CN104818650A - Ultra-hard size and production method and applications thereof - Google Patents
Ultra-hard size and production method and applications thereof Download PDFInfo
- Publication number
- CN104818650A CN104818650A CN201510211026.5A CN201510211026A CN104818650A CN 104818650 A CN104818650 A CN 104818650A CN 201510211026 A CN201510211026 A CN 201510211026A CN 104818650 A CN104818650 A CN 104818650A
- Authority
- CN
- China
- Prior art keywords
- ultrahard
- slurry
- filler
- auxiliary agent
- wallpaper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses ultra-hard size. The size is produced through ingredients of, by weight percentage of the dry size, 20% to 40% of body resin, 10% to 20% of blending resin, 15% to 30% of plasticizer, 10% to 20% of fillers A, 1% to 10% of fillers B, 5% to 15% of fillers C, 2% to 4% of solvent, 7% to 10% of auxiliaries A, 1% to 2% of auxiliaries B and 0% to 0.1% of auxiliaries C. The ingredients are mixed in proportion to obtain the ultra-hard size to be applied to the ultra-hard wallpaper production, and accordingly, the gap of size required by ultra-hard wallpaper is filled. The invention further discloses ultra-hard wallpaper produced through the ultra-hard size, the ultra-hard size is hard, good in touch, high in plasticity and mechanical performance after being dried, the ultra-hard wallpaper has high hardness and mechanical strength and feels good.
Description
Technical field
The present invention relates to a kind of wallpaper slurry, particularly a kind of ultrahard slurry and preparation method thereof and application.
Background technology
Wallpaper is a kind of application indoor hardware fitting widely, and it has, and color is various, pattern abundant, safety and environmental protection, improve the features such as domestic environment, the kind of wall paper products is varied, divide according to base material, existing wall paper products has resinae wallpaper, pure paper class wallpaper, glass fibre class wallpaper, nonwoven fabric wallpaper etc., due to base material different wallpapers between performance difference larger, but, wallpaper slurry is as the important making material producing wallpaper, to the intensity of the excellent degree of reaction wallpaper, toughness, anticorrosive property, the indexs such as surface touch and pattern sight have conclusive effect, at present, wallpaper common is on the market mostly in pliability, the aspect performances such as waterproof anti-corrosion are excellent, but, lack and a kind of there is very high strength and hardness and excellent mechanical performance (ductility simultaneously, pliability) wall paper products, trace it to its cause, lack the wallpaper slurry making this type of wallpaper.
In view of this, the present inventor's especial manufacture a kind of low cost, high performance ultrahard slurry, and this ultrahard slurry is applied to the production of ultrahard wallpaper, this case produces thus.
Summary of the invention
A technical problem to be solved by this invention is open a kind of ultrahard slurry, and it has filled up the blank of wallpaper field ultrahard slurry, has plasticity strong, satisfactory mechanical property and scleroid feature.
Another technical problem to be solved by this invention is open a kind of ultrahard wallpaper applying above-mentioned ultrahard slurry, and it has hardness strong especially, and feel is strong, fastness good, anti-wear performance is excellent, and production cost is low.
To achieve these goals, solution of the present invention is:
A kind of ultrahard slurry, the weight percent content being pressed dry pulp by following component is formulated:
Matrix resin 20-40%
Blending resin 10-20%
Plasticizer 15-30%
Filler A 10-20%
Filler B 1-10%
Filler C 5-15%
Solvent 2-4%
Auxiliary agent A 3-10%
Auxiliary agent B 1-3%
Auxiliary agent C 0-0.1%;
Described matrix resin is the PVC powder body of particle diameter 0.2 ~ 2 μm, and blending resin is the PVC powder body of particle diameter 20 ~ 60 μm.
Described plasticizer is DOP(dioctyl phthalate), the two isobutyrate of TXIB(2,2,4-trimethyl-1,3-pentanediol) and ESO(epoxidized soybean oil) in one or more.
Described filler A is calcium carbonate, and filler B is talcum powder, and filler C is titanium dioxide, and solvent is alkane solvent, and auxiliary agent A is silica gel, and auxiliary agent B is liquid stability agent, and auxiliary agent C is fluorescent whitening agent.
The preparation process of ultrahard slurry comprises the steps:
Step 1: by the standby raw material of formula: matrix resin, blending resin, plasticizer, filler A filler B, filler C, solvent, auxiliary agent A, auxiliary agent B, auxiliary agent C.
