfoam is dimethyl silicone oil.
8. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, metal passivator is the 124 Triazole derivative of mass ratio 50% and the thiadiazoles derivative compound of 50%.
9. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, strengthening agent is sulphur phosphorus fourth octyl group zinc salt T202.
10. Hastelloy Strip cold-rolling lubricant composition as claimed in claim 1, it is characterized in that, auxiliary agent is sulphur phosphoric acid nitrogen containing derivative T305.
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CN201510428659.1A CN104962372A (en) | 2015-07-20 | 2015-07-20 | Hastelloy sheet strip cold-rolling lubricant composition |
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CN201510428659.1A CN104962372A (en) | 2015-07-20 | 2015-07-20 | Hastelloy sheet strip cold-rolling lubricant composition |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106433913A (en) * | 2016-09-21 | 2017-02-22 | 广西大学 | General lubricating agent for 625 alloy cold rolled thin plate |
Citations (5)
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CN1398290A (en) * | 2000-02-08 | 2003-02-19 | 美孚石油法国公司 | Cold rolling process for rolling hard metal or metal alloys |
CN103666676A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Middle cold rolling lubricant for nickel and nickel alloy plate strip |
CN103695114A (en) * | 2013-12-14 | 2014-04-02 | 广西大学 | Lubricant for sheet steel punch-forming |
CN103695127A (en) * | 2013-12-18 | 2014-04-02 | 广西大学 | Lubricant for cold die forging of nickel and nickel alloy metal plates |
JP2014070082A (en) * | 2012-09-27 | 2014-04-21 | Jx Nippon Oil & Energy Corp | Metal processing oil composition |
-
2015
- 2015-07-20 CN CN201510428659.1A patent/CN104962372A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1398290A (en) * | 2000-02-08 | 2003-02-19 | 美孚石油法国公司 | Cold rolling process for rolling hard metal or metal alloys |
JP2014070082A (en) * | 2012-09-27 | 2014-04-21 | Jx Nippon Oil & Energy Corp | Metal processing oil composition |
CN103666676A (en) * | 2013-11-19 | 2014-03-26 | 广西大学 | Middle cold rolling lubricant for nickel and nickel alloy plate strip |
CN103695114A (en) * | 2013-12-14 | 2014-04-02 | 广西大学 | Lubricant for sheet steel punch-forming |
CN103695127A (en) * | 2013-12-18 | 2014-04-02 | 广西大学 | Lubricant for cold die forging of nickel and nickel alloy metal plates |
Non-Patent Citations (1)
Title |
---|
黄文轩: "《润滑剂添加剂性质及应用》", 31 May 2012, 中国石化出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106433913A (en) * | 2016-09-21 | 2017-02-22 | 广西大学 | General lubricating agent for 625 alloy cold rolled thin plate |
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