CN104844987A - 一种汽车线束用氟橡胶改性pvc电缆料及其制备方法 - Google Patents

一种汽车线束用氟橡胶改性pvc电缆料及其制备方法 Download PDF

Info

Publication number
CN104844987A
CN104844987A CN201510285921.1A CN201510285921A CN104844987A CN 104844987 A CN104844987 A CN 104844987A CN 201510285921 A CN201510285921 A CN 201510285921A CN 104844987 A CN104844987 A CN 104844987A
Authority
CN
China
Prior art keywords
parts
cable material
nano
pvc
epoxy resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510285921.1A
Other languages
English (en)
Inventor
琚克刚
关绍文
翟阿蕾
罗杰
谷洪涛
朱艳
刘育峰
胡青霞
琚一辉
张燕
琚一雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Deren Electronic Devices Co Ltd
Original Assignee
Hefei Deren Electronic Devices Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Deren Electronic Devices Co Ltd filed Critical Hefei Deren Electronic Devices Co Ltd
Priority to CN201510285921.1A priority Critical patent/CN104844987A/zh
Publication of CN104844987A publication Critical patent/CN104844987A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246—Intercrosslinking of at least two polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/20—Homopolymers or copolymers of hexafluoropropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

一种汽车线束用氟橡胶改性PVC电缆料，由下列重量份的原料制成：PVC65-70、钙锌稳定剂7-8、偏苯三酸三辛酯40-50、三烯丙基异氰脲酸酯2.5-3、过氧化二异丙苯0.2-0.3、硼酸0.1-0.2、六氟丙烯三元共聚橡胶20-25、纳米氧化锌4-4.5、乙酸乙烯酯1.8-2.1、纳米纤维素1.4-1.8、二乙基二硫代氨基甲酸锌2.4-2.8、三乙醇胺1-1.3、E-12环氧树脂2-2.5、二甲苯1.2-1.6、热塑性聚氨酯18-22、抗氧剂1010 0.8-0.9。本发明电缆料通过使用E-12环氧树脂，提高了电缆料的粘接强度和尺寸稳定性，适用于制作汽车仪表、照明、空调等部件的线束。

