CN104848748A - Light armored armor and preparation method thereof - Google Patents
Light armored armor and preparation method thereof Download PDFInfo
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- CN104848748A CN104848748A CN201510250746.2A CN201510250746A CN104848748A CN 104848748 A CN104848748 A CN 104848748A CN 201510250746 A CN201510250746 A CN 201510250746A CN 104848748 A CN104848748 A CN 104848748A
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Abstract
The invention discloses a light armored armor and a preparation method thereof. The armored armor is in a sandwich structure; a core plate is made of novel aluminum matrix composite of composite enhancing silicon carbide and graphene; a face plate and a back plate are made of 5083 and 7A21 high-intensity aluminum alloy; the core plate, the face plate and the back plate are glued through metallic glue; the composite of the core plate is graphene or silicon carbide enhanced aluminum matrix composite and prepared through the pressure infiltration technology; an infiltration framework is silicon carbide and graphene cold pressing block which are uniformly mixed. According to the light armored armor and the preparation method thereof, the core plate is obtained due to infiltration of aluminum alloy through the silicon carbide and graphene composite framework, the silicon carbide enhancement is used, the enhancement and toughening functions to the aluminum alloy from the graphene are fully played, the ballistic performance of the core plate is improved, and the light armored armor having a good application prospect is finally obtained.
Description
Technical field
The present invention is a kind of lightweight armor armour and preparation method thereof, belongs to lightweight armor protection Material Field.
Background technology
Specific strength and the specific stiffness of aluminum matrix composite are high, have good high-temperature behavior and wearability, and thermal coefficient of expansion are low simultaneously.At present, the reinforcement of aluminum matrix composite is mainly divided into reinforced particulate and fibre reinforcement.Fibre reinforcement not only increases the intensity of aluminum substrate, also makes its plasticity improve.CNT is a kind of important aluminium base fibre reinforcement, but its production cost is high, and it is more and more less to utilize CNT to strengthen the potentiality of aluminium alloy capability further.
Graphene is a kind of New Two Dimensional nano material, and its intensity, up to 1.01TPa, be 100 times of structural steel, and density is 1/5 of structural steel.Compared with CNT, there is larger specific strength, specific area and lower production cost, be expected to replace CNT to become optimal filler and reinforcement in following composite.Therefore, strengthening aluminium alloy with Graphene is the important breakthrough mouth improving Properties of Aluminum Matrix Composites further.
Armor facing technology is most important part among weapon system-of-systems survival ability, and any one modern weapons equipment all be unable to do without protection.Excellent armor protection system can make the main body of opportunity of combat, tank, panzer and other structure and personal security wherein better be protected.At present, the subject matter that armour plate exists is that armour plate density is overweight, adds the burden of opportunity of combat, tank, panzer, its mobility is not in full use.The aluminum matrix composite that Graphene strengthens is used for armour plate field, is expected to the density reducing armour plate further, optimize the performance of lightweight armor plate.
Pressure Infiltration technique originates in the technical study that the Charles Norman sixties in 20th century etc. infiltrates to the gas pressure of precast body, and in the time subsequently, the researcher of various countries carries out extensively Infiltration Technics and gos deep into the research of level.At present, China has prepared alumina fibre enhancing Al alloy composite, SiC reinforcement aluminium composite material, aluminium oxide-silica enhancing aluminium-silicon composite and titanium alloy composite material etc. by Pressure Infiltration technique.Gas pressure infiltration is placed in by skeleton in the mould that can be vented, and then by applying gas pressure to the liquid aluminium in sealed mold, aluminium immersion being seeped in skeleton and going, thus preparing the method for composite.The method is one of common method preparing composite, and its composite density prepared is high, and mechanical property is high.
Summary of the invention
The present invention just for above-mentioned prior art situation and design and provide a kind of lightweight armor armour and preparation method thereof, the carborundum that the core sheet material of " sandwich " structure armor plate in the method adopts Pressure Infiltration to prepare and the aluminum-based composite material plate that Graphene mixing strengthens, the panel of both sides and backboard are respectively 5083 and 7A21 high-strength aluminum alloy, bonding by metal-to-metal adhesive between three.The lightweight armor plate of this high strength all has excellent future in engineering applications in fields such as Aeronautics and Astronautics.
