CN104930492A - Enthalpy difference compensating, capacity expanding, purifying and recovering device for draining sewage of boiler - Google Patents
Enthalpy difference compensating, capacity expanding, purifying and recovering device for draining sewage of boiler Download PDFInfo
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- CN104930492A CN104930492A CN201510319654.5A CN201510319654A CN104930492A CN 104930492 A CN104930492 A CN 104930492A CN 201510319654 A CN201510319654 A CN 201510319654A CN 104930492 A CN104930492 A CN 104930492A
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- stainless steel
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- nano materials
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- 239000010865 sewage Substances 0.000 title claims abstract description 15
- 238000001914 filtration Methods 0.000 claims abstract description 175
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 83
- 239000002131 composite material Substances 0.000 claims abstract description 55
- 239000002086 nanomaterial Substances 0.000 claims abstract description 55
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 55
- 239000010935 stainless steel Substances 0.000 claims description 66
- 229910001220 stainless steel Inorganic materials 0.000 claims description 66
- 238000010521 absorption reaction Methods 0.000 claims description 60
- 238000011084 recovery Methods 0.000 claims description 58
- 239000002351 wastewater Substances 0.000 claims description 58
- 238000000746 purification Methods 0.000 claims description 32
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims description 23
- 239000013589 supplement Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 abstract description 20
- 229920006395 saturated elastomer Polymers 0.000 abstract description 12
- 239000002918 waste heat Substances 0.000 abstract description 11
- 238000001704 evaporation Methods 0.000 abstract description 5
- 238000004064 recycling Methods 0.000 abstract description 5
- 238000007599 discharging Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 19
- 239000002244 precipitate Substances 0.000 description 15
- 238000009834 vaporization Methods 0.000 description 15
- 230000008016 vaporization Effects 0.000 description 15
- 230000001681 protective effect Effects 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 230000001502 supplementing effect Effects 0.000 description 6
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 5
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 229910001424 calcium ion Inorganic materials 0.000 description 5
- 229910001425 magnesium ion Inorganic materials 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 238000004134 energy conservation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910000851 Alloy steel Inorganic materials 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000029142 excretion Effects 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 230000020169 heat generation Effects 0.000 description 3
- 239000010808 liquid waste Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 230000002000 scavenging effect Effects 0.000 description 3
- YRWWOAFMPXPHEJ-OFBPEYICSA-K sodium L-ascorbic acid 2-phosphate Chemical compound [Na+].[Na+].[Na+].OC[C@H](O)[C@H]1OC(=O)C(OP([O-])([O-])=O)=C1[O-] YRWWOAFMPXPHEJ-OFBPEYICSA-K 0.000 description 3
- 229940048058 sodium ascorbyl phosphate Drugs 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002550 fecal effect Effects 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
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- Water Treatment By Sorption (AREA)
Abstract
The invention discloses an enthalpy difference compensating, capacity expanding, purifying and recovering device for draining sewage of a boiler. The device comprises a mixing filtering tank, and a precision filtering tank which is communicated with the mixing filtering tank, wherein a boiler draining sewage feeding pipe and a working steam feeding pipe are mounted on a mixing filtering tank body and respectively connected with venturi injector mounted in the mixing filtering tank body; the venturi injector is communicated with an absorbing filter element which is mounted in the mixing filtering tank body and used for initially filtering amino composite nano materials; the mixing filtering tank is communicated with the precision filtering tank through a communication pipe; the absorbing filtering element for precisely filtering the amino composite nano materials is mounted in the precision filtering tank; a steam discharging pipe is mounted on the precision filtering tank. According to the device, the isothermal pressure-reduced capacity expanding, evaporating, absorbing and purifying are carried out to convert sewage drained from a boiler steam-water system into small and medium pressure overheat or saturated steam which is charged into a heat supply network pipe; therefore, the waste heat recycling rate is more than 98.5%.
Description
Technical field
The present invention relates to a kind of boiler blow-off waste water enthalpy difference and compensate dilatation purification recovery device, particularly relate to the device that low grade residual heat is changed into high-grade low pressure heating steam by a kind of dilatation of boiler blow-off waste water, Recovery Purifying.
Background technology
All the time, the recovery of low grade residual heat and to utilize be a problem of the energy-conservation industry of puzzlement all the time, the rate of recovery is low and useless is the current general present situation of industry.
Boiler blow-off is one of loss in boiler operatiopn, for controlling stove water, steam quality, boiler must carry out continuous blowdown and periodical blowdown, require the successive and regular position the highest from stove water salt alkali concn and the maximum minimum position discharge section stove water of deposit, to reduce salt content in stove water, alkali number containing silicic acid amount and the fecal material content and the calcium ions and magnesium ions deposit that are in suspended state.Its object is exactly to ensure the safe operation that the quality of stove water enables boiler steady in a long-term, and this thermal loss is also one of key factor affecting boiler efficiency.
Current existing recovery technology has the flash distillation of platoon flash vessel and heat exchanger to reclaim, and wherein platoon flash vessel yield is only 20% to 24%, though heat exchanger reclaims more than 50%, hot grade reduces, and when not having sufficient low-temperature receiver, almost cannot use.
Summary of the invention
The object of the invention there are provided a kind of boiler blow-off waste water enthalpy difference and compensates dilatation purification recovery device, apparatus of the present invention are by isothermal step-down dilatation, vaporization, adsorption cleaning, change the waste water that boiler steam and water circuit is discharged into mesolow overheated or saturated vapor, be incorporated to heat supply webmaster again, thus accomplish that Waste Heat Recovery utilization rate reaches more than 98.5%, whole apparatus structure is simple, easy to operate and cost is low.
