CN104877466B - A kind of glutinous rice environmental protection coating material and preparation method thereof - Google Patents
A kind of glutinous rice environmental protection coating material and preparation method thereof Download PDFInfo
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- CN104877466B CN104877466B CN201510288140.8A CN201510288140A CN104877466B CN 104877466 B CN104877466 B CN 104877466B CN 201510288140 A CN201510288140 A CN 201510288140A CN 104877466 B CN104877466 B CN 104877466B
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- starch
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- coating material
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of glutinous rice environmental protection coating material, be made up of following raw material according to mass percent: sticky rice flour 37% ~ 39%, starch crops 15% ~ 20%, ash calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%.The invention discloses the preparation method of above-mentioned glutinous rice environmental protection coating material.Glutinous rice environmental protection coating material of the present invention has that cohesiveness is strong, waterproof and dampproof, non-scale does not come off, nontoxic, harmless, free of contamination feature, can also reach the effect purified air simultaneously.Coating and water by a certain percentage mix and blend can be constructed, and can directly use on blank wall, need not play putty and use emulsion paint, therefore can not cause dust from flying because of polishing, polluting construction environment, it also avoid the threat that formaldehyde is healthy to resident family.
Description
Technical field
The invention belongs to constructional ornamental material technical field, relate to a kind of glutinous rice environmental protection coating material, the invention still further relates to the preparation method of above-mentioned glutinous rice environmental protection coating material.
Background technology
Traditional dope for inner wall of architecture, because of containing formaldehyde, brings serious harm to people are healthy, and gradually by market is eliminated, nontoxic environmental protection coating material then becomes the first-selection of people.Through development for many years, some interior wall coating is up to state standards, meets the requirement of nontoxic coating.But these environment friendly emulsion paints can not directly brush on wall, putty be leaned on as bottom, and can add the glue containing formaldehyde in the construction process of putty, the formaldehyde after finishing in putty slowly volatilizees, and same family and the public place given pollutes and injure.These coating run into wet weather simultaneously, will go bad mouldy and produce mould, causing the peeling that comes off, not only bring many puzzlements, and can produce unnecessary industrial refuse.
Summary of the invention
The object of this invention is to provide a kind of glutinous rice environmental protection coating material, solving existing interior wall coating can not directly use, and construction need take putty as bottom, and then release formaldehyde, is detrimental to health, and easily comes off after construction, produces the problem of unnecessary industrial refuse.
Another object of the present invention is to provide the preparation method of above-mentioned glutinous rice environmental protection coating material.
The technical solution adopted in the present invention is, a kind of glutinous rice environmental protection coating material, it is characterized in that, be made up of following raw material according to mass percent: sticky rice flour 37% ~ 39%, starch crops 15% ~ 20%, grey calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%.
Feature of the present invention is also,
Starch crops is made up of W-Gum, sweet potato starch and yam starch, and the per-cent that each kind of starch accounts for all raw material total masses is respectively: W-Gum 4% ~ 6%, sweet potato starch 5.5% ~ 7%, yam starch 5.5% ~ 7%.
Another technical scheme of the present invention is, a kind of preparation method of glutinous rice environmental protection coating material, implements according to the following steps:
Step 1, takes sticky rice flour, starch crops, grey calcium, coarse whiting, diatom ooze and negative ion powder;
Step 2, by sticky rice flour and starch crops polishing to granularity be 800 order ~ 900 object powders, and powder cured respectively at the temperature of 70 DEG C ~ 80 DEG C stir ripe, churning time is 20 ~ 30min, then the powder after baking and banking up with earth is polished respectively to granularity be 1200 order ~ 1400 orders;
Step 3, the powder after step 2 being cured mixes with grey calcium, coarse whiting, diatom ooze and negative ion powder uniform stirring, and churning time is 20 ~ 30min, namely obtains glutinous rice environmental protection coating material.
Feature of the present invention is also,
The ratio of each raw material is respectively by mass percentage: sticky rice flour 37% ~ 39%, starch crops 15% ~ 20%, grey calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%.
Starch crops is made up of W-Gum, sweet potato starch and yam starch, and the per-cent that each kind of starch accounts for all raw material total masses is respectively: W-Gum 4% ~ 6%, sweet potato starch 5.5% ~ 7%, yam starch 5.5% ~ 7%.
The granularity of ash calcium, coarse whiting, diatom ooze and negative ion powder is 1200 order ~ 1400 orders.
