CN104893426A - Cigarette anti-counterfeiting ink - Google Patents
Cigarette anti-counterfeiting ink Download PDFInfo
- Publication number
- CN104893426A CN104893426A CN201510285311.1A CN201510285311A CN104893426A CN 104893426 A CN104893426 A CN 104893426A CN 201510285311 A CN201510285311 A CN 201510285311A CN 104893426 A CN104893426 A CN 104893426A
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- resin
- solvent
- acetate
- flow agent
- cigarette anti
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Abstract
The invention discloses a cigarette anti-counterfeiting ink. The cigarette anti-counterfeiting ink comprises the following raw materials by weight percent: 10-20% of a resin, 25-50% of methacrylate, 10-25% of a light resin type offset printing ink, 1-8% of propylene glycol methyl ether acetate, 5-9% of a temperature-varied pigment. 1-5% of a pearlescent pigment, 10-25% of a solvent, 0.1-1% of a leveller and 0.5-3% of a dispersant, wherein the resin is selected from acrylic resin or polyurethane resin; the solvent is selected from the composition composed of one of n-propyl acetate, ethyl acetate, n-butyl acetate and isobutyl acetate, and one of ethanol, isopropanol and n-butyl alcohol; the leveller is one of acrylic acids, organosilicones and fluorocarbons; and the dispersant is selected from one of reactants of carboxylates, sulphates, polyethylene glycol type polyalcohols, polyethyleneimine derivatives, polycaprolactone polyol-polyethylenimine segmented copolymers, polycaprolactone and triethylene tetramine. The cigarette anti-counterfeiting ink provided by the invention is low in cost, good in stealthiness, bright in colour and convenient to inspect.
Description
Technical field
The present invention relates to Application in Anti-counterfeiting technical field, particularly relate to a kind of cigarette anti-counterfeit ink.
Background technology
At present, false proof printing ink is an integral part in anti-counterfeiting technology, anti-forgery ink refers to have anti-fraud functional ink, this ink is normally made up of colorant, low-melting ink vehicle and ink addition agent, in ink vehicle, namely adds the anti-fake material of property and the special printing inks processed through special process.Why it can be false proof, is to utilize in ink to have the colorant of specific function and low-melting ink vehicle to come false proof.Nowadays, in the field of many anti-counterfeit printings, the use of false proof printing ink widely, as on the anti-counterfeit printing of various ticket, document, trade mark and mark etc., all uses false proof printing ink.This also mainly implements the features such as convenient, with low cost, disguised better, bright in luster because false proof printing ink has anti-counterfeiting technology.The ink that the anti-counterfeit printing of domestic and international exploitation uses has reached tens kinds, letterpress inks, gravure printing ink, stencil printing ink, lithography (offset printing) ink and aqueous flexible plate printing ink etc. can be divided into by printed form, paper printing ink, tin printing ink, news ink, ink used for plastic etc. can be divided into again by stock difference.
Ink anti-counterfeiting technology is the technology that in bill anti-counterfeit, Valued Securities and trade mark packaging field, practicality is very high, can meet the requirement of a popular line anti-counterfeit recognition, also can meet two wires, the senior expert of three lines, the discriminating of administrative authority, the requirement of supervision.The mechanism that anti-forgery ink fades mainly contains two aspects, and once being use to meet the ink remover pigment that can fade, as some slag dyestuffs etc., two is use the low-melting ink vehicle running into the just energy variable color of ink remover or some other chemical substance as xenol etc.Two kinds of methods can obtain satisfied effect.In anti-forgery ink, add fluorescent material, the effect of its anti-counterfeit package can be better.
But the anti-forgery ink adopted at present mostly exists that cost is high, inspection is inconvenient, or there is printing quality and do not meet the demands, the problems such as the color and luster after printing is of poor quality.
Summary of the invention
The technical problem to be solved in the present invention is, provide that a kind of cost is low, good concealment, bright in luster, check cigarette anti-counterfeit ink easily.