The object of the invention is to be achieved through the following technical solutions:
Lightweight armor armour described in technical solution of the present invention is three-layer sandwich structure, it is characterized in that: the sheet material of to be the trade mark be respectively in the both sides of described three-layer sandwich structure 5083 aluminium alloys and 7A21 aluminium alloy, intermediate layer is the aluminum-based composite material plate that carborundum and Graphene mixing strengthen, the thickness of biside plate is 10mm ~ 20mm, the thickness of mesosphere board is 30mm ~ 50mm, the chemical composition of intermediate layer sheet material and percentage by weight are: Graphene and silicon carbide blend 20% ~ 60%, surplus is aluminium alloy, the intensity of this alloy matrix aluminum is more than 150MPa, in Graphene and silicon carbide blend, the percentage by weight of Graphene is 0.3% ~ 5%.
The step of the method for the described lightweight armor armour of preparation that the present invention proposes is:
(1) mixed with alcoholic solution by Graphene, the percentage by weight that Graphene accounts for mixed solution is 0.5% ~ 5%, utilizes supersonic oscillations to prepare monodispersed graphene uniform solution;
(2) take silicon carbide powder by the weight percent relation of Graphene and carborundum, silicon carbide powder is added in graphene uniform solution;
(3) be encased in ball grinder by the mixed solution that (2) step obtains, carry out mechanical ball milling, Ball-milling Time is 20 ~ 40 hours;
(4) mixed solution takes out after terminating by ball milling, is encased in large beaker and puts into baking oven and dry, obtain the mixture of Graphene and carborundum;
(5) at room temperature, loaded in cold stamping die by the mixture of Graphene and carborundum, utilize hydraulic press to be pressed into plate shaped solid skeleton, pressure is 3 ~ 7MP;
(6) the plate shaped solid skeleton be cold-pressed into is encased in Pressure Infiltration equipment, being weighed by proportioning by alloy matrix aluminum powder for the preparation of mesosphere board is placed in crucible, respectively the solid skeleton of heated plate shape and with alloy matrix aluminum powder, wherein, plate shaped solid skeleton is heated to 300 ~ 400 DEG C and is incubated, alloy matrix aluminum powder is incubated after being heated to 700 ~ 750 DEG C of one-tenth melts, by inert gas, this aluminium alloy melt is applied to the pressure of 5 ~ 10MPa, and keep this pressure state 0.5 ~ 2h to make aluminium alloy melt all infiltrate in plate shaped solid skeleton, then plate shaped solid skeleton is cooled to the furnace room temperature, obtain the aluminum-based composite material plate of carborundum and Graphene mixing enhancing,
(7) select epoxide modified type or inorganic silicic acid salt form metal-to-metal adhesive the aluminum-based composite material plate of 5083 aluminum alloy plate materials, carborundum and Graphene mixing enhancing and 7A21 aluminum alloy plate materials to be bonded together with metal-to-metal adhesive, obtain the lightweight composite armor panel of three-layer sandwich structure.
Along with the development of modern technologies, propose higher requirement to armoring bullet resistant material, traditional handicraft and traditional composite have been difficult to the performance requirement meeting armour material.How from the material selected, in structure and the technique performance that improves armour material be the difficult problem that current researcher runs into.The present invention is directed to the problems referred to above, from the structure and technique of the selection of armour material, armour material, many-side is considered simultaneously, by adopting the technique of Pressure Infiltration, by Graphene and silicon carbide blend and alumina-base material compound, form the composite of a high strength, utilize this composite and high-strength aluminium alloy plate material to prepare the armoring armour sheet material of " sandwich " structure of a kind of lightweight, well meet the performance requirement of present armor facing material.
The present invention has the following advantages compared with existing armour material:
The first, the present invention adopts the mode of ball milling by Graphene and ceramic particle compound, by ball milling pearl at a high speed, the pure Graphene of sheet is embedded into the surface of ceramic particle, forms reasonable combination, and graphene dispersion can be guaranteed simultaneously;
Second, the present invention utilizes Graphene and carborundum to strengthen high-strength aluminum alloy to prepare lightweight armor simultaneously, give full play to the enhancing effect of Graphene, silicon-carbide particle, adopted the less aluminum alloy materials of density simultaneously, make the armour plate of preparation have high strength and low-density feature simultaneously;
3rd, present invention process is simple, is easy to the preparation realizing large-sized Graphene reinforcing material in enormous quantities, reduces production cost, has excellent future in engineering applications.
