CN104927715A - Anti-aging insulating polyolefin adhesive and preparation method thereof - Google Patents
Anti-aging insulating polyolefin adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN104927715A CN104927715A CN201510397505.0A CN201510397505A CN104927715A CN 104927715 A CN104927715 A CN 104927715A CN 201510397505 A CN201510397505 A CN 201510397505A CN 104927715 A CN104927715 A CN 104927715A
- Authority
- CN
- China
- Prior art keywords
- parts
- ageing
- polyolefine
- stick
- resistant insulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
An anti-aging insulating polyolefin adhesive is characterized by being composed of, by weight, 12-15 parts of di-iso-decylphthalate, 5-10 parts of beta-diketone, 5-10 parts of ammonium polyphosphate, 10-15 parts of ethylene-vinyl acetate copolymer, 8-12 parts of magnesium hydroxide, 15-18 parts of chlorosulfonated polyethylene, 10-15 parts of polyving akohol. 10-15 parts of acrylic ester, 1-3 parts of catalyzer, 1-3 parts of mildew preventive, 10-15 parts of gelatin, 1-3 parts of curing agent, 10-15 parts of lignocellulose and 33-47 parts of deionized water. A preparation method has the advantages of being high in activity, high in stability, free of toxin, environmentally friendly, low in price and the like; the invention meanwhile provides the modified preparation method which is scientific, reasonable and easy to implement.
Description
Technical field
The present invention relates to a kind of tackiness agent, be specifically related to a kind of ageing-resistant insulation polyolefine stick and preparation method thereof.
Background technology
In recent years, rapidly, the control of motor-car unit, high speed unit became increasingly complex, and electrical control equipment gets more and more in national track traffic development, and its stick demand is inevitable to be increased thereupon, simultaneously also thereupon more and more stricter to the performance requriements of materials of adhesive.Polyolefine material also exists the shortcomings such as bad mechanical property, weathering resistance is poor, ageing resistance is poor in the market, and district is limited in gradually in Highrise buildings and uses non-environment-friendly adhesive throughout the country.Wherein common tackiness agent chemistry poor performance in weathering resistance, erosion resistance, chemical proofing, anti-stain characteristic etc., environment-friendly aqueous nanometer tackiness agent has the incomparable overall merit of other sizing agent, is subject to the favor of people gradually.And improving constantly along with people's quality of the life, it is also proposed higher requirement to the performance of tackiness agent, wherein weathering resistance is the problem that people pay close attention to the most.
Summary of the invention
The object of the invention is just to provide a kind of ageing-resistant insulation polyolefine stick and preparation method thereof, has active high, good stability, asepsis environment-protecting, the advantage such as cheap; Invention also provides the preparation method of modification, scientific and reasonable, simple.
A kind of ageing-resistant insulation polyolefine stick, is characterized in that: described tackiness agent comprises following weight parts and carries out proportioning than component: Di Iso Decyl Phthalate 12-15 part, beta-diketon 5-10 part, ammonium polyphosphate 5-10 part, ethylene-vinyl acetate copolymer 10-15 part, magnesium hydroxide 8-12 part, chlorosulfonated polyethylene 15-18 part; Polyvinyl alcohol 10-15 part, acrylate 10-15 part, catalyzer 1-3 part, mould inhibitor 1-3 part, gelatin 10-15 part, solidifying agent 1-3 part, lignocellulose 10-15 part, deionized water 33-47 part.
Described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more.
Described catalyzer is dibutyltin dilaurate.
Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
A preparation method for ageing-resistant insulation polyolefine stick, described preparation process is as follows:
(1) in a kettle., add deionized water 17-20 part, polyvinyl alcohol 10-15 part, gelatin 10-15 part and Di Iso Decyl Phthalate 12-15 part, beta-diketon 5-10 part, ammonium polyphosphate 5-10 part, ethylene-vinyl acetate copolymer 10-15 part, magnesium hydroxide 8-12 part, chlorosulfonated polyethylene 15-18 part, heat to temperature be 70-75 DEG C, stir and mixed by mentioned component, insulation 2-3 hour, can obtain solution A;
(2) again in another reactor, add deionized water 16-27 part, lignocellulose 10-15 part, acrylate 10-15 part, is warming up to 70-75 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 1-3 part, at the temperature of 70-75 DEG C, be incubated 30 minutes, add solidifying agent 1-3 part successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 1-3 part, stir finished product after half an hour.
