CN104830223A - Photovoltaic conversion/antireflection dual-functional compound type glass panel and treatment process - Google Patents
Photovoltaic conversion/antireflection dual-functional compound type glass panel and treatment process Download PDFInfo
- Publication number
- CN104830223A CN104830223A CN201510244799.3A CN201510244799A CN104830223A CN 104830223 A CN104830223 A CN 104830223A CN 201510244799 A CN201510244799 A CN 201510244799A CN 104830223 A CN104830223 A CN 104830223A
- Authority
- CN
- China
- Prior art keywords
- concentration
- water
- parts
- sol
- dope layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Surface Treatment Of Optical Elements (AREA)
Abstract
The invention discloses a photovoltaic conversion/antireflection dual-functional compound type glass panel. Compound coating coats the panel surface of the glass panel; the coating comprises a component A coating layer, a component B coating layer and a synthesized resin coating layer; the component A coating layer comprises the following components in parts by mass: 10-20 parts of an antireflection layer, 30-35 parts of a P type conductor, 12-16 parts of acrylic-modified reaction oligomer, 15-18 parts of acrylic-series retarder thinners, 1.2-2 parts of a photopolymerization catalyst, 0.3 part of a polymerization inhibitor and 0.6 part of an additive; the component B coating layer comprises the following components in parts by mass: 60 parts of a N type conductor, 16-20 parts of acrylic-modified reaction oligomer,14-18 parts of acrylic-series retarder thinners,1.2-2 parts of a photopolymerization catalyst, 0.2 part of a polymerization inhibitor and 0.4 part of an additive. The photovoltaic conversion/antireflection dual-functional compound type glass panel can be suitable for an existing solar glass coating and toughening process and is suitable for industrial popularization and application; meanwhile, the light transmittance of the solar galls and the photoelectric conversion efficiency of a solar cell can be remarkably improved, and the ageing resistance is greatly improved.
Description
Technical field
The present invention relates to the manufacturing technology field of face glass in solar power plant, particularly the difunctional composite glass panel of a kind of opto-electronic conversion/antireflective and treatment process.
Background technology
Crystal silicon solar battery component generally glues press seal by solar energy glass cover plate, silicon chip of solar cell, battery back-sheet and EVA film and fills, and reinstalls fixed border and forms; The visible light transmissivity of solar module packaged glass is generally 91.6%, its single surface albedo about 4%; If at the antireflective coating of solar energy glass surface application visible wavelength 1/4th thickness, single surface albedo can be made to be reduced to less than 1%, increase visible light transmissivity 2.5%-3.5%, the visible light transmissivity under peak wavelength can reach 95.5%.
Solar energy glass reflection reduc(t)ing coating main ingredient is the water-sol of nanosized SiO_2, TiO2, MgF2, Al2O3, ZrO2, rare earth oxide or its mixture; Current solar energy glass reflection reduc(t)ing coating is produced and utilisation technology is mature on the whole, the solar energy glass surface that the industrial water-based reflection reduc(t)ing coating roller coat prepared by sol-gel method is cleaning up, baking and curing film forming at 150-180 DEG C, then carry out tempering at about 700 DEG C, will the antireflective coating sintering on solar energy glass surface be coated at solar energy glass on the surface simultaneously; It is a kind ofly improve the simple and easy to do method of solar cell light conversion efficiency that solar energy glass applies antireflective coating, be used widely in photovoltaic industry, current technological development emphasis has turned to the weathering resistance aspect improving further antireflective coating, can serve more than 25 years in complex environment in the wild to realize it.
Under rare earth, light conversion agent has been widely used in agricultural turning in optical plastic film production in recent years, successfully near-ultraviolet light is converted to visible ray, substantially increases photosynthesis of plant efficiency in plastic greenhouse; Semiconductor illumination technique develop the technological development having promoted rare earth doping fluorescent powder rapidly, the commercial fluorescence powder supply of existing many ultraviolet excitations on market, they in theory also can as solar cell light-converting material; In conjunction with the specified conditions exploitation solar cell light conversion antireflective dual functional film that solar energy glass antireflective coating is produced, can while realizing visible light anti-reflection, near-ultraviolet light is converted to visible ray, the UV-light of 2%-4% in solar spectrum is used by light conversion, thus improve crystal silicon solar energy battery photoelectric transformation efficiency, solar cell power generation cost about 20% will be reduced.