Detailed description of the invention
Below with reference to embodiment, technical solution of the present invention is further described:
Lightweight armor armour described in the present embodiment is three-layer sandwich structure, it is characterized in that: the sheet material of to be the trade mark be respectively in the both sides of described three-layer sandwich structure 5083 aluminium alloys and 7A21 aluminium alloy, intermediate layer is the aluminum-based composite material plate that carborundum and Graphene mixing strengthen, the thickness of biside plate is 10mm ~ 20mm, the thickness of mesosphere board is 30mm ~ 50mm, the chemical composition of intermediate layer sheet material and percentage by weight are: Graphene and silicon carbide blend 20% ~ 60%, surplus is aluminium alloy, the intensity of this alloy matrix aluminum is more than 150MPa, in Graphene and silicon carbide blend, the percentage by weight of Graphene is 0.3% ~ 5%.
The step preparing the method for this lightweight armor armour is:
(1) 5g Graphene is joined in 1000ml alcoholic solution, utilize supersonic oscillations to prepare monodispersed graphene uniform solution;
(2) take 1000g silicon carbide powder, silicon carbide powder is added in graphene uniform solution;
(3) be encased in ball grinder by the mixed solution that (2) step obtains, carry out mechanical ball milling, Ball-milling Time is 20 hours;
(4) mixed solution takes out after terminating by ball milling, is encased in large beaker and puts into baking oven and dry, obtain the mixture of Graphene and carborundum;
(5) at room temperature, loaded in cold stamping die by the mixture of Graphene and carborundum, utilize hydraulic press to be pressed into plate shaped solid skeleton, pressure is 3 ~ 7MP;
(6) the plate shaped solid skeleton be cold-pressed into is encased in Pressure Infiltration equipment, being weighed by proportioning by alloy matrix aluminum powder for the preparation of mesosphere board is placed in crucible, respectively the solid skeleton of heated plate shape and with alloy matrix aluminum powder, wherein, plate shaped solid skeleton is heated to 350 DEG C and is incubated, alloy matrix aluminum powder is incubated after being heated to 750 DEG C of one-tenth melts, by inert gas, this aluminium alloy melt is applied to the pressure of 10MPa, and keep this pressure state 2h to make aluminium alloy melt all infiltrate in plate shaped solid skeleton, then plate shaped solid skeleton is cooled to the furnace room temperature, obtain the aluminum-based composite material plate of carborundum and Graphene mixing enhancing,
(7) with epoxide modified type metal-to-metal adhesive, the aluminum-based composite material plate of 5083 aluminum alloy plate materials, carborundum and Graphene mixing enhancing and 7A21 aluminum alloy plate materials are bonded together, obtain the lightweight composite armor panel of three-layer sandwich structure.
Claims (2)
1. a lightweight armor armour, this armoring armour is three-layer sandwich structure, it is characterized in that: the sheet material of to be the trade mark be respectively in the both sides of described three-layer sandwich structure 5083 aluminium alloys and 7A21 aluminium alloy, intermediate layer is the aluminum-based composite material plate that carborundum and Graphene mixing strengthen, the thickness of biside plate is 10mm ~ 20mm, the thickness of mesosphere board is 30mm ~ 50mm, the chemical composition of intermediate layer sheet material and percentage by weight are: Graphene and silicon carbide blend 20% ~ 60%, surplus is aluminium alloy, the intensity of this alloy matrix aluminum is more than 150MPa, in Graphene and silicon carbide blend, the percentage by weight of Graphene is 0.3% ~ 5%.
2. prepare the method for lightweight armor armour described in claim 1, it is characterized in that: steps of the method are:
(1) mixed with alcoholic solution by Graphene, the percentage by weight that Graphene accounts for mixed solution is 0.5% ~ 5%, utilizes supersonic oscillations to prepare monodispersed graphene uniform solution;
(2) take silicon carbide powder by the weight percent relation of Graphene and carborundum, silicon carbide powder is added in graphene uniform solution;
(3) be encased in ball grinder by the mixed solution that (2) step obtains, carry out mechanical ball milling, Ball-milling Time is 20 ~ 40 hours;
(4) mixed solution takes out after terminating by ball milling, is encased in large beaker and puts into baking oven and dry, obtain the mixture of Graphene and carborundum;
(5) at room temperature, loaded in cold stamping die by the mixture of Graphene and carborundum, utilize hydraulic press to be pressed into plate shaped solid skeleton, pressure is 3 ~ 7MP;
(6) the plate shaped solid skeleton be cold-pressed into is encased in Pressure Infiltration equipment, being weighed by proportioning by alloy matrix aluminum powder for the preparation of mesosphere board is placed in crucible, respectively the solid skeleton of heated plate shape and with alloy matrix aluminum powder, wherein, plate shaped solid skeleton is heated to 300 ~ 400 DEG C and is incubated, alloy matrix aluminum powder is incubated after being heated to 700 ~ 750 DEG C of one-tenth melts, by inert gas, this aluminium alloy melt is applied to the pressure of 5 ~ 10MPa, and keep this pressure state 0.5 ~ 2h to make aluminium alloy melt all infiltrate in plate shaped solid skeleton, then plate shaped solid skeleton is cooled to the furnace room temperature, obtain the aluminum-based composite material plate of carborundum and Graphene mixing enhancing,
(7) select epoxide modified type or inorganic silicic acid salt form metal-to-metal adhesive the aluminum-based composite material plate of 5083 aluminum alloy plate materials, carborundum and Graphene mixing enhancing and 7A21 aluminum alloy plate materials to be bonded together with metal-to-metal adhesive, obtain the lightweight composite armor panel of three-layer sandwich structure.
