CN104845514A - Anti-condensation and anti-frosting refrigerating cabinet glass and preparation method thereof - Google Patents
Anti-condensation and anti-frosting refrigerating cabinet glass and preparation method thereof Download PDFInfo
- Publication number
- CN104845514A CN104845514A CN201510177926.2A CN201510177926A CN104845514A CN 104845514 A CN104845514 A CN 104845514A CN 201510177926 A CN201510177926 A CN 201510177926A CN 104845514 A CN104845514 A CN 104845514A
- Authority
- CN
- China
- Prior art keywords
- parts
- glass
- acrylate
- coating layer
- super
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention relates to anti-condensation and anti-frosting refrigerating cabinet glass; the refrigerating cabinet glass is composed of an organic glass base material and a super-hydrophobic photocuring coating layer modified on the base material surface, wherein the super-hydrophobic photocuring coating layer is composed of the following raw materials in parts by weight: 40-60 parts of epoxy acrylate, 20-30 parts of fluorinated acrylate, 10-20 parts of an acrylate modified organic silicone oil, 80-100 parts of polyether tetraacrylate, 1-2 parts of nano silica, and 2-4 parts of a photoinitiator. The surface of the organic glass base material is coated with the photocuring coating layer, the surface of the photocuring coating layer contains fluorine silicon chains, and thus a super-hydrophobic layer is formed and condensation and frost formation are prevented fundamentally; at the same time, the coating layer is relatively high in hardness and has a hardening effect on the surface of the organic glass; the coating layer has a relatively high transparency, thereby not affecting the glass light transmittance; the organic glass has relatively low thermal conductivity, thereby slowing down heat exchange of the inner side and the outer side of the glass; and at the same time, nano silica has extremely strong ultraviolet absorption and infrared reflection properties, thereby enhancing the heat insulation of the coating layer and effectively reducing energy consumption.
Description
Technical field
The present invention relates to a kind of glass for refrigerator, particularly relate to a kind of anti-condensation frosting glass for refrigerator and preparation method thereof.
Background technology
Adopt the low temperature refrigerator of transparent glass door, showcase because of its penetrating attractive in appearance, display function is superior and be commercially more and more subject to the welcome of user, but because refrigerator-freezer internal and external environment exists the temperature difference, glass temperature is lower than ambient dew point, the easy condensation of glass outer side, and refrigerator-freezer internal temperature is lower, be adsorbed on the easy frosting of steam of glass inner side.
The approach of current solution glass door condensation frosting mainly contains two kinds: one lays electric heating film inside freezer door double glazing, by electric heating film heating, improves glass temperature, prevents condensation frosting; Another kind is that warm braw condenser surface being carried heat by ad hoc air-supply arrangement constantly blows on glass door, to improve the temperature of glass, prevents condensation frosting.The Method And Principle laying electric heating film is simple, but power consumption is larger.The method of setting up air-supply arrangement make use of heat that condenser distributes to heat glass, relatively energy-conservation, but extra auxiliary collecting folk songs and supply air system need be added, complex structure, cost increases, also have certain influence to surrounding enviroment during air-supply, the heat that air-supply arrangement transmits simultaneously will cause refrigeration system to strengthen refrigeration power consumption, form pernicious futile cycle.Therefore existing method all fundamentally can not solve condensation frosting problem, if improve glass surface hydrophobicity, make steam can not be adsorbed on glass surface for a long time, can fundamentally prevent condensation frosting.
Summary of the invention
First technical problem to be solved by this invention is the anti-condensation frosting glass for refrigerator providing a kind of anti-condensation frosting effective for prior art.
Second technical problem to be solved by this invention is to provide a kind of preparation method of above-mentioned anti-condensation frosting glass for refrigerator.
The present invention solves the technical scheme that first technical problem adopt: a kind of anti-condensation frosting glass for refrigerator, this glass for refrigerator is made up of organic glass substrate and the super-hydrophobic light solidifying coating being modified at this substrate surface, count by weight, described super-hydrophobic light solidifying coating is made up of following raw material: epoxy acrylate 40 ~ 60 parts, fluorinated acrylate 20 ~ 30 parts, acrylate modified organic silicone oil 10 ~ 20 parts, polyether tetra-acrylate 80 ~ 100 parts, nano silicon 1 ~ 2 part, light trigger 2 ~ 4 parts.
