CN104829192A - Thermal-insulation and energy-saving material and cement plate thereof - Google Patents
Thermal-insulation and energy-saving material and cement plate thereof Download PDFInfo
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- CN104829192A CN104829192A CN201510171948.8A CN201510171948A CN104829192A CN 104829192 A CN104829192 A CN 104829192A CN 201510171948 A CN201510171948 A CN 201510171948A CN 104829192 A CN104829192 A CN 104829192A
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- 238000009413 insulation Methods 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 40
- 239000004568 cement Substances 0.000 title claims description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 30
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000006096 absorbing agent Substances 0.000 claims abstract description 20
- YIBPLYRWHCQZEB-UHFFFAOYSA-N formaldehyde;propan-2-one Chemical class O=C.CC(C)=O YIBPLYRWHCQZEB-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003381 stabilizer Substances 0.000 claims abstract description 20
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003822 epoxy resin Substances 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 claims abstract description 12
- 239000010881 fly ash Substances 0.000 claims abstract description 12
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 12
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 48
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 42
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 34
- 238000004134 energy conservation Methods 0.000 claims description 22
- 229960001860 salicylate Drugs 0.000 claims description 16
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 16
- 238000010792 warming Methods 0.000 claims description 16
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 14
- 239000012965 benzophenone Substances 0.000 claims description 14
- 239000012964 benzotriazole Substances 0.000 claims description 14
- GURWNTAGBOGUEB-UHFFFAOYSA-N acetic acid;n-ethylethanamine Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CCNCC GURWNTAGBOGUEB-UHFFFAOYSA-N 0.000 claims description 13
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 claims description 13
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 13
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 13
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 12
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 11
- 239000011398 Portland cement Substances 0.000 claims description 11
- 239000011324 bead Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 8
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000006260 foam Substances 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 abstract 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000011325 microbead Substances 0.000 abstract 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000003469 silicate cement Substances 0.000 abstract 1
- 239000012774 insulation material Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 150000003902 salicylic acid esters Chemical group 0.000 description 3
- -1 titanic acid ester Chemical class 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The present invention discloses a thermal-insulation and energy-saving material, wherein the raw materials comprise ordinary silicate cement, fly ash, hydrogen peroxide, bis(pentabromophenyl) ethane, a sulfonated acetone formaldehyde polycondensate, a liquid-state epoxy resin dispersant, polyurethane, a foam stabilizer, a coupling agent, mullite fibers, ceramic micro-beads, bis(2,2,6,6,-tetramethyl-4-piperidyl)sebacate, 2-hydroxy-4-methoxy benzophenone, and an ultraviolet ray absorber. The thermal-insulation and energy-saving material has the following characteristics that the thermal insulation property is good, the product dry density is 160-200 kg/m<3>, and the thermal conductivity is 0.05-0.08 W/(m*K); the fire prevention performance is good, the fire resistance limit is more than 3 h, and the material can meet the grade A fire prevention standard so as to provide good fire resistance; the sound insulation performance is good so as to substantially reduce the noise impact; and the durability is good, and characteristics of high temperature resistance, low temperature resistance, corrosion resistance, ultraviolet ray radiation resistance, and good weathering resistance are provided.
Description
Technical field
The present invention relates to one and build field of material technology, particularly a kind of thermal-insulation energy-conservation material and cement plate thereof.
Background technology
The enforcement of Building Energy Conservation Policy has promoted the development of wall heat insulation material.The organic foam plastic such as polystyrene, urethane lagging material is widely used in wall thermal insulating, but such organic foam plastic lagging material very easily burns, during burning, fire spreading is rapid, and produce with a large amount of poison gas and flue gas, bring exceptional hardship to rescue work of extinguishing fire, cause casualties and property damage.Simultaneously also there is the easily shortcoming such as aging, poor dimensional stability in such lagging material.Compare organic foam plastic lagging material, inorganic heat insulation material has that fire line is good, deformation coefficient is little, ageing resistance is strong, steady performance, so be applied in wall thermal insulating by Foam cement insulation material, has popularizing application prospect widely.Cement board is a kind of external-wall heat-insulation material risen gradually at present, it has not easily aging, the complete and buildings same life-span, unit weight is light, thermal conductivity is low, and fire endurance more than 3 hours, can not produce the advantages such as toxic gas under high temperature or fire condition, but the shortcoming of foam cement version also clearly, be exactly that mechanical property is poor, intensity is lower, and fragility is larger, be very easy to fracture, damaged, bring very large inconvenience to transport and construction process.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of novel thermal-insulation energy-conservation material and cement plate thereof, while there is the advantages such as fire-resistant, long service life, thermal conductivity are little, environmental protection, can overcome again that its fragility is large, the problem of cracky.