In order to achieve the above object, technical scheme of the present invention is:
A kind of boiler blow-off waste water enthalpy difference compensates dilatation purification recovery device, the precise filtering tank comprise hybrid filtering tank, being communicated with hybrid filtering tank; Wherein said hybrid filtering tank is provided with boiler blow-off waste water water inlet pipe and working steam steam inlet pipe; Described boiler blow-off waste water water inlet pipe is connected with the venturi-type eductors be arranged in hybrid filtering tank respectively with working steam steam inlet pipe, described boiler blow-off waste water water inlet pipe is provided with nozzle, and described nozzle is placed in venturi-type eductors; Described venturi-type eductors is communicated with the absorption filter element (be purchased from energy-conserving and environment-protective (Beijing) Co., Ltd of Zhong Nengfa section, model is ZNFK-FHANMCL-01) being arranged on the amino composite nano materials of preliminary filtration in hybrid filtering tank; Described hybrid filtering tank was communicated with precise filtering tank by communicating pipe; The absorption filter element (be purchased from energy-conserving and environment-protective (Beijing) Co., Ltd of Zhong Nengfa section, model is ZNFK-FHANMCL-02) of the amino composite nano materials of secondary filter is installed in described precise filtering tank; Described precise filtering tank is provided with steam outlet pipe.
The absorption filter element of the described amino composite nano materials of preliminary filtration is the absorption filter element that cylindrical shape tentatively filters amino composite nano materials; Be set with precision stainless steel silk screen outside the absorption filter element of the described amino composite nano materials of preliminary filtration, described precision stainless steel screen mesh jacket is equipped with 3-5mm stainless steel punched-plate, described stainless steel punched-plate as protective cover to prevent from being washed away by high steam; The outer wall of the stainless steel punched-plate of described close venturi-type eductors is set with the first flange, the tube wall of the venturi-type eductors of described close stainless steel punched-plate is provided with the second flange, is connected by screw between the first described flange and the second flange.
As preferably, described hybrid filtering tank is communicated with by 1 communicating pipe with between precise filtering tank; And described hybrid filtering tank is also provided with the support column the same with communicating pipe size with between precise filtering tank;
The absorption filter element of the amino composite nano materials of cylindrical shape secondary filter is installed in described precise filtering tank; Be set with precision stainless steel silk screen outside the absorption filter element of the amino composite nano materials of described secondary filter, described precision stainless steel screen mesh jacket is equipped with 3-5mm stainless steel punched-plate, described stainless steel punched-plate as protective cover to prevent from being washed away by high steam; The outer wall of described precision stainless steel silk screen is set with three-flange, the 4th flange is installed between the outer wall of described stainless steel punched-plate and the tube wall of precise filtering tank, is connected by screw between described three-flange and the 4th flange.
The absorption filter element of the amino composite nano materials of arc secondary filter is installed in described precise filtering tank; precision stainless steel silk screen is set with outside the absorption filter element of the amino composite nano materials of described secondary filter; described precision stainless steel screen mesh jacket is equipped with 3-5mm stainless steel punched-plate, described stainless steel punched-plate as protective cover to prevent from being washed away by high steam.The precise filtering tank internal face of the absorption filter element both sides of the amino composite nano materials of described arc secondary filter is separately installed with groove baffle plate.
Further preferably, described hybrid filtering tank is communicated with respectively by 2 communicating pipe with between precise filtering tank; The absorption filter element of the amino composite nano materials of arc secondary filter is installed in described precise filtering tank, be set with precision stainless steel silk screen and the thick stainless steel punched-plate protective cover of 3-5mm outside the absorption filter element of the amino composite nano materials of described secondary filter, and the length of the absorption filter element of the amino composite nano materials of described arc secondary filter be greater than for 2 communicating pipe far-end outer wall between distance; The precise filtering tank internal face of the absorption filter element both sides of the amino composite nano materials of described arc secondary filter is separately installed with groove baffle plate.
Described precise filtering tank offers water supplement port, and described precise filtering tank is provided with thermometer and pressure gauge; Described precise filtering tank is also provided with the exhaust outlet being provided with safety valve.
Described hybrid filtering tank wall is also provided with PLC, described boiler blow-off waste water water inlet pipe, working steam steam inlet pipe and steam outlet pipe is separately installed with into water electric control valve, admission electric control valve and goes out vapour electric control valve; And described PLC respectively by circuit with water inlet electric control valve, admission electric control valve, go out vapour electric control valve and be connected.
Described hybrid filtering tank and precise filtering tank offer sewage draining exit respectively.
Described hybrid filtering tank is provided with feet; Described hybrid filtering tank is connected with end cap respectively by flange with secondary filter tank two ends.
The invention has the beneficial effects as follows: boiler blow-off is the HTHP stove water used heat with certain hot grade, successive and regular emitting from boiler in the boiler run, because the stove water main component of the high-temperature high-pressure state of its discharge contains the impurity such as phosphate, calcium ions and magnesium ions deposit, silica.Boiler blow-off waste water boiler blowdown water enthalpy difference of the present invention compensates dilatation purification recovery device and reclaims these boiler blow-off waste water and design, by utilizing a small amount of high temperature heat source of factory, boiler high temperature high pressure sewer used heat according to the physical characteristic of himself, to enter after retracting device first by the water vapor of most of high-grade waste heat oven to the low pressure heating steam under the pressure of setting, the sewer also having sub-fraction not vaporize is compensated by the enthalpy difference of working steam in blending tank venturi mixing tube, evaporation and heat-exchange becomes the heating steam of technological requirement, thus the Waste Heat Recovery utilization rate of having accomplished reaches more than 98.5%, amino absorption filter element made by composite nano materials, it reaches as high as 85-97% to Phosphate Adsorption rate.
The scheme Design of science and robot control system(RCS) can make enthalpy difference compensation dilatation purification recovery device select the working steam of different pressure and temp grades i.e. (draw gas, steam discharge or initial steam point) to carry out the compensation vaporization dilatation of enthalpy difference.The working steam source of 5-20 times of different brackets is selected to vaporize completely to boiler blowdown water as required.Boiler blow-off waste water under certain pressure enters the compensation dilatation purification recovery device of enthalpy difference, in retracting device, the flow process of particular design is vaporized, enthalpy difference compensates and purification is adsorbed, finally be heated to the output steam of heat supply network requirement, be used for supplying relevant temperature pressure rating requirement process steam and heat user vapour.As there is no complete or sufficient corresponding working steam amount, eventually pass through the output steam after this retracting device generally temperature to decline 2-8 DEG C, but this temperature declined can be ignored on whole heat supply network impact.