The present invention solves the technical scheme that second technical problem adopt: the preparation method of above-mentioned anti-condensation frosting glass for refrigerator comprises the following steps:
(1) preparation of organic glass substrate: the PMMA pellet that drying dewaters in advance is added in vented extruder, prepare methacrylate sheet, sheet material is cut into the stock requiring size, be clamped on mold frame, the organic glass substrate requiring shape is prepared in thermoforming;
(2) preparation of light solidifying coating: by above-mentioned mass fraction, nano silicon is added in polyether tetra-acrylate, ultrasonic disperse 20 ~ 30min, form finely dispersed nano silicon dispersion liquid, add acrylate modified organic silicone oil, epoxy acrylate, fluorinated acrylate and light trigger again, and feed in raw material while stir, reinforced complete stirring 20 ~ 30min;
(3) coating of synthetic glass top coat: the organic glass substrate surface cleaning above-mentioned preparation, after surface drying, again light solidifying coating prepared by described step (2) is sprayed to this organic glass substrate surface, spray pressure 0.4 ~ 0.6MPa, spray distance 15 ~ 25cm, spraying rate 30 ~ 40cm/s, spray complete standing 1 ~ 2min, again the base material being coated with light solidifying coating is sent in conveyor type uv curing machine, solidify 120 ~ 150s under nitrogen atmosphere with the ultraviolet lamp of 80W/cm, obtain described anti-condensation frosting glass for refrigerator.
Compared with prior art, the invention has the advantages that: the present invention is at organic glass substrate surface-coated light solidifying coating, and wherein synthetic glass is lower than simple glass density, physical strength is high, shatter-resistant ability is high, and be easy to processing; Light solidifying coating surface fluorine silicon chain, thus form super-hydrophobic layer, fundamentally prevent condensation frosting; The hardness of coating own is higher simultaneously, has sclerization to synthetic glass surface; Coating transparency is higher, does not affect glass light transmitance; Synthetic glass thermal conductivity is lower, can slow down both sides heat exchange inside and outside glass, and nano silicon has extremely strong uv-absorbing and infrared external reflection characteristic simultaneously, strengthens the thermal insulation of coating, effectively reduces energy consumption; This glass for refrigerator preparation method is simple in addition, and operating process is easy to control, and can extensively be extended in the production of anti-condensation frosting glass for refrigerator.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, the VH5 that the synthetic glass (PMMA) used in following embodiment is produced for the beautiful sun of Mitsubishi;
Epoxy acrylate is the amino modified bisphenol A epoxy acrylate EBECRYL 3703 that Qing Te chemical company of the U.S. produces, molecular weight 850, viscosity 4250cP;
Fluorinated acrylate is the methacrylic acid ten trifluoro monooctyl ester that Harbin Xue Jiafu chemistry of silicones company limited produces, molecular weight 432, surface tension (dym/cm) 12.8;
Acrylate modified organic silicone oil is two tip type reactive silicone oil X-22-164A, the kinematic viscosity 25mm of Japanese SHIN-ETSU HANTOTAI chemical production
2/ s;
Polyether tetra-acrylate is the EBECRYL 40, viscosity 160cP that Qing Te chemical company of the U.S. produces;
Nano silicon is the hydrophobic type aerosil R106 that German goldschmidt chemical corporation is produced, median size 7nm; Light trigger is the IRGACURE 184 that German BASF (vapour bar) company produces.
Embodiment 1:
First the PMMA pellet that drying dewaters in advance is added vented extruder, prepare methacrylate sheet, sheet material is cut into the stock requiring size, be clamped on mold frame, the organic glass substrate requiring shape is prepared in thermoforming.Secondly, by the super-hydrophobic light solidifying coating raw material of the recipe configuration in table 1, nano silicon is added polyether tetra-acrylate, ultrasonic disperse 30min, form finely dispersed nano silicon dispersion liquid, then add acrylate modified organic silicone oil, epoxy acrylate, fluorinated acrylate, light trigger successively, feed in raw material while high-speed stirring, reinforced complete stirring 20min, obtained super-hydrophobic photo-cured coating.Finally, the organic glass substrate surface of preparing with alcohol washes, again by the super-hydrophobic photo-cured coating spraying surface of falling organic glass substrate of preparation, spray pressure 0.4MPa, spray distance 15cm, spraying rate 30cm/s, spray complete standing 1min, send into conveyor type uv curing machine again, solidify 120s under nitrogen atmosphere with the ultraviolet lamp of 80W/cm, obtain required anti-condensation frosting glass for refrigerator.
