CN104846686B - A kind of natural moistureproof edible food package paper and preparation method thereof - Google Patents

A kind of natural moistureproof edible food package paper and preparation method thereof Download PDF

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CN104846686B
CN104846686B CN201510279321.4A CN201510279321A CN104846686B CN 104846686 B CN104846686 B CN 104846686B CN 201510279321 A CN201510279321 A CN 201510279321A CN 104846686 B CN104846686 B CN 104846686B
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moistureproof
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liquid
natural
food package
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CN104846686A (en
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史高峰
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JURONG MAOYUAN WEAVING PLANT
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JURONG MAOYUAN WEAVING PLANT
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Abstract

The natural moistureproof edible food package paper of one that the present invention provides, including dietary fiber layer, albuminous coat layer and the moistureproof liquid layer being arranged between dietary fiber layer and albuminous coat layer.Present invention also offers the preparation method of above-mentioned natural moistureproof edible food package paper.This natural moistureproof edible food package paper is completely with the packaging for foodstuff articles for use being a kind of green safety, raw material is easy to get, simple to operate, with low cost, economic and environment-friendly, fully solve the problems such as contradiction between packaging for foodstuff garbage and environmental protection, and its paper strength is high, pliability is good, the most broken, applied widely.

Description

A kind of natural moistureproof edible food package paper and preparation method thereof
Technical field
The present invention relates to a kind of natural moistureproof edible food package paper and preparation method thereof, belong to food service industry technology neck Territory.
Background technology
Along with the development of food service industry, food wrapper kind is the most various, and relatively common have cake paper, candy wrapper, Fine dried noodles carton, bakers paper, cookies carton, ice-cream outer package paper using, wherein waterproof and oilproof type food wrapper gains great popularity, so And most all with macromolecular compounds such as polystyrene, polrvinyl chloride, polypropylene as covering material, these materials tool simultaneously Have that the most degradable, recovery difficult is big, burn and produce the feature such as toxic gas and harm ecological environment.Additionally, in process of production, The chemistry such as permeability-reducing admixture, sizing agent, bleach, stain, stabilizer, UV absorbent and the plasticizer added in paper pulp Product.The harmful components generation migration in the environment of hot and humid of part chemicals makes food be contaminated.In a word, food wrapper Endanger the physical and mental health of people to a certain extent and bring adverse effect to ecological environment.
But being as socioeconomic development and the enhancing of popular environmental consciousness, research and development one has frivolous transparent, colourless Wrapping paper degradable, edible tasteless, nontoxic has become as the major trend of World of Food industrial technology development, is also future The Main way of food packing industry development.
There is the degradable food package film utilizing natural biologic material such as soybean protein to prepare at present for oily food bag Dress, but edible packaging is the most extensive, can't replace synthesis macromolecule plastic film, and its reason is main Being the bad mechanical property of film, natural edible polymer material itself has hydrophilic, and its resistance is moist limited, simultaneously its packaging The problem such as heat sealability and impressionability need to solve.
Summary of the invention
Goal of the invention: in order to overcome the defect of prior art, it is an object of the invention to provide a kind of natural moistureproof edible Food wrapper and preparation method thereof.
Technical scheme: the natural moistureproof edible food package paper of one that the present invention provides, including dietary fiber layer, albumen Film layer and the moistureproof liquid layer being arranged between dietary fiber layer and albuminous coat layer.
Present invention also offers the preparation method of above-mentioned natural moistureproof edible food package paper, comprise the following steps:
(1) preparation of dietary fiber layer: with vegetable or fruit as raw material, cleans and is placed in the boiling water bath containing sodium bicarbonate heat Scald and process, then be placed in cold water and cool down rapidly;Vegetable or the fruit raw material of cooling are placed in beater making beating, separate vegetable juice Or fruit juice;Vegetable slag and marc are pulverized 20-30min, crosses 100-150 mesh sieve;Filtrate is placed in homogenizing 3-5 time under 40-60MPa, Obtain uniform fiber mixed liquor;Boil 2-3min, make fiber mixed liquor swelling;Continue to boil 2-3min, be cooled to 60-70 DEG C, Adding weight ratio hydroxymethyl cellulose and sodium alginate, stirring, to being completely dissolved, adds Cera Flava, stirs, and cooling, in room Preserve 1-2h under temperature, 0.10-0.20Mpa, make degassing, obtain film liquid;Utilize film rod coated film liquid on a glass, control wet film Thickness is 1-2mm;It is dried, obtains dietary fiber layer;
