CN104944493B - A kind of air-conditioning of Winter-summer dual purpose and desalinization co-production and system - Google Patents
A kind of air-conditioning of Winter-summer dual purpose and desalinization co-production and system Download PDFInfo
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- CN104944493B CN104944493B CN201510305463.3A CN201510305463A CN104944493B CN 104944493 B CN104944493 B CN 104944493B CN 201510305463 A CN201510305463 A CN 201510305463A CN 104944493 B CN104944493 B CN 104944493B
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- 238000004378 air conditioning Methods 0.000 title claims abstract description 63
- 230000009977 dual effect Effects 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000013535 sea water Substances 0.000 claims abstract description 304
- 230000000694 effects Effects 0.000 claims abstract description 124
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 100
- 239000013505 freshwater Substances 0.000 claims abstract description 88
- 238000004821 distillation Methods 0.000 claims abstract description 42
- 238000010438 heat treatment Methods 0.000 claims abstract description 32
- 238000009833 condensation Methods 0.000 claims abstract description 29
- 230000005494 condensation Effects 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims description 15
- 230000001351 cycling effect Effects 0.000 claims description 13
- 239000003507 refrigerant Substances 0.000 claims description 8
- 239000002351 wastewater Substances 0.000 claims description 8
- 239000002918 waste heat Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 13
- 102000010637 Aquaporins Human genes 0.000 description 9
- 238000001704 evaporation Methods 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 238000010612 desalination reaction Methods 0.000 description 7
- 238000011033 desalting Methods 0.000 description 7
- 238000005057 refrigeration Methods 0.000 description 7
- 238000005265 energy consumption Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
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- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
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- 239000000203 mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004781 supercooling Methods 0.000 description 2
- 230000009897 systematic effect Effects 0.000 description 2
- 230000002277 temperature effect Effects 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
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- 108010063290 Aquaporins Proteins 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
The invention discloses a kind of air-conditioning of Winter-summer dual purpose and desalinization co-production, comprise the following steps:Using the condensation heat during air conditioner refrigerating or the condensation heat in heating operations as thermal source, desalinization is carried out using low-temperature multiple-effect distillation;The fresh water steam of a upper effect enters next effect and condensed, and the temperature of fresh water steam reduces by effect, and the fresh water vapor (steam) temperature of last effect output is less than 20 DEG C;Take the fresh water steam of last effect output of the seawater condensing of the first source of seawater;The seawater of the second source of seawater is taken to preheat seawater to be diluted by the fresh water and concentrated seawater of its residual effect output, the temperature of second source of seawater is higher than the temperature of the first source of seawater as seawater to be diluted;The invention also discloses a kind of air-conditioning of Winter-summer dual purpose and desalinization co-generation system;Present invention utilizes the temperature difference of seawater in low-temperature waste heat caused by air-conditioning and ocean, condenses fresh water to increase the effect number of distilling apparatus using low temperature seawater, improves fresh water yield.
Description
Technical field
The present invention relates to desalination technology, more particularly to a kind of air-conditioning of Winter-summer dual purpose and desalinization co-production and
System.
Background technology
In recent years, China's domestic air conditioning becomes increasingly popular in city.2001 to 2013, China Domestic air conditioning market
Yield is incremented by with the trend of annual average compound growth rate 17.29%, and China's domestic air conditioning yield in 2013 is 130,570,000.In the summer
Season, its main function was to make room temperature lowering, and the condensation heat of air-conditioning system is directly discharged in air when family expenses air conditioner refrigerating, and
It is not used.Substantial amounts of condensation heat is discharged to atmospheric environment when refrigeration unit is run under air conditioning condition, usual condensation heat can
Up to 1.15~1.3 times of refrigerating capacity.Substantial amounts of condensation heat is directly discharged into air, loses in vain, causes larger energy waste,
Distributing and raising ambient temperature for these heats, causes serious environmental thermal pollution, so, in order to save the energy and guarantor
Retaining ring border, air conditioner afterheat, which recycles, just seems necessary.
Water is to maintain life and the primary demand of health, and although area that the earth has 71% is covered by water, but fresh water
Resource is extremely limited.Current global freshwater resources only account for the 2.5% of its total Water, wherein more than 70% is frozen in south
In the ice sheet of pole and the arctic, plus the alpine glacier and permafrost accumulated snow being difficult by, the freshwater resources for having 86% are difficult by.People
The freshwater resources that class really is able to utilize are the parts in rivers and lakes and underground water, only account for the 0.26% of earth total Water.
At present, there are 1/6 population, about people's water shortage more than 1,000,000,000 in the whole world.Expert's estimation, will be more than 25 to world's water shortage population in 2025
Hundred million.Again due on the earth fresh water be distributed in region, temporal lack of uniformity, and pollution of the mankind to water source, make fresh water
Available quantity is not only restricted, and is drastically reduced.Water shortage problem has been the social sustainable of whole world facing
The problem of development.This severe with water form and current conditions, proposition and the application of desalinization have greatly existing
Sincere justice.
Desalinization refers to remove the excess salt in water and mineral matter to obtain the process of fresh water, and it realizes that technology is main
There are the way of distillation, hyperfiltration, electroosmose process, freezing etc..The way of distillation include multiple-effect distillation, multistage flash vaporization, membrane distillation method,
Solar distilling method etc..The principle of the way of distillation is the heated vaporization of seawater, water vapour is condensed and is obtained fresh water, and it has equipment simple
Single reliable, grime repellancy can it is good, be easy to maximization, aquifer yield and the advantages that using low grade heat energy, but this method needs
Heat energy is externally supplied, and the gasification latent heat of water is bigger, so energy consumption is higher.
