CN104927550A - Coating flame resistant liquid and preparation method thereof - Google Patents
Coating flame resistant liquid and preparation method thereof Download PDFInfo
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- CN104927550A CN104927550A CN201510291023.7A CN201510291023A CN104927550A CN 104927550 A CN104927550 A CN 104927550A CN 201510291023 A CN201510291023 A CN 201510291023A CN 104927550 A CN104927550 A CN 104927550A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K2003/026—Phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Building Environments (AREA)
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses coating flame resistant liquid and a preparation method thereof. The coating flame resistant liquid is prepared from the following raw materials in parts by weight: 10-20 parts of ethyl alcohol, 5-10 parts of coated red phosphorus flame retardant, 5-10 parts of a carbonized agent, 5-10 parts of expansible graphite and 100 parts of phenolic resin. The preparation method comprises the following steps: mixing the coated red phosphorus flame retardant and the ethyl alcohol according to a ratio, and stirring the mixture to dissolve and disperse the coated red phosphorus flame in the ethyl alcohol; then adding the carbonized agent, the expansible graphite and the phenolic resin, and uniformly stirring to obtain the coating flame resistant liquid. The coating flame resistant liquid is safe, environment-friendly, and good in flame resistant effect.
Description
Technical field
The invention belongs to building material technical field, be specifically related to a kind of coating fire resistant fluid and preparation method thereof.
Background technology
EPS warming plate can as exterior wall finishing material, high insulating effect, but its fire prevention and flame retardant properties poor, govern the development of EPS warming plate.The flame retardant properties being improved EPS warming plate by the interpolation of bromide fire retardant is had in existing scheme, the shortcoming of bromide fire retardant is that raw smoke which is large, perishable, generation poison gas, the hydracid mist corrodible metal device produced, and very major injury is caused to the respiratory organs of human body, especially polybromodiphenyl ether can generate multiple carcinogens, and therefore people are actively seeking the substitute of bromide fire retardant.
Summary of the invention
The object of the invention is for above problem, a kind of coating fire resistant fluid and preparation method thereof is provided, there is good flame retardant effect.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of coating fire resistant fluid, is made up of following raw material by weight:
In preferred scheme, be made up of following raw material by weight: ethanol 10-20 part, Wrapped up Phosphorus Fire Retardant 5-10 part, carbonized agent 5-10 part, expansible black lead 5-10 part, 100 parts, resol.
Be made up of following raw material by weight: ethanol 10 parts, Wrapped up Phosphorus Fire Retardant 5 parts, carbonized agent 5 parts, expansible black lead 5 parts, 100 parts, resol.Coating fire resistant fluid prepared by this formula can reach fire-protection standard, and advantage of lower cost.
Described carbonized agent is polyphosphoric acid amine.Allowed by the use of carbonized agent coating is fire-retardant also forms charring layer thus deeply the spreading of the isolated intensity of a fire, such as, after fire resistant fluid coated by the EPS sheet material that 5 cm are thick, accessible effect is: using flame spray gun to burn more than 5 minutes these sheet materials in a point can not be run through by the intensity of a fire.
The expansion multiplying power of described expansible black lead is at more than 300mL/g, and order number is less than 100 orders, and the lower effect of order number is better.
The order number of described Wrapped up Phosphorus Fire Retardant is greater than 1500 orders, and particle is more thin better, and phosphorus content is at 70-75%.
Before described coating fire resistant fluid uses, be that 5:1 adds solidifying agent by the weight ratio of coating fire resistant fluid and solidifying agent, described solidifying agent is resol solidifying agent.Made by the use of solidifying agent that coating is fire-retardant quick and completely can solidify to form protective membrane.General employing NL resol special curing agent, composition is benzene sulfonyl chloride, toluene sulfonyl chloride and sulfovinic acid.
Described ethanol and the weight ratio of Wrapped up Phosphorus Fire Retardant are 2:1.Wrapped up Phosphorus Fire Retardant easily condenses into purees, can carry out partial solvent and fully disperse, prevent sedimentation from condensing by ethanol.
The preparation method of above-mentioned coating fire resistant fluid, concrete steps are:
1) by proportioning, Wrapped up Phosphorus Fire Retardant is mixed with ethanol, stir, make it dissolve and be scattered in ethanol;
2) mixture of step 1) gained is added in resol stir, then add carbonized agent and stir, finally add expansible black lead and stir and can obtain coating fire resistant fluid.
Step 1) in Wrapped up Phosphorus Fire Retardant when mixing with ethanol, the time of stirring is 10-20min.