(2) preparation of protein liquid: with Semen sojae atricolor as raw material, clean, soaking at room temperature 3-5h, defibrination, boil after cross 100-150 mesh Sieve, obtains bean dregs;Bean dregs join gelatinizing in adjunce copper, and stirring is simultaneously introduced sodium bicarbonate aqueous solution and adjusts pH to 7-8, adds albumen Enzymatic hydrolysis reaction 3-5h, obtains amyloid proteins and sticks with paste;Add modifier aqueous solution, 30-60 DEG C of hybrid reaction 10-20min, obtain compound Liquid;Adding plasticizer and auxiliary additive in complex liquid, 30-60 DEG C is continued stirring 10-20min, obtains protein liquid;
(3) preparation of petrifying liquid: take straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, is placed in 5-15 times amount Water in decoct 8-12h;Filter, be concentrated into 1/3 volume;Add chitosan and amylomaize, stirring, obtain moistureproof Liquid;
(4) preparation of natural moistureproof edible food package paper: petrifying liquid is coated on dietary fiber layer, after cooling, Again protein liquid is coated on moistureproof liquid layer, control petrifying liquid below layer thickness 1mm;Control protein liquid thickness 1-2mm;It is dried, Obtain.
In step (1), the mass concentration of sodium bicarbonate is 0.1-0.2%.
In step (1), the weight of hydroxymethyl cellulose is the 0.5-1.0% of fiber mixed liquor weight, the weight of sodium alginate For the 0.25-0.5% of fiber mixed liquor weight, the weight of Cera Flava is the 0.24-1.0% of fiber mixed liquor weight.
In step (2), the mass concentration of sodium bicarbonate aqueous solution is 0.1-0.2%.
In step (3), straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, chitosan and high straight-chain maize form sediment The mass ratio of powder is (10-20): (5-15): (5-15): (5-15): (5-15): (3-5): 1:100.
Beneficial effect: the natural moistureproof edible food package paper that the present invention provides is completely with the food being a kind of green safety Product package packing supplies, raw material is easy to get, simple to operate, with low cost, economic and environment-friendly, fully solves packaging for foodstuff garbage and environmental protection Between the problem such as contradiction, and its paper strength is high, pliability is good, the most broken, applied widely.
Edible food package paper antibacterial effect is the most excellent, antibacterial time is long in the present invention natural protection against the tide, has wide spectrum and resists Bacterium effect.
Detailed description of the invention
According to following embodiment, the present invention be may be better understood.But, as it will be easily appreciated by one skilled in the art that reality Execute concrete material proportion, process conditions and result thereof described by example and be merely to illustrate the present invention, and should also will not limit The present invention described in detail in claims processed.
Embodiment 1
The preparation method of natural moistureproof edible food package paper, comprises the following steps:
(1) preparation of dietary fiber layer: with vegetable or fruit as raw material, cleans and is placed in the boiling water bath containing sodium bicarbonate heat Scalding and process, in boiling water, the mass concentration of sodium bicarbonate is 0.15%;It is placed in cold water again and cools down rapidly;By vegetable or the fruit of cooling Raw material is placed in beater making beating, separates vegetable juice or fruit juice;Vegetable slag and marc are pulverized 25min, crosses 120 mesh sieves;Filtrate It is placed in homogenizing 4 times under 50MPa, obtains uniform fiber mixed liquor;Boil 2.5min, make fiber mixed liquor swelling;Continue to boil 2.5min, is cooled to 65 DEG C, adds weight ratio hydroxymethyl cellulose and sodium alginate, and stirring, to being completely dissolved, adds Cera Flava, Stir, cooling, under room temperature, 0.15Mpa, preserve 1.5h, make degassing, obtain film liquid;Film rod is utilized to be coated with on a glass Film liquid, control wet-film thickness is 1-2mm;It is dried, obtains dietary fiber layer;
(2) preparation of protein liquid: with Semen sojae atricolor as raw material, clean, soaking at room temperature 4h, defibrination, boil after cross 120 mesh sieves, Bean dregs;Bean dregs join gelatinizing in adjunce copper, and it is that 0.15% sodium bicarbonate aqueous solution adjusts pH to 7-that stirring is simultaneously introduced mass concentration 8, add protease hydrolysis reaction 4h, obtain amyloid proteins and stick with paste;Add modifier aqueous solution, 50 DEG C of hybrid reactions 15min, must answer Close liquid;Adding plasticizer and auxiliary additive in complex liquid, 50 DEG C are continued stirring 15min, obtain protein liquid;Wherein, methylol The weight of cellulose is the 0.8% of fiber mixed liquor weight, and the weight of sodium alginate is the 0.35% of fiber mixed liquor weight, Cera Flava Weight is fiber mixed liquor weight 0.50%;
(3) preparation of petrifying liquid: take straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, is placed in 10 times amount Water decocts 10h;Filter, be concentrated into 1/3 volume;Add chitosan and amylomaize, stirring, obtain petrifying liquid;Straw The mass ratio of stalk, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, chitosan and amylomaize is 15:10:10: 10:10:4:1:100;