The invention has the beneficial effects as follows, glutinous rice environmental protection coating material of the present invention is formed through processing and fabricating by multiple agricultural-food and stone, finished product is white powder, have that cohesiveness is strong, waterproof and dampproof, non-scale does not come off, nontoxic, harmless, free of contamination feature, the effect purified air can also be reached simultaneously.Coating and water by a certain percentage mix and blend can be constructed, can directly use on blank wall, putty need not be played and use emulsion paint, therefore dust from flying can not be caused because of polishing, pollute construction environment, it also avoid the threat that formaldehyde is healthy to resident family, this coating application is simple simultaneously, has greatly saved the engineering time.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
The invention provides a kind of glutinous rice environmental protection coating material, be made up of following raw material according to mass percent: sticky rice flour 37% ~ 39%, starch crops 15% ~ 20%, ash calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%.
Wherein starch crops is made up of W-Gum, sweet potato starch and yam starch, and the per-cent that each kind of starch accounts for all raw material total masses is respectively: W-Gum 4% ~ 6%, sweet potato starch 5.5% ~ 7%, yam starch 5.5% ~ 7%.
The preparation method of the above-mentioned glutinous rice environmental protection coating material of the present invention, specifically implements according to the following steps:
Step 1, divides another name sticky rice flour 37% ~ 39%, starch crops 15% ~ 20% by mass percentage, ash calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%; Wherein, starch crops is made up of W-Gum, sweet potato starch and yam starch, and the per-cent that each kind of starch accounts for all raw material total masses is respectively: W-Gum 4% ~ 6%, sweet potato starch 5.5% ~ 7%, yam starch 5.5% ~ 7%;
Step 2, by sticky rice flour and starch crops polishing to granularity be 800 order ~ 900 object powders, and powder cured respectively at the temperature of 70 DEG C ~ 80 DEG C stir ripe, churning time is 20 ~ 30min, then the powder after baking and banking up with earth is polished respectively to granularity be 1200 order ~ 1400 orders;
Step 3, the powder after step 2 being cured mixes with grey calcium, coarse whiting, diatom ooze and negative ion powder uniform stirring, and churning time is 20 ~ 30min, namely obtains glutinous rice environmental protection coating material.
Wherein, the granularity of grey calcium, coarse whiting, diatom ooze and negative ion powder is 1200 order ~ 1400 orders.
Strictly should control stoving temperature in glutinous rice environmental protection coating material preparation process of the present invention, temperature can not lower than 70 °, otherwise the moisture in product can not volatilize totally in time, causes depositing and use procedure mesometamorphism.Can not higher than 80 °, the variable color otherwise meeting is excessively dried up, presents pasty state, cannot use.
In coating, sticky rice flour, W-Gum, sweet potato starch, yam starch are mixed in proportion, and can reduce the surface tension of coating, increase surface free energy and infiltrate, expandable mass Intermolecular Forces simultaneously, and then the bonding and attachment metope making the interaction energy of interface electrostatic introduction fabulous.
Negative ion powder is the mixture of tourmaline powder+lanthanon or rare earth element, the ratio of its rare earth elements greatly exceed tourmaline powder, account for more than 60%, negative ion powder can release air negative ion, conveying negative charge is to bacterium, dust, smoke particles and water droplet etc., electric charge combines with these particulates and is polymerized to ball and sinks, thus reaches the object purified air.In the irritant gass such as the benzene that negative ion powder evaporates art work, formaldehyde, ketone, ammonia and daily life, air peculiar smell etc. all has good adsorption.
Its special multi-pore structure of diatom ooze, equally can objectionable impurities in active adsorption, also has the effect of adjusting air humidity, noise reduction, heat insulating, fire protection flame retarding simultaneously.
Glutinous rice environmental protection coating material of the present invention is formed through processing and fabricating by multiple agricultural-food and stone, finished product is white powder, have that cohesiveness is strong, waterproof and dampproof, non-scale does not come off, nontoxic, harmless, free of contamination feature, the effect purified air can also be reached simultaneously.Coating and water by a certain percentage mix and blend can be constructed, can directly use on blank wall, putty need not be played and use emulsion paint, therefore dust from flying can not be caused because of polishing, pollute construction environment, it also avoid the threat that formaldehyde is healthy to resident family, this coating application is simple simultaneously, has greatly saved the engineering time.
Embodiment 1
Take sticky rice flour 380 kilograms respectively, W-Gum 50 kilograms, sweet potato starch 60 kilograms, yam starch 60 kilograms, grey calcium 100 kilograms, coarse whiting 150 kilograms, diatom ooze 190 kilograms, negative ion powder 10 kilograms.By sticky rice flour, W-Gum, sweet potato starch and yam starch polishing to granularity be 800 order ~ 900 orders, and powder is cured respectively at the temperature of 70 DEG C stirring maturation, churning time is 20min, then the powder after baking and banking up with earth is polished respectively to granularity be 1200 order ~ 1400 orders; Grey calcium, coarse whiting, diatom ooze and negative ion powder are polished respectively simultaneously to granularity be 1200 order ~ 1400 orders.Mixed with grey calcium, coarse whiting, diatom ooze and negative ion powder uniform stirring by powder after baking and banking up with earth, churning time is 30min, namely obtains glutinous rice environmental protection coating material.
