CN104945880A - High-strength foamed plastic - Google Patents

High-strength foamed plastic Download PDF

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Publication number
CN104945880A
CN104945880A CN201510406983.3A CN201510406983A CN104945880A CN 104945880 A CN104945880 A CN 104945880A CN 201510406983 A CN201510406983 A CN 201510406983A CN 104945880 A CN104945880 A CN 104945880A
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CN
China
Prior art keywords
parts
plastic
high strength
inhibitor
expanded plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510406983.3A
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Chinese (zh)
Inventor
徐春华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Huashida Engineering Plastic Co Ltd
Original Assignee
Suzhou New District Huashida Engineering Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Huashida Engineering Plastic Co Ltd filed Critical Suzhou New District Huashida Engineering Plastic Co Ltd
Priority to CN201510406983.3A priority Critical patent/CN104945880A/en
Publication of CN104945880A publication Critical patent/CN104945880A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/044Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2369/00Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/18Homopolymers or copolymers of tetrafluoroethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses high-strength foamed plastic which is composed of polycarbonate raw materials, light inhibitor, antioxidant and plasticizer. The high-strength foamed plastic further comprises fire retardant, foaming agents and filling agents. The filling agent is mixture of glass fibers and teflon fibers, the light inhibitor is diphenyl ketone type stabilizer, and the plasticizer is chlorinated paraffin. The high-strength foamed plastic comprises, by weight, 62-73 parts of polycarbonate raw materials, 2-5 parts of light inhibitor, 3-6 parts of antioxidant, 2-6 parts of plasticizer, 3-5 parts of fire retardant, 2-4 parts of foaming agents, 13-15 parts of glass fibers and 1-3 parts of teflon fibers. In this way, according to the high-strength foamed plastic, the foaming agents form a micro hole structure in the plastic and reduces the density of the plastic, the mixture of the glass fibers and the teflon fibers can improve the strength of the plastic, and plastic products are made light and firm.

Description

A kind of high strength expanded plastic
Technical field
The present invention relates to plastic formula design field, particularly relate to a kind of high strength expanded plastic.
Background technology
In order to reduce the weight of plastic prod, common way adds pore forming material in the feed, makes to form continuous or discontinuous microporous type structure in plastics, thus decrease the use of raw material, reduce raw materials for production cost and product substance.
Because pore forming material reacts in plastics-production process, microporous type structure decreases weight on the one hand, makes product become slim and graceful, on the other hand, also destroys original dense structure, reduce the structural strength of product, need to improve in intensity.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of high strength, lightweight expanded plastic.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of high strength expanded plastic, by polycarbonate raw material, light inhibitor, oxidation inhibitor and softening agent composition, also containing fire retardant in described high strength expanded plastic, whipping agent and weighting agent, described weighting agent is glass fibre and polytetrafluoroethylene fiber mixture, described light inhibitor is benzophenone stablizer, described softening agent clorafin, in described high strength expanded plastic, the parts by weight of each composition are: polycarbonate raw material 62 ~ 73 parts, light inhibitor 2 ~ 5 parts, 3 ~ 6 parts, oxidation inhibitor, 2 ~ 6 parts, softening agent, fire retardant 3 ~ 5 parts, whipping agent 2 ~ 4 parts, 13 ~ 15 parts, glass fibre and polytetrafluoroethylene fiber 1 ~ 3 part.
In a preferred embodiment of the present invention, described oxidation inhibitor is antioxidant 1010.
In a preferred embodiment of the present invention, in described high strength expanded plastic, the parts by weight of each composition are: polycarbonate raw material 65 parts, light inhibitor 3 parts, 4 parts, oxidation inhibitor, 3 parts, softening agent, fire retardant 3.5 parts, whipping agent 2.5 parts, 14 parts, glass fibre and polytetrafluoroethylene fiber 2 parts.
The invention has the beneficial effects as follows: a kind of high strength expanded plastic that the present invention points out, whipping agent forms microporous type structure in the plastic, reduce density, and glass fibre and polytetrafluoroethylene fiber mixture can improve the intensity of plastics, make plastic prod merrily and lightheartedly and firmly.
Embodiment
Be clearly and completely described to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of high strength expanded plastic, by polycarbonate raw material, light inhibitor, oxidation inhibitor and softening agent composition, also containing fire retardant in described high strength expanded plastic, whipping agent and weighting agent, described weighting agent is glass fibre and polytetrafluoroethylene fiber mixture, described light inhibitor is benzophenone stablizer, described softening agent clorafin, in described high strength expanded plastic, the parts by weight of each composition are: polycarbonate raw material 62 ~ 73 parts, light inhibitor 2 ~ 5 parts, 3 ~ 6 parts, oxidation inhibitor, 2 ~ 6 parts, softening agent, fire retardant 3 ~ 5 parts, whipping agent 2 ~ 4 parts, 13 ~ 15 parts, glass fibre and polytetrafluoroethylene fiber 1 ~ 3 part.
Described oxidation inhibitor is antioxidant 1010, oxygenant 1010 wide material sources, with low cost, oxidation resistant effective.
Embodiment 1, weigh get polycarbonate raw material 65kg, light inhibitor 3kg, oxidation inhibitor 4 kg, softening agent 3 kg, fire retardant 3.5 kg, whipping agent 2.5 kg, glass fibre 14 kg and polytetrafluoroethylene fiber 2 kg mixing carry out heating injection moulding production plastic prod.
Embodiment 2, weigh get polycarbonate raw material 69kg, light inhibitor 4kg, oxidation inhibitor 5 kg, softening agent 5 kg, fire retardant 4kg, whipping agent 3 kg, glass fibre 14 kg and polytetrafluoroethylene fiber 2.5 kg mixing carry out heating injection moulding production plastic prod.
In sum, a kind of high strength expanded plastic that the present invention points out, obtained plastic prod is lightweight, and intensity is high, and flame retardant resistance is good, durable in use.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (3)