At present, way of distillation technology maturation, low temperature multiple-effect distillation sea water desalting technology therein are a kind of very promising
Desalination technology, worldwide obtained wide application.The patent text of Application No. 201110398281.7
Offer and disclose a kind of low temperature multi-effect seawater desalting system, it mainly includes multigroup heat pipe-type multi-effect evaporator, steam jet ejector
TVC, cooler, air water release device, steam-water separator, water ring vacuum pump, raw water pump, light pump, Steam Turbine Through IP Admission, steam turbine
Low pressure (LP) cylinder etc..The characteristics of invention, is that the multi-effect evaporator is multigroup, using the heat transfer property of heat pipe, is sprayed by steam
Cyclic steam and turbine low pressure cylinder steam discharge in emitter TVC injection coolers, make cyclic steam and turbine low pressure cylinder steam discharge
The steam for being changed into higher quality enters heat pipe evaporator, so as to improve evaporation of seawater efficiency.Meanwhile the invention is again using low
The turbine low pressure cylinder steam discharge of quality, the utilization rate of the energy and the efficiency of power plant are improved, pass through steaming caused by heat pipes heat
The thermal source of vapour several groups of evaporators as after, improve the utilization rate of steam.What is utilized due to the invention is low-quality steamer
Machine low pressure (LP) cylinder steam discharge, so it is a kind of relatively large payable seawater desalination system in fact.
The patent document of Application No. 201110174880.0 discloses a kind of industrial waste heat low-temperature multi-effect seawater desalting system
System, it includes multiple-effect sea water evaporator, end effect condenser, charging seawater pipe, cooling water outlet pipe, cooling water and flows through pipe, dense salt
Current outlet pipe, condensate delivery pipe, product water return duct, multiple spray equipments, multiple strong brines flow through pipe, multiple product current
Through pipe etc..Industrial exhaust heat is applied in low temperature multi-effect seawater desalting system by the invention, more than high temperature caused by industrial user
Heat is used as the energy, and working steam is converted into by industrial exhaust heat boiler, and low-temperature multiple-effect seawater desalination is carried out using this working steam,
Product water caused by first evaporator is back to industrial exhaust heat boiler, recycles, so as to reduce low-temperature multiple-effect seawater desalination
The water producing cost of system.Equally, the invention is also a kind of relatively large payable seawater desalination system.
Low temperature multi-effect seawater desalting system middle-size and small-size at present consumes one mostly due to that can not obtain stable used heat thermal source
The secondary energy, water producing cost is very high, although also there is researcher to propose using air conditioner heat come the device to desalinize seawater, Application No.
200610124010.1 patent document disclose a kind of air conditioner refrigerating and sea water desalting integral device, it is including compressor, cold
Condenser, expansion valve, evaporator, air-introduced machine, exhaust blower and spray system, the compressor are connected with condenser by pipeline, row
Blower fan is arranged on the side of condenser, is connected between condenser and evaporator by expansion valve, and air-introduced machine is arranged on and condenser
The another side of relative evaporator, and the air channel communicated with air-introduced machine is provided between condenser and evaporator, the one of evaporator
Side is provided with air inlet, and the spray system is arranged between condenser and exhaust blower.Although said apparatus make use of air-conditioning
Used heat carries out desalinization, but is only worked using single-action, and temperature of waste heat is relatively low caused by air-conditioning, typically only 40~
50 DEG C, actual fresh water low yield, actual water supply application can not be met.
The content of the invention
The invention discloses a kind of air-conditioning of Winter-summer dual purpose and desalinization co-production, summer using air-conditioning used heat or
Winter carries out low temperature multiple-effect distillation to produce fresh water using condensation heat caused by air-conditioning, improves energy utilization rate, reduces light
To change the cost of seawater, and reduce environmental thermal pollution, while fresh water yield is improved using temperature difference of seawater, the summer in winter can produce water,
Practicality is high, has good economic benefit.
A kind of air-conditioning of Winter-summer dual purpose and desalinization co-production, comprise the following steps:
Using the condensation heat during air conditioner refrigerating or the condensation heat in heating operations as thermal source, using low temperature multiple-effect distillation
Method carries out desalinization;
The fresh water steam of a upper effect enters next effect and condensed, and the temperature of fresh water steam reduces by effect, last effect production
The fresh water vapor (steam) temperature gone out is less than 20 DEG C;
Take the fresh water steam of last effect output of the seawater condensing of the first source of seawater;
The seawater of the second source of seawater is taken to be treated as seawater to be diluted by fresh water and the concentrated seawater preheating of its residual effect output light
Change seawater, the temperature of second source of seawater is higher than the temperature of the first source of seawater.
During summer, using the condensation heat in the refrigerative circle system of air-conditioning as thermal source in the present invention, for heat production temperature
Relatively low air conditioner condensation heat, desalinization is carried out with reference to low-temperature multiple-effect distillation, improves efficiency of energy utilization, is had well
Seawater fresh water yield;Simultaneously using with change in depth, seawater has the phenomenon of the temperature difference in ocean, using temperature it is relatively low first
Source of seawater condenses last effect fresh water steam, allow the fresh water steam of last effect output temperature set it is relatively low, the
In the case that one effect is temperature-resistant, the temperature difference between the effect of increase first and last effect, so as to increase the effect of low temperature multiple-effect distillation
Number, fresh water yield is improved, and seawater to be diluted is then higher than the second source of seawater of the first source of seawater using temperature, the second source of seawater carries
The temperature of the seawater to be diluted supplied is higher, then required time and energy consumption are fewer when being preheated, it is possible to reduce during preheating
Between, the temperature after the preheating of seawater to be diluted is improved, further improves efficiency of energy utilization and fresh water yield.
The condensation heat in air-conditioning heating cyclic process is used during winter, in the present invention as thermal source, in the winter time when, seawater
Have the temperature difference, now still can utilize ocean in change in depth, seawater has the phenomenon of the temperature difference, using temperature it is relatively low first
Source of seawater condenses last effect fresh water steam, allow the fresh water steam of last effect output temperature set it is relatively low, the
In the case that one effect is temperature-resistant, the temperature difference between the effect of increase first and last effect, so as to increase the effect of low temperature multiple-effect distillation
Number, fresh water yield is improved, and seawater to be diluted is then higher than the second source of seawater of the first source of seawater using temperature, the second source of seawater carries
The temperature of the seawater to be diluted supplied is higher, then required time and energy consumption are fewer when being preheated, it is possible to reduce during preheating
Between, the temperature after the preheating of seawater to be diluted is improved, further improves efficiency of energy utilization and fresh water yield.