Step 2) in mixture when adding in resol churning time be 5-10min, the churning time adding carbonized agent is 10-20min, and adding the churning time after expansible black lead is 10-20 minute.
The coating fire resistant fluid prepared before use, should stir at set intervals, guarantees on average within every 3 hours, to stir more than 30 minutes, best stirring per hour more than 10 minutes; Prevent its precipitation and later stage from adhering to uneven.
The invention has the beneficial effects as follows:
1, this coating fire resistant fluid has A level flame retardant resistance, and can carry out overlay film by p-poly-phenyl ethene (EPS) particle, after steam molding, density is high
,heat insulation capacity at least exceeds 30% than common EPS; Contribute to improving efficiency and the discharge reducing carbonic acid gas.This coating fire resistant fluid successfully solves the problem of the fire resistance difference of conventional EPS warming plate, more remains the original heat-insulating property of EPS warming plate and ventilative when reaching national exterior-wall heat insulation fireproof monitoring A level index, the superior performance such as waterproof.
2, in this coating fire resistant fluid containing expansible black lead, can reflective thermal radiation, can also absorb infrared rays, the performance of expansible black lead, significantly promotes thermal and insulating performance, thus reduces the thermosteresis in house.Form flameproof protection film by being attached on EPS particle by coating fire resistant fluid, form cellular charring layer when meeting fire, this charring layer can isolate the intensity of a fire, stops deeply spreading of the intensity of a fire, carries out fire prevention and reach flame retardant effect; Product itself containing toxic substance, does not meet ROHS monitoring standard, environmental protection of drawing materials, and unharmful substance volatilizees, and does not decompose and does not go mouldy, product burning low-smoke, and does not produce poisonous and contaminate environment gas.Such as, after the thick EPS sheet material coated fire resistant fluid of 5 cm, accessible effect is: use flame spray gun can not be run through by the intensity of a fire in a point more than 5 minutes these sheet materials that burn.
3, this coating fire resistant fluid is based on resol, because the particle of carbonized agent is less, easily disperses attachment, therefore first adds carbonized agent, then adds expansible black lead and adhere to, and makes it have charing and fire-retardant effect.
4, this coating fire resistant fluid is compared to bromide fire retardant, good flame retardation effect, and safety and environmental protection more; Alleviate product weight compared with the thermal insulation mortar material used with tradition, and heat-insulating property is better, is the ideal material replacing traditional fire retardant material.
Embodiment
Further illustrate the present invention below in conjunction with embodiment, but the scope of protection of present invention is not limited to the scope of embodiment statement.
Embodiment 1:
A kind of coating fire resistant fluid, be made up of following raw material by weight:
Ethanol 10 parts, Wrapped up Phosphorus Fire Retardant 5 parts, carbonized agent 5 parts, expansible black lead 5 parts, 100 parts, resol.
Its preparation methods steps is:
1) by proportioning, Wrapped up Phosphorus Fire Retardant is mixed with ethanol, stir, make it dissolve and be scattered in ethanol;
2) mixture of step 1) gained is joined in resol mix, then add carbonized agent, expansible black lead successively, stir and can obtain coating fire resistant fluid.
Embodiment 2:
A kind of coating fire resistant fluid, be made up of following raw material by weight:
Ethanol 15 parts, Wrapped up Phosphorus Fire Retardant 8 parts, carbonized agent 8 parts, expansible black lead 8 parts, 100 parts, resol.
Its preparation methods steps is:
1) by proportioning, Wrapped up Phosphorus Fire Retardant is mixed with ethanol, carry out stirring 10min, make it dissolve and be scattered in ethanol;
2) mixture of step 1) gained is added in resol stir 5min, then add carbonized agent and stir 10min, finally add expansible black lead and stir 10min and can obtain coating fire resistant fluid.
Embodiment 3:
A kind of coating fire resistant fluid, be made up of following raw material by weight:
Ethanol 20 parts, Wrapped up Phosphorus Fire Retardant 10 parts, carbonized agent 10 parts, expansible black lead 10 parts, 100 parts, resol.
Its preparation methods steps is:
1) by proportioning, Wrapped up Phosphorus Fire Retardant is mixed with ethanol, carry out stirring 20min, make it dissolve and be scattered in ethanol;
2) mixture of step 1) gained is added in resol stir 10min, then add carbonized agent and stir 20min, finally add expansible black lead and stir 20min and can obtain coating fire resistant fluid.