Thermal-insulation energy-conservation material of the present invention, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 20-30 part flyash, 11-18 part hydrogen peroxide, 0.5-3 part TDE, 0.5-3 part sulfonated acetone formaldehyde polycondensate, 1-5 part liquid-state epoxy resin dispersion agent, 1-5 part urethane, 2-6 part suds-stabilizing agent, 3-6 part coupling agent, 6-12 part mullite fiber, ceramic fine bead 1-4 part, 0.5-2 part two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 0.1-2 part ESCALOL 567,0.5-2 part UV light absorber;
Further, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 25 parts of flyash, 15 parts of hydrogen peroxide, 2 parts of TDE, 2 parts of sulfonated acetone formaldehyde polycondensates, 2.5 parts of liquid-state epoxy resin dispersion agents, 3 parts of urethane, 4 portions of suds-stabilizing agents, 5 parts of coupling agents, 10 parts of mullite fibers, ceramic fine bead 3 parts, 1.5 parts two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 1 part of ESCALOL 567,1 part of UV light absorber;
Further, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h;
Further, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1;
Further, described suds-stabilizing agent is one or more mixtures in ethylenediamine tetraacetic acid (EDTA), diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic;
Further, described coupling agent is the mixture of titanate coupling agent and silane coupling agent;
Further, described UV light absorber is one or more mixtures in salicylate, benzophenone, benzotriazole.
The present invention also discloses a kind of cement plate, is made up of thermal-insulation energy-conservation material.
Beneficial effect of the present invention: thermal-insulation energy-conservation material of the present invention and cement plate thereof, thermal and insulating performance is good, product dry density 160-200kg/m
3, thermal conductivity, at 0.05-0.08W/ (m*K), has good heat preservation and energy conservation effects; Fire resistance is good, and fire endurance is greater than 3h, can reach A level fire-protection standard, thus have good resistivity against fire; Sound-proofing properties is good, can greatly reduce noise effect; Excellent in durability, has anti-high and low-temp performance, the feature of corrosion-resistant, ultraviolet radiation resisting, good weatherability.
Embodiment
Thermal-insulation energy-conservation material of the present invention, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 20-30 part flyash, 11-18 part hydrogen peroxide, 0.5-3 part TDE, 0.5-3 part sulfonated acetone formaldehyde polycondensate, 1-5 part liquid-state epoxy resin dispersion agent, 1-5 part urethane, 2-6 part suds-stabilizing agent, 3-6 part coupling agent, 6-12 part mullite fiber, ceramic fine bead 1-4 part, 0.5-2 part two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 0.1-2 part ESCALOL 567,0.5-2 part UV light absorber.
In the present embodiment, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 25 parts of flyash, 15 parts of hydrogen peroxide, 2 parts of TDE, 2 parts of sulfonated acetone formaldehyde polycondensates, 2.5 parts of liquid-state epoxy resin dispersion agents, 3 parts of urethane, 4 portions of suds-stabilizing agents, 5 parts of coupling agents, 10 parts of mullite fibers, ceramic fine bead 3 parts, 1.5 parts two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 1 part of ESCALOL 567,1 part of UV light absorber;
In the present embodiment, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
In the present embodiment, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
In the present embodiment, described suds-stabilizing agent is one or more mixtures in ethylenediamine tetraacetic acid (EDTA), diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic.
In the present embodiment, described coupling agent is the mixture of titanate coupling agent and silane coupling agent.
In the present embodiment, described UV light absorber is one or more mixtures in salicylate, benzophenone, benzotriazole.
The present invention also discloses a kind of cement plate, is made up of thermal-insulation energy-conservation material.
Below by specific embodiment, the present invention is further elaborated.
Embodiment one
In the present embodiment, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 25 parts of flyash, 15 parts of hydrogen peroxide, 2 parts of TDE, 2 parts of sulfonated acetone formaldehyde polycondensates, 2.5 parts of liquid-state epoxy resin dispersion agents, 3 parts of urethane, 4 portions of suds-stabilizing agents, 5 parts of coupling agents, 10 parts of mullite fibers, ceramic fine bead 3 parts, 1.5 parts two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 1 part of ESCALOL 567,1 part of UV light absorber;
In the present embodiment, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
In the present embodiment, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
In the present embodiment, in the present embodiment, described suds-stabilizing agent is ethylenediamine tetraacetic acid (EDTA), in the present embodiment, described ethylenediamine tetraacetic acid (EDTA) is replaced with the one in diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic according to equivalent weight part, or the mixture of ethylenediamine tetraacetic acid (EDTA) and diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
In the present embodiment, described coupling agent is the mixture of titanate coupling agent and silane coupling agent.