Embodiment 2:
First the PMMA pellet that drying dewaters in advance is added vented extruder, prepare methacrylate sheet, sheet material is cut into the stock requiring size, be clamped on mold frame, the organic glass substrate requiring shape is prepared in thermoforming.Secondly, by the super-hydrophobic light solidifying coating raw material of the recipe configuration in table 1, nano silicon is added polyether tetra-acrylate, ultrasonic disperse 30min, form finely dispersed nano silicon dispersion liquid, then add acrylate modified organic silicone oil, epoxy acrylate, fluorinated acrylate, light trigger successively, feed in raw material while high-speed stirring, reinforced complete stirring 20min, obtained super-hydrophobic photo-cured coating.Finally, the organic glass substrate surface of preparing with alcohol washes, again by the super-hydrophobic photo-cured coating spraying surface of falling organic glass substrate of preparation, spray pressure 0.4MPa, spray distance 15cm, spraying rate 30cm/s, spray complete standing 1min, send into conveyor type uv curing machine again, solidify 120s under nitrogen atmosphere with the ultraviolet lamp of 80W/cm, obtain required anti-condensation frosting glass for refrigerator.
Embodiment 3:
First the PMMA pellet that drying dewaters in advance is added vented extruder, prepare methacrylate sheet, sheet material is cut into the stock requiring size, be clamped on mold frame, the organic glass substrate requiring shape is prepared in thermoforming.Secondly, by the super-hydrophobic light solidifying coating raw material of the recipe configuration in table 1, nano silicon is added polyether tetra-acrylate, ultrasonic disperse 30min, form finely dispersed nano silicon dispersion liquid, then add acrylate modified organic silicone oil, epoxy acrylate, fluorinated acrylate, light trigger successively, feed in raw material while high-speed stirring, reinforced complete stirring 20min, obtained super-hydrophobic photo-cured coating.Finally, the organic glass substrate surface of preparing with alcohol washes, again by the super-hydrophobic photo-cured coating spraying surface of falling organic glass substrate of preparation, spray pressure 0.4MPa, spray distance 15cm, spraying rate 30cm/s, spray complete standing 1min, send into conveyor type uv curing machine again, solidify 120s under nitrogen atmosphere with the ultraviolet lamp of 80W/cm, obtain required anti-condensation frosting glass for refrigerator.
Embodiment 4:
First the PMMA pellet that drying dewaters in advance is added vented extruder, prepare methacrylate sheet, sheet material is cut into the stock requiring size, be clamped on mold frame, the organic glass substrate requiring shape is prepared in thermoforming.Secondly, by the super-hydrophobic light solidifying coating raw material of the recipe configuration in table 1, nano silicon is added polyether tetra-acrylate, ultrasonic disperse 30min, form finely dispersed nano silicon dispersion liquid, then add acrylate modified organic silicone oil, epoxy acrylate, fluorinated acrylate, light trigger successively, feed in raw material while high-speed stirring, reinforced complete stirring 20min, obtained super-hydrophobic photo-cured coating.Finally, the organic glass substrate surface of preparing with alcohol washes, again by the super-hydrophobic photo-cured coating spraying surface of falling organic glass substrate of preparation, spray pressure 0.4MPa, spray distance 15cm, spraying rate 30cm/s, spray complete standing 1min, send into conveyor type uv curing machine again, solidify 120s under nitrogen atmosphere with the ultraviolet lamp of 80W/cm, obtain required anti-condensation frosting glass for refrigerator.
The super-hydrophobic light solidifying coating formula of table 1
| Component title | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Epoxy acrylate | 40 | 60 | 50 | 50 |
| Fluorinated acrylate | 20 | 30 | 27 | 22 |
| Acrylate modified organic silicone oil | 20 | 10 | 12 | 18 |
| Polyether tetra-acrylate | 100 | 80 | 90 | 96 |
| Nano silicon | 2 | 2 | 1 | 1.5 |
| Light trigger | 2 | 4 | 3 | 3 |
Note: be mass fraction in above-mentioned each super-hydrophobic light solidifying coating formula.
Embodiment 5:
The anti-condensation frosting glass for refrigerator of the present embodiment to above-described embodiment 1 ~ 4 gained carries out correlated performance test, and test result is in table 2, and testing method is as follows:
(1) surface hardness test: test according to GB/T 6739-2006 " paint and varnish pencil method measures hardness of paint film ".
(2) coating adhesion test: test according to GB/T 9286-1998 " cross cut test of paint and varnish paint film ".
(3) contact angle and roll angle test: the JC2000F roll angle survey meter contact angle of test distilled water on synthetic glass surface adopting Beijing China National Instruments Import & Export Corporation Ke Xin Science and Technology Ltd. to produce and roll angle.
(4) transmittance test: test according to GB/T 2410-2008 " mensuration of transparent plastics transmittance and mist degree ".