(4) preparation of natural moistureproof edible food package paper: petrifying liquid is coated on dietary fiber layer, after cooling, Again protein liquid is coated on moistureproof liquid layer, control petrifying liquid below layer thickness 1mm;Control protein liquid thickness 1-2mm;It is dried, Obtain.
Embodiment 2
The preparation method of natural moistureproof edible food package paper, comprises the following steps:
(1) preparation of dietary fiber layer: with vegetable or fruit as raw material, cleans and is placed in the boiling water bath containing sodium bicarbonate heat Scalding and process, in boiling water, the mass concentration of sodium bicarbonate is 0.1%;It is placed in cold water again and cools down rapidly;By former to vegetable or the fruit of cooling Material is placed in beater making beating, separates vegetable juice or fruit juice;Vegetable slag and marc are pulverized 20min, crosses 150 mesh sieves;Filtrate is put Homogenizing 5 times under 40MPa, obtain uniform fiber mixed liquor;Boil 2min, make fiber mixed liquor swelling;Continue to boil 3min, cold But to 60 DEG C, adding weight ratio hydroxymethyl cellulose and sodium alginate, stirring, to being completely dissolved, adds Cera Flava, stirs, Cooling, preserves 2h under room temperature, 0.20Mpa, makes degassing, obtain film liquid;Utilize film rod coated film liquid on a glass, control wet Film thickness is 1-2mm;It is dried, obtains dietary fiber layer;
(2) preparation of protein liquid: with Semen sojae atricolor as raw material, clean, soaking at room temperature 3h, defibrination, boil after cross 100 mesh sieves, Bean dregs;Bean dregs join gelatinizing in adjunce copper, and it is that 0.1% sodium bicarbonate aqueous solution adjusts pH to 7-that stirring is simultaneously introduced mass concentration 8, add protease hydrolysis reaction 3h, obtain amyloid proteins and stick with paste;Add modifier aqueous solution, 60 DEG C of hybrid reactions 10min, must answer Close liquid;Adding plasticizer and auxiliary additive in complex liquid, 60 DEG C are continued stirring 10min, obtain protein liquid;Wherein, methylol The weight of cellulose is the 0.5% of fiber mixed liquor weight, and the weight of sodium alginate is the 0.5% of fiber mixed liquor weight, Cera Flava Weight is fiber mixed liquor weight 0.24%;
(3) preparation of petrifying liquid: take straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, is placed in 15 times amount Water decocts 8h;Filter, be concentrated into 1/3 volume;Add chitosan and amylomaize, stirring, obtain petrifying liquid;Straw The mass ratio of stalk, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, chitosan and amylomaize is 10:5:5:5: 15:3:1:100;
(4) preparation of natural moistureproof edible food package paper: petrifying liquid is coated on dietary fiber layer, after cooling, Again protein liquid is coated on moistureproof liquid layer, control petrifying liquid below layer thickness 1mm;Control protein liquid thickness 1-2mm;It is dried, Obtain.
Embodiment 3
The preparation method of natural moistureproof edible food package paper, comprises the following steps:
(1) preparation of dietary fiber layer: with vegetable or fruit as raw material, cleans and is placed in the boiling water bath containing sodium bicarbonate heat Scalding and process, in boiling water, the mass concentration of sodium bicarbonate is 0.2%;It is placed in cold water again and cools down rapidly;By former to vegetable or the fruit of cooling Material is placed in beater making beating, separates vegetable juice or fruit juice;Vegetable slag and marc are pulverized 30min, crosses 100 mesh sieves;Filtrate is put Homogenizing 3 times under 60MPa, obtain uniform fiber mixed liquor;Boil 3min, make fiber mixed liquor swelling;Continue to boil 2min, cold But to 70 DEG C, adding weight ratio hydroxymethyl cellulose and sodium alginate, stirring, to being completely dissolved, adds Cera Flava, stirs, Cooling, preserves 1h under room temperature, 0.10Mpa, makes degassing, obtain film liquid;Utilize film rod coated film liquid on a glass, control wet Film thickness is 1-2mm;It is dried, obtains dietary fiber layer;
(2) preparation of protein liquid: with Semen sojae atricolor as raw material, clean, soaking at room temperature 5h, defibrination, boil after cross 150 mesh sieves, Bean dregs;Bean dregs join gelatinizing in adjunce copper, and it is that 0.2% sodium bicarbonate aqueous solution adjusts pH to 7-that stirring is simultaneously introduced mass concentration 8, add protease hydrolysis reaction 5h, obtain amyloid proteins and stick with paste;Add modifier aqueous solution, 30 DEG C of hybrid reactions 20min, must answer Close liquid;Adding plasticizer and auxiliary additive in complex liquid, 30 DEG C are continued stirring 20min, obtain protein liquid;Wherein, methylol The weight of cellulose is the 1.0% of fiber mixed liquor weight, and the weight of sodium alginate is the 0.25% of fiber mixed liquor weight, Cera Flava Weight is fiber mixed liquor weight 1.0%;
(3) preparation of petrifying liquid: take straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, is placed in the water of 5 times amount Middle decoction 12h;Filter, be concentrated into 1/3 volume;Add chitosan and amylomaize, stirring, obtain petrifying liquid;Straw, The mass ratio of Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, chitosan and amylomaize is 20:15:15:15: 5:5:1:100;
The preparation of natural moistureproof edible food package paper: petrifying liquid is coated on dietary fiber layer, after cooling, then will Protein liquid is coated on moistureproof liquid layer, controls petrifying liquid below layer thickness 1mm;Control protein liquid thickness 1-2mm;It is dried, to obtain final product.