Beneficial effect:
The present invention is directed to the above-mentioned defect of current tackiness agent and launch, plasticizer and the ethylene-vinyl acetate copolymer of the Di Iso Decyl Phthalate that the present invention adds, beta-diketon, ammonium polyphosphate composition are arranged in pairs or groups, ageing resistance, processing characteristics is improved while improving mechanical property, increase the snappiness of cable, ammonium polyphosphate has the effect in condensed phase simultaneously, and magnesium hydroxide combination has good flame retardant effect; The chlorosulfonated polyethylene added has heat-resisting and lower temperature resistance, oil-proofness, flame resistivity, wear resistance; Tackiness agent of the present invention, has cost low, pollutes few, few to harm, erasibility is good, is all better than conventional adhesive agent simultaneously, is suitable for extensive operation building requirements in the traditional performances such as water tolerance, alkali resistance, scrubbing property of scuff, artificial ageing resistance.
Embodiment
Example illustrates:
Embodiment 1,
A kind of ageing-resistant insulation polyolefine stick, is characterized in that: described tackiness agent comprises following weight parts and carries out proportioning than component: Di Iso Decyl Phthalate 12 parts, beta-diketon 5 parts, ammonium polyphosphate 5 parts, ethylene-vinyl acetate copolymer 10 parts, magnesium hydroxide 8 parts, chlorosulfonated polyethylene 15 parts; Polyvinyl alcohol 10 parts, acrylate 10 parts, catalyzer 1 part, mould inhibitor 1 part, 10 parts, gelatin, 1 part, solidifying agent, lignocellulose 10 parts, deionized water 33 parts.
Described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more.
Described catalyzer is dibutyltin dilaurate.
Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
A preparation method for ageing-resistant insulation polyolefine stick, described preparation process is as follows:
(1) in a kettle., add deionized water 17 parts, polyvinyl alcohol 10 parts, 10 parts, gelatin and Di Iso Decyl Phthalate 12 parts, beta-diketon 5 parts, ammonium polyphosphate 5 parts, ethylene-vinyl acetate copolymer 10 parts, magnesium hydroxide 8 parts, chlorosulfonated polyethylene 15 parts, heat to temperature be 70 DEG C, stir and mentioned component is mixed, be incubated 2 hours, can solution A be obtained;
(2) again in another reactor, add deionized water 16 parts, lignocellulose 10 parts, acrylate 10 parts, is warming up to 70 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 1 part, at the temperature of 70 DEG C, be incubated 30 minutes, add 1 part, solidifying agent successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 1 part, stir finished product after half an hour.
Embodiment 2,
A kind of ageing-resistant insulation polyolefine stick, is characterized in that: described tackiness agent comprises following weight parts and carries out proportioning than component: Di Iso Decyl Phthalate 15 parts, beta-diketon 10 parts, ammonium polyphosphate 10 parts, ethylene-vinyl acetate copolymer 15 parts, magnesium hydroxide 12 parts, chlorosulfonated polyethylene 18 parts; Polyvinyl alcohol 15 parts, acrylate 15 parts, catalyzer 3 parts, mould inhibitor 3 parts, 15 parts, gelatin, 3 parts, solidifying agent, lignocellulose 15 parts, deionized water 47 parts.
Described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more.
Described catalyzer is dibutyltin dilaurate.
Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
A preparation method for ageing-resistant insulation polyolefine stick, described preparation process is as follows:
(1) in a kettle., add deionized water 20 parts, polyvinyl alcohol 15 parts, 15 parts, gelatin and Di Iso Decyl Phthalate 15 parts, beta-diketon 10 parts, ammonium polyphosphate 10 parts, ethylene-vinyl acetate copolymer 15 parts, magnesium hydroxide 12 parts, chlorosulfonated polyethylene 18 parts, heat to temperature be 75 DEG C, stir and mentioned component is mixed, be incubated 3 hours, can solution A be obtained;
(2) again in another reactor, add deionized water 27 parts, lignocellulose 15 parts, acrylate 15 parts, is warming up to 75 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 3 parts, at the temperature of 75 DEG C, be incubated 30 minutes, add 3 parts, solidifying agent successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 3 parts, stir finished product after half an hour.