Summary of the invention
Technical problem to be solved by this invention is, overcomes the shortcoming of prior art, provides the difunctional composite glass panel of a kind of opto-electronic conversion/antireflective and treatment process.
In order to solve above technical problem, the invention provides the difunctional composite glass panel of a kind of opto-electronic conversion/antireflective, the plate face of face glass is coated with composite coating, and this coating is made up of first, second component dope layer and the synthetic resin coated bed of material;
Comprise according to the mass fraction in first component dope layer: antireflection layer 10-20 part, P-type conduction body 30-35 part, acrylic acid modified reactive oligopolymer 12-16 part, acrylic acid series diluting solvent 15-18 part, photopolymerization catalyzer 1.2-2 part, stopper 0.3 part, additive 0.6 part;
Comprise by mass percentage in antireflection layer: concentration 5% nanosized SiO_2 water-sol A:25.0%-45.0%, concentration 6% nanosized SiO_2 water-sol B:21.0%-25.0%, concentration 7% nanometer Zirconia water-sol C:4.0%-6.5%, lanthanum nitrate 0.6%-0.8%, Yttrium trinitrate 0.6%-0.6%, Terbium trinitrate 0.02%-0.1%, concentration 5% aluminium dihydrogen phosphate 2.5%-4.0%, primary ammonium phosphate 0.02%-0.2%, phosphoric acid 0.05%-0.15%, concentration 5% water phase surfactant mixture 0.6%-1.5%, concentration 5% coupling agent aqueous solution 0.5%-2.0%, all the other are deionized water;
Its preparation technology is:
(1) according to mass percent requirement, melting concn 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B and concentration 7% nanometer Zirconia water-sol C, drip lanthanum nitrate, Yttrium trinitrate and the Terbium trinitrate aqueous solution wherein;
(2) the above mixed sols 2-3 hour of rapid stirring, rare earth ion rapid adsorption is on nanosized SiO_2 and ZrO2 water-sol surface;
(3) by above-mentioned mixing solutions hydrothermal treatment consists 18-24 hour in the autoclave pressure of 0.25MPa and 90-110 DEG C;
(4) in above-mentioned mixing solutions, add concentration 5% aluminium dihydrogen phosphate, primary ammonium phosphate, phosphoric acid rapid stirring after 1-2 hour, slowly add concentration 5% water phase surfactant mixture and concentration 5% coupling agent aqueous solution, obtained after rapid stirring 0.5-1 hour;
Comprise according to the mass fraction in second component dope layer: N-type electrical conductor 60 parts, acrylic acid modified reactive oligopolymer 16-20 part, acrylic acid series diluting solvent 14-18 part, photopolymerization catalyzer 1.2-2 part, stopper 0.2 part, additive 0.4 part;
The synthetic resin coated bed of material comprises according to the mass fraction: acrylic acid modified reactive oligopolymer 40-50 part, acrylic acid series diluting solvent 50-40 part, photopolymerization catalyzer 3-5 part, stopper 0.25 part, additive 1;
P-type conduction body mixes boron in silicon crystal, and N-type electrical conductor is in silicon crystal, mix phosphorus, antimony element; Acrylic acid modified reactive oligopolymer is the one in urethane acrylate, epoxy acrylate or Epoxy Phenolic Acrylates; Acrylic acid series diluting solvent is the one in acrylate, vinylformic acid list phenoxy group Diethylene Glycol fat, vinylformic acid-2-hydroxyl-3-phenoxy group third fat; Photopolymerization catalyzer is the one in furfural/oxine aluminium polymer, nano photo-catalytic; Stopper is the one during methacrylic acid stopper or vinylbenzene inhibit; Additive is the one in polyacrylic acid flow agent, solvent-type organosilicon flow agent, carboxymethyl cellulose.