To sum up, blowdown water after dilatation, vaporization, absorption, filtration, purification, is changed into low-pressure saturated steam or superheated steam, then is incorporated to heat supply webmaster by a kind of boiler blow-off waste water boiler blowdown water enthalpy difference compensation dilatation purification recovery device of the present invention; When the setting value of temperature lower than heat supply webmaster, enthalpy difference compensation can also be carried out by hot operation steam, reach the heating steam with heat supply network corresponding temperature, thus the maximized recycling of the used heat accomplished, accomplish that Waste Heat Recovery utilization rate reaches more than 98.5%, thoroughly solve boiler blow-off loss problem; And whole apparatus structure is simple, easy to operate and cost is low.Simultaneously for large-scale and Study and Development that is ultra-large type fluid source heating-cooling device provide new approaches, new technology, new theory and new departure.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention 1;
Fig. 2 is the structural representation of the embodiment of the present invention 2;
Fig. 3 is the structural representation of the embodiment of the present invention 3.
Detailed description of the invention
Embodiment 1
A kind of boiler blow-off waste water enthalpy difference of the present embodiment compensates dilatation purification recovery device, as shown in Figure 1, and the precise filtering tank 2 comprise hybrid filtering tank 1, being communicated with hybrid filtering tank 1; Described hybrid filtering tank 1 is provided with feet 20.Described hybrid filtering tank 1 is connected with end cap 21 respectively by flange with precise filtering tank 2 tank body two ends.
Wherein said hybrid filtering tank 1 tank body is provided with boiler blow-off waste water water inlet pipe 3 and working steam steam inlet pipe 4; Described boiler blow-off waste water water inlet pipe 3 is connected with the venturi-type eductors 5 be arranged in hybrid filtering tank 1 tank body respectively with working steam steam inlet pipe 4, and venturi-type eductors 5 is made up of the steel alloy of 12Gr1MoV.Described boiler blow-off waste water water inlet pipe 3 is provided with nozzle 22, and described nozzle 22 is placed in venturi-type eductors 5, directly accesses the mixing chamber of venturi-type eductors 5; Wherein the end of working steam steam inlet pipe 4 is connected with venturi-type eductors 5 large footpath mouth.
The absorption filter element 6 that described venturi-type eductors 5 tentatively filters amino composite nano materials with the cylindrical shape be arranged in hybrid filtering tank 1 tank body is communicated with; precision stainless steel silk screen 23 is set with outside the absorption filter element 6 that described cylindrical shape tentatively filters amino composite nano materials; be set with 3-5mm stainless steel punched-plate 24 outside described precision stainless steel silk screen 23, described stainless steel punched-plate 24 as protective cover to prevent from being washed away by high steam.The outer wall of the stainless steel punched-plate 24 of described close venturi-type eductors 5 is set with the first flange 10, the tube wall of the venturi-type eductors 5 of described close stainless steel punched-plate 24 is provided with the second flange 11, is connected by screw between the first described flange 10 and the second flange 11.Described hybrid filtering tank 1 was communicated with precise filtering tank 2 by 2 communicating pipe 7, and the communicating pipe 7 of hybrid filtering tank 1 and precise filtering tank 2 junction passes through Flange joint; The absorption filter element 8 of the amino composite nano materials of arc secondary filter is installed in described precise filtering tank 2, precision stainless steel silk screen 23 is set with outside the absorption filter element 8 of the amino composite nano materials of described arc secondary filter, be set with 3-5mm stainless steel punched-plate 24 outside described precision stainless steel silk screen 23, described stainless steel punched-plate 24 as protective cover to prevent from being washed away by high steam; And the length of the absorption filter element 8 of the amino composite nano materials of described arc secondary filter be greater than 2 communicating pipe 7 far-end outer wall between distance; Precise filtering tank 2 internal face of absorption filter element 8 both sides of the amino composite nano materials of described arc secondary filter is separately installed with groove baffle plate 13.Described precise filtering tank 2 is provided with steam outlet pipe 9, and for the discharge of water vapour in tank body, the water vapour of eliminating is conveyed into low pressure heating steam pipe network.
Described precise filtering tank 2 offers water supplement port 14, and described precise filtering tank 2 is provided with thermometer 15 and pressure gauge 16; Described precise filtering tank 2 is also provided with the exhaust outlet 17 being provided with safety valve, the safety excretion during exhaust outlet 17 of safety valve level superfine for pressure is installed.Described hybrid filtering tank 1 and precise filtering tank 2 offer sewage draining exit 19 respectively.
Described hybrid filtering tank 1 outer wall is also provided with PLC 18, described boiler blow-off waste water water inlet pipe 3, working steam steam inlet pipe 4 and steam outlet pipe 9 is separately installed with into water electric control valve (not shown), admission electric control valve (not shown) and goes out vapour electric control valve (not shown); And described PLC 18 respectively by circuit with water inlet electric control valve, admission electric control valve, go out vapour electric control valve and be connected.