The technical solution adopted for the present invention to solve the technical problems is: a kind of cigarette anti-counterfeit ink, and it comprises the raw material of following weight proportion:
Resin 10-20%;
Glycerin monomethyl acrylic ester 25-50%;
Light resin type flexographic ink 10-25%;
Propylene glycol methyl ether acetate 1-8%;
Temperature variable pigments 5-9 %;
Pearly pigment 1-5%;
Solvent 10-25%;
Flow agent 0.1-1%;
Dispersion agent 0.5-3%;
Described resin is selected from acrylic resin or urethane resin;
Described solvent is selected from the composition of a kind of composition in a kind of and ethanol in n-propyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate, Virahol, propyl carbinol;
Described flow agent is the one in acrylic acid or the like, silicone based and fluorocarbon class;
Described dispersion agent be selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how in join one in the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer, many caprolactones and triethylene tetramine.
Improve as to the one of technical scheme of the present invention, described temperature variable pigments selects Reversible temperature variable pigments.
Improve as to the one of technical scheme of the present invention, described flow agent is selected from polydimethylsiloxane, the one in PSI, Organo-modified polysiloxane, polyfluorinated organic polyene hydrocarbon or fluorin modified crylic acid.
Improve as to the one of technical scheme of the present invention, described pearly pigment is selected from the one in natural angle scale, Bismuth Oxychloride, lead hydrogen arsenate, white lead carbonate and multiple layer metal oxide compound coated mica.
Improve as to the one of technical scheme of the present invention, described flow agent is polydimethylsiloxane or PSI.
Improve as to the one of technical scheme of the present invention, resin 20%; Glycerin monomethyl acrylic ester 30%; Light resin type flexographic ink 15%; Propylene glycol methyl ether acetate 5%; Temperature variable pigments 8%; Pearly pigment 4%; Solvent 15%; Flow agent 0.8%; Dispersion agent 2.2%.
Improve as to the one of technical scheme of the present invention, described resin is acrylic resin, described solvent is ethyl acetate, described flow agent is polydimethylsiloxane, described dispersion agent is polyethylene glycol type polyvalent alcohol, described pearly pigment is lead hydrogen arsenate, and described flow agent is polydimethylsiloxane.
Improve as to the one of technical scheme of the present invention, resin 18%; Glycerin monomethyl acrylic ester 37%; Light resin type flexographic ink 17%; Propylene glycol methyl ether acetate 6%; Temperature variable pigments 6%; Pearly pigment 3%; Solvent 10%; Flow agent 1%; Dispersion agent 3%.
Improve as to the one of technical scheme of the present invention, described resin is acrylic resin, described solvent is ethyl acetate, described flow agent is polydimethylsiloxane, described dispersion agent is polyethylene glycol type polyvalent alcohol, described pearly pigment is lead hydrogen arsenate, and described flow agent is polydimethylsiloxane.
Cigarette ink provided by the invention, cost is low, good concealment, bright in luster, inspection convenience.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Cigarette anti-counterfeit ink of the present invention, it comprises the raw material of following weight proportion:
Resin 10-20%;
Glycerin monomethyl acrylic ester 25-50%;
Light resin type flexographic ink 10-25%;
Propylene glycol methyl ether acetate 1-8%;
Temperature variable pigments 5-9 %;
Pearly pigment 1-5%;
Solvent 10-25%;
Flow agent 0.1-1%;
Dispersion agent 0.5-3%;
In the specific embodiment of the invention, resin is selected from acrylic resin or urethane resin; Solvent is selected from the composition of a kind of composition in a kind of and ethanol in n-propyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate, Virahol, propyl carbinol; Flow agent is the one in acrylic acid or the like, silicone based and fluorocarbon class; Dispersion agent be selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how in join one in the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer, many caprolactones and triethylene tetramine.
In the specific embodiment of the invention, warm variable pigments selects Reversible temperature variable pigments.Flow agent is selected from polydimethylsiloxane, the one in PSI, Organo-modified polysiloxane, polyfluorinated organic polyene hydrocarbon or fluorin modified crylic acid.
