CN104856895A - Silicon-free liquid shampoo and preparation method thereof - Google Patents
Silicon-free liquid shampoo and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a silicon-free liquid shampoo and a preparation method thereof. The silicon-free liquid shampoo comprises 0.5-5% of inulin, 0.2-5% of vegetable fat, 0.2-2% of a solubilizing agent, 0.2-2% of a thickening agent, 3-8% of sodium laureth sulfate, 3-8% of cocamidopropyl betaine, 1-5% of alkyl glycoside, 1-5% of sodium cocoyl glycinate, 0.05-0.5% of ethylene diamine tetraacetic acid tetrasodium, 0.05-0.5% of citric acid, 0.2-1% of preservative, 0.2-1% of essence and 58-90% of water. The silicon-free liquid shampoo is mild and non-stimulating, and can nurse hairs efficiently while being used for cleaning hairs; the cleaned hairs are glossy, soft and smooth.
Description
Technical field
The invention belongs to daily use chemicals articles for washing technical field, be specifically related to a kind of without silicon shampoo and preparation method thereof.
Background technology
Shampoo is generally containing primary surfactant, auxiliary surfactant, conditioner, smooth dose, the raw material such as shampoo and essence.Smooth dose refers generally to the full-bodied silicon compound of some high molecular, and they are adsorbed on each root hair surface, forms very smooth thin film, makes hair smooth.Silicon compound conventional in current shampoo has polydimethylsiloxane, amido silicon oil, cyclomethicone etc., and when our hair-washing hair-care, these silicon-containing compounds can fill up the gap between hair scale sheet, and people can be allowed to feel, and hair sense of touch is very smooth.
But along with growth in the living standard, people also more and more pay close attention to the safety of cosmetics of everyday use, although the silicon compound in shampoo can allow hair smooth, but due to the water-fast characteristic of these silicon-containing compounds, the silicon be wrapped on hair and scalp is not too easily cleaned up, enrichment so year in year out, these silicon-containing compounds can make hair lose elasticity gradually, scalp clogging of pores, cause scalp oxygen flow not enough, hair papilla is atrophy gradually, and scalp just starts to occur itching, the phenomenon of even alopecia.Whether the silicon-containing compound in shampoo is existed to the problem of other infringement healths, although not yet obtain authoritative department at present to confirm, but have and suggest that the shampoo of best different brands changes and use, same silicone oil is avoided to deposit on hair, but such way also cannot avoid the silicon-containing compound in shampoo to the possible potential risks of health, therefore people start the shampoo seeking not silicate-containing oil, but have " polydimethylsiloxane " in the current shampoo component list on the market more than ninety percent, the shampoo of silicate-containing oil does not only have several.
Patent documentation CN 104473790 A discloses a kind of without silicon shampoo, and it comprises alkylpolyoxyethylene sodium sulfate, cocamido propyl betaine, cocinic acid, diglycollic amide, glycol stearate, cellulose quaternary ammonium salt, citric acid, sodium chloride, shredding, essence, disodium EDTA and water.Though this shampoo not silicate-containing oil, but containing cationic surfactant cellulose quaternary ammonium salt, larger to skin irritation.
In shampoo, surfactant plays regulatory role, and the electrostatic in hair is minimized, and makes hair be easy to combing, is easy to unclamp, and is that the combing of wet hair and dry hair is easy and smooth and easy.Meanwhile, shampoo requires the micelle structure etc. of high spumescence, low degreasing power, low zest, the easily higher system viscosity of formation, and the selection of such Surfactant just has certain restriction.The zest of cationic surfactant as cationic polymers such as guar gum quaternary ammonium salt, polyquaternary ammonium salt is large, biological degradability is poor, and due to hair and dirt general all electronegative, this will make dirt-removing power be deteriorated, attachment is serious.Simultaneously cationic polymer can show the eutrophication to surface water, this be due to they nitrogen content and a large amount of can wash at cosmetic the cationic polymer that compositions uses and cause every year.Therefore, there is a kind of trend will limit cationic polymer and can wash compositions use at cosmetic.Accordingly, people are just seeking cosmetic and can wash the substitute of compositions cationic polymer, specific saccharide and glycocalix open, as sucrose, alginate, inulin, guar gum etc.
Inulin is mainly derived from plant, is to be contained in the protoplasm of cell with colloid form, and its molecule is about polymerized by 31 beta-D-fructofuranoses and 1 ~ 2 pyrans inulin residue, by β-2 between residue of fructose, 1-key connects, and the polymeric mixture of fructose, in nonionic.Compared with cationic polymer, there is non-stimulated, avirulence, the advantage such as biodegradable.