The using method of the present embodiment device is: from each boiler-steam dome out 312 DEG C, the HTHP blowdown water of 10.3MPa connects by blowdown the boiler blow-off waste water water inlet pipe 3 that female pipe enters the compensation dilatation purification recovery device of enthalpy difference, then enters in hybrid filtering tank 1, 280 DEG C, 0.98MPa working steam (directly can utilize the steam in low pressure heating steam pipe network) after working steam steam inlet pipe 4 with 312 DEG C, the HTHP blowdown water of 10.3MPa carries out step-down in venturi-type eductors 5, dilatation, vaporization are carried out mixing and enthalpy difference fully and compensated, wherein 312 DEG C, during the entering of the HTHP blowdown water of 10.3MPa and working steam, initial flow is than being 1:(5-20), namely carry out coagulation to improve flow velocity, reduce pressure, sufficient steam-water mixing obtains sufficient enthalpy difference and compensates and then make liquid waste water be converted to the saturated of low pressure or superheated steam state, boiler blow-off waste water vapor, enter after the anemostat of venturi-type eductors 5 after mixing enthalpy difference compensates and block absorption filter element 6 that filter tentatively filters amino composite nano materials and carry out secondary super large dilatation step-down and filter, the effect that secondary blocks filter mainly reduces steam flow rate, stop vaporization precipitate, silica, calcium ions and magnesium ions deposit etc. is taken out of with steam, run precipitate after a period of time to adhere to gradually and be accumulated on filter core, pressure reduction before and after filter core can be caused to increase, after before and after filter core, pressure reduction reaches setting pressure reduction, by supplementing water pipe, backwash is carried out to filter core with cleaning supplementary water, precipitate is fully dissolved and is got rid of by the sewage draining exit 19 bottom hybrid filtering tank 1 again.(before and after filter screen pressure differential resetting alarming value access PLC) is then through entering the three-level filter system in precise filtering tank 2 tank cavity communicating pipe 7, the effect of three-level filter system is mainly by high-new scavenging material and technology---the absorption filter element made by amino composite nano materials, to to be separated out by steam and the sodium ascorbyl phosphate ion brought out carries out last absorption, precipitate, got rid of (the same) by the sewage draining exit 19 bottom precise filtering tank 2 again by washing precipitate fully to dissolve to filter-core back-flushing by supplementing water, steam is discharged finally by the steam outlet pipe 9 of precise filtering tank 2.When detect from steam outlet pipe 9 discharge vapor (steam) temperature pressure lower than setting value time, by regulating the valve of the admission electric control valve on hybrid filtering tank 1 end cap portions working steam steam inlet pipe 4, regulate and control the throttle flow of working steam steam inlet pipe 4 input service steam, increase working steam amount to improve the final heat enthalpy value exporting steam, the low-pressure saturated steam heated in tank body increases enthalpy difference compensation rate, and then makes the vapor (steam) temperature force value of output meet the requirement of lower road technique.The described absorption filter element made by amino composite nano materials, it reaches as high as 85-97% to Phosphate Adsorption rate.
The present embodiment recovery boiler blowdown water volume energy saving profit is settled accounts:
A boiler reclaims the calculating of blowdown water by minimum blowdown rate 2%
The boiler of 1 boiler capacity 240 tons/hour, boiler blow-off water pressure 10.3MPa, temperature 312 DEG C, by the blowdown rate of the minimum evaporation capacity 2% of boiler, boiler wastewater discharges 4.8 tons of/hour high-grade used heat.Be incorporated to heat supply network (pressure 0.98MPa, temperature 280 DEG C) again after the hot grade of raising after being compensated its filtration, vaporization, heating enthalpy difference by working steam, its hot grade is equivalent to the calorific value of heating steam, can produce very considerable economic benefit after recovery.But this boiler wastewater of 4.8 tons/hour originally had and reclaimed the heat of a part of flash-off steam by platoon flash vessel, yield was about 24%, so the economic benefit that this heat of 24% that this recovery system should deduct original oxygen-eliminating device produces.
Energy valuation benchmark:
Heating steam pressure 0.98Mpa temperature 280 DEG C, steam calorific value is pressed: 70.3 × 10
4kcal/ ton; Steam price 150 yuan/ton accounting, runs clearing in 8000 hours per year:
Steam Recovery benefit can be produced: the economic benefit of the boiler blow-off waste heat generation of recovery: ton/hour × the 8000 hours × 150 yuan × 76%(former platoon flash vessel rate of recovery is 24%)=437.76 ten thousand yuan,
Indirect recovery benefit: reclaim water for industrial use 28800 tons X6 yuan/ton=17.2 ten thousand yuan,
Year energy-conservation total revenue: sewer reclaims the indirect benefit 170,000 yuan=4,540,000 yuan of benefit 4,370,000 yuan+recycle-water.
To sum up, blowdown water after dilatation, vaporization, absorption, filtration, purification, is changed into low-pressure saturated steam or superheated steam, then is incorporated to heat supply webmaster by a kind of boiler blow-off waste water boiler blowdown water enthalpy difference compensation dilatation purification recovery device of the present embodiment; When the setting value of temperature lower than heat supply webmaster, enthalpy difference compensation can also be carried out by hot operation steam, reach the output steam with heat supply network corresponding temperature, thus the maximized recycling of the used heat accomplished, accomplish that Waste Heat Recovery utilization rate reaches more than 98.5%, thoroughly solve boiler blow-off loss problem; And whole apparatus structure is simple, easy to operate and cost is low.
Embodiment 2
A kind of boiler blow-off waste water enthalpy difference of the present embodiment compensates dilatation purification recovery device, as shown in Figure 2, and the precise filtering tank 2 comprise hybrid filtering tank 1, being communicated with hybrid filtering tank 1; Described hybrid filtering tank 1 is provided with feet 20.Described hybrid filtering tank 1 is connected with end cap 21 respectively by flange with precise filtering tank 2 tank body two ends.
Wherein said hybrid filtering tank 1 tank body is provided with boiler blow-off waste water water inlet pipe 3 and working steam steam inlet pipe 4; Described boiler blow-off waste water water inlet pipe 3 is connected with the venturi-type eductors 5 be arranged in hybrid filtering tank 1 tank body respectively with working steam steam inlet pipe 4, and venturi-type eductors 5 is made up of the steel alloy of 12Gr1MoV.Described boiler blow-off waste water water inlet pipe 3 is provided with nozzle 22, and described nozzle 22 is placed in venturi-type eductors 5, directly accesses the mixing chamber of venturi-type eductors 5; Wherein the end of working steam steam inlet pipe 4 is connected with venturi-type eductors 5 large footpath mouth.