Preferably, the low-temperature multiple-effect distillation uses reverse-flow low-temperature multiple-effect distillation.Under adverse current feeding mode, material
Seawater is first introduced into low temperature effect group, receives partly to evaporate from neighbouring hotter steam in this seawater, is remained in each effect
Remaining seawater has been preheated and concentrated, and enters next hotter effect group by pump.Due to making full use of the heat transfer of cold fluid and hot fluid
The temperature difference, material seawater degree of supercooling is minimum under adverse current feeding mode, systematic heat utilization rate highest.
In order to reduce energy consumption, it is preferred that control described heat source temperature at 30~55 DEG C.40~55 DEG C are the common air-conditioning summers
Condensation heat temperature caused by season refrigeration, need not increase the power of air-conditioning to improve temperature using the inventive method, still have compared with
High fresh water yield, so as to reduce the consumption of the energy, when heat source temperature is 40 DEG C, minimum number of imitating is up to 7 effects;During winter, commonly
Air-conditioning is heated using condensation heat, and heating-up temperature is typically at 30~45 DEG C.
The top layer temperature of the refrigerating function, now ocean of air-conditioning is generally used in the case of temperature higher summer
Degree is higher, and deep sea water temperature is relatively low;And the skin temperature of the heat-production functions, now ocean of the relatively low use in winter air-conditioning of temperature
Relatively low, deep sea water temperature is higher;General sea water advanced more than 10 meters ocean temperatures are less protected from environmental, overall to be relatively
Stable about 13~18 DEG C;Surface seawater is then affected by environment larger, and general summer is about 27~35 DEG C, and winter is 0~7 DEG C,
Therefore, when summer using air conditioner refrigerating, the first relatively low source of seawater of temperature is derived from deep sea water, the second higher seawater of temperature
Source is derived from shallow layer sea water;When using air-conditioning heating in the winter time, the first relatively low source of seawater of temperature is derived from shallow layer sea water, and temperature is higher
The second source of seawater be derived from deep sea water.
In the present invention, as long as the temperature of the first source of seawater is i.e. achievable cold less than the fresh water vapor (steam) temperature of last effect output
Solidifying, it is preferred, therefore, that during air conditioner refrigerating, the temperature of first source of seawater is 13~18 DEG C, during air-conditioning heating, described first
The temperature of source of seawater is 0~7 DEG C.
The temperature of second source of seawater is the higher the better, it is possible to reduce preheats required energy, it is preferred that during air conditioner refrigerating, institute
The temperature for stating the second source of seawater is 27~35 DEG C, and during air-conditioning heating, the temperature of second source of seawater is 13~18 DEG C.
The invention also discloses a kind of air-conditioning of Winter-summer dual purpose and desalinization co-generation system, compact-sized, using energy source
Rate is high, and there is fresh water output in the summer in winter, has good practicality, and have higher fresh water yield.
A kind of air-conditioning of Winter-summer dual purpose and desalinization co-generation system, including it is single with refrigerating cycle unit and heating circulation
The air-conditioning of member, in addition to low temperature multiple-effect distillation device, the low temperature multiple-effect distillation device include:Multi-effect distilling unit, collection liquid
The fresh water of state fresh water collects pipeline, the outer comb of density wastewater for collecting end concentrated seawater, condenses last effect distillation unit output
The fresh water condenser of fresh water steam and the seawater preheating device of preheating seawater to be diluted, the fresh water of last effect distillation unit output
The temperature of steam is less than 20 DEG C;
The heating parts of the heating cycling element include the indoor heat exchanger that is heated by compressor compresses refrigerant with
Condenser, the heating cycling element and refrigerating cycle unit share same condenser, and the condenser is as the first effect distillation
The condensation module of unit;
The fresh water condenser includes fresh water steam channel and condensation water channel, the both ends connection of the condensation water channel the
One seawater inlet pipe and seawater drainpipe;
The seawater preheating device includes connection fresh water and collects the product water channel of pipeline, the concentrated seawater of the outer comb of connection density wastewater
Passage and sea water passage, the both ends of the sea water passage connect the second seawater inlet pipe and pre- hot sea water outlet pipe, the preheating
Seawater outlet pipe accesses the preheating sea intake of multi-effect distilling unit, is passed through the ocean temperature of the second seawater inlet pipe higher than being passed through the
The ocean temperature of one seawater inlet pipe.
In present system, the condensation module using the condenser of air-conditioning as the first effect distillation unit, and kind of refrigeration cycle
Unit and heating cycling element share same condenser, so that system is integrally more compact, reduce overall volume;By last
Imitate the condensation of fresh water steam and the preheating of seawater to be diluted is entered by the seawater of different two heat exchange units and different temperatures
Row heat exchange, last effect fresh water steam is condensed using low temperature seawater, last effect fresh water vapor (steam) temperature is set relatively low, so as to
In the case where the first effect is temperature-resistant, the effect number of distillation unit is added, improves fresh water yield;And it is passed through the second seawater to enter
The ocean temperature to be diluted of pipe is higher than the ocean temperature for being passed through the first seawater inlet pipe, is passed through the seawater to be diluted of the second seawater inlet pipe
Temperature it is higher, then required time and energy consumption are fewer when being preheated, it is possible to reduce preheating time, improve sea to be diluted
Temperature after the preheating of water, further improve efficiency of energy utilization and fresh water yield.