Description

一种汽车线束用氟橡胶改性PVC电缆料及其制备方法
技术领域
本发明涉及电缆料领域，尤其涉及一种汽车线束用氟橡胶改性PVC电缆料及其制备方法。
背景技术
热塑性聚氨酯( TPU) 是一种性能极好的弹性体，具有优良的耐酸碱性、耐油性和力学性能，并且使用温度范围大，可作为PVC 材料的增韧剂或改性剂。TPU 还能提高PVC 材料的加工流动性，起到增塑效果。但由于TPU 价格较贵，且阻燃性较差，其应用受到限制。PVC 的牌号多，应用广，成本低，是一种重要的通用塑料。TPU 与PVC混合交联，能有效降低TPU的成本，提高性能，扩大其应用范围; 另一方面，TPU 的加入能有效改善PVC 的耐低温性能。
《汽车用PVC/热塑性聚氨酯交联电缆料的研制》一文使用配方: PVC100 份，钙锌稳定剂8份，TOTM 50份，TAIC 3份，DCP 0.2份，TPU 30份，抗氧剂0.8 份，其他助剂适量，生产出合格的汽车用电缆料，但是该电缆料在耐热性、耐油性、耐紫外性、抗氧化性、耐腐蚀性、耐大气老化性、气密性、耐磨性、耐低温性等方面还不尽如人意。
氟橡胶具有非常优异的耐辐射、耐高温、耐油、耐高真空及耐酸碱、耐多种化学药品的特点，可以使用氟橡胶以及其他原料和工艺对PVC/热塑性聚氨酯交联电缆料进行改性，以提高该电缆料的各项性能。
发明内容
本发明的目的在于提供一种汽车线束用氟橡胶改性PVC电缆料，该电缆料的耐低温性、耐热性、抗氧化性、耐油性、耐腐蚀性、绝缘性、气密性和耐大气老化性好，而且耐磨性、韧性好，粘接强度和尺寸稳定性好，适用于制作汽车仪表、照明、空调等部件的线束。
本发明的技术方案如下：
一种汽车线束用氟橡胶改性PVC电缆料，其特征在于由下列重量份的原料制成：PVC65-70、钙锌稳定剂7-8、偏苯三酸三辛酯40-50、三烯丙基异氰脲酸酯2.5-3、过氧化二异丙苯0.2-0.3、硼酸0.1-0.2、六氟丙烯三元共聚橡胶20-25、纳米氧化锌4-4.5、乙酸乙烯酯1.8-2.1、纳米纤维素1.4-1.8、二乙基二硫代氨基甲酸锌2.4-2.8、三乙醇胺1-1.3、E-12环氧树脂2-2.5、二甲苯1.2-1.6、热塑性聚氨酯18-22、抗氧剂1010 0.8-0.9。
所述的汽车线束用氟橡胶改性PVC电缆料的生产方法，其特征在于：
（1）将六氟丙烯三元共聚橡胶、过氧化二异丙苯、硼酸、乙酸乙烯酯、纳米纤维素、三乙醇胺、E-12环氧树脂、纳米氧化锌、二甲苯混合，送入开炼机中，在60-70℃下开练4-5分钟，得到胶体；
（2）将第（1）步得到的胶体与PVC、钙锌稳定剂、偏苯三酸三辛酯、三烯丙基异氰脲酸酯、抗氧剂1010送入高速混合机中，高速搅拌，当物料温度达到115-120℃时，将物料放入冷混机中低速搅拌，当物料冷却至45-55℃时出料，得到混合物料；
（3）在不加热的情况下，将步骤(2)制得的物料与其他剩余成分送入高速混合机中混合4-5分钟，再送入平行双螺杆挤出机，在140-145℃下挤出造粒；
（4）将第（3）步得到的粒料送入开炼机中在140-145℃下开片，再送入热模压机中，在170-180℃下压片处理3-4分钟，在室温下交联1-2个小时，即得。
本发明的有益效果
本发明电缆料使用热塑性聚氨酯、氟橡胶与PVC共混，交联改性，能有效提高电缆料的性能，能有效改善PVC的耐低温性、耐热性、抗氧化性、耐油性、耐腐蚀性、绝缘性、气密性和耐大气老化性，扩大其应用范围；通过使用乙酸乙烯酯、纳米纤维素、三乙醇胺、E-12环氧树脂，提高了电缆料的粘接强度和尺寸稳定性，适用于制作汽车仪表、照明、空调等部件的线束。
具体实施方式
一种汽车线束用氟橡胶改性PVC电缆料，由下列重量份（公斤）的原料制成：PVC67、钙锌稳定剂7.5、偏苯三酸三辛酯45、三烯丙基异氰脲酸酯2.8、过氧化二异丙苯0.2、硼酸0.1、六氟丙烯三元共聚橡胶23、纳米氧化锌4.3、乙酸乙烯酯2、纳米纤维素1.6、二乙基二硫代氨基甲酸锌2.6、三乙醇胺1.1、E-12环氧树脂2.3、二甲苯1.4、热塑性聚氨酯20、抗氧剂1010 0.8。
所述的汽车线束用氟橡胶改性PVC电缆料的生产方法，其特征在于：
（1）将六氟丙烯三元共聚橡胶、过氧化二异丙苯、硼酸、乙酸乙烯酯、纳米纤维素、三乙醇胺、E-12环氧树脂、纳米氧化锌、二甲苯混合，送入开炼机中，在65℃下开练4分钟，得到胶体；
（2）将第（1）步得到的胶体与PVC、钙锌稳定剂、偏苯三酸三辛酯、三烯丙基异氰脲酸酯、抗氧剂1010送入高速混合机中，高速搅拌，当物料温度达到117℃时，将物料放入冷混机中低速搅拌，当物料冷却至50℃时出料，得到混合物料；
（3）在不加热的情况下，将步骤(2)制得的物料与其他剩余成分送入高速混合机中混合4分钟，再送入平行双螺杆挤出机，在140℃下挤出造粒；
（4）将第（3）步得到的粒料送入开炼机中在140℃下开片，再送入热模压机中，在175℃下压片处理3分钟，在室温下交联1个小时，即得。
实验数据：
经测试该实施例电缆料的拉伸强度为25MPa，断裂伸长率为310%，老化后拉伸强度变化率为-8%，老化后断裂伸长率变化率为-10%，200℃热稳定时间为185min，冲击脆化温度为-45℃，20℃体积电阻率为2.4×1012Ω﹒m，热延伸率为128%。