1. a high strength expanded plastic, by polycarbonate raw material, light inhibitor, oxidation inhibitor and softening agent composition, it is characterized in that, also containing fire retardant in described high strength expanded plastic, whipping agent and weighting agent, described weighting agent is glass fibre and polytetrafluoroethylene fiber mixture, described light inhibitor is benzophenone stablizer, described softening agent clorafin, in described high strength expanded plastic, the parts by weight of each composition are: polycarbonate raw material 62 ~ 73 parts, light inhibitor 2 ~ 5 parts, 3 ~ 6 parts, oxidation inhibitor, 2 ~ 6 parts, softening agent, fire retardant 3 ~ 5 parts, whipping agent 2 ~ 4 parts, 13 ~ 15 parts, glass fibre and polytetrafluoroethylene fiber 1 ~ 3 part.
2. high strength expanded plastic according to claim 1, is characterized in that, described oxidation inhibitor is antioxidant 1010.
3. high strength expanded plastic according to claim 1, it is characterized in that, in described high strength expanded plastic, the parts by weight of each composition are: polycarbonate raw material 65 parts, light inhibitor 3 parts, 4 parts, oxidation inhibitor, 3 parts, softening agent, fire retardant 3.5 parts, whipping agent 2.5 parts, 14 parts, glass fibre and polytetrafluoroethylene fiber 2 parts.
CN201510406983.3A 2015-07-13 2015-07-13 High-strength foamed plastic Pending CN104945880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510406983.3A CN104945880A (en) 2015-07-13 2015-07-13 High-strength foamed plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510406983.3A CN104945880A (en) 2015-07-13 2015-07-13 High-strength foamed plastic

Publications (1)

Publication Number Publication Date
CN104945880A true CN104945880A (en) 2015-09-30

Family

ID=54160975

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510406983.3A Pending CN104945880A (en) 2015-07-13 2015-07-13 High-strength foamed plastic

Country Status (1)

Country Link
CN (1) CN104945880A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1898328A (en) * 2003-12-30 2007-01-17 通用电气公司 Polycarbonate composition
CN101619161A (en) * 2009-07-29 2010-01-06 深圳市华力兴工程塑料有限公司 Padding strengthening flame-retardant polycarbonate and preparation method thereof
US20130131241A1 (en) * 2011-11-21 2013-05-23 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions
CN103182818A (en) * 2011-12-29 2013-07-03 上海杰事杰新材料(集团)股份有限公司 Polycarbonate extrusion foaming composite sheet material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1898328A (en) * 2003-12-30 2007-01-17 通用电气公司 Polycarbonate composition
CN101619161A (en) * 2009-07-29 2010-01-06 深圳市华力兴工程塑料有限公司 Padding strengthening flame-retardant polycarbonate and preparation method thereof
US20130131241A1 (en) * 2011-11-21 2013-05-23 Sabic Innovative Plastics Ip B.V. Flame retardant thermoplastic polycarbonate compositions
CN103182818A (en) * 2011-12-29 2013-07-03 上海杰事杰新材料(集团)股份有限公司 Polycarbonate extrusion foaming composite sheet material and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
桂一枝: "《高分子材料用有机助剂》", 30 November 1981 *

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Application publication date: 20150930