Patent documentation CN 1889924 A discloses a kind of cosmetic containing inulin-type levan can wash compositions, this washing compositions contains 0.10 ~ 10%, preferably 0.5 ~ 5%, the most preferably inulin-type levan (to wash the percentage by weight of the dry of composition total weight) of 1 ~ 3%, inulin-type levan is inulin and fructo-oligosaccharide in that patent.This patent research finds that the use of inulin-type levan can substitute traditional cosmetic completely and can wash cationic polymer in compositions.But in actual applications, the raw material type of shampoo is so many, inulin might not with its generation synergism, be therefore necessary that research and development are a kind of and substitute cationic polymer with inulin, and effectively clean and hair conditioning without silicon shampoo.
Summary of the invention
The object of the present invention is to provide a kind of without silicon shampoo, it is silicate-containing oil not, avoids because silicone oil gathers, make hair collapse subsides, dimness, tarnish, not cation-containing copolymer, avoids scalp irritate and cause the problem of head pruritus.
The present invention is by the following technical programs to realize above-mentioned purpose, a kind of without silicon shampoo, comprise the component of following weight percent meter: inulin 0.5 ~ 5%, Vegetable oil lipoprotein 0.2 ~ 5%, solubilizing agent 0.2 ~ 2%, thickening agent 0.2 ~ 2%, sodium laureth sulfate 3 ~ 8%, cocamido propyl betaine 3 ~ 8%, alkyl polyglucoside 1 ~ 5%, sodium cocoyl glycinate 1 ~ 5%, tetrasodium ethylenediamine tetraacetate 0.05 ~ 0.5%, citric acid 0.05 ~ 0.5%, antiseptic 0.2 ~ 1%, essence 0.2 ~ 1% and water 58 ~ 90%.As the preferred embodiment of the present invention, the present invention forms without the component of silicon shampoo by following weight percent meter: inulin 3%, Vegetable oil lipoprotein 4%, solubilizing agent 1.5%, thickening agent 1.2%, sodium laureth sulfate 5%, cocamido propyl betaine 6%, alkyl polyglucoside 2%, sodium cocoyl glycinate 3%, tetrasodium ethylenediamine tetraacetate 0.2%, citric acid 0.2%, antiseptic 0.5%, essence 0.8% and water 72.6%.
Further, described Vegetable oil lipoprotein is one in almond oil, macadamia nut oil or its combination.
Further, described Vegetable oil lipoprotein is the compositions of almond oil and macadamia nut oil, and the weight ratio of described almond oil and macadamia nut oil is (1 ~ 3): (2 ~ 5); The weight ratio of preferred described almond oil and macadamia nut oil is 2:5 again.
Further, described solubilizing agent is one in PEG-60 castor oil hydrogenated, polysorbate-20 or its combination; Be preferably PEG-60 castor oil hydrogenated.
Further, described thickening agent is PEG-120 methyl dioleate.
Further, described antiseptic is one in phenoxyethanol, Methylisothiazolinone or its combination.
Further, described antiseptic is the compositions of phenoxyethanol and Methylisothiazolinone, and the weight ratio of described phenoxyethanol and Methylisothiazolinone is 9:1.
Present invention also offers the above-mentioned preparation method without silicon shampoo, comprise the following steps:
(1) by solubilizing agent, Vegetable oil lipoprotein and essence mixing, stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 25 ~ 35% is got, add thickening agent, be warming up to 70 ~ 75 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 25 ~ 35%, system temperature is down to 55 ~ 60 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 15 ~ 25%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
Compared with prior art, advantage of the present invention is:
1) the present invention replaces the cationic polymer such as guar gum, polyquaternary ammonium salt with natural inulin, silicone oil is replaced with natural plant grease, adopt the gentle surfactant such as cocamido propyl betaine, alkyl polyglucoside, sodium laureth sulfate as cleansing, be a kind of gentleness non-stimulated, not cation-containing copolymer without silicone oil shampoo.It is silicate-containing oil not, does not therefore have silicone oil and gathers, can not filthy dust in absorbed air, hair is collapsed subsides, dimness, greasy, tarnishes; Not cation-containing copolymer, can not bring scalp irritate and cause the problem of head pruritus.