The absorption filter element 6 that described venturi-type eductors 5 tentatively filters amino composite nano materials with the cylindrical shape be arranged in hybrid filtering tank 1 tank body is communicated with; precision stainless steel silk screen 23 is set with outside the absorption filter element 6 that described cylindrical shape tentatively filters amino composite nano materials; be set with 3-5mm stainless steel punched-plate 24 outside described precision stainless steel silk screen 23, described stainless steel punched-plate 24 as protective cover to prevent from being washed away by high steam.The outer wall of the stainless steel punched-plate 24 of described close venturi-type eductors 5 is set with the first flange 10, the tube wall of the venturi-type eductors 5 of described close stainless steel punched-plate 24 is provided with the second flange 11, is connected by screw between the first described flange 10 and the second flange 11.Described hybrid filtering tank 1 was communicated with precise filtering tank 2 by 1 communicating pipe 7; The communicating pipe 7 of hybrid filtering tank 1 and precise filtering tank 2 junction passes through Flange joint; And described hybrid filtering tank 1 with the support column 12 the same with communicating pipe 7 size is also installed between precise filtering tank 2; The absorption filter element 8 of the amino composite nano materials of cylindrical shape secondary filter is installed in described precise filtering tank 2; Precision stainless steel silk screen 23 is set with outside the absorption filter element 8 of the amino composite nano materials of described cylindrical shape secondary filter, be set with 3-5mm stainless steel punched-plate 24 outside described precision stainless steel silk screen 23, described stainless steel punched-plate 24 as protective cover to prevent from being washed away by high steam; The outer wall of described precision stainless steel silk screen 23 is set with three-flange 25, the 4th flange 26 is installed between the outer wall of described stainless steel punched-plate 24 and the tube wall of precise filtering tank 2, is connected by screw between described three-flange 25 and the 4th flange 26.
Described precise filtering tank 2 is provided with steam outlet pipe 9, and for the discharge of water vapour in tank body, the water vapour of eliminating is conveyed into low pressure heating steam pipe network.
Described precise filtering tank 2 offers water supplement port 14, and described precise filtering tank 2 is provided with thermometer 15 and pressure gauge 16; Described precise filtering tank 2 is also provided with the exhaust outlet 17 being provided with safety valve, the safety excretion during exhaust outlet 17 of safety valve level superfine for pressure is installed.Described hybrid filtering tank 1 and precise filtering tank 2 offer sewage draining exit 19 respectively.
Described hybrid filtering tank 1 outer wall is also provided with PLC 18, described boiler blow-off waste water water inlet pipe 3, working steam steam inlet pipe 4 and steam outlet pipe 9 is separately installed with into water electric control valve (not shown), admission electric control valve (not shown) and goes out vapour electric control valve (not shown); And described PLC 18 respectively by circuit with water inlet electric control valve, admission electric control valve, go out vapour electric control valve and be connected.
The using method of the present embodiment device is: from each boiler-steam dome out 312 DEG C, the HTHP blowdown water of 10.3MPa connects by blowdown the boiler blow-off waste water water inlet pipe 3 that female pipe enters the compensation dilatation purification recovery device of enthalpy difference, then enters in hybrid filtering tank 1, 280 DEG C, 0.98MPa working steam (directly can utilize the steam in low pressure heating steam pipe network) after working steam steam inlet pipe 4 with 312 DEG C, the HTHP blowdown water of 10.3MPa carries out step-down in venturi-type eductors 5, dilatation, vaporization are carried out mixing and enthalpy difference fully and compensated, wherein 312 DEG C, during the entering of the HTHP blowdown water of 10.3MPa and working steam, initial flow is than being 1:(5-20), namely carry out coagulation to improve flow velocity, reduce pressure, sufficient steam-water mixing obtains sufficient enthalpy difference and compensates and then make liquid waste water be converted to the saturated of low pressure or superheated steam state, boiler blow-off waste water vapor, enter after the anemostat of venturi-type eductors 5 after mixing enthalpy difference compensates and block absorption filter element 6 that filter tentatively filters amino composite nano materials and carry out secondary super large dilatation step-down and filter, the effect that secondary blocks filter mainly reduces steam flow rate, stop vaporization precipitate, silica, calcium ions and magnesium ions deposit etc. is taken out of with steam, after running a period of time, precipitate is by can gradually attachment be accumulated on filter core, pressure reduction before and after filter core is caused to increase, after before and after filter core, pressure reduction reaches setting pressure reduction, by supplementing water pipe, backwash is carried out to filter core with cleaning supplementary water, precipitate is fully dissolved and is got rid of by the sewage draining exit 19 bottom hybrid filtering tank 1 again.(before and after filter screen pressure reduction alarm settings access PLC).Then through entering the three-level filter system in precise filtering tank 2 tank cavity communicating pipe 7, the effect of three-level filter system is mainly by high-new scavenging material and technology---the absorption filter element made by amino composite nano materials, to to be separated out by steam and the sodium ascorbyl phosphate ion brought out carries out last absorption, precipitate, got rid of (the same) by the sewage draining exit 19 bottom precise filtering tank 2 by washing precipitate fully to dissolve to filter-core back-flushing by supplementing water, steam is discharged finally by the steam outlet pipe 9 of precise filtering tank 2 again.When detect from steam outlet pipe 9 discharge vapor (steam) temperature pressure lower than setting value time, by regulating the valve of the admission electric control valve on hybrid filtering tank 1 end cap portions working steam steam inlet pipe 4, regulate and control the throttle flow of working steam steam inlet pipe 4 input service steam, increase working steam amount to improve the final heat enthalpy value exporting steam, the low-pressure saturated steam heated in tank body increases enthalpy difference compensation rate, and then makes the vapor (steam) temperature force value of output meet the requirement of next procedure.The described absorption filter element made by amino composite nano materials, it reaches as high as 85-97% to Phosphate Adsorption rate.