Claims (2)

1.一种汽车线束用氟橡胶改性PVC电缆料，其特征在于由下列重量份的原料制成：PVC65-70、钙锌稳定剂7-8、偏苯三酸三辛酯40-50、三烯丙基异氰脲酸酯2.5-3、过氧化二异丙苯0.2-0.3、硼酸0.1-0.2、六氟丙烯三元共聚橡胶20-25、纳米氧化锌4-4.5、乙酸乙烯酯1.8-2.1、纳米纤维素1.4-1.8、二乙基二硫代氨基甲酸锌2.4-2.8、三乙醇胺1-1.3、E-12环氧树脂2-2.5、二甲苯1.2-1.6、热塑性聚氨酯18-22、抗氧剂1010 0.8-0.9。
2.根据权利要求1所述的汽车线束用氟橡胶改性PVC电缆料的生产方法，其特征在于：
（1）将六氟丙烯三元共聚橡胶、过氧化二异丙苯、硼酸、乙酸乙烯酯、纳米纤维素、三乙醇胺、E-12环氧树脂、纳米氧化锌、二甲苯混合，送入开炼机中，在60-70℃下开练4-5分钟，得到胶体；
（2）将第（1）步得到的胶体与PVC、钙锌稳定剂、偏苯三酸三辛酯、三烯丙基异氰脲酸酯、抗氧剂1010送入高速混合机中，高速搅拌，当物料温度达到115-120℃时，将物料放入冷混机中低速搅拌，当物料冷却至45-55℃时出料，得到混合物料；
（3）在不加热的情况下，将步骤(2)制得的物料与其他剩余成分送入高速混合机中混合4-5分钟，再送入平行双螺杆挤出机，在140-145℃下挤出造粒；
（4）将第（3）步得到的粒料送入开炼机中在140-145℃下开片，再送入热模压机中，在170-180℃下压片处理3-4分钟，在室温下交联1-2个小时，即得。
CN201510285921.1A 2015-05-29 2015-05-29 一种汽车线束用氟橡胶改性pvc电缆料及其制备方法 Pending CN104844987A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510285921.1A CN104844987A (zh) 2015-05-29 2015-05-29 一种汽车线束用氟橡胶改性pvc电缆料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510285921.1A CN104844987A (zh) 2015-05-29 2015-05-29 一种汽车线束用氟橡胶改性pvc电缆料及其制备方法

Publications (1)

Publication Number Publication Date
CN104844987A true CN104844987A (zh) 2015-08-19

Family

ID=53845002

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510285921.1A Pending CN104844987A (zh) 2015-05-29 2015-05-29 一种汽车线束用氟橡胶改性pvc电缆料及其制备方法

Country Status (1)

Country Link
CN (1) CN104844987A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105670260A (zh) * 2016-01-23 2016-06-15 中山顺富节能科技有限公司 一种耐寒耐腐蚀空调节电装置
CN106674795A (zh) * 2016-11-17 2017-05-17 铜陵信邦实业有限公司 一种耐磨防火的导线
CN106977850A (zh) * 2017-04-20 2017-07-25 温州网牌电线电缆有限公司 耐火聚氯乙烯护套电缆
CN108752869A (zh) * 2018-05-28 2018-11-06 安徽顺彤包装材料有限公司 一种优质耐疲劳复合材料
EP3747970A4 (en) * 2018-02-01 2021-10-20 Hokuetsu Corporation WATER-REPELLENT OIL-REPELLENT AGENT AND METHOD FOR MANUFACTURING IT, AND WATER-REPELLENT OIL-REPELLENT PRODUCT AND METHOD FOR MANUFACTURING IT