2) each component of the present invention and proportioning thereof are worked in coordination with, there is fine and smooth abundant foam, effectively clean hair but do not hinder scalp, have hair and well nurse one's health nursing role, obviously can reduce hair wet comb resistance and maintenance and improve hair gloss, use that rear scalp is light, hair is full, glossy, a softer and smoother touch, hair is without entanglement.
Detailed description of the invention
Further describe the present invention below by way of detailed description of the invention, but the present invention is not limited only to following examples.Within the scope of the invention or not departing from content of the present invention, spirit and scope, to of the present inventionly suitably improving without silicon shampoo and preparation method thereof, replacing the identical component of effect, will become apparent to those skilled in the art that they are all deemed to be included within scope of the present invention.
Each component in the present invention is conventional commercial product, and such as, the inulin in embodiment is purchased from Guangzhou Xian Ting trading company NATULIN NC100; Almond oil refines Semen pruni armeniacae oil CROPURE SWEET ALMOND purchased from standing grain major company; Macadamia nut oil refines macadimia nut seed oil purchased from standing grain major company; Alkyl polyglucoside is purchased from Kening Co., Ltd APG 1200.
embodiment 1, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 30g, Vegetable oil lipoprotein (weight ratio of almond oil and macadamia nut oil is 2:5) 40g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 726g.
Preparation: PEG-60 castor oil hydrogenated, Vegetable oil lipoprotein and essence mix by (1), and stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 30% is got, add PEG-120 methyl dioleate, be warming up to 70 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 30%, system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 20%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
embodiment 2, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 5g, Vegetable oil lipoprotein (weight ratio of almond oil and macadamia nut oil is 1:2) 50g, PEG-60 castor oil hydrogenated 20g, PEG-120 methyl dioleate 2g, sodium laureth sulfate 60g, cocamido propyl betaine 30g, alkyl polyglucoside 50g, sodium cocoyl glycinate 10g, tetrasodium ethylenediamine tetraacetate 5g, citric acid 5g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 2g, essence 2g, water 759g.
Preparation: PEG-60 castor oil hydrogenated, Vegetable oil lipoprotein and essence mix by (1), and stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 25% is got, add PEG-120 methyl dioleate, be warming up to 75 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 35%, system temperature is down to 60 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 15%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
embodiment 3, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 50g, Vegetable oil lipoprotein (weight ratio of almond oil and macadamia nut oil is 3:4) 2g, polysorbate-20 2g, PEG-120 methyl dioleate 20g, sodium laureth sulfate 30g, cocamido propyl betaine 80g, alkyl polyglucoside 10g, sodium cocoyl glycinate 50g, tetrasodium ethylenediamine tetraacetate 1g, citric acid 1g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 9g, essence 10g, water 735g.
Preparation: polysorbate-20, Vegetable oil lipoprotein and essence mix by (1), and stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 35% is got, add PEG-120 methyl dioleate, be warming up to 70 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 25%, system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 25%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
embodiment 4, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 30g, almond oil 40g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 5g, citric acid 4g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 721g.
Preparation: PEG-60 castor oil hydrogenated, almond oil and essence mix by (1), and stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 30% is got, add PEG-120 methyl dioleate, be warming up to 70 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 30%, system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 20%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
embodiment 5, the present invention are without silicon shampoo and preparation thereof
Formula: inulin 30g, macadamia nut oil 40g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 5g, citric acid 4g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 721g.
Preparation: PEG-60 castor oil hydrogenated, macadamia nut oil and essence mix by (1), and stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 30% is got, add PEG-120 methyl dioleate, be warming up to 70 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 30%, system temperature is down to 55 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 20%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
comparative example 1,
Formula: Vegetable oil lipoprotein (weight ratio of almond oil and macadamia nut oil is 2:5) 70g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 726g.
Preparation method is with embodiment 1.
comparative example 2,
Formula: inulin 70g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 726g.
Preparation method is with embodiment 1.
comparative example 3,
Formula: Polyquaternium-10 3g, Vegetable oil lipoprotein (weight ratio of almond oil and macadamia nut oil is 2:5) 40g, PEG-60 castor oil hydrogenated 15g, PEG-120 methyl dioleate 12g, sodium laureth sulfate 50g, cocamido propyl betaine 60g, alkyl polyglucoside 20g, sodium cocoyl glycinate 30g, tetrasodium ethylenediamine tetraacetate 2g, citric acid 2g, antiseptic (weight ratio of phenoxyethanol and Methylisothiazolinone is 9:1) 5g, essence 8g, water 753g.