In the present invention, pearly pigment is selected from the one in natural angle scale, Bismuth Oxychloride, lead hydrogen arsenate, white lead carbonate and multiple layer metal oxide compound coated mica.
Embodiment one
The cigarette anti-counterfeit ink of the present embodiment comprises the raw material of following weight proportion: resin 20%; Glycerin monomethyl acrylic ester 30%; Light resin type flexographic ink 15%; Propylene glycol methyl ether acetate 5%; Temperature variable pigments 8%; Pearly pigment 4%; Solvent 15%; Flow agent 0.8%; Dispersion agent 2.2%.
In the present embodiment, resin is acrylic resin, and solvent is ethyl acetate, and flow agent is polydimethylsiloxane, and dispersion agent is polyethylene glycol type polyvalent alcohol, and pearly pigment is lead hydrogen arsenate, and flow agent is polydimethylsiloxane.
Adopt the cigarette anti-counterfeit ink of the present embodiment, prepare convenient and swift, cost is low, good concealment, bright in luster, inspection is convenient.
Embodiment two
The cigarette anti-counterfeit ink of the present embodiment comprises the raw material of following weight proportion: resin 18%; Glycerin monomethyl acrylic ester 37%; Light resin type flexographic ink 17%; Propylene glycol methyl ether acetate 6%; Temperature variable pigments 6%; Pearly pigment 3%; Solvent 10%; Flow agent 1%; Dispersion agent 3%.
Improve as to the one of technical scheme of the present invention, described resin is acrylic resin, described solvent is ethyl acetate, described flow agent is polydimethylsiloxane, described dispersion agent is polyethylene glycol type polyvalent alcohol, described pearly pigment is lead hydrogen arsenate, and described flow agent is polydimethylsiloxane.
Adopt the cigarette anti-counterfeit ink of the present embodiment, prepare convenient and swift, cost is low, good concealment, bright in luster, inspection is convenient.
The warm variable pigments adopted in the specific embodiment of the invention, also referred to as temperature change powder, heat discoloration powder, temperature-sensitive powder, heat discoloration pigment.It can be that temperature reddens, temperature flavescences, Wen Bianlan, temperature turn bright red, warm change golden red.Heat discoloration pigment is prepared by electron transfer type organic compound system.Electron transfer type organic compound is the organic chromophoric system that a class has special chemical structure.At a certain temperature, because transfer transport makes this organic molecular structure change, thus color transition is realized.Temperature variable pigments of the present invention can use any one disclosed in prior art to be applicable to temperature variable pigments of the present invention, also can use commercially available prod.
Show certain particular color under anti-counterfeiting ink for cigarette packets normal temperature of the present invention, after heating, color disappears and becomes colorless, and return to original color immediately after cooling, change procedure is reversible.The large paper of warm temperature is at about 40-50 DEG C.Compared with prior art, anti-forgery ink of the present invention can be exclusively used in cigarette filter and outer packaging, and main base material is tipping paper, enamelled paper.Mode of printing is offset printing or gravure.Anti-forgery ink of the present invention belongs to temperature sensitive ink, at a certain temperature, achieves colourless change coloured, coloured bleach.The present invention, is obtained by blending dispersion, grinding for starting material with resin, warm variable pigments, filler, auxiliary agent, solvent.Its reasonable recipe, cost is low, has the features such as easy to operate, look becomes sensitive, stable performance.Above-mentioned materials obtains anti-forgery ink by the technique such as blending dispersion, grinding.Gravure mode is adopted by anti-forgery ink to be imprinted on base material enamelled paper.Result is shown as large red at normal temperatures, and disappearing through color after to about 50 DEG C of heating becomes colorless, and returns to large red immediately, prove that its change procedure is reversible after cooling.