General sea water advanced more than 10 meters ocean temperatures are less protected from environmental, overall than relatively stable about 13~18
℃;Surface seawater is then affected by environment larger, and general summer is about 27~35 DEG C, and winter is 0~7 DEG C, due to winter and summer
Seawater water temperature can change, and can use two circuits, in the winter time with summer respectively to the first seawater inlet pipe and the second seawater inlet pipe
Supply water, but such structure is complex, pipeline consumption is big, and installation is complicated, therefore, in order to simplify structure, it is preferred that institute
State the first seawater inlet pipe and the second seawater inlet pipe is connected with the conducting selector for exchanging water inlet.Selector is turned on by setting,
So that the water inlet of the first seawater inlet pipe and the second seawater inlet pipe can exchange, now if the water inlet of the first seawater inlet pipe
Deep sea water is accessed, and the water inlet of the second seawater inlet pipe is located at shallow layer sea water, is adapted to summer to use, when winter arrives, only
To use conducting selector to change the water inlet of the first seawater inlet pipe and the second seawater inlet pipe, the second seawater inlet pipe can both led to
Enter the low temperature seawater of shallow-layer, the first seawater inlet pipe is passed through the high temperature seawater of deep layer.Conducting selector can be direct adjustment pipeline,
It can also be realized by adjusting valve module.
Preferably, the low temperature multiple-effect distillation device uses reverse-flow, and described preheating sea intake is arranged on last
In the distillation unit of effect, the concentrated seawater water inlet of previous effect is connected with the concentrated seawater delivery port of latter effect, the distillation list of the first effect
The concentrated seawater outlet of member is connected to the outer comb of density wastewater.Under adverse current feeding mode, material seawater is first introduced into low temperature effect group,
This seawater receives partly to evaporate from neighbouring hotter steam, and remaining seawater has been preheated and concentrated in each effect,
Next hotter effect group is entered by pump.Due to making full use of the heat transfer temperature difference of cold fluid and hot fluid, material sea under adverse current feeding mode
Super cooling degree of water is minimum, systematic heat utilization rate highest.
During using reverse-flow low temperature multiple-effect distillation device, the concentrated seawater that the outer comb of density wastewater is collected into is arranged from the first effect
Go out, temperature highest, therefore, fresh water collects the fresh water temperature that pipeline is collected into and is less than the concentrated seawater that the outer comb of density wastewater is collected into
Temperature, it is preferred that the seawater preheating device includes the First Heat Exchanger and the second heat exchanger of sea water passage series connection, second sea
The sea water passage of water inlet pipe and First Heat Exchanger connects, and the sea water passage of the pre- hot sea water outlet pipe and the second heat exchanger connects
Connect, the concentrated seawater passage is arranged in the second heat exchanger, and the product water channel is arranged in First Heat Exchanger.So that with light
The seawater of change first exchanges heat with the relatively low fresh water of temperature, then is exchanged heat with the higher concentrated seawater of temperature, improves heat exchange efficiency.
The effect number of distilling apparatus is more, then the temperature difference required between the first effect and last effect is bigger, in order to reduce energy consumption,
Preferably, the condenser heating temperature of the air-conditioning is 30~55 DEG C.
In order to simplify the structure of equipment, it is preferred that the refrigerating cycle unit of the air-conditioning and the heating cycling element can
Mutually conversion, the air-conditioning include:Shared compressor, shared indoor heat exchanger, shared choke valve and outdoor heat exchange
Device;
The refrigerating cycle unit includes:Compressor, condenser, choke valve and the indoor heat exchanger of cycle installation;
The heating cycling element includes:Compressor, indoor heat exchanger, condenser, choke valve and the room of cycle installation
External heat exchanger.
Compared with common air-conditioning, air-conditioning of the invention is simply additionally arranged an outdoor heat exchanger, and scrap build is simple, transformation
Cost is low.
When in the winter time, the heating cycling element work of air-conditioning, it is preferred that the heating parts of the heating cycling element include
For the outdoor heat exchanger of heat absorption, the outdoor heat exchanger includes coolant channel and the 3rd sea water passage, is passed through the 3rd sea
The ocean temperature of aquaporin is higher than the ocean temperature for being passed through the first seawater inlet pipe.3rd sea water passage is passed through temperature higher than being passed through the
The deep sea water of the shallow layer sea water of one seawater inlet pipe is exchanged heat, and is evaporated the refrigerant fast endothermic in outdoor heat exchanger, is carried
The heating efficiency of high air-conditioning, the logical seawater that can drain directly into the second seawater inlet pipe of the 3rd sea water passage.Outdoor heat exchanger
Work in the winter time, what now the 3rd sea water passage was passed through is deep sea water.
In order to improve heat transfer effect, it is preferred that described seawater preheating device is connected using hot and cold stream countercurrent heat exchange method.
In order to improve heat transfer effect, it is preferred that described fresh water condenser is connected using hot and cold stream countercurrent heat exchange method.
Beneficial effects of the present invention:
The air-conditioning of the present invention and desalinization co-production and system, make use of in low-temperature waste heat and ocean caused by air-conditioning
The temperature difference of seawater, fresh water is condensed to increase the effect number of distilling apparatus using low temperature seawater, improves fresh water yield, while utilize high temperature
Seawater is used as seawater to be diluted and preheated, and reduces seawater and is warming up to up to evaporating temperature institute calorific requirement, improves evaporation of seawater rate
And energy utilization rate, fresh water yield is further improved, and water can be produced season in summer in winter two, and with refrigeration or heat supply function, it is practical
Property it is high, there is good economic benefit.
Brief description of the drawings
Fig. 1 is the structural representation of present system.
Embodiment
The present invention is described in further detail below in conjunction with the drawings and specific embodiments.
As shown in figure 1, the air-conditioning of the Winter-summer dual purpose of the present embodiment includes having refrigerating cycle unit with desalinization coproduction
Air-conditioning and reverse-flow low temperature multiple-effect distillation device with heating cycling element.