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| CN105216397A (en) * | 2015-10-23 | 2016-01-06 | 中国航空工业集团公司北京航空材料研究院 | A kind of Novel light high-strength Protective armor plate |
| CN105216398A (en) * | 2015-10-23 | 2016-01-06 | 中国航空工业集团公司北京航空材料研究院 | A kind of Novel light high-strength Protective armor plate |
| CN105238975A (en) * | 2015-10-23 | 2016-01-13 | 中国航空工业集团公司北京航空材料研究院 | Preparation method for novel light-weight and high-strength protection armor plate |
| CN105238972A (en) * | 2015-10-23 | 2016-01-13 | 中国航空工业集团公司北京航空材料研究院 | Preparation method for novel light-weight and high-strength protection armor plate |
| CN105256205A (en) * | 2015-10-23 | 2016-01-20 | 中国航空工业集团公司北京航空材料研究院 | Preparing method for novel light high-strength protection armor plate |
| CN105277071A (en) * | 2015-10-23 | 2016-01-27 | 中国航空工业集团公司北京航空材料研究院 | Novel low-weight high-strength protective armor plate |
| CN105274409A (en) * | 2015-10-23 | 2016-01-27 | 中国航空工业集团公司北京航空材料研究院 | Manufacturing method for novel light high-strength protection armor plate |
| CN105331861A (en) * | 2015-10-23 | 2016-02-17 | 中国航空工业集团公司北京航空材料研究院 | Novel light high-strength protective armor plate |
| CN105331862A (en) * | 2015-10-23 | 2016-02-17 | 中国航空工业集团公司北京航空材料研究院 | Novel light high-strength protective armor plate |
| CN105349813A (en) * | 2015-10-23 | 2016-02-24 | 中国航空工业集团公司北京航空材料研究院 | Preparing method of novel light high-strength protection armour plate |
| CN105349812A (en) * | 2015-10-23 | 2016-02-24 | 中国航空工业集团公司北京航空材料研究院 | Manufacturing method for novel lightweight high-strength protective armor plate |
| CN105371703A (en) * | 2015-10-23 | 2016-03-02 | 中国航空工业集团公司北京航空材料研究院 | Novel lightweight and high-strength protective armor plate |
| CN105543576A (en) * | 2015-12-22 | 2016-05-04 | 中国航空工业集团公司北京航空材料研究院 | Electronic encapsulating material |
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| CN105783597A (en) * | 2016-02-29 | 2016-07-20 | 中国航空工业集团公司北京航空材料研究院 | Novel high-strength protecting amour plate |
| CN106399879A (en) * | 2016-08-26 | 2017-02-15 | 蔡磊 | Novel mineral fiber and aluminum-base alloy composite panel and production method |
| CN108484132A (en) * | 2018-02-06 | 2018-09-04 | 孝感奥新新材料技术有限公司 | A kind of preparation method of dense form bullet proof composite plating |
| CN108660398A (en) * | 2018-05-24 | 2018-10-16 | 兰州交通大学 | A kind of preparation method of graphene-silicon carbide fibre reinforced metal composite material |
| CN108842081A (en) * | 2018-07-05 | 2018-11-20 | 西安航空学院 | A kind of vacuum gas pressure infiltration prepares the preparation method of Al/SiC-C-SiC composite material |
| GB2587523B (en) * | 2018-05-18 | 2021-12-01 | Graphene Composites Ltd | Protective shield and sheild wall |
| WO2022104441A1 (en) * | 2020-11-18 | 2022-05-27 | CAMPOSO PEREIRA, Artur | Optimization of multilayer armor system of epoxy matrix composite with curaua fabric functioned with graphene oxide |
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| CN105216398A (en) * | 2015-10-23 | 2016-01-06 | 中国航空工业集团公司北京航空材料研究院 | A kind of Novel light high-strength Protective armor plate |