Technique effect: be entrained in after aluminium dihydrogen phosphate is water-soluble in silica hydrosol structure, has good normal temperature cohesiveness and high temperature cementing properties, as rete toughener, can improve film hardness and wear resistance, makes up the rear-earth-doped disadvantageous effect to film toughness;
Phosphoric acid is chemical reagent, and the activity hydroxy that can remove film surface with silicon dioxde reaction under the high temperature conditions generates silicon phosphate, and rete weather resistance is strengthened;
Primary ammonium phosphate is the phosphoric acid salt with producing during weak ammonia adjusting coating acidity, is decomposed into phosphoric acid and ammonia when rete pyroprocessing, has and phosphoric acid identical function;
Tensio-active agent and coupling agent organic constituent almost decompose completely in the follow-up tempering process of solar energy glass.Deionized water as paint solvent adopts reverse osmosis method or ion exchange method to produce, and has that volatility is moderate, safety and environmental protection and a cheap advantage.
The technical scheme that the present invention limits further is:
Further, the difunctional composite glass panel of aforesaid opto-electronic conversion/antireflective, the average diameter grain of concentration 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B is 20nm, and the average diameter grain of concentration 7% nanometer Zirconia water-sol C is 35nm.
The difunctional composite glass panel of aforesaid opto-electronic conversion/antireflective, tensio-active agent is lauric acid diethyl amide or sodium lauryl sulphate, and coupling agent is organo-silicon coupling agent or Union carbide A-162.
The present invention have also been devised the treatment process of the difunctional composite glass panel of a kind of opto-electronic conversion/antireflective, comprises following concrete steps:
A. all first the synthetic resin coated bed of material of one deck is sprayed on the positive and negative surface of face glass;
B. positive and negative surface resin synthetic dope layer after solidification sprays first, second component dope layer respectively, and first component dope layer electrode outlet line is drawn, as positive pole, second component dope layer electrode outlet line is drawn, as negative pole;
C. first, second component dope layer after solidification sprays the synthetic resin coated bed of material of one deck respectively again, namely complete the process of face glass.
The present invention have also been devised the treatment process of the difunctional composite glass panel of a kind of opto-electronic conversion/antireflective, comprises following concrete steps:
A. the synthetic resin coated bed of material of one deck is first sprayed at face glass one side surface;
B. the synthetic resin coated bed of material after solidification sprays first component dope layer, and first component dope layer electrode outlet line is drawn, as positive pole;
C. on first component dope layer after solidification, then one deck synthetic resin layer is sprayed;
D., on synthetic resin layer after solidification, spraying one deck second component dope layer, draws, as negative pole with electrode outlet line;
E. on second component dope layer after solidification, the more synthetic resin coated bed of material of even application one deck, namely complete the process of face glass.
6. according to the treatment process of the difunctional composite glass panel of the opto-electronic conversion/antireflective of claim 4 or 5, it is characterized in that, the thickness of every layer of spraying is 15 microns-25 microns.
The present invention possesses antireflective and light transition function simultaneously, crystal silicon solar energy battery effectively can be utilized harmful UV-light, the present invention is applied on solar energy glass can significantly improve solar energy glass transmittance and crystal silicon solar energy battery photoelectric transformation efficiency, and ageing resistance improves greatly;
The present invention can adapt to existing solar energy glass plated film and steel process, alternative existing solar energy glass reflection reduc(t)ing coating, easy Industry Promotion application; The present invention is similar to existing solar energy glass reflection reduc(t)ing coating production method, and production unit is compatible, and do not use machine solvent and poisonous and harmful raw material, production cost is low, environment protection health.
