CN104891624A

CN104891624A - Water treatment chemical for removing chlorobenzene compounds in water

Info

Publication number: CN104891624A
Application number: CN201510355908.9A
Authority: CN
Inventors: 金双蕾
Original assignee: Individual
Current assignee: Individual
Priority date: 2015-06-25
Filing date: 2015-06-25
Publication date: 2015-09-09

Abstract

The invention relates to water treatment chemical for removing chlorobenzene compounds in water. The water treatment chemical is made from 3, 7-dimethyl-6-octenal, 3-amino-2- hydroxypropionic acid, thymopentin, aluminum sulfate, trans, trans-2, 4-nonadienal, 2-hydroxyl-4-isopropyl-2, 4, 6-cycloheptatriene-1-one, alpha-aminoisocaproic acid, sodium alginate, methylandrostenediol, DL-2-amino-3-hydroxyvaleric acid, isoimperatorin, sodium polyacrylate, 3, 7, 11-trimethyl-1, 6, 10-dodecatriene-3-ol, D-acridine-2-carboxylic acid, and 2-ethyl-2, 5-dimethylhexanoic acid. The water treatment chemical has the advantages that the chemical has high ability to complex with the chlorobenzene compounds, complex precipitant forms fast, the removal rate of the phenolic compounds is up to 99%, and the chemical is low in toxicity, low in use amount, free of harm to water and low in treatment cost.

Description

A kind of water conditioner removing chlorobenzene compounds in water

Technical field

The present invention relates to a kind of water conditioner removing chlorobenzene compounds in water, belong to environmental protection technical field.

Background technology

Chlorobenzene compound is one of principal pollutant in water environment pollution, chloro-benzenes contamination thing has all been listed in priority pollutant list by the U.S., Japan, China etc. in the world a lot of country, China is by chlorobenzene, orthodichlorobenzene, santochlor, and Perchlorobenzene is classified as the chloro-benzenes contamination thing of priority acccess control.Wherein chlorobenzene to central nervous system have suppression and anesthetic action, to skin and mucous membrane irritant; There is serious harm to environment, can pollute water body, soil and air.Santochlor to eye and the upper respiratory tract irritant, have restraining effect to nervus centralis, cause liver, renal impairment; There is harm to environment, can pollute water body and air, in mankind's important foodstuffs chain, particularly biological accumulation can occur in hydrobiont.Orthodichlorobenzene can cause respiratory tract, headache, dizziness, anxiety, anesthetic action, so that unconsciousness.Cause after Perchlorobenzene contact and have stimulation to eye, mouth, nose, liver can be affected time poisoning, central nervous system unifies cardiovascular systems, can skin ulcer be caused; There is serious harm to environment, can pollute water body.

Although the degradation technique of existing chlorobenzene compound achieves certain progress, be mostly in the laboratory study stage.High-level oxidation technology, because condition is harsh, it is high to invest, reactor manufactures the shortcomings such as complicated, is difficult to scale process chlorobenzene class waste water, is only suitable for pre-treatment or aftertreatment.Microbiological deterioration CBs is utilized to be very promising environment clearance technique, but the reaction mechanism of microbiological deterioration chlorobenzene still imperfectly understands, and the impact of outside atmosphere on microorganism growth and chlorobenzene degraded is very large, the impact how overcoming environment is the difficult point of practical application.Although reduction method process chlorobenzene has some superiority, along with a large amount of metal ion for the treatment of processes enters waste water, cause new pollution, the high flow rate of zero-valent metal also result in the difficulty of practical application.

Summary of the invention

The object of the invention is to overcome the deficiencies in the prior art, provide a kind of water conditioner removing chlorobenzene compounds in water, it can with the chlorobenzene compound effect in water, form complex compound sediment, remove by filtering, there is low toxicity, non-environmental-pollution, clearance is high, the advantage that cost is low.

