CN104927233A - Weather-proof durable plastic door window - Google Patents
Weather-proof durable plastic door window Download PDFInfo
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- CN104927233A CN104927233A CN201510300748.8A CN201510300748A CN104927233A CN 104927233 A CN104927233 A CN 104927233A CN 201510300748 A CN201510300748 A CN 201510300748A CN 104927233 A CN104927233 A CN 104927233A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/02—Alkyl or cycloalkyl ethers
- C08B11/04—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
- C08B11/06—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals with halogen-substituted hydrocarbon radials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention discloses a weather-proof durable plastic door window which is prepared from the following raw materials in parts by weight: 1-3 parts of gluconolactone, 2-3 parts of diphenyl imidazoline, 4-6 parts of monopotassium phosphate, 2-4 parts of butyltin tris(2-ethylhexanoate), 30-40 parts of graphite powder, 27-30 parts of wollastonite powder, 7-10 parts of poly (butyl acrylate), 1-2 parts of amophophallus gum, 320-370 parts of polyvinyl chloride, 60-70 parts of a 20-30% sodium hydroxide solution, 36-40 parts of benzyl chloride, 40-42 parts of divinylbenzene, 70-80 parts of styrene, 0.3-0.6 part of benzoyl peroxide and 1-2 parts of Span-80. According to the weather-proof durable plastic door window, since sisal fibers are subjected to refrigeration and swelling treatment, the dispersity of cellulose is improved, the accessibility of benzyl chloride to cellulose is increased, the quantity of hydroxyl is reduced after etherification, the cellulose crystal texture is damaged, the thermoplasticity is obtained, and meanwhile, the dimensional stability, weather resistance, corrosion resistance and the like of fibers are correspondingly improved since the quantity of hydroxyl is reduced.
Description
Technical field
The present invention relates generally to plastic door-window field, particularly relates to a kind of weathering durability plastic door-window.
Background technology
Plastic door-window can be divided into PVC plastic door-window and glass filament reinforced plastics (glass reinforced plastic) door and window by material, wherein in all kinds of building window, PVC plastic window repeats there is outstanding advantage in recycling and Energy in use at saving section bar production energy consumption, reclaimed materials, has the excellent ratio of performance to price in heat preservation energy-saving.For increasing the rigidity of window, in the stressed member of window frame, sash, stile's section bar, according to the design of wind pressure resistant strength and other service requirements, should determine to use which kind of enhanced type steel.By the coextrusion of UPVC resin and painted polymethylmethacrylate (PMMA) or acrylonitrile-styrene-acrylic ester copolymer (ASA), and overlay film, spraying can obtain the decorative effect of multiple texture and kinds of surface color on white section bar.In addition the mass coloration technology adding coloring material for mixing and extrude in UPVC resin-oatmeal is also had.But different views are still had to this technology, therefore should be prudent especially when selecting, the colour-change situation of this kind of section bar after artificial accelerated aging test be checked.Suggestion covers same color film to improve its weathering resistance on mass coloration section bar.
At global energy growing tension, under the pressure that environment constantly worsens, biological material is due to the feature of environmental protection and functional outstanding great attention also more and more causing people, reproducible biomass resource is converted into the important trend that consumption that novel material carrys out alternative Nonrenewable resources is nowadays social construction and development, the present invention is then with the additive of sisal fibers as plastic door-window, can play and economize on resources, and the good net effect of reinforced plastics door and window overall performance.
Summary of the invention
The object of the invention is exactly a kind of weathering durability plastic door-window.
The present invention is achieved by the following technical solutions:
A kind of weathering durability plastic door-window, it is made up of the raw material of following weight parts:
Glucono-lactone 1-3, diphenyl-imidazole quinoline 2-3, potassium primary phosphate 4-6, three sad butyl tin 2-4, Graphite Powder 99 30-40, wollastonite powder 27-30, butyl polyacrylate 7-10, konjak gum 1-2, polyvinyl chloride 320-370,20-30% sodium hydroxide solution 60-70, Benzyl Chloride 36-40, divinylbenzene 40-42, vinylbenzene 70-80, benzoyl peroxide 0.3-0.6, sorbester p17 1-2.