In the present embodiment, described UV light absorber is salicylate, in the present embodiment, described salicylate is replaced with the one in benzophenone, benzotriazole according to equivalent weight part, or the mixture of salicylate and benzophenone, benzotriazole is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
Embodiment two
The thermal-insulation energy-conservation material of the present embodiment, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 20 parts of flyash, 11 parts of hydrogen peroxide, 0.5 part of TDE, 0.5 part of sulfonated acetone formaldehyde polycondensate, 1 part of liquid-state epoxy resin dispersion agent, 1 part of urethane, 2 portions of suds-stabilizing agents, 3 parts of coupling agents, 6 parts of mullite fibers, ceramic fine bead 1 part, 0.5 pair (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 0.1 part of ESCALOL 567,0.5 part of UV light absorber.
In the present embodiment, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
In the present embodiment, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
In the present embodiment, in the present embodiment, described suds-stabilizing agent is diethylamine pentaacetic acid, in the present embodiment, described quadrol pentaacetic acid is replaced with the one in ethylenediamine tetraacetic acid (EDTA), N-hydroxyethyl-ethylenediamine nitrilotriacetic according to equivalent weight part, or the mixture of diethylamine pentaacetic acid and ethylenediamine tetraacetic acid (EDTA), N-hydroxyethyl-ethylenediamine nitrilotriacetic is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
In the present embodiment, described coupling agent is the mixture of titanate coupling agent and silane coupling agent.
In the present embodiment, described UV light absorber is benzophenone, in the present embodiment, described benzophenone is replaced with the one in salicylate, benzotriazole according to equivalent weight part, or the mixture of benzophenone and salicylate, benzotriazole is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
Embodiment three
The thermal-insulation energy-conservation material of the present embodiment, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 20-30 part flyash, 11-18 part hydrogen peroxide, 0.5-3 part TDE, 0.5-3 part sulfonated acetone formaldehyde polycondensate, 1-5 part liquid-state epoxy resin dispersion agent, 1-5 part urethane, 2-6 part suds-stabilizing agent, 3-6 part coupling agent, 6-12 part mullite fiber, ceramic fine bead 1-4 part, 0.5-2 part two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 0.1-2 part ESCALOL 567,0.5-2 part UV light absorber.
In the present embodiment, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
In the present embodiment, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
In the present embodiment, in the present embodiment, described suds-stabilizing agent is ethylenediamine tetraacetic acid (EDTA), in the present embodiment, described ethylenediamine tetraacetic acid (EDTA) is replaced with the one in diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic according to equivalent weight part, or the mixture of ethylenediamine tetraacetic acid (EDTA) and diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
In the present embodiment, described coupling agent is the mixture of titanate coupling agent and silane coupling agent.
In the present embodiment, described UV light absorber is salicylate, in the present embodiment, described salicylate is replaced with the one in benzophenone, benzotriazole according to equivalent weight part, or the mixture of salicylate and benzophenone, benzotriazole is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
Embodiment four
The thermal-insulation energy-conservation material of the present embodiment, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 30 parts of flyash, 18 parts of hydrogen peroxide, 3 parts of TDE, 3 parts of sulfonated acetone formaldehyde polycondensates, 5 parts of liquid-state epoxy resin dispersion agents, 5 parts of urethane, 6 portions of suds-stabilizing agents, 6 parts of coupling agents, 12 parts of mullite fibers, ceramic fine bead 4 parts, 2 parts two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 2 parts of ESCALOL 567s, 2 parts of UV light absorber.
In the present embodiment, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
In the present embodiment, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
In the present embodiment, in the present embodiment, described suds-stabilizing agent is N-hydroxyethyl-ethylenediamine nitrilotriacetic, in the present embodiment, described ethylenediamine tetraacetic acid (EDTA) is replaced with the one in diethylamine pentaacetic acid, ethylenediamine tetraacetic acid (EDTA) according to equivalent weight part, or the mixture of N-hydroxyethyl-ethylenediamine nitrilotriacetic and diethylamine pentaacetic acid, ethylenediamine tetraacetic acid (EDTA) is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
In the present embodiment, described coupling agent is the mixture of titanate coupling agent and silane coupling agent.