Embodiment 4:
A kind of coating fire resistant fluid, be made up of following raw material by weight:
Ethanol 20 parts, Wrapped up Phosphorus Fire Retardant 8 parts, carbonized agent 5 parts, expansible black lead 10 parts, 100 parts, resol.
Its preparation methods steps is:
1) by proportioning, Wrapped up Phosphorus Fire Retardant is mixed with ethanol, carry out stirring 15min, make it dissolve and be scattered in ethanol;
2) mixture of step 1) gained is added in resol stir 8min, then add carbonized agent and stir 15min, finally add expansible black lead and stir 15min and can obtain coating fire resistant fluid.
Make 5cm after being attached to by the coating fire resistant fluid of above-described embodiment gained on EPS particle thick, length and width are respectively carry out combustion testing after the sheet material of 1 meter, all can meet following standard:
1, temperature rise≤50 DEG C and mass loss rate≤50%;
2, sustained combustion time≤20 seconds;
3, combustion heat value standard: total heating value≤3.0MJ/kg;
4, monomer combustion experimental test: burning rate of increase index≤120W/s, flame laterally spreads length≤150mm, always puts smoke which and heat≤7.5MJ during burning 600s.
Claims (10)
1. a coating fire resistant fluid, is characterized in that, is made up of following raw material by weight:
Ethanol 10-20 part, Wrapped up Phosphorus Fire Retardant 5-10 part, carbonized agent 5-10 part, expansible black lead 5-10 part, 100 parts, resol.
2. coating fire resistant fluid according to claim 1, is characterized in that, is made up of following raw material by weight: ethanol 10 parts, Wrapped up Phosphorus Fire Retardant 5 parts, carbonized agent 5 parts, expansible black lead 5 parts, 100 parts, resol.
3. coating fire resistant fluid according to claim 1 and 2, is characterized in that: described carbonized agent is polyphosphoric acid amine.
4. coating fire resistant fluid according to claim 1, is characterized in that: the expansion multiplying power of described expansible black lead is at more than 300mL/g, and order number is less than 100 orders.
5. coating fire resistant fluid according to claim 1, is characterized in that: the order number of described Wrapped up Phosphorus Fire Retardant is greater than 1500 orders, and phosphorus content is at 70-75%.
6. coating fire resistant fluid according to claim 1, is characterized in that: before described coating fire resistant fluid uses, be that 5:1 adds solidifying agent by the weight ratio of coating fire resistant fluid and solidifying agent, described solidifying agent is resol solidifying agent.
7. coating fire resistant fluid according to claim 1, is characterized in that: described ethanol and the weight ratio of Wrapped up Phosphorus Fire Retardant are 2:1.
8. the preparation method of the coating fire resistant fluid according to claim 1-7 any one, is characterized in that, concrete steps are:
1) by proportioning, Wrapped up Phosphorus Fire Retardant is mixed with ethanol, stir, make it dissolve and be scattered in ethanol;
2) mixture of step 1) gained is added in resol stir, then add carbonized agent and stir, finally add expansible black lead and stir and can obtain coating fire resistant fluid.
9. preparation method according to claim 8, is characterized in that: step 1) in Wrapped up Phosphorus Fire Retardant when mixing with ethanol, the time of stirring is 10-20min.
10. preparation method according to claim 8, it is characterized in that: step 2) in mixture when adding in resol churning time be 5-10min, the churning time adding carbonized agent is 10-20min, and adding the churning time after expansible black lead is 10-20 minute.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105295297A (en) * | 2015-12-08 | 2016-02-03 | 苏州鑫德杰电子有限公司 | Corrosion-resistant electronic insulating material and preparation method thereof |
CN105860741A (en) * | 2016-06-21 | 2016-08-17 | 江苏科技大学 | Phenolic-resin-base metal hot working protective paint and preparation method thereof |
US11383116B2 (en) * | 2019-11-22 | 2022-07-12 | Anhui University Of Science & Technology | Foam material for fire prevention and extinguishing and a preparation method and a use thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105295297A (en) * | 2015-12-08 | 2016-02-03 | 苏州鑫德杰电子有限公司 | Corrosion-resistant electronic insulating material and preparation method thereof |
CN105860741A (en) * | 2016-06-21 | 2016-08-17 | 江苏科技大学 | Phenolic-resin-base metal hot working protective paint and preparation method thereof |
US11383116B2 (en) * | 2019-11-22 | 2022-07-12 | Anhui University Of Science & Technology | Foam material for fire prevention and extinguishing and a preparation method and a use thereof |
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Application publication date: 20150923 |