The embodiment products obtained therefrom the performance test results that table 2 is different
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Surface hardness | 5H | 6H | 6H | 6H |
| Sticking power, level | 0 | 0 | 0 | 0 |
| Contact angle, ° | 151 | 153 | 152 | 154 |
| Roll angle, ° | 13 | 12 | 12 | 10 |
| Transmittance, % | 92 | 92 | 92 | 92 |
Claims (2)
1. an anti-condensation frosting glass for refrigerator, it is characterized in that, this glass for refrigerator is made up of organic glass substrate and the super-hydrophobic light solidifying coating being modified at this substrate surface, count by weight, described super-hydrophobic light solidifying coating is made up of following raw material: epoxy acrylate 40 ~ 60 parts, fluorinated acrylate 20 ~ 30 parts, acrylate modified organic silicone oil 10 ~ 20 parts, polyether tetra-acrylate 80 ~ 100 parts, nano silicon 1 ~ 2 part, light trigger 2 ~ 4 parts.
2. a preparation method for anti-condensation frosting glass for refrigerator as claimed in claim 1, is characterized in that comprising the following steps:
(1) preparation of organic glass substrate: the PMMA pellet that drying dewaters in advance is added in vented extruder, prepare methacrylate sheet, sheet material is cut into the stock requiring size, be clamped on mold frame, the organic glass substrate requiring shape is prepared in thermoforming;
(2) preparation of light solidifying coating: by above-mentioned mass fraction, nano silicon is added in polyether tetra-acrylate, ultrasonic disperse 20 ~ 30min, form finely dispersed nano silicon dispersion liquid, add acrylate modified organic silicone oil, epoxy acrylate, fluorinated acrylate and light trigger again, and feed in raw material while stir, reinforced complete stirring 20 ~ 30min;
(3) coating of synthetic glass top coat: the organic glass substrate surface cleaning above-mentioned preparation, after surface drying, again light solidifying coating prepared by described step (2) is sprayed to this organic glass substrate surface, spray pressure 0.4 ~ 0.6MPa, spray distance 15 ~ 25cm, spraying rate 30 ~ 40cm/s, spray complete standing 1 ~ 2min, again the base material being coated with light solidifying coating is sent in conveyor type uv curing machine, solidify 120 ~ 150s under nitrogen atmosphere with the ultraviolet lamp of 80W/cm, obtain described anti-condensation frosting glass for refrigerator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510177926.2A CN104845514B (en) | 2015-04-15 | 2015-04-15 | A kind of anti-condensation frosting glass for refrigerator and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510177926.2A CN104845514B (en) | 2015-04-15 | 2015-04-15 | A kind of anti-condensation frosting glass for refrigerator and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104845514A true CN104845514A (en) | 2015-08-19 |
| CN104845514B CN104845514B (en) | 2017-07-04 |
Family
ID=53845520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510177926.2A Active CN104845514B (en) | 2015-04-15 | 2015-04-15 | A kind of anti-condensation frosting glass for refrigerator and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104845514B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105040446A (en) * | 2015-08-29 | 2015-11-11 | 福建鑫华股份有限公司 | Preparation method of breathable self-cleaning fabric |
| CN107032634A (en) * | 2017-03-20 | 2017-08-11 | 广东省新材料研究所 | A kind of preparation method of glass hydrophobic film |
| CN110588102A (en) * | 2019-07-11 | 2019-12-20 | 中国航发北京航空材料研究院 | Lightweight vehicle window for high-speed train and manufacturing method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225272A (en) * | 2008-01-31 | 2008-07-23 | 中国科学院化学研究所 | Rime-proof coating material and method of use thereof |
| CN101824273A (en) * | 2010-03-31 | 2010-09-08 | 中科院广州化学有限公司 | Fluoropolymer/inorganic nano-hybrid particle modified ultraviolet photocured paint and preparation method thereof |
| US20110104467A1 (en) * | 2009-10-29 | 2011-05-05 | Xerox Corporation | Uv cured intermediate transfer members |
| CN102585635A (en) * | 2012-01-12 | 2012-07-18 | 中山大桥化工集团有限公司 | Anti-icing paint and preparation method thereof |
| CN103073934A (en) * | 2012-12-28 | 2013-05-01 | 上海维凯化学品有限公司 | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof |
