CN104945584A

CN104945584A - Photoaging-resistant graphene oxide melamine resin and preparation method thereof

Info

Publication number: CN104945584A
Application number: CN201510220714.8A
Authority: CN
Inventors: 张庆
Original assignee: Wuhu Baoyi Amusement Equipment Co Ltd
Current assignee: Wuhu Baoyi Amusement Equipment Co Ltd
Priority date: 2015-05-04
Filing date: 2015-05-04
Publication date: 2015-09-30

Abstract

The invention relates to a photoaging-resistant graphene oxide melamine resin which is prepared from the following raw materials in parts by weight: 1.3-1.4 parts of nano zinc oxide, 20-25 parts of melamine, 40-45 parts of 37% formalin, 1.8-2.1 parts of graphene oxide, 0.7-0.9 part of trifluoroethyl methacrylate, 0.7-0.9 part of polyacrylonitrile, a right amount of dimethylformamide, 0.2-0.3 part of polyoxyethylene, a right amount of double solvent composed of dimethylformamide and dichloromethane in a volume ratio of 1:1, 0.3-0.5 part of tert-butyl hydroperoxide, a right amount of citric acid, a right amount of alkaline pH regulator AMP-95 and a right amount of ethanol. The added graphene oxide greatly enhances the thermal conductivity and heat stability of the resin. The added titanium dioxide nanotube enhances the ultraviolet resistance of the resin, enhances the photoaging resistance, has antibacterial and photocatalytic properties, enhances the toughness of the resin, and prevents cracking.

Description

A kind of light aging resisting graphene oxide melmac and preparation method thereof

Technical field

The present invention relates to melmac Material Field, particularly relate to a kind of light aging resisting graphene oxide melmac and preparation method thereof.

Background technology

Graphene is by the carbonaceous material with the cellular crystalline network of two dimensional surface of the tightly packed one-tenth of monolayer carbon atom, and the nanostructure of its uniqueness determines that it has the performance of a series of excellence, and theoretical specific surface area is up to 2600 ㎡/g; Thermal conductivity is up to 5000W/ (m.K), for adamantine 5 times, intensity is the highest in known materials, reach 130GPa, it is more than 100 times of steel, at present, Graphene is considered to have a wide range of applications space in functional composite material, nano-device, energy storage material and support of the catalyst etc.

Utilize the excellent properties of Graphene, prepare Graphene/polymer composites, first the problem of Graphene stable dispersion in the polymer will be solved, surface of graphene oxide is with many oxygen-containing functional groups, although oxygenizement to a certain degree destroys the crystalline network of Graphene, but the interaction that these functional groups can be strong with polymer formation, thus improve the performance of matrix material.The method preparing graphene oxide/polymer composites mainly contains solution blended process, melt-blending process, in-situ polymerization intercalated method.

Melmac and melamine formaldehyde resin are a kind of widely used thermosetting resines.By using graphene oxide to carry out polymeric modification, the thermostability of resin can be improved, electroconductibility, thermal conductivity.But the improvement in performance of single graphene oxide to resin is limited, also need the performance further improving resin, can by improving technique and the performance becoming to assign to improve resin; Such as need to improve intensity, water-resistant capacity, thermostability, wear resistance, hardness, to the resistivity of chemicals, the performance such as poor toughness is easily broken, the shelf lives is short, make this resin widely for aspects such as furniture, vehicle, buildings.

Summary of the invention

The object of the present invention is to provide a kind of light aging resisting graphene oxide melmac, the thermal conductivity of this resin and Heat stability is good, light fastness aging is good, and has germ resistance and photocatalysis performance.

Technical scheme of the present invention is as follows:

A kind of light aging resisting graphene oxide melmac, is characterized in that being made up of the raw material of following weight part: nano zine oxide 1.3-1.5, trimeric cyanamide 20-25,37% formalin 40-45, graphene oxide 1.8-2.1, trifluoroethyl methacrylate 0.7-0.9, polyacrylonitrile 0.7-0.9, dimethyl formamide are appropriate, polyoxyethylene 0.2-0.3, dimethylformamide/dichloromethane volume ratio are that 1:1 double solvents is appropriate, appropriate, the alkaline pH value regulator AMP-95 of tertbutyl peroxide 0.3-0.5, citric acid is appropriate, appropriate amount of ethanol.

The production method of described light aging resisting graphene oxide melmac, is characterized in that:

(1) polyacrylonitrile is dissolved in dimethyl formamide, is mixed with the solution of 4wt%; Polyoxyethylene being dissolved in dimethylformamide/dichloromethane volume ratio is 1:1 double solvents, be mixed with the solution of 4wt%, again above-mentioned two kinds of solution are mixed, add nano zine oxide, graphene oxide, stir, add trifluoroethyl methacrylate, tertbutyl peroxide again, be heated to 60-70 DEG C, stirring reaction 1-2 hour, filter, by filter cake ethanol purge 2-3 time, obtain the graphene oxide of modification.