The present embodiment recovery boiler blowdown water volume energy saving profit is settled accounts:
A boiler reclaims the calculating of blowdown water by minimum blowdown rate 2%
The boiler of 1 boiler capacity 240 tons/hour, boiler blow-off water pressure 10.3MPa, temperature 312 DEG C, by the blowdown rate of the minimum evaporation capacity 2% of boiler, boiler wastewater discharges 4.8 tons of/hour high-grade used heat.Be incorporated to heat supply network (pressure 0.98MPa, temperature 280 DEG C) again after the hot grade of raising after being compensated its filtration, vaporization, heating enthalpy difference by working steam, its hot grade is equivalent to the calorific value of heating steam, can produce very considerable economic benefit after recovery.But this boiler wastewater of 4.8 tons/hour originally had and reclaimed the heat of a part of flash-off steam by platoon flash vessel, yield was about 24%, so the economic benefit that this heat of 24% that this recovery system should deduct original oxygen-eliminating device produces.
Energy valuation benchmark:
Heating steam pressure 0.98Mpa temperature 280 DEG C, steam calorific value is pressed: 70.3 × 10
4kcal/ ton; Steam price 150 yuan/ton accounting, runs clearing in 8000 hours per year:
Steam Recovery benefit can be produced: the economic benefit of the boiler blow-off waste heat generation of recovery: ton/hour × 8000 hours × 150 yuan × 76%(former platoon flash vessel recovery surplus)=437.76 ten thousand yuan
Indirect recovery benefit: reclaim water for industrial use 28800 tons X6 yuan/ton=17.2 ten thousand yuan,
Year energy-conservation total revenue: platoon reclaims the indirect benefit 170,000 yuan of benefit 4,370,000 yuan+recycle-water
=457 ten thousand yuan.
To sum up, blowdown water after dilatation, vaporization, absorption, filtration, purification, is changed into low-pressure saturated steam or superheated steam, then is incorporated to heat supply webmaster by a kind of boiler blow-off waste water boiler blowdown water enthalpy difference compensation dilatation purification recovery device of the present embodiment; When the setting value of temperature lower than heat supply webmaster, enthalpy difference compensation can also be carried out by hot operation steam, reach the output steam with heat supply network corresponding temperature, thus the maximized recycling of the used heat accomplished, accomplish that Waste Heat Recovery utilization rate reaches more than 98.5%, thoroughly solve boiler blow-off loss problem; And whole apparatus structure is simple, easy to operate and cost is low.
Embodiment 3
A kind of boiler blow-off waste water enthalpy difference of the present embodiment compensates dilatation purification recovery device, as shown in Figure 3, and the precise filtering tank 2 comprise hybrid filtering tank 1, being communicated with hybrid filtering tank 1; Described hybrid filtering tank 1 is provided with feet 20.Described hybrid filtering tank 1 is connected with end cap 21 respectively by flange with precise filtering tank 2 tank body two ends.
Wherein said hybrid filtering tank 1 tank body is provided with boiler blow-off waste water water inlet pipe 3 and working steam steam inlet pipe 4; Described boiler blow-off waste water water inlet pipe 3 is connected with the venturi-type eductors 5 be arranged in hybrid filtering tank 1 tank body respectively with working steam steam inlet pipe 4, and venturi-type eductors 5 is made up of the steel alloy of 12Gr1MoV.Described boiler blow-off waste water water inlet pipe 3 is provided with nozzle 22, and described nozzle 22 is placed in venturi-type eductors 5, directly accesses the mixing chamber of venturi-type eductors 5; Wherein the end of working steam steam inlet pipe 4 is connected with venturi-type eductors 5 large footpath mouth.
The absorption filter element 6 that described venturi-type eductors 5 tentatively filters amino composite nano materials with the cylindrical shape be arranged in hybrid filtering tank 1 tank body is communicated with; precision stainless steel silk screen 23 is set with outside the absorption filter element 6 that described cylindrical shape tentatively filters amino composite nano materials; be set with 3-5mm stainless steel punched-plate 24 outside described precision stainless steel silk screen 23, described stainless steel punched-plate 24 as protective cover to prevent from being washed away by high steam.The outer wall of the stainless steel punched-plate 24 of described close venturi-type eductors 5 is set with the first flange 10, the tube wall of the venturi-type eductors 5 of described close stainless steel punched-plate 24 is provided with the second flange 11, is connected by screw between the first described flange 10 and the second flange 11.Described hybrid filtering tank 1 was communicated with precise filtering tank 2 by 1 communicating pipe 7, and the communicating pipe 7 of hybrid filtering tank 1 and precise filtering tank 2 junction passes through Flange joint; And described hybrid filtering tank 1 with the support column 12 the same with communicating pipe 7 size is also installed between precise filtering tank 2; The absorption filter element 8 of the amino composite nano materials of arc secondary filter is installed in described precise filtering tank 2, precision stainless steel silk screen 23 is set with outside the absorption filter element 8 of the amino composite nano materials of described arc secondary filter, be set with 3-5mm stainless steel punched-plate 24 outside described precision stainless steel silk screen 23, described stainless steel punched-plate 24 as protective cover to prevent from being washed away by high steam; Precise filtering tank 2 internal face of absorption filter element 8 both sides of the amino composite nano materials of described arc secondary filter is separately installed with groove baffle plate 13.Described precise filtering tank 2 is provided with steam outlet pipe 9, and for the discharge of water vapour in tank body, the water vapour of eliminating is conveyed into low pressure heating steam pipe network.
Described precise filtering tank 2 offers water supplement port 14, and described precise filtering tank 2 is provided with thermometer 15 and pressure gauge 16; Described precise filtering tank 2 is also provided with the exhaust outlet 17 being provided with safety valve, the safety excretion during exhaust outlet 17 of safety valve level superfine for pressure is installed.Described hybrid filtering tank 1 and precise filtering tank 2 offer sewage draining exit 19 respectively.