Step 2: after first plasticizer, stirring solvent being mixed, raise turn up 500-600 r/min to stir, then filler A, filler B filler C, matrix resin and blending resin is added, stir ten minutes, then add auxiliary agent A, auxiliary agent B and auxiliary agent C, being stir five minutes under the condition of 1000 r/min at rotating speed, is finally stir under the condition of 400-500 r/min at rotating speed, cooling discharging, obtains ultrahard slurry.
A kind of ultrahard wallpaper, comprises paper substrate, precoating liquid layer, the pearlite slurry bed of material and ultrahard pulp layer; Paper substrate sprays pre-coating solution adhesive and form precoating liquid layer, the water paste that precoating liquid layer top roll is coated with containing pearl essence forms the pearlite slurry bed of material, the pearlite slurry bed of material is coated with above-mentioned ultrahard slurry and forms ultrahard pulp layer.
The preparation process of ultrahard wallpaper comprises the steps:
The first step: paper substrate surface spraying last layer pre-coating solution adhesive is the oven drying of 90-100 DEG C through temperature, forms precoating liquid layer;
Second step: precoating liquid layer surface roller coating contains the water paste of pearl essence is the oven drying of 140 ~ 160 DEG C through temperature, forms the pearlite slurry bed of material;
3rd step: pearlite slurry bed of material surface coating one deck ultrahard slurry forms ultrahard pulp layer, after ultrahard pulp layer undertakes the printing of pattern, entering temperature is carry out dry tack free in the baking oven of 180 ~ 200 DEG C, dries, rolling, and last normal temperature slaking i.e. obtained ultrahard wallpaper.
Described paper substrate is pure paper or non-woven paper.
After adopting technique scheme, ultrahard slurry of the present invention has the following advantages:
One, the blank of ultrahard slurry in wallpaper slurry field filled up by ultrahard slurry, and the production for ultrahard wallpaper provides the hard slurry of low cost;
Two, blending resin and matrix resin with the use of the space decreased between Large stone PVC powder body, in conjunction with the synergy of filler and auxiliary agent, realize the dense packing of powder, strengthen the mechanical strength after sizing material forming; The plasticity after sizing material forming is improve again in conjunction with plasticizer;
Three, after ultrahard slurry drying, quality is hard, and sense of touch is comfortable, and fastness is good, and anti-wear performance is excellent.
Accompanying drawing explanation
Fig. 1 is the generalized section of ultrahard wallpaper of the present invention.
Label declaration
Paper substrate 1, precoating liquid layer 2, the pearlite slurry bed of material 3, ultrahard pulp layer 4.
Detailed description of the invention
Embodiment one:
A kind of ultrahard slurry, is formed by the weight percent content configuration of following component by dry pulp, the PVC powder 25% of diameter of particle 0.2-2 μm, the PVC powder 15% of diameter of particle 20-60 μm, DOP14%, ESO8%, calcium carbonate 12%, talcum powder 8%, titanium dioxide 10%, alkane solvent 2%, silica gel 4.96%, liquid stability agent 1%, fluorescent whitening agent 0.04%.The present embodiment employing model is the liquid stability agent of KZ-3608, and fluorescent whitening agent is fluorescent whitening agent OB, and alkane solvent is that D40(takes off aromatic hydrocarbon solvent).
The preparation process of ultrahard slurry is as follows: get out raw material according to said ratio, first by plasticizer DOP, after plasticizer ESO and alkane solvent are uniformly mixed, raise turn up 500-600r/min to stir, then calcium carbonate is added, talcum powder, titanium dioxide, matrix resin (PVC powder of particle diameter 0.2-2 μm) and blending resin (PVC powder of diameter of particle 20-60 μm), stir ten minutes, then silica gel is added, liquid stability agent, fluorescent whitening agent, raise turn up 1000 r/min and stir five minutes, finally stir under rotating speed is the condition of 400-500r/min, cooling discharging, obtain ultrahard slurry.
