CN104927460A - Medical aluminum powder anticorrosive paint and preparation method therefor - Google Patents
Medical aluminum powder anticorrosive paint and preparation method therefor Download PDFInfo
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- CN104927460A CN104927460A CN201510384631.2A CN201510384631A CN104927460A CN 104927460 A CN104927460 A CN 104927460A CN 201510384631 A CN201510384631 A CN 201510384631A CN 104927460 A CN104927460 A CN 104927460A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses medical aluminum powder anticorrosive paint and a preparation method therefor The paint is prepared from the following raw materials: pure water, aluminum powder, phosphoric acid, iron oxide red, sodium chromate, magnesium chromate, chromic anhydride, chromic anhydride, lithopone and sodium hydrogen carbonate. The paint which is applied to medical apparatuses is antirust and antiseptic, the viscosity of the paint is 80-100s, the fineness is 25-45 [mu]m, and the paint is methanol corrosion resistant; the paint has good antiseptic property, impact resistance within 55-75cm and salt water resistance of not blistering and falling within 1-5 days; and the surface-drying time is 4-8 hours, the hard-drying time is 18-22 hours, and the covering power is 100-120g/cm<2>.
Description
Technical field
The present invention relates to medical material tech field, particularly relate to a kind of medical aluminium antirust paint and preparation method thereof.
Background technology
Rust-inhibiting paint a kind ofly protects the chemistry of metallic surface from air, seawater etc. or the coating of galvanic corrosion.Mainly be divided into physical property and the large class of chemically antirust paint two.The former leans on the suitable cooperation of pigment and paint vehicle, forms fine and close paint film to stop the intrusion of corrosives, as aluminium powder, aluminium powder, graphite rust-inhibiting paint etc.; The latter presses down rust effect, as pure water, zinc yellow anticorrosive paint etc. by the chemistry of rust-stabilising pigment.Antirust for metals such as bridge, boats and ships, pipelines.Pure water rust-inhibiting paint is the paint that a kind of pure water and siccative oil mix.Its perviousness, wettability are good, and paint film is soft, attachment is strong, but drying is slower.In addition because pure water is than great, easily precipitate, and stored for a long time can be thickening, brushing property is also poor.
The rust-inhibiting paint used is roughly oiliness and water-based two kinds.Oily antirust varniss makes the greasy removal difficulty of material surface, seldom uses.Oily antirust varniss is easy to use, cheap, but because of containing the toxic substance such as nitrite, chromic salt, comparatively large to operator's harm, country limits use, and these type of product performance are single, can not meet the antirust requirement of magnetic alloy material.Epoxy anti-rust paint is used for polymeric amide as solidifying agent, and dihydroxyphenyl propane phosphoric acid is cakingagent, and film is good to substrate adhesion, and workability is good, and paint film flexibility is good, water-fast, oil resistant chemicals-resistant is good.Add different rust-stabilising pigments, different rust-inhibiting paints can be mixed with, mostly be priming paint.
Water-based metal rust-inhibiting paint selects the powerful sequestrant myo-Inositol hexaphosphate of metal to be main component, and several aqueous promoter is composite forms with other.Myo-Inositol hexaphosphate is the Nantural non-toxic Organic chemical products extracted from food crop; when it uses as magneticsubstance rust-preventive agent; at surface and the rapid chelating of metal, the unit molecule complex compound protective membrane of one deck densification can be formed, effectively can suppress corrosion of metal.Material surface after this product treatment keeps primary colors, need not wash and can enter the next procedures such as application.Conventional epoxy anti-rust paint has Epoxy Aluminum rust-inhibiting paint, Epoxy Aluminum rust-inhibiting paint, epoxy Sodium chromate rust-inhibiting paint, Epoxy Aluminum rust-inhibiting paint and epoxy zinc rich primer etc.
Rust-stabilising pigment is the important component part of rust-inhibiting paint. physics rust-stabilising pigment is the pigment that the chemical property of a class own is comparatively stable, they are the physicalies by itself, stable chemical performance, quality is hard, particle is trickle, excellent fillibility, improve the density of paint film, reduce the permeable of paint film thus play antirust effect. aluminum oxide powder just belongs to this kind of material. and the rust-preventing characteristic of metallic aluminium powder is because aluminium powder has flaky texture, formation paint film is tight, also have the ability of stronger reflect UV linear light, paint film aging-resistant ability can be improved.Epoxy Aluminum, Epoxy Aluminum and epoxy Sodium chromate rust-inhibiting paint aluminum oxide powder are the rust-stabilising pigments that epoxy anti-rust paint is conventional, if add aluminium powder, then can strengthen its rustless property, epoxy Sodium chromate rust-inhibiting paint containing Sodium chromate and aluminum oxide powder rust-stabilising pigment, antirust except for steel surface, also may be used for the antirust of galvanized workpiece especially.Should be noted that and be, because Sodium chromate is slightly soluble in water, although so the rust-inhibiting paint rustless property containing Sodium chromate pigment is better than the rust-inhibiting paint only containing aluminium powder, it does not recommend long-term for underwater sites, otherwise can produce the problems such as foaming.