Plasticizer and the ethylene-vinyl acetate copolymer of the Di Iso Decyl Phthalate that the present invention adds, beta-diketon, ammonium polyphosphate composition are arranged in pairs or groups, ageing resistance, processing characteristics is improved while improving mechanical property, increase the snappiness of cable, ammonium polyphosphate has the effect in condensed phase simultaneously, and magnesium hydroxide combination has good flame retardant effect; The chlorosulfonated polyethylene added has heat-resisting and lower temperature resistance, oil-proofness, flame resistivity, wear resistance; Tackiness agent of the present invention, has cost low, pollutes few, few to harm, erasibility is good, is all better than conventional adhesive agent simultaneously, is suitable for extensive operation building requirements in the traditional performances such as water tolerance, alkali resistance, scrubbing property of scuff, artificial ageing resistance.
Claims (5)
1. an ageing-resistant insulation polyolefine stick, is characterized in that: described tackiness agent comprises following weight parts and carries out proportioning than component: Di Iso Decyl Phthalate 12-15 part, beta-diketon 5-10 part, ammonium polyphosphate 5-10 part, ethylene-vinyl acetate copolymer 10-15 part, magnesium hydroxide 8-12 part, chlorosulfonated polyethylene 15-18 part; Polyvinyl alcohol 10-15 part, acrylate 10-15 part, catalyzer 1-3 part, mould inhibitor 1-3 part, gelatin 10-15 part, solidifying agent 1-3 part, lignocellulose 10-15 part, deionized water 33-47 part.
2. one according to claim 1 ageing-resistant insulation polyolefine stick agent, is characterized in that: described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more.
3. one according to claim 1 ageing-resistant insulation polyolefine stick, is characterized in that: described catalyzer is dibutyltin dilaurate.
4. one according to claim 1 ageing-resistant insulation polyolefine stick, is characterized in that: described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
5. a preparation method for ageing-resistant insulation polyolefine stick, is characterized in that: described preparation process is as follows:
(1) in a kettle., add deionized water 17-20 part, polyvinyl alcohol 10-15 part, gelatin 10-15 part and Di Iso Decyl Phthalate 12-15 part, beta-diketon 5-10 part, ammonium polyphosphate 5-10 part, ethylene-vinyl acetate copolymer 10-15 part, magnesium hydroxide 8-12 part, chlorosulfonated polyethylene 15-18 part, heat to temperature be 70-75 DEG C, stir and mixed by mentioned component, insulation 2-3 hour, can obtain solution A;
(2) again in another reactor, add deionized water 16-27 part, lignocellulose 10-15 part, acrylate 10-15 part, is warming up to 70-75 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 1-3 part, at the temperature of 70-75 DEG C, be incubated 30 minutes, add solidifying agent 1-3 part successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 1-3 part, stir finished product after half an hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510397505.0A CN104927715A (en) | 2015-07-09 | 2015-07-09 | Anti-aging insulating polyolefin adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510397505.0A CN104927715A (en) | 2015-07-09 | 2015-07-09 | Anti-aging insulating polyolefin adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104927715A true CN104927715A (en) | 2015-09-23 |
Family
ID=54115150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510397505.0A Pending CN104927715A (en) | 2015-07-09 | 2015-07-09 | Anti-aging insulating polyolefin adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104927715A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07164598A (en) * | 1993-10-19 | 1995-06-27 | Sumitomo Chem Co Ltd | Acrylic resin plate |
| JP2004083649A (en) * | 2002-08-23 | 2004-03-18 | Chuo Rika Kogyo Corp | Aqueous dispersion and adhesive using the same |
| US20080113206A1 (en) * | 2006-11-15 | 2008-05-15 | Dean Edward Hoy | Waterborne adhesives for elastomers |