The modulation of heat-sensitive colour-changing ink of the present invention must use the resin of high solid content low-viscosity (low polymerization degree or lower molecular weight), could obtain good result like this.The tolerance of temperature variable pigments pigment to different solvents is different, soak in some solvent and also can not affect its discoloration in 6 months, but other solvents littlely can corrode microcapsule top layer and infiltrate that it is inner several within a few week, make taking off of the discoloration even completely dissolve of pigment.After evaporation of the solvent, this taking off of discoloration some can partly recover, some is completely expendable.In general, comparatively large to the erosion destruction of camouflage paint containing the solvent below 3 carbon atoms, very little on the impact of pigment containing solvents more than 6 carbon atoms.In addition, the erosion action of solvent can be more obvious at a higher temperature.
Should be understood that, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.
Claims (8)
1. a cigarette anti-counterfeit ink, is characterized in that, comprises the raw material of following weight proportion:
Resin 10-20%;
Glycerin monomethyl acrylic ester 25-50%;
Light resin type flexographic ink 10-25%;
Propylene glycol methyl ether acetate 1-8%;
Temperature variable pigments 5-9 %;
Pearly pigment 1-5%;
Solvent 10-25%;
Flow agent 0.1-1%;
Dispersion agent 0.5-3%;
Described resin is selected from acrylic resin or urethane resin;
Described solvent is selected from the composition of a kind of composition in a kind of and ethanol in n-propyl acetate, ethyl acetate, n-butyl acetate, isobutyl acetate, Virahol, propyl carbinol;
Described flow agent is the one in acrylic acid or the like, silicone based and fluorocarbon class;
Described dispersion agent be selected from carboxylate salt, sulfuric acid, polyethylene glycol type polyvalent alcohol, polyethylenimine derivates, how in join one in the reactant of polyvalent alcohol-many ethyleneimines segmented copolymer, many caprolactones and triethylene tetramine.
2. cigarette anti-counterfeit ink according to claim 1, is characterized in that, described temperature variable pigments selects Reversible temperature variable pigments.
3. cigarette anti-counterfeit ink according to claim 1, is characterized in that, described flow agent is selected from polydimethylsiloxane, the one in PSI, Organo-modified polysiloxane, polyfluorinated organic polyene hydrocarbon or fluorin modified crylic acid.
4. cigarette anti-counterfeit ink according to claim 1, is characterized in that, described pearly pigment is selected from the one in natural angle scale, Bismuth Oxychloride, lead hydrogen arsenate, white lead carbonate and multiple layer metal oxide compound coated mica.
5. cigarette anti-counterfeit ink according to claim 1, is characterized in that, resin 20%; Glycerin monomethyl acrylic ester 30%; Light resin type flexographic ink 15%; Propylene glycol methyl ether acetate 5%; Temperature variable pigments 8%; Pearly pigment 4%; Solvent 15%; Flow agent 0.8%; Dispersion agent 2.2%.
6. cigarette anti-counterfeit ink according to claim 5, it is characterized in that, described resin is acrylic resin, described solvent is ethyl acetate, described flow agent is polydimethylsiloxane, described dispersion agent is polyethylene glycol type polyvalent alcohol, and described pearly pigment is lead hydrogen arsenate, and described flow agent is polydimethylsiloxane.
7. cigarette anti-counterfeit ink according to claim 1, is characterized in that, resin 18%; Glycerin monomethyl acrylic ester 37%; Light resin type flexographic ink 17%; Propylene glycol methyl ether acetate 6%; Temperature variable pigments 6%; Pearly pigment 3%; Solvent 10%; Flow agent 1%; Dispersion agent 3%.
8. cigarette anti-counterfeit ink according to claim 7, it is characterized in that, described resin is acrylic resin, described solvent is ethyl acetate, described flow agent is polydimethylsiloxane, described dispersion agent is polyethylene glycol type polyvalent alcohol, and described pearly pigment is lead hydrogen arsenate, and described flow agent is polydimethylsiloxane.