Preparation method is with embodiment 1.
test example one, the present invention are without the impact on hair gloss and carding property of silicon shampoo
1, experiment material and instrument
The shampoo of the embodiment of the present invention 1 ~ 5, comparative example 1 ~ 3 preparation
Commercially available without silicon shampoo
Topknot is provided by beauty parlor
Vancometer: the miniature glossometer A-4430 of German BYK
Tensiometer: Diastron Miniature Tensile Tester(DIA-STRON Limited England)
2, method of testing
2.1, topknot preparation and process
2.1.1 prepared by topknot:
With cord, the topknot that 25cm is long is divided into 10g a branch of.Topknot is put into isopropyl alcohol to soak 10 minutes, make solvent remove waxiness; Soak 30 minutes in the 1.6% sodium laureth sulfate solution of 50 DEG C subsequently, soaking solution removing waxiness; With tap water topknot to removing cleaning mixture completely; Again topknot is placed in 10% lauryl sodium sulfate aqueous solution and cleans; Finally use tap water topknot, electricity consumption dries up, and topknot is placed in room temperature and treats to use for second day.
2.1.2 topknot process:
Get 45 bundle topknots, be divided into 9 groups, first using glossometer to measure the gloss index of 9 groups of topknots respectively, determining the gloss index of 9 groups of topknots zero difference under 95% confidence degree, re-using testing sample.
9 groups of topknots use embodiment 1 ~ 5, comparative example 1 ~ 3 and commercially available without the process of silicon shampoo respectively, after topknot moistening, often restraint topknot and use the process of 2g shampoo, use finger (band latex glove) tow sides to rub hair washing bundle 2 minutes.In glass beaker, prepare 2000ml tap water, the topknot of process is immersed in the water, stir 2 minutes clockwise, unnecessary water is extruded by taking-up finger, after natural drying, surveys its cardability, often restraint topknot and comb three times, 9 bundles are combed 27 times altogether, therefrom obtain average combing power.
2.2, cardability measures
Tensiometer computer shows three parameters: slope, young's modulus, area under curve.By alternative area under curve as measurement foundation, often restraint topknot and repeat survey 3 times, average, outcome record is in following table 1.
2.3, gloss measures
What use glossometer to measure 9 groups of topknots washes front glossiness, and uses shampoo process, the glossiness after natural airing.Often restraint topknot and repeat survey 3 times, average, often organize topknot and average, outcome record is in following table 2.
3, experimental result
The each shampoo of table 1 affects result to the wet comb of hair
The each shampoo of table 2 affects result to hair gloss
From upper table 1 and table 2, by contrast, the average combing power of embodiment 1 ~ 3 is lower, after hair washing, gloss keeps percentage rate more than 100%, illustrates that embodiment 1 ~ 3 shampoo effectively can reduce wet comb resistance, makes hair smooth, improve hair gloss brightness, its Be very effective is better than commercially available without silicon shampoo; Wherein minimum with the average combing power of embodiment 1, gloss keeps percentage rate the highest, illustrates that each component synergism of embodiment 1 is strong, good to the conditioning effect of hair.
The Vegetable oil lipoprotein of embodiment 4 and embodiment 5 is only the one in almond oil and macadamia nut oil, and its average combing power and gloss keep percentage rate to be all slightly weaker than embodiment 1 ~ 3, and illustrate that almond oil and macadamia nut oil exist certain synergism, it is better that both combinationally use effect.
Comparative example 1 does not only contain inulin containing Vegetable oil lipoprotein, and comparative example 2 does not only contain Vegetable oil lipoprotein containing inulin, and its hair conditioning effect, all not as good as embodiment 1 ~ 3, illustrates that inulin of the present invention and Vegetable oil lipoprotein exist fine synergism.Comparative example 3 substitutes inulin with Polyquaternium-10, and other components are with embodiment 1, but its effect is obviously not as embodiment 1, illustrates that the synergism of inulin and each component of the present invention is strong.
test example two, the present invention test without the zest of silicon shampoo
According to irritation test in cosmetics health specification (2007 editions), carry out dermoreaction scoring to the shampoo of embodiment 1, concrete operations are as follows:
1, laboratory animal: healthy white rabbit 3, female, 1.8 ~ 2.2kg, skin zero damage.
2, experimental procedure:
24h before test, cut off the hair of experiment spinal column both sides, white rabbit back, not lesional epidermis is respectively 3cm × 3cm about unhairing scope.Get tested material (i.e. the shampoo of embodiment 1) 0.5g to be added on 4 layers of gauze of 2.5cm × 2.5cm, be affixed on side skin, after covering with one deck oilpaper, with immobilization with adhesive tape, opposite side is blank.Close after 4h and remove tested material, and wash away residual tested material with clear water, after removing tested material 1,24,48h observes the reaction of recipient site local skin, contrast rear scoring with matched group position.Put top average according to each observing time, evaluate the rank of this tested material to animal skin stimulus intensity.