Air-conditioning include compressor 3, outdoor heat exchanger 4, condenser 26, throttling arrangement 27, indoor heat exchanger 1, four-way valve 2,
Totally 6 valves form for filter 28 and 001~valve of valve 006.The outlet of compressor 3 is connected with the c mouths of four-way valve 2, four-way valve 2
D mouths are divided into two passages, wherein a branch road is connected with the entrance of valve 002, the outlet of valve 002 is divided into two passages again, wherein one logical
Road is connected with the outlet of valve 001, and the entrance of valve 001 is connected with the outlet of indoor heat exchanger 1;Valve 002 exports another passage and condenser 26
Entrance is connected, and the outlet of condenser 26 is divided into two passages, wherein a passage is connected with the entrance of valve 003, valve 003 exports and valve
006 entrance is connected, and condenser 24 exports another passage and is connected with the entrance of valve 004, the outlet of valve 004 and the entrance phase of indoor heat exchanger 1
Even.The outlet d of four-way valve 2 another passage is connected with the outlet of valve 005, the outlet g2 phases of the entrance of valve 005 and outdoor heat exchanger 4
Even, the entrance h2 of outdoor heat exchanger 4 is connected with the outlet of valve 006, and the entrance of valve 006 exports with the entrance of throttling arrangement 27, valve 003 respectively
Be connected, throttling arrangement 27 outlet is connected with the entrance of filter 28, filter 28 export respectively with the entrance of indoor heat exchanger 1, valve 004
Outlet is connected, and indoor heat exchanger 1 exports the b mouths with four-way valve 2, the entrance of valve 001 respectively and is connected, a mouths and the compression of four-way valve 2
The entrance of machine 3 is connected, and during winter, condenser 26 is in parallel with indoor heat exchanger 1.
Reverse-flow low temperature multiple-effect distillation device includes:N imitates distilling apparatus 5, the respectively first effect distilling apparatus 5-1, and second
Imitate distilling apparatus 5-2 ... n-th and imitate distilling apparatus 5-n, wherein cold comprising Air-conditioning Cycle device in the first effect distilling apparatus 5-1
Condenser 26, spray equipment 9 and gas-liquid separation device 10, the second effect 5-2 to n-th, which is imitated in distilling apparatus 5-n, includes evaporative condenser
22nd, spray equipment 9 and gas-liquid separation device 10, n sprayed sea water entrance stopper 6-1~6-n, n vacuum pump inlet are cut
Locking apparatus 7-1~7-n, vavuum pump 8, fresh water condenser 11, the first seawater inlet filter 12, the first seawater inlet water pump 13,
Second seawater inlet water pump 14, concentrated seawater outlet water pump 15, water outlet water pump 16, the second seawater inlet filter 17, dense sea
Water out stopper 18, water outlet stopper 19, First Heat Exchanger 20, the second heat exchanger 21, n-1 seawer outlet drop
Pressure device 23-1~23-n-1, n-2 water outlet dropping equipment 24-2~24-n-1, the fresh water in water outlet passage collect
Collect to fresh water in pipeline, n-1 seawater send water water pump 25-2~25-n and valve A~valves of valve D tetra-, valve A~valve D tetra-
Valve combination pipeline forms conducting selector.
Second seawater inlet II is connected with valve C entrances, valve D entrances respectively, and valve C outlets enter with the first seawater inlet water pump 13
Mouth is connected, and valve D outlets are connected with the entrance of the second seawater inlet water pump 14, and the outlet of the second seawater inlet water pump 14 enters with the second seawater
The entrance of filter 17 of making a slip of the tongue is connected, and the second seawater inlet filter 17 exports the entrance g1 with the outdoor heat exchanger 4 of air-conditioning, respectively
The entrance f2 of one heat exchanger 20 is connected, and the outlet h1 of outdoor heat exchanger 4 is connected with seawer outfall V, and First Heat Exchanger 20 exports e2
It is connected with the entrance b1 of the second heat exchanger 21, the second heat exchanger 21 effect shower seawater inlet stopper 6-n entrances of outlet a1 and n-th
It is connected, the n-th effect sprayed sea water entrance stopper 6-n outlets are connected with the spray equipment 9 in the n-th effect distilling apparatus.I-th (i=
2~n-1) the seawer outlet passage of effect distilling apparatus bottom is connected with i-th effect seawer outlet dropping equipment (23-i) entrance respectively
(the seawer outlet passage of the n-th effect distilling apparatus bottom is without dropping equipment), the i-th effect dropping equipment 23-i outlets are imitated with i-th respectively
Seawater send water water pump 25-i entrances to be connected, and the i-th effect seawater send water water pump 25-i outlets to be filled with the i-th -1 effect sprayed sea water entrance cut-off
Posting port is connected, and the i-th -1 effect sprayed sea water entrance stopper outlet is connected with the spray equipment 9 in the i-th -1 effect distilling apparatus.