| CN101845282A (en) * | 2010-01-18 | 2010-09-29 | 宝鸡市广仁生物科技有限公司 | Components of armyworm adhesive and method for preparing same |
| CN102676086A (en) * | 2012-05-23 | 2012-09-19 | 宝鸡市广仁生物科技有限公司 | Mosquito attracting and sticking adhesive, and preparation and application thereof |
| CN103571373A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Ageing-resistant hot melt adhesive |
| CN104531007A (en) * | 2014-12-23 | 2015-04-22 | 安徽助成信息科技有限公司 | Flame-retardant EVA (ethylene-vinyl acetate) hot-melt adhesive |
-
2015
- 2015-07-09 CN CN201510397505.0A patent/CN104927715A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07164598A (en) * | 1993-10-19 | 1995-06-27 | Sumitomo Chem Co Ltd | Acrylic resin plate |
| JP2004083649A (en) * | 2002-08-23 | 2004-03-18 | Chuo Rika Kogyo Corp | Aqueous dispersion and adhesive using the same |
| US20080113206A1 (en) * | 2006-11-15 | 2008-05-15 | Dean Edward Hoy | Waterborne adhesives for elastomers |
| CN101845282A (en) * | 2010-01-18 | 2010-09-29 | 宝鸡市广仁生物科技有限公司 | Components of armyworm adhesive and method for preparing same |
| CN102676086A (en) * | 2012-05-23 | 2012-09-19 | 宝鸡市广仁生物科技有限公司 | Mosquito attracting and sticking adhesive, and preparation and application thereof |
| CN103571373A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Ageing-resistant hot melt adhesive |
| CN104531007A (en) * | 2014-12-23 | 2015-04-22 | 安徽助成信息科技有限公司 | Flame-retardant EVA (ethylene-vinyl acetate) hot-melt adhesive |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101280081B (en) | Weatherproof halogen-free flame-retardant termite-resistant rodent-resistant electric wire and cable | |
| CN102504509A (en) | Unsaturated polyester glass fiber reinforced molding compound and application thereof | |
| CN103614025A (en) | Environmentally-friendly highly-elastic waterproof coating | |
| CN103146058B (en) | Toughened polypropylene composite material and preparation method thereof | |
| CN104650714A (en) | Flame-retardant waterproof coating for interior wall of building and preparation method thereof | |
| CN103725246A (en) | Hydrophobic bonder for glass fiber cotton | |
| CN104650726A (en) | Thermal insulation high-elasticity waterproof paint and preparation method thereof | |
| CN104927715A (en) | Anti-aging insulating polyolefin adhesive and preparation method thereof | |
| CN104946140A (en) | Anti-mould corrosion-resistant flame-retardant polyethylene adhesive and preparation method thereof | |
| CN105273675B (en) | A kind of water-based fireproof binding agent | |
| CN104497946A (en) | Adhesive resistant to water and deformation | |
| CN104312380A (en) | Aromatic epoxy resin composite material for indoor coating and manufacturing method of aromatic epoxy resin composite material | |
| CN102504487B (en) | Insulation sealing plaster used for wire terminal | |
| CN108929498B (en) | Polyamino cyclotriphosphazene synergistic flame-retardant smoke-suppressing PVC and preparation method thereof | |
| CN104673088A (en) | Waterproof coating for building roof and preparation method of waterproof coating | |
| CN105462300B (en) | A kind of coating and preparation method thereof | |
| CN104194115A (en) | Antioxygenic and adhesive rheological agent cable accessory material | |
| CN106398535A (en) | Anticorrosion coating for cable | |
| CN101824254A (en) | Organosilicon-modified polyvinyl butyral coil coating | |
| CN106300043B (en) | A kind of fire-retardant power distribution cabinet | |
| CN105665964A (en) | Environment-friendly welding rod coating with waterproof and dampproof functions and preparation method thereof | |
| CN104610803A (en) | Activated rice hull ash-containing polyethylene powder coating for metal corrosion prevention and preparation method thereof | |
| CN103980773A (en) | Flame retardant coating for exterior wall | |
| CN104946170A (en) | Environment-friendly water-based nanometer adhesive and preparing method thereof | |
| CN108689633A (en) | A kind of environment-friendly type building material and preparation method thereof with flame retarding function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150923 |