In the present embodiment, described UV light absorber is benzotriazole, in the present embodiment, described benzotriazole is replaced with the one in benzophenone, salicylate according to equivalent weight part, or the mixture of benzotriazole and benzophenone, salicylate is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
Embodiment five
The thermal-insulation energy-conservation material of the present embodiment, described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 20 parts of flyash, 18 parts of hydrogen peroxide, 0.5 part of TDE, 3 parts of sulfonated acetone formaldehyde polycondensates, 1 part of liquid-state epoxy resin dispersion agent, 5 parts of urethane, 2 portions of suds-stabilizing agents, 6 parts of coupling agents, 6 parts of mullite fibers, ceramic fine bead 4 parts, 0.5 part two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 2 parts of ESCALOL 567s, 0.5 part of UV light absorber.
In the present embodiment, described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
In the present embodiment, the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
In the present embodiment, in the present embodiment, described suds-stabilizing agent is ethylenediamine tetraacetic acid (EDTA), in the present embodiment, described ethylenediamine tetraacetic acid (EDTA) is replaced with the one in diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic according to equivalent weight part, or the mixture of ethylenediamine tetraacetic acid (EDTA) and diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
In the present embodiment, described coupling agent is the mixture of titanate coupling agent and silane coupling agent, and described titanate coupling agent is one or more mixtures in Di(dioctylpyrophosphato) ethylene titanate, two (octyl phenol Soxylat A 25-7) phosphide, titanate coupling agent TMC-931, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester; Described silane coupling agent is one or more mixtures in γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-(methacryloxypropyl) propyl trimethoxy silicane, N-(β mono-aminoethyl)-γ-aminopropyl front three (second) TMOS.
In the present embodiment, described UV light absorber is salicylate, in the present embodiment, described salicylate is replaced with the one in benzophenone, benzotriazole according to equivalent weight part, or the mixture of salicylate and benzophenone, benzotriazole is replaced with by equivalent weight part, products obtained therefrom character there is no significant difference.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (8)
1. a thermal-insulation energy-conservation material, is characterized in that: described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 20-30 part flyash, 11-18 part hydrogen peroxide, 0.5-3 part TDE, 0.5-3 part sulfonated acetone formaldehyde polycondensate, 1-5 part liquid-state epoxy resin dispersion agent, 1-5 part urethane, 2-6 part suds-stabilizing agent, 3-6 part coupling agent, 6-12 part mullite fiber, ceramic fine bead 1-4 part, 0.5-2 part two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 0.1-2 part ESCALOL 567,0.5-2 part UV light absorber.
2. thermal-insulation energy-conservation material according to claim 2, is characterized in that: described energy-saving material raw material comprises following component by weight:
Ordinary Portland cement 100 parts, 25 parts of flyash, 15 parts of hydrogen peroxide, 2 parts of TDE, 2 parts of sulfonated acetone formaldehyde polycondensates, 2.5 parts of liquid-state epoxy resin dispersion agents, 3 parts of urethane, 4 portions of suds-stabilizing agents, 5 parts of coupling agents, 10 parts of mullite fibers, ceramic fine bead 3 parts, 1.5 parts two (2,2,6,6 ,-tetramethyl--4-piperidyls) sebate, 1 part of ESCALOL 567,1 part of UV light absorber.
3. thermal-insulation energy-conservation material according to claim 1, it is characterized in that: described sulfonated acetone formaldehyde polycondensate obtains by the following method: after slowly dripping acetone after S-WAT and water mix and blend at temperature is 50 DEG C, be warming up to 50 DEG C, insulation 1h, and then be warming up to 90 DEG C slowly drip formaldehyde at temperature is 70 DEG C after, insulation 4h.
4. thermal-insulation energy-conservation material according to claim 2, is characterized in that: the mol ratio of described sulfurous acid, formaldehyde, acetone is: n (S-WAT): n (formaldehyde): n (acetone)=0.8:2.65:1.
5. thermal-insulation energy-conservation material according to claim 1, is characterized in that: described suds-stabilizing agent is one or more mixtures in ethylenediamine tetraacetic acid (EDTA), diethylamine pentaacetic acid, N-hydroxyethyl-ethylenediamine nitrilotriacetic.
6. thermal-insulation energy-conservation material according to claim 1, is characterized in that: described coupling agent is the mixture of titanate coupling agent and silane coupling agent.
7. thermal-insulation energy-conservation material according to claim 1, is characterized in that: described UV light absorber is one or more mixtures in salicylate, benzophenone, benzotriazole.
8. a cement plate, is characterized in that: be made up of the thermal-insulation energy-conservation material described in the arbitrary claim of claim 1-7.
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