The concentrated seawater exit passageway of first effect distilling apparatus 5-1 bottoms is connected with the first effect seawer outlet dropping equipment 23-1 entrances, the
One effect seawer outlet dropping equipment outlet 23-1 is connected with the entrance a2 of the second heat exchanger 21, the second heat exchanger 21 outlet b2 and dense sea
The entrance of water out stopper 18 is connected, and the concentrated seawater outlet outlet of stopper 18 is connected with the concentrated seawater outlet entrance of water pump 15,
The concentrated seawater outlet outlet of water pump 15 is connected with concentrated seawater outlet I.In addition to last effect, each gas-liquid separation imitated inside distilling apparatus
Device 10, its entrance communicate with the effect distilling apparatus, and export then with it is next effect distilling apparatus in the entrance of evaporative condenser 22
Communicate, the outlet of evaporative condenser 22 is each product water channel.The product water channel difference of i-th (i=2~n-1) effect distilling apparatus
Being connected with the i-th effect water outlet dropping equipment 24-i entrances, (the water outlet passage of the n-th effect distilling apparatus bottom fills without decompression
Put), while the outlet of gas-liquid separation device 10 of last effect is connected with the entrance c2 of fresh water condenser 11, fresh water condenser 11 exports
D2 collects with fresh water and is connected after pipeline converges with the entrance e1 of First Heat Exchanger 20, the outlet f1 and water outlet of First Heat Exchanger 20
The entrance of stopper 19 is connected, and the outlet of water outlet stopper 19 is connected with the entrance of water outlet water pump 16, water outlet water
The outlet of pump 16 is connected with water outlet III.First seawater inlet IV is connected with valve A entrances, valve B entrances respectively, valve B outlets and the
The entrance of two seawater inlet water pump 14 is connected, and valve A outlets are connected with the entrance of the first seawater inlet water pump 13, the first seawater inlet water pump
13 outlets are connected with the entrance of the first seawater inlet filter 12, the outlet of the first seawater inlet filter 12 and sea water desalinating unit
The entrance d1 of fresh water condenser 9 is connected, and fresh water condenser 9 exports c1 and is connected with seawer outfall V.The top of each effect distilling apparatus
One outlet passage is also left, i-th (i=1~n) imitates the exit passageway and the i-th effect vacuum pump outlet cut-off at the top of distilling apparatus
Device 7-i outlets are connected, and the i-th effect vacuum pump inlet stopper 7-i entrances and vavuum pump 8 outlet is connected, the entrance of vavuum pump 8 and
Air communicates.
In the present embodiment, access deep sea water heat exchange in outdoor heat exchanger 4 during winter.
In the present embodiment, the refrigerant of air-conditioning selection R134a can also select other refrigerants, such as R1234yf,
R410A or R407C, the present embodiment use under the refrigerating environment of daily air-conditioning, now, the temperature of heat caused by condenser 24
Typically at 40~50 DEG C.
In the present embodiment, the refrigerating cycle unit and heating cycling element of air-conditioning can mutually switch, summer, kind of refrigeration cycle
Cell operation, shutoff valve 001, valve 004, valve 005, valve 006, opening valve 002, valve 003, refrigerant are compressed in compressor 3
Four-way valve 2 is entered by entrance c into high temperature and high pressure gas, then by exporting d outflow four-way valves 2, by valve 002 enter condenser 26 with
Sea water desalinating unit first imitates the seawater to make heat exchange in distilling apparatus 5-1, is cooled and is further condensed into after liquid by valve 003
Depressurized into throttling arrangement 27, partially liq flashes into steam, after the mixtures of these gas-liquid two-phases is filtered by filter 26
Enter back into indoor heat exchanger 1, while refrigeration indoors in heat exchanger 1 from indoor absorption heat evaporation turn into steam after by entrance
B enters four-way valve 2, then by exporting after a leaves four-way valve 2, returns in compressor 3, so as to complete a kind of refrigeration cycle.
Winter, heating cycling element work, shutoff valve 002, valve 003, opening valve 001, valve 004, valve 005, valve 006, system
Cryogen is compressed into compressor 3 after high temperature and high pressure gas four-way valve 2 is entered by entrance c after, then by exporting b leave four-way valve
2, refrigerant vapour is divided into two strands, and one is condensed into liquid by indoor heat exchanger 1, and it is cold that another stock-traders' know-how crosses the entrance of valve 001
Condenser 26 imitates the seawater to make heat exchange in distilling apparatus 5-1 with sea water desalinating unit first, after being cooled and being further condensed into liquid
By valve 004 with from indoor heat exchanger 1 come out liquid joint, then by filter 28 filter after, subtract into throttling arrangement 27
Pressure, partially liq flash into steam, and the mixture of these gas-liquid two-phases enters outdoor heat exchanger 4 by valve 006, in outdoor heat exchange
The heat from winter deep layer high temperature seawater is absorbed in device 4 and is evaporated four-way valve is entered by entrance d by valve 005 as after steam
2, then by exporting after a leaves four-way valve 2, return in compressor 3, so as to complete a heating circulation.
Summer shallow layer sea water temperature is higher, typically at 27~35 DEG C, using shallow layer sea water as the second source of seawater, the second seawater
Entrance II is passed through shallow layer sea water, and the temperature of deep sea water is relatively low, extra large as first in 13~18 DEG C of deep sea water using temperature
Water source, the first seawater inlet IV are passed through deep sea water.
During winter, the first seawater inlet IV is passed through the higher deep sea water of water temperature, and deep sea water is as the second source of seawater, water
The relatively low shallow layer sea water of the warm water temperature that typically at 13~18 DEG C, the second seawater inlet II is passed through, shallow layer sea water is as the first seawater
Source, water temperature, by turning on the regulation of valve in selector, make the high temperature seawater of deep layer flow to First Heat Exchanger typically at 0~7 DEG C
20 are preheated, and the low temperature seawater of shallow-layer is flowed to the fresh water steam that fresh water condenser 11 condenses last effect output, wherein, the
The temperature of one source of seawater is less than the temperature of the second source of seawater.