Embodiment
embodiment 1
The difunctional composite glass panel of a kind of opto-electronic conversion/antireflective that the present embodiment provides, the plate face of face glass is coated with composite coating, and this coating is made up of first, second component dope layer and the synthetic resin coated bed of material;
Comprise according to the mass fraction in first component dope layer: antireflection layer 10 parts, P-type conduction body 30 parts, acrylic acid modified reactive oligopolymer 16 parts, acrylic acid series diluting solvent 15 parts, photopolymerization catalyzer 2 parts, stopper 0.3 part, additive 0.6 part;
Comprise by mass percentage in antireflection layer: concentration 5% nanosized SiO_2 water-sol A:25.0%-45.0%, concentration 6% nanosized SiO_2 water-sol B:21.0%-25.0%, concentration 7% nanometer Zirconia water-sol C:4.0%-6.5%, lanthanum nitrate 0.6%-0.8%, Yttrium trinitrate 0.6%-0.6%, Terbium trinitrate 0.02%-0.1%, concentration 5% aluminium dihydrogen phosphate 2.5%-4.0%, primary ammonium phosphate 0.02%-0.2%, phosphoric acid 0.05%-0.15%, concentration 5% water phase surfactant mixture 0.6%-1.5%, concentration 5% coupling agent aqueous solution 0.5%-2.0%, all the other are deionized water;
Its preparation technology is:
(1) according to mass percent requirement, melting concn 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B and concentration 7% nanometer Zirconia water-sol C, drip lanthanum nitrate, Yttrium trinitrate and the Terbium trinitrate aqueous solution wherein;
(2) the above mixed sols of rapid stirring 2 hours, rare earth ion rapid adsorption is on nanosized SiO_2 and ZrO2 water-sol surface;
(3) by above-mentioned mixing solutions hydrothermal treatment consists 18 hours in the autoclave pressure of 0.25MPa and 110 DEG C;
(4) in above-mentioned mixing solutions, add concentration 5% aluminium dihydrogen phosphate, primary ammonium phosphate, phosphoric acid rapid stirring after 2 hours, slowly add concentration 5% water phase surfactant mixture and concentration 5% coupling agent aqueous solution, rapid stirring is obtained after 0.5 hour;
Comprise according to the mass fraction in second component dope layer: N-type electrical conductor 60 parts, acrylic acid modified reactive oligopolymer 20 parts, acrylic acid series diluting solvent 14 parts, photopolymerization catalyzer 2 parts, stopper 0.2 part, additive 0.4 part;
The synthetic resin coated bed of material comprises according to the mass fraction: acrylic acid modified reactive oligopolymer 40 parts, acrylic acid series diluting solvent 40 parts, photopolymerization catalyzer 3 parts, stopper 0.25 part, additive 1;
P-type conduction body mixes boron in silicon crystal, and N-type electrical conductor is in silicon crystal, mix phosphorus, antimony element; Acrylic acid modified reactive oligopolymer is epoxy acrylate; Acrylic acid series diluting solvent is acrylate; Photopolymerization catalyzer is nano photo-catalytic; Stopper is methacrylic acid stopper; Additive is polyacrylic acid flow agent;
The average diameter grain of concentration 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B is 20nm, and the average diameter grain of concentration 7% nanometer Zirconia water-sol C is 35nm;
Tensio-active agent is lauric acid diethyl amide, and coupling agent is organo-silicon coupling agent;
In the present embodiment, the treatment process of composite glass panel comprises following concrete steps:
A. all first the synthetic resin coated bed of material of one deck is sprayed on the positive and negative surface of face glass;
B. positive and negative surface resin synthetic dope layer after solidification sprays first, second component dope layer respectively, and first component dope layer electrode outlet line is drawn, as positive pole, second component dope layer electrode outlet line is drawn, as negative pole;
C. first, second component dope layer after solidification sprays the synthetic resin coated bed of material of one deck respectively again, namely complete the process of face glass.
embodiment 2
The difunctional composite glass panel of a kind of opto-electronic conversion/antireflective that the present embodiment provides, the plate face of face glass is coated with composite coating, and this coating is made up of first, second component dope layer and the synthetic resin coated bed of material;