The main component of rust-inhibiting paint is rust-stabilising pigment and filmogen.Usually name with the title of rust-stabilising pigment, as: pure water anticorrosive paint, aluminium powder anticorrosive paint etc.If divided with its rust inhibition, be broadly divided into four large classes: physical action anticorrosive paint, chemical action anticorrosive paint, electrochemical action anticorrosive paint, comprehensive action anticorrosive paint.Pure water rust-inhibiting paint forms: by modified alkyd resin, rust-stabilising pigment, pigment extender, siccative, the compositions such as organic solvent.Characteristic: sticking power is good, and rustless property is high, water tolerance is strong, and seasoning is fast at normal temperatures.Some anticorrosive paints with trickle flakey material for main pigments.Physical action rust-stabilising pigment mainly contains: aluminium powder, natural aluminium powder, iron mica, aluminium powder, Graphite Powder 99 and trickle sheet glass etc.Aluminium powder chlorinated rubber anti-rust paint is mainly applicable to the corrosion protection of hull bottom waterline, sluice, underwater steel construction, underground pipeline and other structures, is the good rust-inhibiting paint of a kind of shielding.
Summary of the invention
The invention provides a kind of fast drying, medical aluminium antirust paint that preservative property are good and preparation method thereof, solve the technical problems such as the dry slow and antiseptic property of existing medical material is poor.
The present invention is by the following technical solutions: a kind of medical aluminium antirust paint, it is as follows that mass fraction proportioning pressed by its raw material: pure water 100 parts, aluminium powder 30-50 part, phosphoric acid 20-40 part, red iron oxide 2-8 part, Sodium chromate 5-25 part, magnesium chromate 3-7 part, chromic anhydride 0.4-0.8 part, tolylene diisocyanate 15-35 part, zinc sulfide white 10-30 part, sodium bicarbonate 0.5-2.5 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described medical aluminium antirust paint: pure water 100 parts, aluminium powder 35 parts, phosphoric acid 25 parts, red iron oxide 3 parts, Sodium chromate 10 parts, magnesium chromate 4 parts, chromic anhydride 0.5 part, tolylene diisocyanate 20 parts, 15 parts, zinc sulfide white, sodium bicarbonate 1 part.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described medical aluminium antirust paint: pure water 100 parts, aluminium powder 45 parts, phosphoric acid 35 parts, red iron oxide 7 parts, Sodium chromate 20 parts, magnesium chromate 6 parts, chromic anhydride 0.7 part, tolylene diisocyanate 30 parts, 25 parts, zinc sulfide white, sodium bicarbonate 2 parts.
As a preferred technical solution of the present invention: it is as follows that mass fraction proportioning pressed by the raw material of described medical aluminium antirust paint: pure water 100 parts, aluminium powder 40 parts, phosphoric acid 30 parts, red iron oxide 5 parts, Sodium chromate 15 parts, magnesium chromate 5 parts, chromic anhydride 0.6 part, tolylene diisocyanate 25 parts, 20 parts, zinc sulfide white, sodium bicarbonate 1.5 parts.
Prepare a method for described medical aluminium antirust paint, step is:
The first step: take pure water, aluminium powder, phosphoric acid, red iron oxide, Sodium chromate, magnesium chromate, chromic anhydride, toluene diisocynate, zinc sulfide white and sodium bicarbonate according to mass fraction proportioning;
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 135-155 DEG C, stirs 30-50min with 260-440r/min speed;
3rd step: the liquid after stirring is left standstill 90-110min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 10-14h, packaging after filtering at 160-200 DEG C after mixing.
beneficial effect
Medical aluminium antirust paint of one of the present invention and preparation method thereof adopts above technical scheme compared with prior art, has following technique effect: 1, antirust for medical apparatus, anticorrosion, viscosity 80-100s, fineness 25-45 μm, and methanol tolerant corrodes; 2, antiseptic property is good, impact 55-75cm, and resistance to salt water 1-5d is non-foaming, do not come off; 3, surface drying 4-8h, does solid work 18-22h, opacifying power 100-120g/cm
2, preparation method is simple, and raw material is simple and easy to get, the widespread production not division of history into periods can replace current material.