Desalting process:
Summer, low temperature multiple-effect distillation device shutoff valve B, valve C, opening valve A, valve D, shallow-layer high temperature seawater flow through the second seawater
Entrance II and valve D enter;Winter, low temperature multiple-effect distillation device shutoff valve A, valve D, opening valve B, valve C, deep layer high temperature seawater flow through
First seawater inlet IV and valve B enter, and high temperature seawater introduces the second seawater filtering device 17, mistake by the second seawater inlet water pump 14
Filter rear portion be passed through Air-conditioning Cycle device outdoor heat exchanger 4 exchange heat therewith cool after excluded by seawer outfall V, one
Point exchanged heat and heated up with the fresh water flowed out from fresh water condenser 11 by First Heat Exchanger 20, enter back into the second heat exchanger 21 with from the
The concentrated seawater heat exchange heating of one effect distilling apparatus 5-1 outflows, the high temperature seawater after heating are ended by the n-th effect sprayed sea water entrance
After device 6-n, into the n-th effect distilling apparatus 5-n, and the pipeline external of evaporative condenser 22 is sprayed on by seawater spraying device 9.Steam
The seawater to feel cold outside the pipe of condenser 22 is exchanged heat with the steam as caused by the (n-1)th effect distilling apparatus 5-n-1 in evaporative condenser 22:
A part of seawater heating is dropped after flashing to steam through gas-liquid separation device 10 into fresh water condenser 11, and with low temperature seawater heat exchange
Temperature, it is condensed into fresh water;Another part seawater is condensed into concentrated seawater, from the n-th effect distilling apparatus 5-n bottoms concentrated seawater exit passageway stream
Go out, send water water pump 25-n to enter the (n-1)th effect sprayed sea water entrance stopper 6-n-1 by the n-th effect seawater, filled through seawater spraying
9 introducings (n-1)th effect distilling apparatus 5-n-1 is put, is sprayed in (the seawater spray of the first effect distilling apparatus of the pipeline external of evaporative condenser 22
Leaching in the pipeline external of condenser 26), and with n-th -2 effect distilling apparatus caused by fresh water steam exchanged heat (enter first effect steam
The seawater of distillation unit is exchanged heat with the condenser 26 of Air-conditioning Cycle device):A part of evaporation of seawater passes through gas-liquid point into steam
From after device 10 enter next effect evaporative condenser pipeline 22 in, and with the seawater to make heat exchange of next effect;Another part seawater is dense
Shorten into by the (n-1)th effect seawer outlet dropping equipment 23-n-1 after concentrated seawater, then send water water pump 25-n-1 to draw by the (n-1)th effect seawater
Enter previous effect, and repeat (process in n-1 effect distilling apparatus, so to realize the adverse current of seawater.I-th (i=2~n) effect distillation dresses
The steam in evaporative condenser pipe 22 put becomes fresh water after heat exchange cools down, and passes through the i-th effect water outlet dropping equipment 22-i drops
It is cold through fresh water with the steam as caused by the n-th effect distilling apparatus after pressure (the n-th effect distilling apparatus bottom product water channel is without dropping equipment)
After the fresh water that the condensation of condenser 11 obtains converges, cooled by First Heat Exchanger 20 and the heat exchange of entrance high temperature seawater, then passed through again
Water outlet stopper 19 is discharged via water outlet water pump 16.Concentrated seawater caused by first effect distilling apparatus passes through the first effect
Enter the second heat exchanger 21 after seawer outlet dropping equipment 23-1, with being cut after the seawater to make heat exchange cooling of import through overrich seawer outlet
Locking apparatus 18, then drawn by concentrated seawater outlet water pump 15.
Summer, the low temperature seawater of deep layer flows through the first seawater inlet IV and valve A enters fresh water condenser 11;Winter, shallow-layer
Low temperature seawater flow through the second seawater inlet II and valve C enters fresh water condenser 11.Low temperature seawater passes through the first seawater inlet water
Enter fresh water condenser 11 after pump 13 and deep sea water ingress filtering device 12, wherein with from n-th effect distilling apparatus gas-liquid
It is expelled directly out after being heated up after the fresh water steam heat-exchanging that separator 10 comes out by seawer outfall V.
Each effect distilling apparatus is evacuated to the vacuum set by vavuum pump 8 before plant running, and vavuum pump steams with each effect
Vacuum pump outlet stopper 7-i, an i=1~n are provided between distillation unit, for controlling gas in each effect distilling apparatus
Pressure.N effect shower seawater inlet stoppers 6-i, i=1~n, concentrated seawater outlet stopper 18 and water outlet cut-off fill
19 are put to be respectively intended to control seawater, the disengaging of concentrated seawater and fresh water.
The heat that desalinization first is imitated needed for the water evaporation of distilling apparatus inland sea during this produces for the condenser of air-conditioning
Cryogenic condensation heat, temperature is about 40~50 DEG C.
The carrying out practically process of the present invention is further described below in conjunction with accompanying drawing 1:
1. before system operation, confirm anhydrous in each pipeline and device and seal.Summer, Air-conditioning Cycle device part are closed
Valve 001, valve 004, valve 005, valve 006, opening valve 002, valve 003, low temperature multiple-effect distillation device shutoff valve B, valve C, opening valve A,
Valve D;Winter, then Air-conditioning Cycle device part shutoff valve 002, valve 003, opening valve 001, valve 004, valve 005, valve 006, low temperature is more
Imitate distilling apparatus shutoff valve A, valve D, opening valve B, valve C.N effect sprayed sea water entrance stopper 6-i, i=1~n are then shut off,
Concentrated seawater exports stopper 18 and water outlet stopper 19, opens the n effect vacuum pump outlets being connected with vavuum pump 8 and cuts
Locking apparatus 7-i, i=1~n, vavuum pump is opened, each effect distilling apparatus is evacuated to the vacuum set.Vacuum pump outlet ends
Device 7-i, i=1~n, for controlling air pressure in each effect distilling apparatus.N effect sprayed sea water entrance stoppers 6-i, i=1~
N, concentrated seawater outlet stopper 18 and water outlet stopper 19 are respectively intended to control seawater, and concentrated seawater and fresh water enter
Go out.
After 2. completion vacuumizes, n effect vacuum pump outlet stopper 7-i, the i=1~n being connected with vavuum pump 8 are closed, then
Vavuum pump 8 is closed, is then turned on the first seawater inlet water pump 13, water outlet water pump 16, the second seawater inlet water pump 14, dense sea
Water out water pump 15, n effect sprayed sea water entrance stopper 6-i, i=1~n are opened, start compressor 3 and run Air-conditioning Cycle dress
Put, treat that product water channel and concentrated seawater passage are full of after water, start water outlet water pump 16 and concentrated seawater outlet water pump 15, so
After be then turned on concentrated seawater outlet stopper 18 and water outlet stopper 19, treat that whole system operation a period of time is stable
Afterwards, you can utilize 40~50 DEG C of a certain amount of seawater of desalination of air conditioner low temperature condensation heat.
