CN104862815A - Antibacterial antistatic fibers based on polytrimethylene terephthalate - Google Patents
Antibacterial antistatic fibers based on polytrimethylene terephthalate Download PDFInfo
- Publication number
- CN104862815A CN104862815A CN201410548018.5A CN201410548018A CN104862815A CN 104862815 A CN104862815 A CN 104862815A CN 201410548018 A CN201410548018 A CN 201410548018A CN 104862815 A CN104862815 A CN 104862815A
- Authority
- CN
- China
- Prior art keywords
- polytrimethylene terephthalate
- fiber based
- antibiotic
- antistatic
- antibacterial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses antibacterial antistatic fibers based on polytrimethylene terephthalate. The antibacterial antistatic fibers comprise the following ingredients, by weight, 70%-90% of PTT, 5%-15% of TPEE, 2%-6% of poly(diisobutyl adipate), 2%-5% of antibacterial agent, 1%-3% of antistatic agents, 0.5%-2% of ultraviolet ray absorbers, 0.1%-0.5% of anti-oxidants and 0.1%-1% of lubricants. The antibacterial agent is one selected from silver ion calcium phosphate, silver ion antibacterial zeolite, silicon dioxide modified organic antibacterial agent and phosphonium salt antibacterial agent. The beneficial effects are that the antibacterial antistatic fibers have good antibacterial and anti-ultraviolet radiation functions, the antistatic performance is good, the chemical resistance is high, the flexibility is good, the anti-pollution performance is strong, and the fibers are suitable for the textile fabric field.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of antibiotic antistatic fiber based on polytrimethylene terephthalate.
Background technology
Polytrimethylene terephthalate (PTT) is as a kind of new polyester macromolecular material of excellent combination property, be widely used in fiber at present, film, the fields such as engineering plastics, ptt fiber combines the flexibility of nylon, with the outstanding rigid phase ratio of polyster fibre and goods, the feel of ptt fiber and fabric can give the soft and comfortable sensation close to nylon, add the good drapability of fabric and suitable elasticity, for fashion designer provides design inspiration and more wide space of thinking, ptt fiber has the advantage of spandex class elastic fabric, lower than spandex class elastic fabric cost again, and the good stability of the dimension of fabric, anti-fold increases, therefore PTT is integrated in one the excellent wearability of various fiber, be highly suitable for producing knitting and woven stretch fabric, ptt fiber is valued by the people because it has excellent comprehensive applicability.
Summary of the invention
The object of the present invention is to provide a kind of antibiotic antistatic fiber based on polytrimethylene terephthalate.
The technical solution adopted for the present invention to solve the technical problems is: based on the antibiotic antistatic fiber of polytrimethylene terephthalate, its component by mass percent proportioning is: PTT 70% ~ 90%, TPEE 5% ~ 15%, poly-adipic acid isobutyl diester 2% ~ 6%, antiseptic 2% ~ 5%, antistatic additive 1% ~ 3%, ultra-violet absorber 0.5% ~ 2%, antioxidant 0.1% ~ 0.5%, lubricant 0.1% ~ 1%.
Described PTT is polytrimethylene terephthalate.
Described TPEE is thermoplastics type's polyethers fat.
Described antiseptic is the one in silver ion calcium phosphate, silver-ion antibiotic zeolite, silica modified organic antibacterial agent, quaternary alkylphosphonium salt antiseptic.
Described antistatic additive is commercially available antistatic additive HKD-510 or antistatic additive HKD-912.
Described ultra-violet absorber is the one in Hydroxyphenyltriazines ultra-violet absorber, bisphenol a disalicylate ultra-violet absorber, 2-hydroxyl-4 n-octyloxies-benzophenone, 2,4-DihydroxyBenzophenone.
Described antioxidant is the hindered phenol antioxygen 1076 of mass ratio 1:1 and the compound of phosphite antioxidant 168.
Described lubricant is the one in pentaerythritol stearate, silicone powder, modification ethylene bis stearamide.
The preparation method of the above-mentioned antibiotic antistatic fiber based on polytrimethylene terephthalate is: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, blended through screw machine extruding, melting, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, winding speed controls at 1000 ~ 3000m/min, heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 6 times, obtain the antibiotic antistatic fiber based on polytrimethylene terephthalate of the present invention.
The invention has the beneficial effects as follows, the present invention has good antibacterial and ultraviolet radiation preventing function, and antistatic property is good, and chemical resistance is strong, and flexibility is good, and antifouling property is strong, is suitable for textile fabric field.