Technology contents of the present invention is: a kind of water conditioner removing chlorobenzene compounds in water, comprises the raw material of the following meter of mark by weight:

3,7-dimethyl-6-octenal 10-20 part,

3-amino-2 hydroxy propanoic acid 6-10 part,

Thymopeptide-5 0.4-1.0 part,

Tai-Ace S 150 15-20 part,

Instead, trans-2,4-nonadienal 10-20 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.5-1.2 part,

Alpha-amino group isocaproic acid 6-14 part,

Sodium Alginate 10-15 part,

Anadrol 3-8 part,

DL-2-amino-3-hydroxypentanoic acid 2-4 part,

Isoimperatorin 2-5 part,

Sodium polyacrylate 5-10 part,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 15-30 part,

D-acridine-2-carboxylic acid 5-8 part,

2-ethyl-2,5-dimethylhexanoic acid 4-6 part.

Preferably, the raw material of the following meter of mark is by weight comprised:

3,7-dimethyl-6-octenal 15 parts,

3-amino-2 hydroxy propanoic acid 8 parts,

Thymopeptide-5 0.7 part,

17 parts, Tai-Ace S 150,

Instead, trans-2,4-nonadienal 15 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.8 part,

Alpha-amino group isocaproic acid 10 parts,

Sodium Alginate 12 parts,

Anadrol 5 parts,

DL-2-amino-3-hydroxypentanoic acid 3 parts,

Isoimperatorin 3 parts,

Sodium polyacrylate 7 parts,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,

D-acridine-2-carboxylic acid 6 parts,

2-ethyl-2,5-dimethylhexanoic acid 5 parts.

The present invention has following beneficial effect:

(1) 3,7-dimethyl-6-octenal, 3-amino-2 hydroxy propanoic acid, thymopeptide-5, Tai-Ace S 150 four kinds of materials produce synergy, can with chlorobenzene effect, form complex compound sediment; Instead, trans-2,4-nonadienal, 2-hydroxyl-4-sec.-propyl-2,4, these six kinds of materials of 6-cycloheptatriene-1-ketone, alpha-amino group isocaproic acid, Sodium Alginate, anadrol, DL-2-amino-3-hydroxypentanoic acid produce synergy, can with orthodichlorobenzene and santochlor effect, formed complex compound sediment; Isoimperatorin, sodium polyacrylate, 3,7,11-trimethylammoniums-1,6,10-12 carbon triolefin-3-alcohol, D-acridine-2-carboxylic acid, 2-ethyl-2,5-dimethylhexanoic acid five kinds of materials produce synergy, can with Perchlorobenzene effect, form complex compound sediment;

(2) strong with the complex ability of chlorobenzene compound, form complex compound sediment speed fast, clearance can reach 99%;

(3) hypotoxicity, consumption is few, does not produce harm to water body;

(4) only need dosing and filtering separation device, low for equipment requirements, processing cost is low.

Embodiment

Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the described scope of embodiment.

Embodiment 1

Remove a water conditioner for chlorobenzene compounds in water, comprise the raw material of the following meter of mark by weight:

3,7-dimethyl-6-octenal 11 parts,

3-amino-2 hydroxy propanoic acid 7 parts,

Thymopeptide-5 0.5 part,

16 parts, Tai-Ace S 150,

Instead, trans-2,4-nonadienal 12 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.6 part,

Alpha-amino group isocaproic acid 13 parts,

Sodium Alginate 12 parts,

Anadrol 4 parts,

DL-2-amino-3-hydroxypentanoic acid 3 parts,

Isoimperatorin 4 parts,

Sodium polyacrylate 8 parts,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 23 parts,

D-acridine-2-carboxylic acid 7 parts,

2-ethyl-2,5-dimethylhexanoic acid 6 parts.

Before process: containing chlorobenzene 10mg, orthodichlorobenzene 10mg, santochlor 10mg in 1L water sample, add this water conditioner 50mg;

After process: containing chlorobenzene 0.01mg, orthodichlorobenzene 0.01 mg in 1L water sample, santochlor does not detect.