Claims (7)

1. the preparation method of a natural moistureproof edible food package paper, it is characterised in that: comprise the following steps:
(1) preparation of dietary fiber layer: with vegetable or fruit as raw material, cleans and is placed in the boiling water bath containing sodium bicarbonate at burn Reason, then be placed in cold water and cool down rapidly;Vegetable or the fruit raw material of cooling are placed in beater making beating, separate vegetable juice or fruit Juice;Vegetable slag and marc are pulverized 20-30min, crosses 100-150 mesh sieve;Filtrate is placed in homogenizing 3-5 time under 40-60MPa, obtains all Even fiber mixed liquor;Boil 2-3min, make fiber mixed liquor swelling;Continue to boil 2-3min, be cooled to 60-70 DEG C, add Weight ratio hydroxymethyl cellulose and sodium alginate, stirring to being completely dissolved, add Cera Flava, stir, cooling, room temperature, Preserve 1-2h under 0.10-0.20MPa, make degassing, obtain film liquid;Utilize film rod coated film liquid on a glass, control wet coating thickness Degree is 1-2mm;It is dried, obtains dietary fiber layer;
(2) preparation of protein liquid: with Semen sojae atricolor as raw material, clean, soaking at room temperature 3-5h, defibrination, boil after cross 100-150 mesh sieve, Obtain bean dregs;Bean dregs join gelatinizing in adjunce copper, and stirring is simultaneously introduced sodium bicarbonate aqueous solution and adjusts pH to 7-8, adds protease Hydrolysis 3-5h, obtains amyloid proteins and sticks with paste;Add modifier aqueous solution, 30-60 DEG C of hybrid reaction 10-20min, obtain compound Liquid;Adding plasticizer and auxiliary additive in complex liquid, 30-60 DEG C is continued stirring 10-20min, obtains protein liquid;
(3) preparation of petrifying liquid: take straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, is placed in the water of 5-15 times amount Middle decoction 8-12h;Filter, be concentrated into 1/3 volume;Add chitosan and amylomaize, stirring, obtain petrifying liquid;
(4) preparation of natural moistureproof edible food package paper: petrifying liquid is coated on dietary fiber layer, after cooling, then will Protein liquid is coated on moistureproof liquid layer, controls petrifying liquid below layer thickness 1mm;Control protein liquid thickness 1-2mm;It is dried, to obtain final product.
The preparation method of a kind of natural moistureproof edible food package paper the most according to claim 1, it is characterised in that: step Suddenly, in (1), the mass concentration of sodium bicarbonate is 0.1-0.2%.
The preparation method of a kind of natural moistureproof edible food package paper the most according to claim 1, it is characterised in that: step Suddenly, in (1), the weight of hydroxymethyl cellulose is the 0.5-1.0% of fiber mixed liquor weight.
The preparation method of a kind of natural moistureproof edible food package paper the most according to claim 1, it is characterised in that: step Suddenly, in (1), the weight of sodium alginate is the 0.25-0.5% of fiber mixed liquor weight.
The preparation method of a kind of natural moistureproof edible food package paper the most according to claim 1, it is characterised in that: step Suddenly, in (1), the weight of Cera Flava is the 0.24-1.0% of fiber mixed liquor weight.
The preparation method of a kind of natural moistureproof edible food package paper the most according to claim 1, it is characterised in that: In step (2), the mass concentration of sodium bicarbonate aqueous solution is 0.1-0.2%.
The preparation method of a kind of natural moistureproof edible food package paper the most according to claim 1, it is characterised in that: step Suddenly in (3), the mass ratio of straw, Herba Houttuyniae, Radix Et Rhizoma Fagopyri Tatarici, Fructus Sapindi Mukouossi, stalky tea, Semen Cassiae, chitosan and amylomaize For (10-20): (5-15): (5-15): (5-15): (5-15): (3-5): 1:100.
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