Detailed description of the invention
Technical scheme of the present invention is further illustrated below in conjunction with concrete preferred embodiment.
Embodiment 1:
A kind of antibiotic antistatic fiber based on polytrimethylene terephthalate, its component by mass percent proportioning is: PTT 71%, TPEE 15%, poly-adipic acid isobutyl diester 5%, silver ion calcium phosphate 5%, antistatic additive HKD-510 2%, Hydroxyphenyltriazines ultra-violet absorber 1.5%, antioxidant 0.1%, pentaerythritol stearate 0.4%, described PTT is polytrimethylene terephthalate, described TPEE is thermoplastics type's polyethers fat, and described antioxidant is the hindered phenol antioxygen 1076 of mass ratio 1:1 and the compound of phosphite antioxidant 168.
Preparation method: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, through blended, the melting of screw machine extruding, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, winding speed controls at 1000 ~ 3000m/min, heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 6 times, obtains the antibiotic antistatic fiber based on polytrimethylene terephthalate of the present invention.
Embodiment 2:
A kind of antibiotic antistatic fiber based on polytrimethylene terephthalate, its component by mass percent proportioning is: PTT 80%, TPEE 10%, poly-adipic acid isobutyl diester 3%, silver-ion antibiotic zeolite 3%, antistatic additive HKD-912 3%, bisphenol a disalicylate ultra-violet absorber 0.5%, antioxidant 0.1%, silicone powder 0.4%, described PTT is polytrimethylene terephthalate, described TPEE is thermoplastics type's polyethers fat, and described antioxidant is the hindered phenol antioxygen 1076 of mass ratio 1:1 and the compound of phosphite antioxidant 168.
Preparation method: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, through blended, the melting of screw machine extruding, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, winding speed controls at 1000 ~ 3000m/min, heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 6 times, obtains the antibiotic antistatic fiber based on polytrimethylene terephthalate of the present invention.
Claims (7)
1. the antibiotic antistatic fiber based on polytrimethylene terephthalate, it is characterized in that, its component by mass percent proportioning is: PTT 70% ~ 90%, TPEE 5% ~ 15%, poly-adipic acid isobutyl diester 2% ~ 6%, antiseptic 2% ~ 5%, antistatic additive 1% ~ 3%, ultra-violet absorber 0.5% ~ 2%, antioxidant 0.1% ~ 0.5%, lubricant 0.1% ~ 1%.
2. the antibiotic antistatic fiber based on polytrimethylene terephthalate according to claim 1, it is characterized in that, described antiseptic is the one in silver ion calcium phosphate, silver-ion antibiotic zeolite, silica modified organic antibacterial agent, quaternary alkylphosphonium salt antiseptic.
3. the antibiotic antistatic fiber based on polytrimethylene terephthalate according to claim 1, is characterized in that, described antistatic additive is commercially available antistatic additive HKD-510 or antistatic additive HKD-912.
4. the antibiotic antistatic fiber based on polytrimethylene terephthalate according to claim 1, it is characterized in that, described ultra-violet absorber is the one in Hydroxyphenyltriazines ultra-violet absorber, bisphenol a disalicylate ultra-violet absorber, 2-hydroxyl-4 n-octyloxies-benzophenone, 2,4-DihydroxyBenzophenone.
5. the antibiotic antistatic fiber based on polytrimethylene terephthalate according to claim 1, is characterized in that, described antioxidant is the hindered phenol antioxygen 1076 of mass ratio 1:1 and the compound of phosphite antioxidant 168.
6. the antibiotic antistatic fiber based on polytrimethylene terephthalate according to claim 1, is characterized in that, described lubricant is the one in pentaerythritol stearate, silicone powder, modification ethylene bis stearamide.