(2) by trimeric cyanamide, 37% formalin mixing, be heated to 70-75 DEG C, stir until all dissolve, add the graphene oxide of the modification that (1) step obtains again, stir 10-20 minute, add alkaline pH value regulator AMP-95, regulate pH value to be 8-9, reaction 3-4 hour, obtains the melmac performed polymer containing graphene oxide;

(3) performed polymer is placed in 30 DEG C of vacuum drying ovens, except being 5-6 by citric acid adjust ph after anhydrating, solidify in 50 DEG C of baking ovens 8-9 hour shaping, obtain graphene oxide/melmac matrix material.

Beneficial effect of the present invention

Resin of the present invention with the addition of graphene oxide, substantially increases thermal conductivity and the thermostability of resin; By adding titania nanotube, improve the UV-light tolerance of resin, improve light fastness aging, and there is germ resistance and photocatalysis performance, improve the toughness of resin, prevent cracking; Production technique of the present invention can improve the dispersing uniformity of graphene oxide, and composite material surface and section all do not have obvious particle agglomeration phenomenon, improve bonding strength, improves toughness and the anti-bending strength of melmac.

Embodiment

A kind of light aging resisting graphene oxide melmac, is made up of the raw material of following weight part: nano zine oxide 1.3-1.5, trimeric cyanamide 23,37% formalin 43, graphene oxide 2, trifluoroethyl methacrylate 0.7-0.9, polyacrylonitrile 0.8, dimethyl formamide are appropriate, polyoxyethylene 0.2, dimethylformamide/dichloromethane volume ratio are that 1:1 double solvents is appropriate, appropriate, the alkaline pH value regulator AMP-95 of tertbutyl peroxide 0.4, citric acid is appropriate, appropriate amount of ethanol.

(1) polyacrylonitrile is dissolved in dimethyl formamide, is mixed with the solution of 4wt%; Polyoxyethylene being dissolved in dimethylformamide/dichloromethane volume ratio is 1:1 double solvents, be mixed with the solution of 4wt%, again above-mentioned two kinds of solution are mixed, add nano zine oxide, graphene oxide, stir, add trifluoroethyl methacrylate, tertbutyl peroxide again, be heated to 65 DEG C, stirring reaction 1.5 hours, filter, by filter cake ethanol purge 2 times, obtain the graphene oxide of modification.

(2) by trimeric cyanamide, 37% formalin mixing, be heated to 73 DEG C, stir until all dissolve, add the graphene oxide of the modification that (1) step obtains again, stir 15 minutes, add alkaline pH value regulator AMP-95, regulate pH value to be 8.6, react 3.5 hours, obtain the melmac performed polymer containing graphene oxide;

(3) performed polymer is placed in 30 DEG C of vacuum drying ovens, except being 6 by citric acid adjust ph after anhydrating, solidify in 50 DEG C of baking ovens 8.6 hours shaping, obtain graphene oxide/melmac matrix material.

Experimental data:

The polypropylene of this embodiment is through extrusion moulding, and after tested, thermal conductivity is 0.39W/ (m ﹒ K), flexural strength 105MPa, water-intake rate < 0.1%.

Claims

1. a light aging resisting graphene oxide melmac, is characterized in that being made up of the raw material of following weight part: nano zine oxide 1.3-1.5, trimeric cyanamide 20-25,37% formalin 40-45, graphene oxide 1.8-2.1, trifluoroethyl methacrylate 0.7-0.9, polyacrylonitrile 0.7-0.9, dimethyl formamide are appropriate, polyoxyethylene 0.2-0.3, dimethylformamide/dichloromethane volume ratio are that 1:1 double solvents is appropriate, tertbutyl peroxide 0.3-0.5, citric acid are appropriate, alkaline pH adjuster AMP-95 is appropriate, appropriate amount of ethanol.

2. the production method of light aging resisting graphene oxide melmac according to claim 1, is characterized in that:

(1) polyacrylonitrile is dissolved in dimethyl formamide, is mixed with the solution of 4wt%; Polyoxyethylene being dissolved in dimethylformamide/dichloromethane volume ratio is 1:1 double solvents, be mixed with the solution of 4wt%, again above-mentioned two kinds of solution are mixed, add nano zine oxide, graphene oxide, stir, add trifluoroethyl methacrylate, tertbutyl peroxide again, be heated to 60-70 DEG C, stirring reaction 1-2 hour, filter, by filter cake ethanol purge 2-3 time, obtain the graphene oxide of modification;

(2) by trimeric cyanamide, 37% formalin mixing, be heated to 70-75 DEG C, stir until all dissolve, add the graphene oxide of the modification that (1) step obtains again, stir 10-20 minute, add alkaline pH adjuster AMP-95, adjust ph is 8-9, reaction 3-4 hour, obtains the melmac performed polymer containing graphene oxide;