Comprise according to the mass fraction in first component dope layer: antireflection layer 16 parts, P-type conduction body 32 parts, acrylic acid modified reactive oligopolymer 15 parts, acrylic acid series diluting solvent 16 parts, photopolymerization catalyzer 1.6 parts, stopper 0.3 part, additive 0.6 part;
Comprise by mass percentage in antireflection layer: concentration 5% nanosized SiO_2 water-sol A:25.0%-45.0%, concentration 6% nanosized SiO_2 water-sol B:21.0%-25.0%, concentration 7% nanometer Zirconia water-sol C:4.0%-6.5%, lanthanum nitrate 0.6%-0.8%, Yttrium trinitrate 0.6%-0.6%, Terbium trinitrate 0.02%-0.1%, concentration 5% aluminium dihydrogen phosphate 2.5%-4.0%, primary ammonium phosphate 0.02%-0.2%, phosphoric acid 0.05%-0.15%, concentration 5% water phase surfactant mixture 0.6%-1.5%, concentration 5% coupling agent aqueous solution 0.5%-2.0%, all the other are deionized water;
Its preparation technology is:
(1) according to mass percent requirement, melting concn 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B and concentration 7% nanometer Zirconia water-sol C, drip lanthanum nitrate, Yttrium trinitrate and the Terbium trinitrate aqueous solution wherein;
(2) the above mixed sols of rapid stirring 2.5 hours, rare earth ion rapid adsorption is on nanosized SiO_2 and ZrO2 water-sol surface;
(3) by above-mentioned mixing solutions hydrothermal treatment consists 21 hours in the autoclave pressure of 0.25MPa and 95 DEG C;
(4) in above-mentioned mixing solutions, add concentration 5% aluminium dihydrogen phosphate, primary ammonium phosphate, phosphoric acid rapid stirring after 1.5 hours, slowly add concentration 5% water phase surfactant mixture and concentration 5% coupling agent aqueous solution, rapid stirring is obtained after 0.8 hour;
Comprise according to the mass fraction in second component dope layer: N-type electrical conductor 60 parts, acrylic acid modified reactive oligopolymer 18 parts, acrylic acid series diluting solvent 16 parts, photopolymerization catalyzer 1.6 parts, stopper 0.2 part, additive 0.4 part;
The synthetic resin coated bed of material comprises according to the mass fraction: acrylic acid modified reactive oligopolymer 45 parts, acrylic acid series diluting solvent 44 parts, photopolymerization catalyzer 4 parts, stopper 0.25 part, additive 1;
P-type conduction body mixes boron in silicon crystal, and N-type electrical conductor is in silicon crystal, mix phosphorus, antimony element; Acrylic acid modified reactive oligopolymer is Epoxy Phenolic Acrylates; Acrylic acid series diluting solvent is vinylformic acid-2-hydroxyl-3-phenoxy group third fat; Photopolymerization catalyzer is furfural/oxine aluminium polymer; Stopper is methacrylic acid stopper; Additive is carboxymethyl cellulose;
The average diameter grain of concentration 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B is 20nm, and the average diameter grain of concentration 7% nanometer Zirconia water-sol C is 35nm;
Tensio-active agent is sodium lauryl sulphate, and coupling agent is Union carbide A-162;
In the present embodiment, the treatment process of composite glass panel comprises following concrete steps:
A. the synthetic resin coated bed of material of one deck is first sprayed at face glass one side surface;
B. the synthetic resin coated bed of material after solidification sprays first component dope layer, and first component dope layer electrode outlet line is drawn, as positive pole;
C. on first component dope layer after solidification, then one deck synthetic resin layer is sprayed;
D., on synthetic resin layer after solidification, spraying one deck second component dope layer, draws, as negative pole with electrode outlet line;
E. on second component dope layer after solidification, the more synthetic resin coated bed of material of even application one deck, namely complete the process of face glass: the thickness of above-mentioned every layer of spraying is 21 microns.
Above embodiment is only and technological thought of the present invention is described, can not limit protection scope of the present invention with this, and every technological thought proposed according to the present invention, any change that technical scheme basis is done, all falls within scope.