Such circulate operation, it can be achieved with carrying out continuous desalinization using air-conditioning condenser used heat.
The present embodiment actual use when,
The parameter of air-conditioning:
Power:1.5P;
Refrigerating capacity:3500W;
Refrigerant:R134a;
During summer:
The evaporating temperature of indoor heat exchanger:7.2℃;
The condensation temperature of condenser:54.4℃;
During winter:
The evaporating temperature of outdoor heat exchanger:13℃;
The condensation temperature of indoor heat exchanger:45℃;
The condensation temperature of condenser:45℃;
The parameter of low temperature multiple-effect distillation device:
During summer:
The temperature for the first source of seawater that first seawater inlet IV is passed through:15℃;
The temperature for the second source of seawater that second seawater inlet II is passed through:30℃;
First effect distilling apparatus temperature:50℃;
End effect vapor (steam) temperature:18℃;
During winter:
The temperature for the second source of seawater that first seawater inlet IV is passed through:15℃;
The temperature for the first source of seawater that second seawater inlet II is passed through:5℃;
First effect distilling apparatus temperature:42℃;
End effect vapor (steam) temperature:8℃;
Second source of seawater inlet flow rate:0.042kg/s.
Imitate number:12;
Summer simulates producing water ratio:0.02kg/s, produces water about 72kg per hour, produces water daily up to 1.72 tons;Winter
It is about 0.015kg/s to simulate producing water ratio, produces water about 54kg per hour, produces water daily up to 1.29 tons, quantity of heat production about 3.5kW.
Claims (3)
1. a kind of air-conditioning of Winter-summer dual purpose and desalinization co-generation system, including with refrigerating cycle unit and heating cycling element
Air-conditioning, it is characterised in that also include including low temperature multiple-effect distillation device, the low temperature multiple-effect distillation device:Multi-effect distilling list
Member, the fresh water of collection liquid fresh water collect pipeline, the outer comb of density wastewater for collecting end concentrated seawater, condense last effect distillation list
The fresh water condenser of the fresh water steam of first output and the seawater preheating device of preheating seawater to be diluted, last effect distillation unit production
The temperature of the fresh water steam gone out is less than 20 DEG C;
The heating parts of the heating cycling element include indoor heat exchanger and the condensation heated by compressor compresses refrigerant
Device, the heating cycling element and refrigerating cycle unit share same condenser, and the condenser is as the first effect distillation unit
Condensation module;
The fresh water condenser includes fresh water steam channel and condensation water channel, the sea of both ends connection first of the condensation water channel
Water inlet pipe and seawater drainpipe;
The seawater preheating device includes connection fresh water and collects the product water channel of pipeline, the concentrated seawater passage of the outer comb of connection density wastewater
And sea water passage, the both ends of the sea water passage connect the second seawater inlet pipe and pre- hot sea water outlet pipe, the pre- hot sea water
Outlet pipe accesses the preheating sea intake of multi-effect distilling unit, and the ocean temperature for being passed through the second seawater inlet pipe is extra large higher than being passed through first
The ocean temperature of water inlet pipe;
During air conditioner refrigerating, the ocean temperature for being passed through the first seawater inlet pipe is 13~18 DEG C, during air-conditioning heating, is passed through the first seawater and enters
The ocean temperature of pipe is 0~7 DEG C;
During air conditioner refrigerating, the ocean temperature for being passed through the second seawater inlet pipe is 27~35 DEG C, during air-conditioning heating, is passed through the second seawater
The ocean temperature of inlet pipe is 13~18 DEG C;The first seawater inlet pipe and the second seawater inlet pipe are connected with the conducting for exchanging water inlet
Selector;The condenser heating temperature of the air-conditioning is 40~55 DEG C.
2. the air-conditioning of Winter-summer dual purpose as claimed in claim 1 and desalinization co-generation system, it is characterised in that the low temperature is more
Distilling apparatus is imitated using reverse-flow, described preheating sea intake is arranged in the distillation unit that last is imitated, previous effect it is dense
Seawater inlet port is connected with the concentrated seawater delivery port of latter effect, and the concentrated seawater outlet of the distillation unit of the first effect is connected to density wastewater
Outer comb.
3. the air-conditioning of the Winter-summer dual purpose as described in claim 1~2 any claim and desalinization co-generation system, its feature
It is, the seawater preheating device includes the First Heat Exchanger and the second heat exchanger of sea water passage series connection, the second seawater inlet pipe
It is connected with the sea water passage of First Heat Exchanger, the pre- hot sea water outlet pipe is connected with the sea water passage of the second heat exchanger, described
Concentrated seawater passage is arranged in the second heat exchanger, and the product water channel is arranged in First Heat Exchanger.
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CN101948148A (en) * | 2010-10-22 | 2011-01-19 | 河北宏润重工集团有限公司 | Energy-saving low-temperature multiple-effect seawater desalting device |
WO2011010205A1 (en) * | 2009-07-20 | 2011-01-27 | National University Of Singapore | Desalination system and method |
CN203159268U (en) * | 2013-01-23 | 2013-08-28 | 中国电子工程设计院 | solar air conditioning seawater desalination system |
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WO2011010205A1 (en) * | 2009-07-20 | 2011-01-27 | National University Of Singapore | Desalination system and method |
CN101948148A (en) * | 2010-10-22 | 2011-01-19 | 河北宏润重工集团有限公司 | Energy-saving low-temperature multiple-effect seawater desalting device |
CN203159268U (en) * | 2013-01-23 | 2013-08-28 | 中国电子工程设计院 | solar air conditioning seawater desalination system |
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WO2023152509A1 (en) * | 2022-02-11 | 2023-08-17 | The University Of Manchester | Method and apparatus for performing a primary and a secondary process |
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