A preparation method for weathering durability plastic door-window, comprises the following steps:
(1) above-mentioned sisal fibers is dried abrasive dust, add 20-30% sodium hydroxide solution, stir, be placed in swollen 120-130 minute at-10--5 DEG C of temperature, park under room temperature to normal temperature, add the 75-80% of Benzyl Chloride, above-mentioned divinylbenzene weight, heated and stirred 6.5-7 hour in the oil bath of 105-110 DEG C, discharging cools, mix with sorbester p17, join in compound weight 0.5-1 deionized water doubly, stir, obtain preplasticizing fiber liquid;
(2) konjak gum is joined in 3-4 times of deionized water, add glucono-lactone, be heated to 60-70 DEG C, stir, obtain dispersion liquid;
(3) vinylbenzene is joined in 1.8-2 deionized water doubly, add dispersion liquid, 60-100 rev/min is stirred 10-20 minute, adds remaining divinylbenzene, benzoyl peroxide, after stirring at 80-90 DEG C insulation reaction 60-70 minute, add above-mentioned preplasticizing fiber liquid, insulated and stirred 70-80 minute, then be incubated 40-50 minute under 95-100, suction filtration, replace washed product to neutral with dehydrated alcohol and distilled water, vacuum-drying at 60-70 DEG C, obtains thermoplastic fibre resin;
(4) 10-20% getting above-mentioned polyvinyl chloride weight mixes with butyl polyacrylate, at 80-90 DEG C, pre-heat agitated 20-30 divides, mix with Graphite Powder 99, ball milling is even, with thermoplastic fibre resin, remains each raw material and mixes, in feeding charging extruder, melt, to fusing, to be clamp-oned in mould and to shape by heated and stirred, and extruded velocity controls as 2-2.5m/min, PVC section bar via mould shape is shaping by cooling water tank Water cooling, and in cooling water tank, water temperature controls as 20-22 DEG C.
Advantage of the present invention is:
The present invention by sisal fibers through freezing swollen process, improve cellulosic dispersiveness, Benzyl Chloride is increased cellulosic accessibility, after etherificate process, hydroxyl quantity reduces, crystal structure of cellulose is destroyed, obtain thermoplasticity, simultaneously due to the minimizing of hydroxyl quantity, the dimensional stability, weathering resistance, erosion resistance etc. of fiber are obtained for corresponding increase, with solution blendings such as vinylbenzene, can effectively be dispersed in the polystyrene of formation, improve surface strength, toughness, erosion resistance, further increase the properties of finished product.The dispersion agent wherein added can make styrene monomer phase and aqueous phase interface interlayer form protective layer, promotes the dispersiveness that each raw material is mutual, not easily cluster.
Embodiment
Embodiment 1:
A kind of weathering durability plastic door-window, is characterized in that what it was made up of the raw material of following weight parts:
Glucono-lactone 3, diphenyl-imidazole quinoline 3, the sad butyl tin 4 of potassium primary phosphate 6, three, Graphite Powder 99 40, wollastonite powder 30, butyl polyacrylate 10, konjak gum 2, polyvinyl chloride 370,30% sodium hydroxide solution 70, Benzyl Chloride 40, divinylbenzene 42, vinylbenzene 80, benzoyl peroxide 0.6, sorbester p17 2.
A preparation method for weathering durability plastic door-window, comprises the following steps:
(1) above-mentioned sisal fibers is dried abrasive dust, add 30% sodium hydroxide solution, stir, to be placed at-5 DEG C of temperature swollen 130 minutes, park under room temperature to normal temperature, add Benzyl Chloride, above-mentioned divinylbenzene weight 80%, heated and stirred 6.5 hours in the oil bath of 110 DEG C, discharging cool, mix with sorbester p17, join in the deionized water of compound weight 0.5 times, stir, obtain preplasticizing fiber liquid;
(2) konjak gum is joined in 4 times of deionized waters, add glucono-lactone, be heated to 70 DEG C, stir, obtain dispersion liquid;
(3) vinylbenzene is joined in 1.8-2 deionized water doubly, add dispersion liquid, 100 revs/min are stirred 20 minutes, add remaining divinylbenzene, benzoyl peroxide, after stirring at 90 DEG C insulation reaction 70 minutes, add above-mentioned preplasticizing fiber liquid, insulated and stirred 80 minutes, then be incubated 50 minutes at 100, suction filtration, replace washed product to neutral with dehydrated alcohol and distilled water, vacuum-drying at 60 DEG C, obtains thermoplastic fibre resin;
(4) 10-20% getting above-mentioned polyvinyl chloride weight mixes with butyl polyacrylate, pre-heat agitated 30 points at 90 DEG C, mix with Graphite Powder 99, ball milling is even, with thermoplastic fibre resin, remains each raw material and mixes, in feeding charging extruder, melt, to fusing, to be clamp-oned in mould and to shape by heated and stirred, and extruded velocity controls as 2.5m/min, PVC section bar via mould shape is shaping by cooling water tank Water cooling, and in cooling water tank, water temperature controls is 22 DEG C.
To detect, the present invention is lightweight 5-10% compared with similar plastic door-window, thermally uses all without any unusual phenomenon in district at high and cold and height; Resistance to impact shock strengthens 10-20%; Noise reduction usefulness is better, realizes noise reduction 50dB; Principal mode material weldability is good, and fillet weld strength minimum stress can reach 43MPa.
Claims (2)
1. a weathering durability plastic door-window, is characterized in that what it was made up of the raw material of following weight parts:
Glucono-lactone 1-3, diphenyl-imidazole quinoline 2-3, potassium primary phosphate 4-6, three sad butyl tin 2-4, Graphite Powder 99 30-40, wollastonite powder 27-30, butyl polyacrylate 7-10, konjak gum 1-2, polyvinyl chloride 320-370,20-30% sodium hydroxide solution 60-70, Benzyl Chloride 36-40, divinylbenzene 40-42, vinylbenzene 70-80, benzoyl peroxide 0.3-0.6, sorbester p17 1-2.