Described hybrid filtering tank 1 outer wall is also provided with PLC 18, described boiler blow-off waste water water inlet pipe 3, working steam steam inlet pipe 4 and steam outlet pipe 9 is separately installed with into water electric control valve (not shown), admission electric control valve (not shown) and goes out vapour electric control valve (not shown); And described PLC 18 respectively by circuit with water inlet electric control valve, admission electric control valve, go out vapour electric control valve and be connected.
The using method of the present embodiment device is: from each boiler-steam dome out 312 DEG C, the HTHP blowdown water of 10.3MPa connects by blowdown the boiler blow-off waste water water inlet pipe 3 that female pipe enters the compensation appearance purification recovery device of enthalpy difference, then enters in hybrid filtering tank 1, 280 DEG C, 0.98MPa working steam (directly can utilize the steam in low pressure heating steam pipe network) after working steam steam inlet pipe 4 with 312 DEG C, the HTHP blowdown water of 10.3MPa carries out step-down in venturi-type eductors 5, dilatation, vaporization are carried out mixing and enthalpy difference fully and compensated, wherein 312 DEG C, during the entering of the HTHP blowdown water of 10.0MPa and working steam, initial flow is than being 1:(5-20), namely carry out coagulation to improve flow velocity, reduce pressure, sufficient steam-water mixing obtains sufficient enthalpy difference and compensates and then make liquid waste water be converted to the saturated of low pressure or superheated steam state, boiler blow-off waste water vapor, enter after the anemostat of venturi-type eductors 5 after mixing enthalpy difference compensates and block absorption filter element 6 that filter tentatively filters amino composite nano materials and carry out secondary super large dilatation step-down and filter, the effect that secondary blocks filter mainly reduces steam flow rate, stop vaporization precipitate, silica, calcium ions and magnesium ions deposit etc. is taken out of with steam, run precipitate after a period of time to adhere to gradually and be accumulated on filter core, pressure reduction before and after filter core can be caused to increase, after before and after filter core, pressure reduction reaches setting pressure reduction, by supplementing water pipe, backwash is carried out to filter core with cleaning supplementary water, precipitate is fully dissolved and is got rid of by the sewage draining exit 19 bottom hybrid filtering tank 1 again.(before and after filter screen pressure differential resetting alarming value access PLC) is then through entering the three-level filter system in precise filtering tank 2 tank cavity communicating pipe 7, the effect of three-level filter system is mainly by high-new scavenging material and technology---the absorption filter element made by amino composite nano materials, to to be separated out by steam and the sodium ascorbyl phosphate ion brought out carries out last absorption, precipitate, got rid of (the same) by the sewage draining exit 19 bottom precise filtering tank 2 again by washing precipitate fully to dissolve to filter-core back-flushing by supplementing water, steam is discharged finally by the steam outlet pipe 9 of precise filtering tank 2.When detect from steam outlet pipe 9 discharge vapor (steam) temperature pressure lower than setting value time, by regulating the valve of the admission electric control valve on hybrid filtering tank 1 end cap portions working steam steam inlet pipe 4, regulate and control the throttle flow of working steam steam inlet pipe 4 input service steam, increase working steam amount to improve the final heat enthalpy value exporting steam, the low-pressure saturated steam heated in tank body increases enthalpy difference compensation rate, and then makes the vapor (steam) temperature force value of output meet the requirement of next procedure.The described absorption filter element made by amino composite nano materials, it reaches as high as 85-97% to Phosphate Adsorption rate.
The present embodiment recovery boiler blowdown water volume energy saving profit is settled accounts:
A boiler reclaims the calculating of blowdown water by minimum blowdown rate 2%
The boiler of 1 boiler capacity 240 tons/hour, boiler blow-off water pressure 10.3MPa, temperature 312 DEG C, by the blowdown rate of the minimum evaporation capacity 2% of boiler, boiler wastewater discharges 4.8 tons of/hour high-grade used heat.Be incorporated to heat supply network (pressure 0.98MPa, temperature 280 DEG C) again after the hot grade of raising after being compensated its filtration, vaporization, heating enthalpy difference by working steam, its hot grade is equivalent to the calorific value of heating steam, can produce very considerable economic benefit after recovery.But this boiler wastewater of 4.8 tons/hour originally had and reclaimed the heat of a part of flash-off steam by platoon flash vessel, yield was about 24%, so the economic benefit that this heat of 24% that this recovery system should deduct original oxygen-eliminating device produces.
Energy valuation benchmark:
Heating steam pressure 0.98Mpa temperature 280 DEG C, steam calorific value is pressed: 70.3 × 10
4kcal/ ton; Steam price 150 yuan/ton accounting, runs clearing in 8000 hours per year:
Steam Recovery benefit can be produced: the economic benefit of the boiler blow-off waste heat generation of recovery: ton/hour × 8000 hours × 150 yuan × 76%(former platoon flash vessel recovery surplus)=437.76 ten thousand yuan.
Indirect recovery benefit: reclaim water for industrial use 28800 tons X6 yuan/ton=17.2 ten thousand yuan,
Year energy-conservation total revenue: platoon reclaims the indirect benefit 170,000 yuan of benefit 4,370,000 yuan+recycle-water
=454 ten thousand yuan.
To sum up, blowdown water after dilatation, vaporization, absorption, filtration, purification, is changed into low-pressure saturated steam or superheated steam, then is incorporated to heat supply webmaster by a kind of boiler blow-off waste water boiler blowdown water enthalpy difference compensation dilatation purification recovery device of the present embodiment; When the setting value of temperature lower than heat supply webmaster, enthalpy difference compensation can also be carried out by hot operation steam, reach the output steam with heat supply network corresponding temperature, thus the maximized recycling of the used heat accomplished, accomplish that Waste Heat Recovery utilization rate reaches more than 98.5%, thoroughly solve boiler blow-off loss problem; And whole apparatus structure is simple, easy to operate and cost is low.