Claims (6)
1. the difunctional composite glass panel of opto-electronic conversion/antireflective, is characterized in that, the plate face of described face glass is coated with composite coating, and this coating is made up of first, second component dope layer and the synthetic resin coated bed of material;
Comprise according to the mass fraction in described first component dope layer: antireflection layer 10-20 part, P-type conduction body 30-35 part, acrylic acid modified reactive oligopolymer 12-16 part, acrylic acid series diluting solvent 15-18 part, photopolymerization catalyzer 1.2-2 part, stopper 0.3 part, additive 0.6 part;
Comprise by mass percentage in described antireflection layer: concentration 5% nanosized SiO_2 water-sol A:25.0%-45.0%, concentration 6% nanosized SiO_2 water-sol B:21.0%-25.0%, concentration 7% nanometer Zirconia water-sol C:4.0%-6.5%, lanthanum nitrate 0.6%-0.8%, Yttrium trinitrate 0.6%-0.6%, Terbium trinitrate 0.02%-0.1%, concentration 5% aluminium dihydrogen phosphate 2.5%-4.0%, primary ammonium phosphate 0.02%-0.2%, phosphoric acid 0.05%-0.15%, concentration 5% water phase surfactant mixture 0.6%-1.5%, concentration 5% coupling agent aqueous solution 0.5%-2.0%, all the other are deionized water;
Its preparation technology is:
(1) according to mass percent requirement, melting concn 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B and concentration 7% nanometer Zirconia water-sol C, drip lanthanum nitrate, Yttrium trinitrate and the Terbium trinitrate aqueous solution wherein;
(2) the above mixed sols 2-3 hour of rapid stirring, rare earth ion rapid adsorption is on nanosized SiO_2 and ZrO2 water-sol surface;
(3) by above-mentioned mixing solutions hydrothermal treatment consists 18-24 hour in the autoclave pressure of 0.25MPa and 90-110 DEG C;
(4) in above-mentioned mixing solutions, add concentration 5% aluminium dihydrogen phosphate, primary ammonium phosphate, phosphoric acid rapid stirring after 1-2 hour, slowly add concentration 5% water phase surfactant mixture and concentration 5% coupling agent aqueous solution, obtained after rapid stirring 0.5-1 hour;
Comprise according to the mass fraction in described second component dope layer: N-type electrical conductor 60 parts, acrylic acid modified reactive oligopolymer 16-20 part, acrylic acid series diluting solvent 14-18 part, photopolymerization catalyzer 1.2-2 part, stopper 0.2 part, additive 0.4 part;
The described synthetic resin coated bed of material comprises according to the mass fraction: acrylic acid modified reactive oligopolymer 40-50 part, acrylic acid series diluting solvent 50-40 part, photopolymerization catalyzer 3-5 part, stopper 0.25 part, additive 1;
Described P-type conduction body mixes boron in silicon crystal, and described N-type electrical conductor is in silicon crystal, mix phosphorus, antimony element; Described acrylic acid modified reactive oligopolymer is the one in urethane acrylate, epoxy acrylate or Epoxy Phenolic Acrylates; Described acrylic acid series diluting solvent is the one in acrylate, vinylformic acid list phenoxy group Diethylene Glycol fat, vinylformic acid-2-hydroxyl-3-phenoxy group third fat; Described photopolymerization catalyzer is the one in furfural/oxine aluminium polymer, nano photo-catalytic; Described stopper is the one during methacrylic acid stopper or vinylbenzene inhibit; Described additive is the one in polyacrylic acid flow agent, solvent-type organosilicon flow agent, carboxymethyl cellulose.
2. the difunctional composite glass panel of opto-electronic conversion/antireflective according to claim 1, it is characterized in that, the average diameter grain of concentration 5% nanosized SiO_2 water-sol A, concentration 6% nanosized SiO_2 water-sol B is 20nm, and the average diameter grain of concentration 7% nanometer Zirconia water-sol C is 35nm.
3. the difunctional composite glass panel of opto-electronic conversion/antireflective according to claim 1, is characterized in that, described tensio-active agent is lauric acid diethyl amide or sodium lauryl sulphate, and coupling agent is organo-silicon coupling agent or Union carbide A-162.
4. the treatment process of the difunctional composite glass panel of opto-electronic conversion/antireflective according to claim 1, is characterized in that, comprise following concrete steps:
A. all first the synthetic resin coated bed of material of one deck is sprayed on the positive and negative surface of face glass;
B. positive and negative surface resin synthetic dope layer after solidification sprays first, second component dope layer respectively, and first component dope layer electrode outlet line is drawn, as positive pole, second component dope layer electrode outlet line is drawn, as negative pole;
C. first, second component dope layer after solidification sprays the synthetic resin coated bed of material of one deck respectively again, namely complete the process of face glass.
5. the treatment process of the difunctional composite glass panel of opto-electronic conversion/antireflective according to claim 1, is characterized in that, comprise following concrete steps:
A. the synthetic resin coated bed of material of one deck is first sprayed at face glass one side surface;
B. the synthetic resin coated bed of material after solidification sprays first component dope layer, and first component dope layer electrode outlet line is drawn, as positive pole;
C. on first component dope layer after solidification, then one deck synthetic resin layer is sprayed;
D., on synthetic resin layer after solidification, spraying one deck second component dope layer, draws, as negative pole with electrode outlet line;
E. on second component dope layer after solidification, the more synthetic resin coated bed of material of even application one deck, namely complete the process of face glass.