Embodiment 2

3,7-dimethyl-6-octenal 16 parts,

3-amino-2 hydroxy propanoic acid 7 parts,

Thymopeptide-5 0.8 part,

17 parts, Tai-Ace S 150,

Instead, trans-2,4-nonadienal 17 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.9 part,

Alpha-amino group isocaproic acid 11 parts,

Sodium Alginate 13 parts,

Anadrol 6 parts,

DL-2-amino-3-hydroxypentanoic acid 3 parts,

Isoimperatorin 4 parts,

Sodium polyacrylate 8 parts,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 25 parts,

D-acridine-2-carboxylic acid 7 parts,

2-ethyl-2,5-dimethylhexanoic acid 5 parts.

Before process: containing chlorobenzene 10mg, orthodichlorobenzene 10mg, Perchlorobenzene 10mg in 1L water sample, add this water conditioner 50mg;

After process: all do not detect containing chlorobenzene, orthodichlorobenzene and Perchlorobenzene in 1L water sample.

Embodiment 3

3,7-dimethyl-6-octenal 15 parts,

3-amino-2 hydroxy propanoic acid 8 parts,

Thymopeptide-5 0.7 part,

17 parts, Tai-Ace S 150,

Instead, trans-2,4-nonadienal 15 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.8 part,

Alpha-amino group isocaproic acid 10 parts,

Sodium Alginate 12 parts,

Anadrol 5 parts,

DL-2-amino-3-hydroxypentanoic acid 3 parts,

Isoimperatorin 3 parts,

Sodium polyacrylate 7 parts,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,

D-acridine-2-carboxylic acid 6 parts,

2-ethyl-2,5-dimethylhexanoic acid 5 parts.

Before process: in 1L water sample containing chlorobenzene 15mg, santochlor 15mg, Perchlorobenzene 15mg, add this water conditioner 50mg;

After process: in 1L water sample, chlorobenzene, santochlor and Perchlorobenzene all do not detect.

The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims

1. remove a water conditioner for chlorobenzene compounds in water, it is characterized in that, comprise the raw material of the following meter of mark by weight:

3,7-dimethyl-6-octenal 10-20 part,

3-amino-2 hydroxy propanoic acid 6-10 part,

Thymopeptide-5 0.4-1.0 part,

Tai-Ace S 150 15-20 part,

Instead, trans-2,4-nonadienal 10-20 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.5-1.2 part,

Alpha-amino group isocaproic acid 6-14 part,

Sodium Alginate 10-15 part,

Anadrol 3-8 part,

DL-2-amino-3-hydroxypentanoic acid 2-4 part,

Isoimperatorin 2-5 part,

Sodium polyacrylate 5-10 part,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 15-30 part,

D-acridine-2-carboxylic acid 5-8 part,

2-ethyl-2,5-dimethylhexanoic acid is about 4-6 part.

2. the water conditioner of removal chlorobenzene compounds in water according to claim 1, is characterized in that, comprises the raw material of the following meter of mark by weight:

3,7-dimethyl-6-octenal 15 parts,

3-amino-2 hydroxy propanoic acid 8 parts,

Thymopeptide-5 0.7 part,

17 parts, Tai-Ace S 150,

Instead, trans-2,4-nonadienal 15 parts,

2-hydroxyl-4-sec.-propyl-2,4,6-cycloheptatriene-1-ketone 0.8 part,

Alpha-amino group isocaproic acid 10 parts,

Sodium Alginate 12 parts,

Anadrol 5 parts,

DL-2-amino-3-hydroxypentanoic acid 3 parts,

Isoimperatorin 3 parts,

Sodium polyacrylate 7 parts,

3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,

D-acridine-2-carboxylic acid 6 parts,

2-ethyl-2,5-dimethylhexanoic acid 5 parts.