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CN201510285311.1A CN104893426B (en) | 2015-05-29 | 2015-05-29 | A kind of cigarette anti-counterfeit ink |
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CN104893426B CN104893426B (en) | 2016-06-29 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105385241A (en) * | 2015-12-28 | 2016-03-09 | 王丽萍 | Efficient anti-forgery printing ink |
CN107686681A (en) * | 2017-09-22 | 2018-02-13 | 安徽顺彤包装材料有限公司 | A kind of cigarette pack bar code anti-counterfeit magnetic printing ink |
CN111534153A (en) * | 2020-06-05 | 2020-08-14 | 浙江特美新材料股份有限公司 | Temperature-sensitive color-changing ink for cigarettes and production process thereof |
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CN2567712Y (en) * | 2002-09-13 | 2003-08-20 | 上海复旦天臣感光材料有限公司 | Optical-angle discolour composite |
CN101333353A (en) * | 2008-05-13 | 2008-12-31 | 常德金鹏印务有限公司 | Purple pearly luster optical variable anti-counterfeiting ink |
CN102399470A (en) * | 2011-11-04 | 2012-04-04 | 江苏泰格油墨有限公司 | Anti-counterfeiting ink for cigarette packets |
CN102964913A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Environment-friendly UV (ultraviolet) silk-screen printing anti-counterfeiting ink and preparation method thereof |
CN103509410A (en) * | 2012-06-23 | 2014-01-15 | 董祺文 | Anti-forgery ink |
CN104164137A (en) * | 2013-05-15 | 2014-11-26 | 株式会社理光 | Photopolymerizable composition, photopolymerizable inkjet ink, ink cartridge, and coated matter |
CN104312277A (en) * | 2014-11-10 | 2015-01-28 | 惠州德斯坤实业有限公司 | Anti-counterfeiting magnetic-conductive printing ink and preparation method thereof |
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2015
- 2015-05-29 CN CN201510285311.1A patent/CN104893426B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN2567712Y (en) * | 2002-09-13 | 2003-08-20 | 上海复旦天臣感光材料有限公司 | Optical-angle discolour composite |
CN101333353A (en) * | 2008-05-13 | 2008-12-31 | 常德金鹏印务有限公司 | Purple pearly luster optical variable anti-counterfeiting ink |
CN102399470A (en) * | 2011-11-04 | 2012-04-04 | 江苏泰格油墨有限公司 | Anti-counterfeiting ink for cigarette packets |
CN103509410A (en) * | 2012-06-23 | 2014-01-15 | 董祺文 | Anti-forgery ink |
CN102964913A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Environment-friendly UV (ultraviolet) silk-screen printing anti-counterfeiting ink and preparation method thereof |
CN104164137A (en) * | 2013-05-15 | 2014-11-26 | 株式会社理光 | Photopolymerizable composition, photopolymerizable inkjet ink, ink cartridge, and coated matter |
CN104312277A (en) * | 2014-11-10 | 2015-01-28 | 惠州德斯坤实业有限公司 | Anti-counterfeiting magnetic-conductive printing ink and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105385241A (en) * | 2015-12-28 | 2016-03-09 | 王丽萍 | Efficient anti-forgery printing ink |
CN107686681A (en) * | 2017-09-22 | 2018-02-13 | 安徽顺彤包装材料有限公司 | A kind of cigarette pack bar code anti-counterfeit magnetic printing ink |
CN111534153A (en) * | 2020-06-05 | 2020-08-14 | 浙江特美新材料股份有限公司 | Temperature-sensitive color-changing ink for cigarettes and production process thereof |
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Effective date of registration: 20160520 Address after: 211106 Jiangning economic and Technological Development Zone, Jiangsu, Jiangsu Province, the source of the road, No. 19, No. Applicant after: Nanjing Tamper-resistant Security Technology Co.,Ltd. Address before: 215300, No. 335 middle Lu Bai Lu, Yushan Town, Suzhou City, Jiangsu, Kunshan Applicant before: Kunshan Dongda Zhihui Technology Consulting Co., Ltd. |
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