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509274A (zh) * 2013-08-30 2014-01-15 安徽天民电气科技有限公司 一种耐油耐寒防紫外线聚氯乙烯/丁腈橡胶复合电缆料及其制备方法
CN103524946A (zh) * 2013-10-17 2014-01-22 宁波一舟塑胶有限公司 一种耐高温的热塑性聚氯乙烯电缆料及其制备方法
CN103589102A (zh) * 2013-10-29 2014-02-19 绿宝电缆（集团）有限公司 一种柔韧耐寒耐老化改性丙烯酸酯橡胶电缆料

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509274A (zh) * 2013-08-30 2014-01-15 安徽天民电气科技有限公司 一种耐油耐寒防紫外线聚氯乙烯/丁腈橡胶复合电缆料及其制备方法
CN103524946A (zh) * 2013-10-17 2014-01-22 宁波一舟塑胶有限公司 一种耐高温的热塑性聚氯乙烯电缆料及其制备方法
CN103589102A (zh) * 2013-10-29 2014-02-19 绿宝电缆（集团）有限公司 一种柔韧耐寒耐老化改性丙烯酸酯橡胶电缆料

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105670260A (zh) * 2016-01-23 2016-06-15 中山顺富节能科技有限公司 一种耐寒耐腐蚀空调节电装置
CN106674795A (zh) * 2016-11-17 2017-05-17 铜陵信邦实业有限公司 一种耐磨防火的导线
CN106977850A (zh) * 2017-04-20 2017-07-25 温州网牌电线电缆有限公司 耐火聚氯乙烯护套电缆
EP3747970A4 (en) * 2018-02-01 2021-10-20 Hokuetsu Corporation WATER-REPELLENT OIL-REPELLENT AGENT AND METHOD FOR MANUFACTURING IT, AND WATER-REPELLENT OIL-REPELLENT PRODUCT AND METHOD FOR MANUFACTURING IT
US11905650B2 (en) 2018-02-01 2024-02-20 Hokuetsu Corporation Water repellent oil repellent agent and method for producing same, and water repellent oil repellent product and method for producing same
CN108752869A (zh) * 2018-05-28 2018-11-06 安徽顺彤包装材料有限公司 一种优质耐疲劳复合材料

Similar Documents

Publication Publication Date Title
CN104844973A (zh) 一种耐磨耐热汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN104844987A (zh) 一种汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN103739957A (zh) 一种汽车保险杠用形状记忆聚丙烯复合材料及其制备方法
CN103709659A (zh) 玻纤增强pbt/pet合金材料
CN103122106A (zh) 一种改性塑料及其制备方法和用途
CN104861352A (zh) 抗冲改性聚氯乙烯电缆料
CN103589092A (zh) 一种环保型耐寒聚氯乙烯防水卷材及其制作工艺
CN103849044A (zh) 一种应用于聚乙烯的防老化母粒及其制备方法
CN104844985A (zh) 一种抗拉伸汽车线束用氟橡胶改性pvc电缆料及其制备方法
JP5200563B2 (ja) 絶縁電線
CN104844983A (zh) 一种耐久汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN105885169A (zh) 一种耐磨、高强度复合电力电缆材料及其制备方法
CN106188975B (zh) 一种特软高透明阻燃耐热聚氯乙烯材料及其制备方法
CN104844988A (zh) 一种耐老化汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN104844978A (zh) 一种耐磨汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN104844977A (zh) 一种耐油汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN103360661B (zh) 一种耐油电缆护套料
CN105037894A (zh) 一种柔性防水聚乙烯电缆料及其制备方法
CN104877271A (zh) 一种镁盐晶须增强汽车线束用氟橡胶改性pvc电缆料及其制备方法
CN104893085A (zh) 一种家电用柔软无卤阻燃绝缘料及其制备方法
CN104861381A (zh) 一种高灼热丝聚氯乙烯电缆料及其制备方法
CN106832698A (zh) 一种氯化聚氯乙烯管材组合物及管材制备方法
CN103937124A (zh) 高速挤出雾面聚氯乙烯线缆料及其制备方法
CN103289151B (zh) 环保型低硬度nbr/pvc共混胶及制备方法
CN104844975A (zh) 一种抗静电汽车线束用氟橡胶改性pvc电缆料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150819