6. the treatment process of the difunctional composite glass panel of the opto-electronic conversion/antireflective according to claim 4 or 5, is characterized in that, the thickness of described every layer of spraying is 15 microns-25 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244799.3A CN104830223A (en) | 2015-05-14 | 2015-05-14 | Photovoltaic conversion/antireflection dual-functional compound type glass panel and treatment process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510244799.3A CN104830223A (en) | 2015-05-14 | 2015-05-14 | Photovoltaic conversion/antireflection dual-functional compound type glass panel and treatment process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104830223A true CN104830223A (en) | 2015-08-12 |
Family
ID=53808432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510244799.3A Pending CN104830223A (en) | 2015-05-14 | 2015-05-14 | Photovoltaic conversion/antireflection dual-functional compound type glass panel and treatment process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104830223A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105262194A (en) * | 2015-11-03 | 2016-01-20 | 江苏万丰光伏有限公司 | Distributed photovoltaic intelligent power supply terminal system |
| CN105470330A (en) * | 2015-11-23 | 2016-04-06 | 浙江昱辉阳光能源江苏有限公司 | Low-cost high-yield solar assembly employing high-efficiency lamination process |
| CN105470329A (en) * | 2015-11-23 | 2016-04-06 | 浙江昱辉阳光能源江苏有限公司 | Double-glass high-conversion-power solar photovoltaic assembly |
| CN108165077A (en) * | 2018-01-25 | 2018-06-15 | 淄博职业学院 | Solar power generation coating and preparation method and application thereof |
| CN109052991A (en) * | 2018-09-05 | 2018-12-21 | 苏州市灵通玻璃制品有限公司 | A kind of aobvious control coated glass panel preparation method of solar energy |
| CN109052986A (en) * | 2018-09-05 | 2018-12-21 | 苏州市灵通玻璃制品有限公司 | A kind of aobvious control coated glass panel preparation method of green energy conservation |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4336648A (en) * | 1979-11-02 | 1982-06-29 | Licentia Patent-Verwaltungs-G.M.B.H. | Method of contacting a solar cell |
| CN101280131A (en) * | 2008-06-05 | 2008-10-08 | 保定维特瑞交通设施工程有限责任公司 | Photovoltaic coating capable of converting solar energy into electric energy and preparation thereof |
| US20100163759A1 (en) * | 2008-12-31 | 2010-07-01 | Stmicroelectronics S.R.L. | Radiation sensor with photodiodes being integrated on a semiconductor substrate and corresponding integration process |
| CN102061111A (en) * | 2010-10-27 | 2011-05-18 | 中山市旌旗纳米材料科技有限公司 | Preparation method of self-cleaning ceramic nanometer glass antireflective coating material and preparation method of reflection deducting coating |
| CN103154152A (en) * | 2010-10-06 | 2013-06-12 | 3M创新有限公司 | Coating composition and method of making and using the same |
| CN103804967A (en) * | 2014-02-20 | 2014-05-21 | 天津顺御科技有限公司 | Solar glass light conversion and antireflection bifunctional coating and production method thereof |
| CN104134714A (en) * | 2014-07-18 | 2014-11-05 | 成都新柯力化工科技有限公司 | Solar photoelectric conversion coating for building and fabrication method for solar photoelectric conversion coating |
-
2015
- 2015-05-14 CN CN201510244799.3A patent/CN104830223A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4336648A (en) * | 1979-11-02 | 1982-06-29 | Licentia Patent-Verwaltungs-G.M.B.H. | Method of contacting a solar cell |
| CN101280131A (en) * | 2008-06-05 | 2008-10-08 | 保定维特瑞交通设施工程有限责任公司 | Photovoltaic coating capable of converting solar energy into electric energy and preparation thereof |
| US20100163759A1 (en) * | 2008-12-31 | 2010-07-01 | Stmicroelectronics S.R.L. | Radiation sensor with photodiodes being integrated on a semiconductor substrate and corresponding integration process |
| CN103154152A (en) * | 2010-10-06 | 2013-06-12 | 3M创新有限公司 | Coating composition and method of making and using the same |
| CN102061111A (en) * | 2010-10-27 | 2011-05-18 | 中山市旌旗纳米材料科技有限公司 | Preparation method of self-cleaning ceramic nanometer glass antireflective coating material and preparation method of reflection deducting coating |