Have employed two kinds of resins that diameter of particle is different in ultrahard slurry of the present invention, i.e. matrix resin and blending resin, after blending resin adds matrix resin, space between powder granule is filled, form the dense packing of PVC powder body, the mechanical strength of Reinforced PVC resin, and powder kind and consumption increase; Polyvinyl chloride resin is softening when 130-150 DEG C, plasticizer weakens the polarity active force between the strand of polyvinyl chloride resin, thus improve the plasticity of slurry, add as the calcium carbonate of filler, talcum powder and titanium dioxide again, with the gap between further filled PVC powder granule and the gap between PVC powder body particle and plasticizer particle, improve the intensity after slurry hardens again, wherein, the talcum powder of 8% is have employed in this example, it is enriched in around blending resin particle, increase the volume of resin on the one hand, can also protect resin on the other hand; When temperature increase to 160 DEG C, polyvinyl chloride resin plasticizing is hardening, and the silica gel as auxiliary agent is also hardening, obtains the wallpaper slurry of ultrahard after the drying.
In the present embodiment, blending resin (15%) contained by ultrahard slurry and talcum powder (8%) ratio higher, the viscosity of slurry is higher, after slurry at a certain temperature drying, due to blending resin and talcous large usage quantity, make the higher of the simple matrix resin of its mechanical strength ratio, ABRASION RESISTANCE is better.
With reference to shown in Fig. 1, a kind of ultrahard wallpaper disclosed by the invention, comprises paper substrate 1, precoating liquid layer 2, the pearlite slurry bed of material 3 and ultrahard pulp layer 4; Paper substrate 1 is pure paper or non-woven paper, and the present embodiment adopts cheap non-woven paper as the base material producing wallpaper; Paper substrate 1 sprays pre-coating solution adhesive and form precoating liquid layer 2, the water paste that on precoating liquid layer 2, roller coat contains pearl essence forms the pearlite slurry bed of material 3, the pearlite slurry bed of material 3 is coated with above-mentioned ultrahard slurry and forms ultrahard pulp layer 4.
The preparation process of ultrahard wallpaper comprises the steps:
The first step: paper substrate 1 surface spraying last layer pre-coating solution adhesive is 90-100 DEG C of oven drying through temperature, forms precoating liquid layer 2;
Second step: precoating liquid layer 2 surface roller coating contains the water paste of pearl essence is the oven drying of 140 ~ 160 DEG C through temperature, forms the pearlite slurry bed of material 3;
3rd step: the pearlite slurry bed of material 3 surface coating one deck ultrahard slurry forms ultrahard pulp layer 4, after ultrahard pulp layer 4 undertakes the printing of pattern, entering temperature is carry out dry tack free in the baking oven of 180 ~ 200 DEG C, dries, rolling, and last normal temperature slaking i.e. obtained ultrahard wallpaper.
In the ultrahard slurry of the ultrahard wallpaper employing of the present embodiment, because price lower blending resin content (reaching 15%) is higher, the production cost of obtained wallpaper reduces, simultaneously due to particle diameter that blending resin is larger, and amount of talc also reaches 8%, the crocking resistance of wallpaper, performance of fading reach the requirement (Rubbing number reaches more than 25 times nondiscolourings, and fadedness experiment is qualified) of wallpaper industry standard QB/T 4034-2010.
Embodiment two:
A kind of ultrahard slurry, is formed by following component content configuration by weight percentage, the PVC powder 29% of diameter of particle 0.2-2 μm, the PVC powder 10%, DOP10%, TXIB5% of diameter of particle 20-60 μm, ESO4%, calcium carbonate 15%, talcum powder 4%, titanium dioxide 10%, alkane solvent 4%, silica gel 6%, liquid stability agent 2.94%, fluorescent whitening agent 0.06%.The present embodiment also adopts model to be the liquid stability agent of KZ-3608, and fluorescent whitening agent is fluorescent whitening agent OB, and alkane solvent is that D40(takes off aromatic hydrocarbon solvent).
The preparation process of ultrahard slurry is as follows: get out raw material according to said ratio, after first DOP, TXIB, ESO and alkane solvent being uniformly mixed, raise turn up 500-600r/min to stir, then calcium carbonate is added, talcum powder, titanium dioxide, matrix resin and blending resin, stir ten minutes, then silica gel is added, liquid stability agent, fluorescent whitening agent, raise turn up 1000 r/min and stir five minutes, finally stir under rotating speed is the condition of 400-500r/min, cooling discharging, obtains ultrahard slurry.
The blending resin less (10%) that the ultrahard slurry of the present embodiment adds, and mainly matrix resin, and calcium carbonate (15%), silica gel (6%) is all more, a large amount of calcium carbonate add the cost both reducing slurry, calcium carbonate serves the effect of enhance mechanical strength as filler simultaneously, and a large amount of existence of silica gel make slurry become firmer after drying, and the performances such as ABRASION RESISTANCE are more superior.
A kind of ultrahard wallpaper, comprises paper substrate 1, precoating liquid layer 2, the pearlite slurry bed of material 3 and ultrahard pulp layer 4; Paper substrate 1 is pure paper or non-woven paper, and the present embodiment adopts cheap non-woven paper as the base material producing wallpaper; Paper substrate 1 sprays pre-coating solution adhesive and form precoating liquid layer 2, the water paste that on precoating liquid layer 2, roller coat contains pearl essence forms the pearlite slurry bed of material 3, the pearlite slurry bed of material 3 is coated with above-mentioned ultrahard slurry and forms ultrahard pulp layer 4.
The preparation process of the ultrahard wallpaper of this example is identical with the ultrahard wallpaper preparation process in embodiment one.
In the ultrahard slurry of the ultrahard wallpaper employing of the present embodiment, because blending resin content (only 10%) is less, and calcium carbonate (15%), silica gel (6%) is all more, after high temperature drying, ultrahard pulp layer makes wallpaper have extremely strong mechanical strength, simultaneously also firmer, the crocking resistance of wallpaper, performance of fading reach the requirement (Rubbing number reaches more than 25 times nondiscolourings, and fadedness experiment is qualified) of wallpaper industry standard QB/T 4034-2010.
Embodiment three:
A kind of ultrahard slurry, is formed by following component content configuration by weight percentage, the PVC powder 30% of diameter of particle 0.2-2 μm, the PVC powder 13%, DOP6%, TXIB6% of diameter of particle 20-60 μm, ESO10%, calcium carbonate 13%, talcum powder 4%, titanium dioxide 9%, alkane solvent 2%, silica gel 5%, liquid stability agent 1.95%, fluorescent whitening agent 0.05%.The present embodiment adopts model to be the liquid stability agent of KZ-3608 equally, and fluorescent whitening agent is fluorescent whitening agent OB, and alkane solvent is that D40(takes off aromatic hydrocarbon solvent).
The preparation process of ultrahard slurry is as follows: get out raw material according to said ratio, after first DOP, TXIB, ESO and alkane solvent being uniformly mixed, raise turn up 500-600r/min to stir, then calcium carbonate is added, talcum powder, titanium dioxide, matrix resin and blending resin, stir ten minutes, then silica gel is added, liquid stability agent, fluorescent whitening agent, raise turn up 1000 r/min and stir five minutes, finally stir under rotating speed is the condition of 400-500r/min, cooling discharging, obtains ultrahard slurry.
The blending resin (13%) that the ultrahard slurry of the present embodiment adds, calcium carbonate (13%), ESO(10%) all more.At high proportion blending resin and calcium carbonate add the cost both reducing slurry, calcium carbonate also strengthens the mechanical strength of ultrahard pulp layer further as filler, meanwhile, a large amount of ESO adds, and greatly reduces migration of plasticizer.
A kind of ultrahard wallpaper, comprises paper substrate 1, precoating liquid layer 2, the pearlite slurry bed of material 3 and ultrahard pulp layer 4; Paper substrate 1 is pure paper or non-woven paper, and the present embodiment adopts cheap non-woven paper as the base material producing wallpaper; Paper substrate 1 sprays pre-coating solution adhesive and form precoating liquid layer 2, the water paste that on precoating liquid layer 2, roller coat contains pearl essence forms the pearlite slurry bed of material 3, the pearlite slurry bed of material 3 is coated with above-mentioned ultrahard slurry and forms ultrahard pulp layer 4.
The preparation process of the ultrahard wallpaper of this example is also identical with the ultrahard wallpaper preparation process in embodiment one.
In the ultrahard slurry of the ultrahard wallpaper employing of the present embodiment, due to matrix resin content (30%), blending resin content (13%), calcium carbonate (13%) and ESO(10%) content are all higher, filler proportion (being combined into 27%) is lower, the easier plastotype of ultrahard pulp layer 4, make the top layer of wallpaper (ultrahard pulp layer) easier printing pattern and pattern, keep preferably hardness and mechanical strength simultaneously, the crocking resistance of obtained wallpaper, performance of fading reaches the requirement of wallpaper industry standard QB/T 4034-2010, and (Rubbing number reaches more than 25 times nondiscolourings, fadedness experiment is qualified).
Above-described embodiment and graphic and non-limiting product form of the present invention and style, any person of an ordinary skill in the technical field, to its suitable change done or modification, all should be considered as not departing from patent category of the present invention.
Claims (7)
1. a ultrahard slurry, is characterized in that: formulated by the weight percent content of dry pulp by following component:
Matrix resin 20-40%
Blending resin 10-20%
Plasticizer 15-30%
Filler A 10-20%
Filler B 1-10%
Filler C 5-15%
Solvent 2-4%
Auxiliary agent A 3-10%
Auxiliary agent B 1-3%
Auxiliary agent C 0-0.1%;
Described matrix resin is the PVC powder body of particle diameter 0.2 ~ 2 μm, and blending resin is the PVC powder body of particle diameter 20 ~ 60 μm.
2. a kind of ultrahard slurry as claimed in claim 1, is characterized in that: described plasticizer is one or more in DOP, TXIB and ESO.
3. a kind of ultrahard slurry as claimed in claim 1, it is characterized in that: described filler A is calcium carbonate, filler B is talcum powder, filler C is titanium dioxide, and solvent is alkane solvent, and auxiliary agent A is silica gel, auxiliary agent B is liquid stability agent, and auxiliary agent C is fluorescent whitening agent.
4. a kind of ultrahard slurry as claimed in claim 1, is characterized in that: preparation process comprises the steps:
Step 1: by the standby raw material of formula: matrix resin, blending resin, plasticizer, filler A filler B, filler C, solvent, auxiliary agent A, auxiliary agent B, auxiliary agent C;
Step 2: after first plasticizer, stirring solvent being mixed, raise turn up 500-600 r/min to stir, then filler A, filler B filler C, matrix resin and blending resin is added, stir ten minutes, then add auxiliary agent A, auxiliary agent B and auxiliary agent C, being stir five minutes under the condition of 1000 r/min at rotating speed, is finally stir under the condition of 400-500 r/min at rotating speed, cooling discharging, obtains ultrahard slurry.
5. a ultrahard wallpaper, is characterized in that: comprise paper substrate, precoating liquid layer, the pearlite slurry bed of material and ultrahard pulp layer; Paper substrate sprays pre-coating solution adhesive and form precoating liquid layer, the water paste that precoating liquid layer top roll is coated with containing pearl essence forms the pearlite slurry bed of material, the pearlite slurry bed of material is coated with ultrahard slurry according to claim 1 and forms ultrahard pulp layer.
6. a kind of ultrahard wallpaper as claimed in claim 5, is characterized in that: preparation process comprises the steps:
The first step: paper substrate surface spraying last layer pre-coating solution adhesive is the oven drying of 90-100 DEG C through temperature, forms precoating liquid layer;
Second step: precoating liquid layer surface roller coating contains the water paste of pearl essence is the oven drying of 140 ~ 160 DEG C through temperature, forms the pearlite slurry bed of material;
3rd step: pearlite slurry bed of material surface coating one deck ultrahard slurry forms ultrahard pulp layer, after ultrahard pulp layer undertakes the printing of pattern, entering temperature is carry out dry tack free in the baking oven of 180 ~ 200 DEG C, dries, rolling, and last normal temperature slaking i.e. obtained ultrahard wallpaper.
7. a kind of ultrahard wallpaper as claimed in claim 5, is characterized in that: described paper substrate is pure paper or non-woven paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510211026.5A CN104818650A (en) | 2015-04-29 | 2015-04-29 | Ultra-hard size and production method and applications thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510211026.5A CN104818650A (en) | 2015-04-29 | 2015-04-29 | Ultra-hard size and production method and applications thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104818650A true CN104818650A (en) | 2015-08-05 |
Family
ID=53729118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510211026.5A Pending CN104818650A (en) | 2015-04-29 | 2015-04-29 | Ultra-hard size and production method and applications thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104818650A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108729298A (en) * | 2018-06-06 | 2018-11-02 | 苏州华尔美特装饰材料股份有限公司 | A kind of seamless hard wallpaper recruitment skill slurry |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1458444A (en) * | 1973-03-24 | 1976-12-15 | Pickhardt Siebert | Method of producing a water vapour-permeable plastics-coated wallpaper or wall covering and a wallpaper or wall covering produced by such a method |
| CN1072978A (en) * | 1991-12-03 | 1993-06-09 | 上海宝山钢铁总厂 | A kind of preparation method of antistatic wallpaper |
| US5413829A (en) * | 1991-09-13 | 1995-05-09 | Forbo-Cp Limited | Self-adhesive wallcoverings |
| CN1241580A (en) * | 1999-06-03 | 2000-01-19 | 天津渤海化工(集团)股份有限公司天津化工厂 | Production of resin admixture for polyvinyl chloride paste |
| CN204001562U (en) * | 2014-03-25 | 2014-12-10 | 福建圣莉雅环保壁纸有限公司 | A kind of wallpaper of making incrustation of pearl essence |
| CN104278592A (en) * | 2014-09-16 | 2015-01-14 | 福建圣莉雅环保壁纸有限公司 | Flexo slurry and application of flexo slurry in flexo wallpaper |
-
2015
- 2015-04-29 CN CN201510211026.5A patent/CN104818650A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1458444A (en) * | 1973-03-24 | 1976-12-15 | Pickhardt Siebert | Method of producing a water vapour-permeable plastics-coated wallpaper or wall covering and a wallpaper or wall covering produced by such a method |
| US5413829A (en) * | 1991-09-13 | 1995-05-09 | Forbo-Cp Limited | Self-adhesive wallcoverings |
| CN1072978A (en) * | 1991-12-03 | 1993-06-09 | 上海宝山钢铁总厂 | A kind of preparation method of antistatic wallpaper |
| CN1241580A (en) * | 1999-06-03 | 2000-01-19 | 天津渤海化工(集团)股份有限公司天津化工厂 | Production of resin admixture for polyvinyl chloride paste |
| CN204001562U (en) * | 2014-03-25 | 2014-12-10 | 福建圣莉雅环保壁纸有限公司 | A kind of wallpaper of making incrustation of pearl essence |
| CN104278592A (en) * | 2014-09-16 | 2015-01-14 | 福建圣莉雅环保壁纸有限公司 | Flexo slurry and application of flexo slurry in flexo wallpaper |
Non-Patent Citations (1)
| Title |
|---|
| 邴涓林 等主编: "《聚氯乙烯工艺技术》", 30 April 2008, 北京：化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108729298A (en) * | 2018-06-06 | 2018-11-02 | 苏州华尔美特装饰材料股份有限公司 | A kind of seamless hard wallpaper recruitment skill slurry |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101780603B1 (en) | Granite based paint composition with acrylic color chip and its usage | |
| CN102391767B (en) | High-solid-content interior and exterior crosslinked type water-in-water colorful granite paint and preparation method thereof | |
| CN103849280B (en) | Preparation method of ultra-stable high-weather-resistance water-in-water granite-like multicolor paint | |
| CN103627306B (en) | Mist surface hand feeling scratch-resistant coating paint and preparation method thereof | |
| CN104672702B (en) | PVC (Polyvinyl Chloride) paste for PVC suede wallpaper and preparation method thereof | |
| CN102363685A (en) | Multifunctional environment-friendly low-carbon interior wall paint and preparation method thereof | |
| CN105086554A (en) | Artistic pigment and preparation method thereof | |
| CN103757990B (en) | A kind of wallpaper with rubber handfeel and preparation method thereof | |
| JP5420520B2 (en) | Pattern surface formation method | |
| CN212405859U (en) | Novel inorganic board of precoating | |
| CN104119754B (en) | A kind of acrylic ester multicolor finish | |
| CN101230230A (en) | Polyurethane modified unsaturated polyester colored finish or priming paint | |
| CN107502102A (en) | A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof | |
| JP5420522B2 (en) | Pattern surface formation method | |
| JP5398402B2 (en) | Pattern surface formation method | |
| CN104818650A (en) | Ultra-hard size and production method and applications thereof | |
| US10150876B2 (en) | Paint coating material for producing an imitation ceramic effect and its application method thereof | |
| CN109370334A (en) | A kind of insulating moulding coating and preparation method thereof for aqueous acrylamide acid type finishing coat | |
| CN103741546B (en) | A kind of corn particle effect wallpaper and production technology thereof | |
| CN104817916A (en) | Water-in-water colorful paint and preparation method thereof | |
| CN108373758A (en) | A kind of environment-friendly type antibiotic resistance and fingerprint resistance ultrafine powder paint and preparation method thereof | |
| JP5232834B2 (en) | Pattern surface formation method | |
| CN108250852A (en) | Environment-friendly type has the PVC water paints of three-dimensional stereopsis color | |
| CN205242903U (en) | Acrylic acid outer wall lacquer coat structure | |
| CN206581079U (en) | A kind of novel plastic particle wallpaper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150805 |
|
| RJ01 | Rejection of invention patent application after publication |