Embodiment
Below in conjunction with example, the invention will be further described, and embodiment, only for the present invention will be described, does not form the restriction to right, and other alternative means that it may occur to persons skilled in the art that, all within the scope of the claims in the present invention.
Embodiment 1:
The first step: take pure water 100 parts according to mass fraction proportioning, aluminium powder 30 parts, phosphoric acid 20 parts, red iron oxide 2 parts, Sodium chromate 5 parts, magnesium chromate 3 parts, chromic anhydride 0.4 part, tolylene diisocyanate 15 parts, 10 parts, zinc sulfide white, sodium bicarbonate 0.5 part.
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 135 DEG C, stirs 30min with 260r/min speed.
3rd step: the liquid after stirring is left standstill 90min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 10h, packaging after filtering at 160 DEG C after mixing.
Antirust for medical apparatus, anticorrosion, viscosity 80s, fineness 45 μm, methanol tolerant corrodes; Antiseptic property is good, impact 55cm, and resistance to salt water 1d is non-foaming, do not come off; Surface drying 8h, does solid work 22h, opacifying power 100g/cm
2.
Embodiment 2:
The first step: take pure water 100 parts according to mass fraction proportioning, aluminium powder 50 parts, phosphatase 24 0 part, red iron oxide 8 parts, Sodium chromate 25 parts, magnesium chromate 7 parts, chromic anhydride 0.8 part, tolylene diisocyanate 35 parts, 30 parts, zinc sulfide white, sodium bicarbonate 2.5 parts.
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 155 DEG C, stirs 50min with 440r/min speed.
3rd step: the liquid after stirring is left standstill 110min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 14h, packaging after filtering at 200 DEG C after mixing.
Antirust for medical apparatus, anticorrosion, viscosity 85s, fineness 40 μm, methanol tolerant corrodes; Antiseptic property is good, impact 60cm, and resistance to salt water 2d is non-foaming, do not come off; Surface drying 7h, does solid work 21h, opacifying power 115g/cm
2.
Embodiment 3:
The first step: take pure water 100 parts according to mass fraction proportioning, aluminium powder 35 parts, phosphoric acid 25 parts, red iron oxide 3 parts, Sodium chromate 10 parts, magnesium chromate 4 parts, chromic anhydride 0.5 part, tolylene diisocyanate 20 parts, 15 parts, zinc sulfide white, sodium bicarbonate 1 part.
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 135 DEG C, stirs 30min with 260r/min speed.
3rd step: the liquid after stirring is left standstill 90min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 10h, packaging after filtering at 160 DEG C after mixing.
Antirust for medical apparatus, anticorrosion, viscosity 90s, fineness 35 μm, methanol tolerant corrodes; Antiseptic property is good, impact 65cm, and resistance to salt water 3d is non-foaming, do not come off; Surface drying 6h, does solid work 20h, opacifying power 110g/cm
2.
Embodiment 4:
The first step: take pure water 100 parts according to mass fraction proportioning, aluminium powder 45 parts, phosphoric acid 35 parts, red iron oxide 7 parts, Sodium chromate 20 parts, magnesium chromate 6 parts, chromic anhydride 0.7 part, tolylene diisocyanate 30 parts, 25 parts, zinc sulfide white, sodium bicarbonate 2 parts.
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 155 DEG C, stirs 50min with 440r/min speed.
3rd step: the liquid after stirring is left standstill 110min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 14h, packaging after filtering at 200 DEG C after mixing.
Antirust for medical apparatus, anticorrosion, viscosity 95s, fineness 30 μm, methanol tolerant corrodes; Antiseptic property is good, impact 70cm, and resistance to salt water 4d is non-foaming, do not come off; Surface drying 5h, does solid work 19h, opacifying power 115g/cm
2.
Embodiment 5:
The first step: take pure water 100 parts according to mass fraction proportioning, aluminium powder 40 parts, phosphoric acid 30 parts, red iron oxide 5 parts, Sodium chromate 15 parts, magnesium chromate 5 parts, chromic anhydride 0.6 part, tolylene diisocyanate 25 parts, 20 parts, zinc sulfide white, sodium bicarbonate 1.5 parts.