7. the preparation method of the antibiotic antistatic fiber based on polytrimethylene terephthalate according to claim 1, it is characterized in that, comprise the following steps: take each component by weight ratio, and add respectively in medium speed mixer, make to stir 3 ~ 15 minutes together, evenly rear discharging to be mixed adds twin (double) screw extruder, blended through screw machine extruding, melting, carry out spinning again, the melt temperature of spinning controls between 220 DEG C ~ 280 DEG C, winding speed controls at 1000 ~ 3000m/min, heat setting temperature is 80 DEG C ~ 150 DEG C, drafting multiple controls between 2 ~ 6 times, obtain the antibiotic antistatic fiber based on polytrimethylene terephthalate of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410548018.5A CN104862815A (en) | 2014-10-16 | 2014-10-16 | Antibacterial antistatic fibers based on polytrimethylene terephthalate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410548018.5A CN104862815A (en) | 2014-10-16 | 2014-10-16 | Antibacterial antistatic fibers based on polytrimethylene terephthalate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104862815A true CN104862815A (en) | 2015-08-26 |
Family
ID=53908965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410548018.5A Pending CN104862815A (en) | 2014-10-16 | 2014-10-16 | Antibacterial antistatic fibers based on polytrimethylene terephthalate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104862815A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463594A (en) * | 2015-11-09 | 2016-04-06 | 浙江易彤色纺科技有限公司 | Melt spinning method by directly adding functional materials and/or pigments |
| CN109518301A (en) * | 2018-11-26 | 2019-03-26 | 合肥卓汇新材料科技有限公司 | A kind of easily combing antistatic wig fiber |
| CN115287824A (en) * | 2022-06-29 | 2022-11-04 | 惠州市普林摩斯无纺布有限公司 | Antibacterial anti-mite non-woven fabric for mattress lining and preparation process thereof |
-
2014
- 2014-10-16 CN CN201410548018.5A patent/CN104862815A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463594A (en) * | 2015-11-09 | 2016-04-06 | 浙江易彤色纺科技有限公司 | Melt spinning method by directly adding functional materials and/or pigments |
| CN109518301A (en) * | 2018-11-26 | 2019-03-26 | 合肥卓汇新材料科技有限公司 | A kind of easily combing antistatic wig fiber |
| CN115287824A (en) * | 2022-06-29 | 2022-11-04 | 惠州市普林摩斯无纺布有限公司 | Antibacterial anti-mite non-woven fabric for mattress lining and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104862812A (en) | Antibiosis-functionalized PTT polyester fibers and preparation method therefor | |
| US9523160B2 (en) | Method of preparing antimicrobial 3D-printing filament | |
| CN104862815A (en) | Antibacterial antistatic fibers based on polytrimethylene terephthalate | |
| CN104558776B (en) | A kind of antibacterial plastic concentrate and preparation method thereof and antibacterial artificial grass and preparation method thereof | |
| CN111621091B (en) | Ultraviolet-resistant sterilized polypropylene spunbonded fabric with antibacterial performance and preparation method and application thereof | |
| EP2499916A1 (en) | Antimicrobial water treatment agent | |
| CN111662505B (en) | Antibacterial nonwoven material and preparation method thereof | |
| CN105239194A (en) | Method of preparing flame-retarding anti-microbial polylactic acid fibers, spinning fibers into yarn and making fabric | |
| CN103627129A (en) | Antibacterial dust-suppression halogen-free flam-retardant ABS and preparation technology thereof | |
| CN105420926A (en) | Anti-radiation fabric | |
| US10385477B2 (en) | Method for preparing nylon yarns | |
| CN105177758A (en) | Antistatic polyacrylonitrile/polyaniline composite fiber material and preparation method thereof | |
| CN102485981A (en) | Flame-retardant nanometer bamboo charcoal antibiosis filler fiber and manufacturing method thereof | |
| CN114532354A (en) | Antibacterial compound, antibacterial polycarbonate material, and preparation method and application thereof | |
| CN104372446A (en) | Dry-process spandex spinning oil agent | |
| CN110438577A (en) | Polypropylene flame redardant composite material and its product | |
| CN105906913A (en) | Flame-retardant antibacterial antistatic polyethylene plastic for packaging and preparation method thereof | |
| CN112225936A (en) | Porous aerogel, preparation method thereof and antibacterial flame-retardant PP (polypropylene) fiber containing porous aerogel | |
| CN106049043A (en) | Fabric antibacterial finishing agent and preparation method thereof | |
| CN107383529B (en) | Master batch and preparation method thereof is melted in a kind of fire-retardant toughened increasing for polypropylene fiber | |
| CN103421242A (en) | PP (polypropylene) and PET composite antibacterial plastic alloy | |
| CN106280301A (en) | A kind of flame-retardant color master batch grain | |
| CN104846475A (en) | Antibacterial and anti-static PET/PTT/TPEE composite fiber | |
| CN112143095A (en) | Flame-retardant polypropylene composite material and preparation method and application thereof | |
| CN105483850B (en) | Sulfur-bearing anti-bacterial fibre material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150826 |
|
| WD01 | Invention patent application deemed withdrawn after publication |