| CN103804967A (en) * | 2014-02-20 | 2014-05-21 | 天津顺御科技有限公司 | Solar glass light conversion and antireflection bifunctional coating and production method thereof |
| CN104134714A (en) * | 2014-07-18 | 2014-11-05 | 成都新柯力化工科技有限公司 | Solar photoelectric conversion coating for building and fabrication method for solar photoelectric conversion coating |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105262194A (en) * | 2015-11-03 | 2016-01-20 | 江苏万丰光伏有限公司 | Distributed photovoltaic intelligent power supply terminal system |
| CN105470330A (en) * | 2015-11-23 | 2016-04-06 | 浙江昱辉阳光能源江苏有限公司 | Low-cost high-yield solar assembly employing high-efficiency lamination process |
| CN105470329A (en) * | 2015-11-23 | 2016-04-06 | 浙江昱辉阳光能源江苏有限公司 | Double-glass high-conversion-power solar photovoltaic assembly |
| CN108165077A (en) * | 2018-01-25 | 2018-06-15 | 淄博职业学院 | Solar power generation coating and preparation method and application thereof |
| CN109052991A (en) * | 2018-09-05 | 2018-12-21 | 苏州市灵通玻璃制品有限公司 | A kind of aobvious control coated glass panel preparation method of solar energy |
| CN109052986A (en) * | 2018-09-05 | 2018-12-21 | 苏州市灵通玻璃制品有限公司 | A kind of aobvious control coated glass panel preparation method of green energy conservation |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104830223A (en) | Photovoltaic conversion/antireflection dual-functional compound type glass panel and treatment process | |
| CN102061111B (en) | Preparation method of self-cleaning ceramic nanometer glass antireflective coating material and preparation method of reflection deducting coating | |
| CN103804966A (en) | Solar glass self-cleaned high anti-reflection coating and production method thereof | |
| CN102277022B (en) | Water-based chrome-free Dacromet coating solution and preparation method thereof | |
| CN110387751B (en) | Radiation self-cooling functional fiber fabric and preparation method thereof | |
| CN103804967A (en) | Solar glass light conversion and antireflection bifunctional coating and production method thereof | |
| CN106702363B (en) | A kind of electrophoretic painting pre-treatment vitrified agent, preparation method and its application method | |
| CN104140693A (en) | Production method for solar battery glass self-cleaning antireflection light-conversion coating | |
| CN106242312A (en) | The preparation of a kind of photovoltaic glass coating liquid and application | |
| CN103031056B (en) | A kind of Metal surface silane treatment agent containing water nano zinc oxide material and preparation method thereof | |
| CN104891824A (en) | Solar glass film-coating liquid and production method thereof | |
| CN104030575B (en) | A kind of solar cell glass antireflective light conversion synergy coating and production method thereof | |
| CN104098937A (en) | Solar-cell glass self-cleaning anti-reflection light-converting coating | |
| CN103031007A (en) | Preparation method of nanosilicon dioxide sol coating solution with low volatility | |
| CN103436137A (en) | High-wear-resistant and heavy-corrosion-protection ceramic coating | |
| CN102276163B (en) | Near infrared luminescent antireflective composite film, its preparation method and its application | |
| CN104194626A (en) | Nano antireflection coating for solar energy glass as well as preparation method and application thereof | |
| CN102766379B (en) | Nano composite transparent heat-insulating coating and preparation method thereof | |
| CN103013203A (en) | Compound type ultraviolet light-cured anticorrosive paint and preparation method thereof | |
| CN115873465A (en) | Nano self-cleaning dustproof coating | |
| CN105541123A (en) | Photovoltaic glass-based high antireflection composite nanometer film | |
| CN104004393A (en) | Water-based inorganic zinc-rich anticorrosive paint and preparing method of high-modulus potassium silicate solution | |
| CN101824254B (en) | Organosilicon-modified polyvinyl butyral coil coating | |
| CN101891399B (en) | Preparation method of coating slurry and method for manufacturing solar cell packaging glass by using same | |
| CN107986636A (en) | A kind of production method of photovoltaic module self-cleaning film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150812 |
|
| WD01 | Invention patent application deemed withdrawn after publication |