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 145 DEG C, stirs 40min with 350r/min speed.
3rd step: the liquid after stirring is left standstill 100min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 12h, packaging after filtering at 180 DEG C after mixing.
Antirust for medical apparatus, anticorrosion, viscosity 100s, fineness 25 μm, methanol tolerant corrodes; Antiseptic property is good, impact 75cm, and resistance to salt water 5d is non-foaming, do not come off; Surface drying 48h, does solid work 18h, opacifying power 120g/cm
2.
Claims (5)
1. a medical aluminium antirust paint, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described medical aluminium antirust paint: pure water 100 parts, aluminium powder 30-50 part, phosphoric acid 20-40 part, red iron oxide 2-8 part, Sodium chromate 5-25 part, magnesium chromate 3-7 part, chromic anhydride 0.4-0.8 part, tolylene diisocyanate 15-35 part, zinc sulfide white 10-30 part, sodium bicarbonate 0.5-2.5 part.
2. the medical aluminium antirust paint of one according to claim 1, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described medical aluminium antirust paint: pure water 100 parts, aluminium powder 35 parts, phosphoric acid 25 parts, red iron oxide 3 parts, Sodium chromate 10 parts, magnesium chromate 4 parts, chromic anhydride 0.5 part, tolylene diisocyanate 20 parts, 15 parts, zinc sulfide white, sodium bicarbonate 1 part.
3. the medical aluminium antirust paint of one according to claim 2, it is characterized in that, it is as follows that mass fraction proportioning pressed by the raw material of described medical aluminium antirust paint: pure water 100 parts, aluminium powder 45 parts, phosphoric acid 35 parts, red iron oxide 7 parts, Sodium chromate 20 parts, magnesium chromate 6 parts, chromic anhydride 0.7 part, tolylene diisocyanate 30 parts, 25 parts, zinc sulfide white, sodium bicarbonate 2 parts.
4. the medical aluminium antirust paint of one according to claim 1, it is characterized in that: the raw material of described medical aluminium antirust paint is as follows by mass fraction proportioning: pure water 100 parts, aluminium powder 40 parts, phosphoric acid 30 parts, red iron oxide 5 parts, Sodium chromate 15 parts, magnesium chromate 5 parts, chromic anhydride 0.6 part, tolylene diisocyanate 25 parts, 20 parts, zinc sulfide white, sodium bicarbonate 1.5 parts.
5. prepare a method for medical aluminium antirust paint according to claim 1, it is characterized in that, comprise the steps:
The first step: take pure water, aluminium powder, phosphoric acid, red iron oxide, Sodium chromate, magnesium chromate, chromic anhydride, toluene diisocynate, zinc sulfide white and sodium bicarbonate according to mass fraction proportioning;
Second step: pure water, aluminium powder, phosphoric acid, red iron oxide and magnesium chromate are dropped in reactor, be heated to 135-155 DEG C, stirs 30-50min with 260-440r/min speed;
3rd step: the liquid after stirring is left standstill 90-110min, adds Sodium chromate, chromic anhydride, tolylene diisocyanate, zinc sulfide white and sodium bicarbonate, drops into shredder grinding 10-14h, packaging after filtering at 160-200 DEG C after mixing.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105969159A (en) * | 2016-07-21 | 2016-09-28 | 朱小龙 | Antirust anti-crush paint for metals |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102453361A (en) * | 2010-10-21 | 2012-05-16 | 吴江龙泾红贝家装有限公司 | Environmentally-friendly antirust paint |
CN103740154A (en) * | 2013-12-20 | 2014-04-23 | 吴江邻苏精密机械有限公司 | Deoiling dedusting antirust paint and preparation method thereof |
-
2015
- 2015-06-30 CN CN201510384631.2A patent/CN104927460A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102453361A (en) * | 2010-10-21 | 2012-05-16 | 吴江龙泾红贝家装有限公司 | Environmentally-friendly antirust paint |
CN103740154A (en) * | 2013-12-20 | 2014-04-23 | 吴江邻苏精密机械有限公司 | Deoiling dedusting antirust paint and preparation method thereof |
Non-Patent Citations (1)
Title |
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《实用化学品配方手册》编委会: "《实用化学品配方手册》", 31 March 2009, 四川出版集团 四川科学技术出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105969159A (en) * | 2016-07-21 | 2016-09-28 | 朱小龙 | Antirust anti-crush paint for metals |
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Application publication date: 20150923 |