Experimental result: in test, each observing time puts top average < 0.5, belongs to nonirritant.Therefore embodiment 1 irritates without silicon shampoo formula gentleness, nothing, effectively avoids the problem causing head pruritus because scalp irritates.
Below be only the preferred embodiment of the present invention, it should be pointed out that above-mentioned preferred implementation should not be considered as limitation of the present invention, protection scope of the present invention should be as the criterion with claim limited range.For those skilled in the art, without departing from the spirit and scope of the present invention, can also make some improvement and modification, these improve and modify and also should be considered as protection scope of the present invention.
Claims (10)
1. one kind without silicon shampoo, it is characterized in that, comprise the component of following weight percent meter: inulin 0.5 ~ 5%, Vegetable oil lipoprotein 0.2 ~ 5%, solubilizing agent 0.2 ~ 2%, thickening agent 0.2 ~ 2%, sodium laureth sulfate 3 ~ 8%, cocamido propyl betaine 3 ~ 8%, alkyl polyglucoside 1 ~ 5%, sodium cocoyl glycinate 1 ~ 5%, tetrasodium ethylenediamine tetraacetate 0.05 ~ 0.5%, citric acid 0.05 ~ 0.5%, antiseptic 0.2 ~ 1%, essence 0.2 ~ 1% and water 58 ~ 90%.
2. as claimed in claim 1 without silicon shampoo, it is characterized in that, be made up of the component of following weight percent meter: inulin 3%, Vegetable oil lipoprotein 4%, solubilizing agent 1.5%, thickening agent 1.2%, sodium laureth sulfate 5%, cocamido propyl betaine 6%, alkyl polyglucoside 2%, sodium cocoyl glycinate 3%, tetrasodium ethylenediamine tetraacetate 0.2%, citric acid 0.2%, antiseptic 0.5%, essence 0.8% and water 72.6%.
3. as claimed in claim 1 or 2 without silicon shampoo, it is characterized in that, described Vegetable oil lipoprotein be one in almond oil, macadamia nut oil or its combine.
4. as claimed in claim 3 without silicon shampoo, it is characterized in that, described Vegetable oil lipoprotein is the compositions of almond oil and macadamia nut oil, and the weight ratio of described almond oil and macadamia nut oil is (1 ~ 3): (2 ~ 5).
5. as claimed in claim 4 without silicon shampoo, it is characterized in that, the weight ratio of described almond oil and macadamia nut oil is 2:5.
6. as claimed in claim 1 or 2 without silicon shampoo, it is characterized in that, described solubilizing agent be one in PEG-60 castor oil hydrogenated, polysorbate-20 or its combine.
7. as claimed in claim 1 or 2 without silicon shampoo, it is characterized in that, described thickening agent is PEG-120 methyl dioleate.
8. as claimed in claim 1 or 2 without silicon shampoo, it is characterized in that, described antiseptic be one in phenoxyethanol, Methylisothiazolinone or its combine.
9. as claimed in claim 8 without silicon shampoo, it is characterized in that, described antiseptic is the compositions of phenoxyethanol and Methylisothiazolinone, and the weight ratio of described phenoxyethanol and Methylisothiazolinone is 9:1.
10. prepare as arbitrary in claim 1 ~ 9 as described in without a silicon shampoo, it is characterized in that, comprise the following steps:
(1) by solubilizing agent, Vegetable oil lipoprotein and essence mixing, stir to obtain mixed liquor, for subsequent use;
(2) water of component weight 25 ~ 35% is got, add thickening agent, be warming up to 70 ~ 75 DEG C to be stirred to and to dissolve completely, continue the water adding component weight 25 ~ 35%, system temperature is down to 55 ~ 60 DEG C, adds sodium laureth sulfate, cocamido propyl betaine, alkyl polyglucoside, sodium cocoyl glycinate, is stirred to and dissolves completely, obtain liquid one, for subsequent use;
(3) separately get the water of component weight 15 ~ 25%, add after inulin stirs, add the liquid one of step (2), stir, obtain liquid two;
(4) in step (3) liquid two, add step (1) mixed liquor, stir, then add tetrasodium ethylenediamine tetraacetate, citric acid, antiseptic and water, stir.
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