Embodiment 2
Take sticky rice flour 370 kilograms respectively, W-Gum 60 kilograms, sweet potato starch 55 kilograms, yam starch 70 kilograms, grey calcium 95 kilograms, coarse whiting 145 kilograms, diatom ooze 185 kilograms, negative ion powder 20 kilograms.By sticky rice flour, W-Gum, sweet potato starch and yam starch polishing to granularity be 800 order ~ 900 orders, and powder is cured respectively at the temperature of 80 DEG C stirring maturation, churning time is 25min, then the powder after baking and banking up with earth is polished respectively to granularity be 1200 order ~ 1400 orders; Grey calcium, coarse whiting, diatom ooze and negative ion powder are polished respectively simultaneously to granularity be 1200 order ~ 1400 orders.Mixed with grey calcium, coarse whiting, diatom ooze and negative ion powder uniform stirring by powder after baking and banking up with earth, churning time is 20min, namely obtains glutinous rice environmental protection coating material.
Embodiment 3
Take sticky rice flour 390 kilograms respectively, W-Gum 40 kilograms, sweet potato starch 70 kilograms, yam starch 55 kilograms, grey calcium 110 kilograms, coarse whiting 140 kilograms, diatom ooze 180 kilograms, negative ion powder 15 kilograms.By sticky rice flour, W-Gum, sweet potato starch and yam starch polishing to granularity be 800 order ~ 900 orders, and powder is cured respectively at the temperature of 75 DEG C stirring maturation, churning time is 30min, then the powder after baking and banking up with earth is polished respectively to granularity be 1200 order ~ 1400 orders; Grey calcium, coarse whiting, diatom ooze and negative ion powder are polished respectively simultaneously to granularity be 1200 order ~ 1400 orders.Mixed with grey calcium, coarse whiting, diatom ooze and negative ion powder uniform stirring by powder after baking and banking up with earth, churning time is 25min, namely obtains glutinous rice environmental protection coating material.
Claims (3)
1. a glutinous rice environmental protection coating material, it is characterized in that, be made up of following raw material according to mass percent: sticky rice flour 37% ~ 39%, starch crops 15% ~ 20%, ash calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%;
Described starch crops is made up of W-Gum, sweet potato starch and yam starch, and the per-cent that each kind of starch accounts for all raw material total masses is respectively: W-Gum 4% ~ 6%, sweet potato starch 5.5% ~ 7%, yam starch 5.5% ~ 7%.
2. a preparation method for glutinous rice environmental protection coating material, is characterized in that, specifically implements according to the following steps:
Step 1, take sticky rice flour, starch crops, grey calcium, coarse whiting, diatom ooze and negative ion powder, the ratio of each raw material is respectively by mass percentage: sticky rice flour 37% ~ 39%, starch crops 15% ~ 20%, ash calcium 9.5% ~ 11%, coarse whiting 14% ~ 15%, diatom ooze 18% ~ 19%, negative ion powder 1.5% ~ 2%, above constituent mass per-cent sum is 100%;
Described starch crops is made up of W-Gum, sweet potato starch and yam starch, and the per-cent that each kind of starch accounts for all raw material total masses is respectively: W-Gum 4% ~ 6%, sweet potato starch 5.5% ~ 7%, yam starch 5.5% ~ 7%;
Step 2, by sticky rice flour and starch crops polishing to granularity be 800 order ~ 900 object powders, and powder cured respectively at the temperature of 70 DEG C ~ 80 DEG C stir ripe, churning time is 20 ~ 30min, then the powder after baking and banking up with earth is polished respectively to granularity be 1200 order ~ 1400 orders;
Step 3, the powder after step 2 being cured mixes with grey calcium, coarse whiting, diatom ooze and negative ion powder uniform stirring, and churning time is 20 ~ 30min, namely obtains glutinous rice environmental protection coating material.
3. the preparation method of a kind of glutinous rice environmental protection coating material according to claim 2, is characterized in that, the granularity of described grey calcium, coarse whiting, diatom ooze and negative ion powder is 1200 order ~ 1400 orders.
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CN1052996C (en) * | 1996-01-25 | 2000-05-31 | 翟广玉 | Wall plaster |
CN101117539A (en) * | 2006-08-04 | 2008-02-06 | 中宏(天津)实业有限公司 | Method for preparing waterproofing paint |
CN104109444B (en) * | 2014-07-08 | 2016-03-23 | 甘肃圣邦布兰卡新材料有限公司 | Biomass interior wall coating and preparation method thereof |
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