Claims (10)
1. boiler blow-off waste water enthalpy difference compensates a dilatation purification recovery device, it is characterized in that, the precise filtering tank (2) comprise hybrid filtering tank (1), being communicated with hybrid filtering tank (1); Wherein said hybrid filtering tank (1) tank body is provided with boiler blow-off waste water water inlet pipe (3) and working steam steam inlet pipe (4); Described boiler blow-off waste water water inlet pipe (3) and working steam steam inlet pipe (4) are connected with the venturi-type eductors (5) be arranged in hybrid filtering tank (1) tank body respectively, described boiler blow-off waste water water inlet pipe (3) is provided with nozzle (22), and described nozzle (22) is placed in venturi-type eductors (5); Described venturi-type eductors (5) is communicated with the absorption filter element (6) of the amino composite nano materials of preliminary filtration be arranged in hybrid filtering tank (1) tank body; Described hybrid filtering tank (1) was communicated with precise filtering tank (2) by communicating pipe (7); The absorption filter element (8) of the amino composite nano materials of secondary filter is installed in described precise filtering tank (2); Described precise filtering tank (2) is provided with steam outlet pipe (9).
2. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, it is characterized in that, the absorption filter element (6) of the described amino composite nano materials of preliminary filtration tentatively filters the absorption filter element of amino composite nano materials for cylindrical shape; Be set with precision stainless steel silk screen (23) outside the absorption filter element (6) of the described amino composite nano materials of preliminary filtration, outside described precision stainless steel silk screen (23), be set with 3-5mm stainless steel punched-plate (24); The outer wall of the stainless steel punched-plate (24) of described close venturi-type eductors (5) is set with the first flange (10), the tube wall of the venturi-type eductors (5) of described close stainless steel punched-plate (24) is provided with the second flange (11), is connected by screw between described the first flange (10) and the second flange (11).
3. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, it is characterized in that, described hybrid filtering tank (1) with pass through between precise filtering tank (2) to be communicated with 1 communicating pipe (7); And described hybrid filtering tank (1) with the support column (12) the same with communicating pipe (7) size is also installed between precise filtering tank (2).
4. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 3 compensates dilatation purification recovery device, it is characterized in that, is provided with the absorption filter element (8) of the amino composite nano materials of cylindrical shape secondary filter in described precise filtering tank (2); Be set with precision stainless steel silk screen (23) outside the absorption filter element (8) of the amino composite nano materials of described secondary filter, outside described precision stainless steel silk screen (23), be set with 3-5mm stainless steel punched-plate (24); The outer wall of described precision stainless steel silk screen (23) is set with three-flange (25), 4th flange (26) is installed between the outer wall of described stainless steel punched-plate (24) and the tube wall of precise filtering tank (2), is connected by screw between described three-flange (25) and the 4th flange (26).
5. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 3 compensates dilatation purification recovery device, it is characterized in that, the absorption filter element (8) of the amino composite nano materials of arc secondary filter is installed in described precise filtering tank (2), be set with precision stainless steel silk screen (23) outside the absorption filter element (8) of the amino composite nano materials of described secondary filter, outside described precision stainless steel silk screen (23), be set with 3-5mm stainless steel punched-plate (24); Precise filtering tank (2) internal face of absorption filter element (8) both sides of the amino composite nano materials of described arc secondary filter is separately installed with groove baffle plate (13).
6. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, and it is characterized in that, described hybrid filtering tank (1) is communicated with respectively by 2 communicating pipe (7) with between precise filtering tank (2); The absorption filter element (8) of the amino composite nano materials of arc secondary filter is installed in described precise filtering tank (2), be set with precision stainless steel silk screen (23) outside the absorption filter element (8) of the amino composite nano materials of described secondary filter, outside described precision stainless steel silk screen (23), be set with 3-5mm stainless steel punched-plate (24); And the length of the absorption filter element (8) of the amino composite nano materials of described arc secondary filter be greater than 2 communicating pipe (7) far-end outer wall between distance; Precise filtering tank (2) internal face of absorption filter element (8) both sides of the amino composite nano materials of described arc secondary filter is separately installed with groove baffle plate (13).
7. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, it is characterized in that, described precise filtering tank (2) offers water supplement port (14), and described precise filtering tank (2) is provided with thermometer (15) and pressure gauge (16); Described precise filtering tank (2) is also provided with the exhaust outlet (17) being provided with safety valve.
8. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, it is characterized in that, described hybrid filtering tank (1) outer wall is also provided with PLC (18), described boiler blow-off waste water water inlet pipe (3), working steam steam inlet pipe (4) and steam outlet pipe (9) is separately installed with into water electric control valve, admission electric control valve and goes out vapour electric control valve; And described PLC (18) respectively by circuit with water inlet electric control valve, admission electric control valve, go out vapour electric control valve and be connected.
9. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, it is characterized in that, described hybrid filtering tank (1) and precise filtering tank (2) offer sewage draining exit (19) respectively.
10. a kind of boiler blow-off waste water enthalpy difference as claimed in claim 1 compensates dilatation purification recovery device, it is characterized in that, described hybrid filtering tank (1) is provided with feet (20); Described hybrid filtering tank (1) is connected with end cap (21) respectively by flange with precise filtering tank (2) tank body two ends.
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CN111470566A (en) * | 2020-05-20 | 2020-07-31 | 杭州万得斯环保科技有限公司 | Boiler waste water desalination mixing arrangement |
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Effective date of registration: 20210913 Address after: 310000 room 519, floor 5, No. 1190, Linding Road, Jianggan District, Hangzhou, Zhejiang Patentee after: Zhejiang Zhida Energy Technology Co.,Ltd. Address before: 312000 No. 209, Wurong village, sunduan Town, Yuecheng District, Shaoxing City, Zhejiang Province Patentee before: Ma Jianying |