| CN105238975A (en) * | 2015-10-23 | 2016-01-13 | 中国航空工业集团公司北京航空材料研究院 | Preparation method for novel light-weight and high-strength protection armor plate |
| CN105238972A (en) * | 2015-10-23 | 2016-01-13 | 中国航空工业集团公司北京航空材料研究院 | Preparation method for novel light-weight and high-strength protection armor plate |
| CN105256205A (en) * | 2015-10-23 | 2016-01-20 | 中国航空工业集团公司北京航空材料研究院 | Preparing method for novel light high-strength protection armor plate |
| CN105277071A (en) * | 2015-10-23 | 2016-01-27 | 中国航空工业集团公司北京航空材料研究院 | Novel low-weight high-strength protective armor plate |
| CN105274409B (en) * | 2015-10-23 | 2017-12-26 | 中国航空工业集团公司北京航空材料研究院 | A kind of preparation method of high-strength light Protective armor plate |
| CN105331861A (en) * | 2015-10-23 | 2016-02-17 | 中国航空工业集团公司北京航空材料研究院 | Novel light high-strength protective armor plate |
| CN105331862A (en) * | 2015-10-23 | 2016-02-17 | 中国航空工业集团公司北京航空材料研究院 | Novel light high-strength protective armor plate |
| CN105349813A (en) * | 2015-10-23 | 2016-02-24 | 中国航空工业集团公司北京航空材料研究院 | Preparing method of novel light high-strength protection armour plate |
| CN105349812A (en) * | 2015-10-23 | 2016-02-24 | 中国航空工业集团公司北京航空材料研究院 | Manufacturing method for novel lightweight high-strength protective armor plate |
| CN105371703A (en) * | 2015-10-23 | 2016-03-02 | 中国航空工业集团公司北京航空材料研究院 | Novel lightweight and high-strength protective armor plate |
| CN105216397A (en) * | 2015-10-23 | 2016-01-06 | 中国航空工业集团公司北京航空材料研究院 | A kind of Novel light high-strength Protective armor plate |
| CN105543576A (en) * | 2015-12-22 | 2016-05-04 | 中国航空工业集团公司北京航空材料研究院 | Electronic encapsulating material |
| CN105783597A (en) * | 2016-02-29 | 2016-07-20 | 中国航空工业集团公司北京航空材料研究院 | Novel high-strength protecting amour plate |
| CN105737674A (en) * | 2016-02-29 | 2016-07-06 | 中国航空工业集团公司北京航空材料研究院 | Manufacturing method of novel high-strength protecting armor plate |
| CN106399879A (en) * | 2016-08-26 | 2017-02-15 | 蔡磊 | Novel mineral fiber and aluminum-base alloy composite panel and production method |
| CN108484132A (en) * | 2018-02-06 | 2018-09-04 | 孝感奥新新材料技术有限公司 | A kind of preparation method of dense form bullet proof composite plating |
| CN108484132B (en) * | 2018-02-06 | 2021-11-02 | 淮北特旭信息科技有限公司 | Preparation method of compact composite bulletproof plate |
| GB2587523B (en) * | 2018-05-18 | 2021-12-01 | Graphene Composites Ltd | Protective shield and sheild wall |
| US11635280B2 (en) | 2018-05-18 | 2023-04-25 | Graphene Composites Limited | Protective shield, shield wall and shield wall assembly |
| CN108660398A (en) * | 2018-05-24 | 2018-10-16 | 兰州交通大学 | A kind of preparation method of graphene-silicon carbide fibre reinforced metal composite material |
| CN108842081A (en) * | 2018-07-05 | 2018-11-20 | 西安航空学院 | A kind of vacuum gas pressure infiltration prepares the preparation method of Al/SiC-C-SiC composite material |
| WO2022104441A1 (en) * | 2020-11-18 | 2022-05-27 | CAMPOSO PEREIRA, Artur | Optimization of multilayer armor system of epoxy matrix composite with curaua fabric functioned with graphene oxide |
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