2. a preparation method for weathering durability plastic door-window as claimed in claim 1, is characterized in that comprising the following steps:
(1) above-mentioned sisal fibers is dried abrasive dust, add 20-30% sodium hydroxide solution, stir, be placed in swollen 120-130 minute at-10--5 DEG C of temperature, park under room temperature to normal temperature, add the 75-80% of Benzyl Chloride, above-mentioned divinylbenzene weight, heated and stirred 6.5-7 hour in the oil bath of 105-110 DEG C, discharging cools, mix with sorbester p17, join in compound weight 0.5-1 deionized water doubly, stir, obtain preplasticizing fiber liquid;
(2) konjak gum is joined in 3-4 times of deionized water, add glucono-lactone, be heated to 60-70 DEG C, stir, obtain dispersion liquid;
(3) vinylbenzene is joined in 1.8-2 deionized water doubly, add dispersion liquid, 60-100 rev/min is stirred 10-20 minute, adds remaining divinylbenzene, benzoyl peroxide, after stirring at 80-90 DEG C insulation reaction 60-70 minute, add above-mentioned preplasticizing fiber liquid, insulated and stirred 70-80 minute, then be incubated 40-50 minute under 95-100, suction filtration, replace washed product to neutral with dehydrated alcohol and distilled water, vacuum-drying at 60-70 DEG C, obtains thermoplastic fibre resin;
(4) 10-20% getting above-mentioned polyvinyl chloride weight mixes with butyl polyacrylate, at 80-90 DEG C, pre-heat agitated 20-30 divides, mix with Graphite Powder 99, ball milling is even, with thermoplastic fibre resin, remains each raw material and mixes, in feeding charging extruder, melt, to fusing, to be clamp-oned in mould and to shape by heated and stirred, and extruded velocity controls as 2-2.5m/min, PVC section bar via mould shape is shaping by cooling water tank Water cooling, and in cooling water tank, water temperature controls as 20-22 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510300748.8A CN104927233A (en) | 2015-06-04 | 2015-06-04 | Weather-proof durable plastic door window |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510300748.8A CN104927233A (en) | 2015-06-04 | 2015-06-04 | Weather-proof durable plastic door window |
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| CN104927233A true CN104927233A (en) | 2015-09-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510300748.8A Pending CN104927233A (en) | 2015-06-04 | 2015-06-04 | Weather-proof durable plastic door window |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106638111A (en) * | 2016-12-20 | 2017-05-10 | 宁波蓝星包装印务有限公司 | Antifreeze sol raw paper material for packing cartons and preparation method thereof |
Citations (6)
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|---|---|---|---|---|
| CN101041725A (en) * | 2006-03-24 | 2007-09-26 | 陈书怡 | Reproduction new method for waste elastomer and plastic |
| CN101143952A (en) * | 2007-09-12 | 2008-03-19 | 东北林业大学 | Flame-proof smoke-inhibiting wood-plastic composite material |
| CN101235211A (en) * | 2007-02-02 | 2008-08-06 | 甘益力 | Plastic-wood material and its preparation method and application |
| CN101747644A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | Plant powder modified thermoplastic wood-plastic composite and preparation method and application |
| CN102558894A (en) * | 2012-02-21 | 2012-07-11 | 常熟市方塔涂料化工有限公司 | Method for preparing wood-like mould composite material |
| CN102558893A (en) * | 2012-02-21 | 2012-07-11 | 常熟市方塔涂料化工有限公司 | Wood-like bamboo fiber mould composite material |
-
2015
- 2015-06-04 CN CN201510300748.8A patent/CN104927233A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041725A (en) * | 2006-03-24 | 2007-09-26 | 陈书怡 | Reproduction new method for waste elastomer and plastic |
| CN101235211A (en) * | 2007-02-02 | 2008-08-06 | 甘益力 | Plastic-wood material and its preparation method and application |
| CN101143952A (en) * | 2007-09-12 | 2008-03-19 | 东北林业大学 | Flame-proof smoke-inhibiting wood-plastic composite material |
| CN101747644A (en) * | 2008-12-16 | 2010-06-23 | 金发科技股份有限公司 | Plant powder modified thermoplastic wood-plastic composite and preparation method and application |
| CN102558894A (en) * | 2012-02-21 | 2012-07-11 | 常熟市方塔涂料化工有限公司 | Method for preparing wood-like mould composite material |
| CN102558893A (en) * | 2012-02-21 | 2012-07-11 | 常熟市方塔涂料化工有限公司 | Wood-like bamboo fiber mould composite material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106638111A (en) * | 2016-12-20 | 2017-05-10 | 宁波蓝星包装印务有限公司 | Antifreeze sol raw paper material for packing cartons and preparation method thereof |
| CN106638111B (en) * | 2016-12-20 | 2019-01-01 | 宁波蓝星包装印务有限公司 | A kind of Packaging Box freeze proof procollagen paper material and preparation method thereof |
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Application publication date: 20150923 |
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