| CN103305116A (en) * | 2013-06-17 | 2013-09-18 | 武汉绿凯科技有限公司 | Photo-curing transparency-increased film coating solution as well as preparation method and application thereof |
| CN103709800A (en) * | 2013-11-19 | 2014-04-09 | 北京化工大学常州先进材料研究院 | High glass adhesion UV (ultraviolet) resin |
-
2015
- 2015-04-15 CN CN201510177926.2A patent/CN104845514B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225272A (en) * | 2008-01-31 | 2008-07-23 | 中国科学院化学研究所 | Rime-proof coating material and method of use thereof |
| US20110104467A1 (en) * | 2009-10-29 | 2011-05-05 | Xerox Corporation | Uv cured intermediate transfer members |
| CN101824273A (en) * | 2010-03-31 | 2010-09-08 | 中科院广州化学有限公司 | Fluoropolymer/inorganic nano-hybrid particle modified ultraviolet photocured paint and preparation method thereof |
| CN102585635A (en) * | 2012-01-12 | 2012-07-18 | 中山大桥化工集团有限公司 | Anti-icing paint and preparation method thereof |
| CN103073934A (en) * | 2012-12-28 | 2013-05-01 | 上海维凯化学品有限公司 | Ultraviolet curing anti-fingerprint coating for acrylic and composite material base material thereof |
| CN103305116A (en) * | 2013-06-17 | 2013-09-18 | 武汉绿凯科技有限公司 | Photo-curing transparency-increased film coating solution as well as preparation method and application thereof |
| CN103709800A (en) * | 2013-11-19 | 2014-04-09 | 北京化工大学常州先进材料研究院 | High glass adhesion UV (ultraviolet) resin |
Non-Patent Citations (1)
| Title |
|---|
| 李辉 等: "抗结冰涂层:从表面化学到功能化表面", 《化学进展》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105040446A (en) * | 2015-08-29 | 2015-11-11 | 福建鑫华股份有限公司 | Preparation method of breathable self-cleaning fabric |
| CN107032634A (en) * | 2017-03-20 | 2017-08-11 | 广东省新材料研究所 | A kind of preparation method of glass hydrophobic film |
| CN107032634B (en) * | 2017-03-20 | 2020-01-03 | 广东省新材料研究所 | Preparation method of glass hydrophobic film |
| CN110588102A (en) * | 2019-07-11 | 2019-12-20 | 中国航发北京航空材料研究院 | Lightweight vehicle window for high-speed train and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104845514B (en) | 2017-07-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104845514A (en) | Anti-condensation and anti-frosting refrigerating cabinet glass and preparation method thereof | |
| CN103192562A (en) | Stainless steel plate with 3D (three dimensional) surface effect and machining process of stainless steel plate | |
| ATE552222T1 (en) | METHOD FOR PRODUCING A THERMALLY TENSIONED COATED ARTICLE WITH TCO COATING AND PRODUCT PRODUCED IN THIS WAY | |
| CN101665330A (en) | Hydrophober and method for preparing hydrophobic glass by same | |
| CN103420620A (en) | Glass bottle surface spraying technology | |
| CN105365233A (en) | Preparation method of imitation metal wiredrawing composite high light film | |
| CN109485780B (en) | Acrylic sheet and preparation process thereof | |
| CN113969074A (en) | Transparent radiation refrigeration film of DCPDA/DPHA photocuring monomer | |
| CN203901861U (en) | High-end glass decoration faceplate | |
| CN202630635U (en) | Vacuum drying box with heating device on box door | |
| CN204270735U (en) | The full-automatic ageing oven of a kind of conductive film for touch screen tunnel type | |
| CN204396309U (en) | Drying tunnel is dried in a kind of solidification | |
| CN205553449U (en) | Good dull polish plastics panel of dull polish effect | |
| CN203527994U (en) | Stainless steel plate with 3D (three-dimensional) surface effect | |
| CN202685485U (en) | UV (ultraviolet) soft touch membrane | |
| CN102602095B (en) | Refrigerator painted sculptures overlay film panel and preparation method thereof | |
| CN201033765Y (en) | Modified flat glass film coating device | |
| CN202319170U (en) | MS (styrene-methyl methacrylate copolymer), PS (polystyrene) plastic reinforced board structure | |
| CN104210184B (en) | Thermal insulation, temperature rising glass | |
| CN101792894A (en) | Crack plating process | |
| CN204172446U (en) | Thermal insulation, temperature rising glass | |
| CN206098051U (en) | Enameled wire japanning device | |
| CN206861989U (en) | A kind of refrigerator extrusion molding IMD Handicraft decorative bars | |
| CN109353036A (en) | Hydrophilic group Silica Surface treatment process | |
| CN205722982U (en) | A kind of resistant to elevated temperatures enameled wire machining device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |