CN104818168A - Laundry soap solution and preparation method thereof - Google Patents
Laundry soap solution and preparation method thereof Download PDFInfo
- Publication number
- CN104818168A CN104818168A CN201510206598.4A CN201510206598A CN104818168A CN 104818168 A CN104818168 A CN 104818168A CN 201510206598 A CN201510206598 A CN 201510206598A CN 104818168 A CN104818168 A CN 104818168A
- Authority
- CN
- China
- Prior art keywords
- laundry soap
- soap lye
- acid
- sanitas
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention belongs to the detergent technical field and provides a laundry soap solution. The laundry soap solution comprises the following components of, by mass, 2 to 15% of mixed fatty acid soap, 2 to 10% of sodium ethoxylated alkyl sulfate, 1 to 5% of fatty alcohol-polyoxyethylene ether, 0.2 to 5% of lauramidopropyl betaine, 0.2 to 5% ofalkyl glycoside, 0.1 to 3% of citrate, 0.1 to 1.0% of chelating agent, 0.5 to 3% of thickening agent, 0.1 to 2% of styrene and acrylate copolymer, 0.1 to 2% of preservative, 0 to 1% of essence and 50 to 90% of water. The laundry soap solution is excellent in detergency and washing performance.
Description
Technical field
The invention belongs to washing composition technical field, particularly relate to a kind of laundry soap lye and preparation method thereof.
Background technology
Laundry liquid agent is developed so far, and as can be seen from its ever-increasing market share, human consumer generally receives laundry liquid agent.Compared with solid laundry agent, laundry liquid agent has that production technique is simple, and product is easy to use, dissolves rapidly, to the action temperature of clothing and etc. advantage.
As the one of laundry liquid agent, the activeconstituents of laundry soap lye comprises fatty acid soaps and other tensio-active agents.Because fatty acid soaps has good clean effect, can reduce the consumption of other tensio-active agents, soap lye becomes the new lover in scouring agent gradually.
Chinese patent 200780019337.5 discloses a kind of liquid handling components and fabrics, this liquid handling components and fabrics is while comprising fatty acid soaps, also comprise a certain amount of free fatty acids and fatty acid ester, soap and softening agent is generated containing ester soap precursor and alkali reaction, this laundry product can realize SPE deposition preferably, can be made into superconcentrate.
Chinese patent 201210563439.6 discloses a kind of Liquid laundry composition, this Liquid laundry composition uses single coco-nut oil fatty acid potash soap as fatty acid soaps, use nonionogenic tenside and anion surfactant as tensio-active agent, at use dimethyl silicone oil as having preferably easily rinsing performance when defoamer.But silicone oil defoamer is more unstable in washing liquid system, easily occur the situation of oily water separation, and it presses down bubble effect and is greater than froth breaking effect, easily produces the phenomenon that washing liquid difficulty is bubbled when main washing.
It is not ideal enough to there is detersive power in laundry soap lye of the prior art, and other dosage of surfactant beyond fatty acid soaps are comparatively large, needs to use the shortcomings such as defoamer.Therefore, be necessary that research and development one is not containing defoamer, the comparatively strong and laundry soap lye of easily rinsing of detersive power, to meet the higher demand of human consumer.
Summary of the invention
For solving problems of the prior art, contriver carries out screening and composite, unforeseeable discovery: combine by special component the laundry soap lye obtained and have excellent detersive power and easily float performance by the composition of lot of experiments to fatty acid soaps and other tensio-active agents.Based on above-mentioned discovery, thus complete the present invention.
Object of the present invention will be further described in detail below reflect and description.
The invention provides a kind of laundry soap lye, comprise following component and mass percent thereof: mixed fatty acid soap 2 ~ 15%, ethoxylated alkyl sulfate 2 ~ 10%, fatty alcohol-polyoxyethylene ether 1 ~ 5%, lauroyl amido CAB 0.2 ~ 5%, alkyl glycoside 0.2 ~ 5%, Citrate trianion 0.1 ~ 3%, sequestrant 0.1 ~ 1.0%, thickening material 0.5 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 2%, sanitas 0.1 ~ 2%, essence 0 ~ 1%, water 50 ~ 90%.
Generate mixed fatty acid soap, the introducing of multiple soap base, both adjustable pH value by the reaction of saturated fatty acid, unsaturated fatty acids and alkali, play effect of decontamination, all right sequester heavy metal ions, chelate products can do at washing process and falls infusion and subtract lubrication prescription; Calcium salt in soap base and water, magnesium salts generate lipid acid calcium soap or magnesium soap through replacement(metathesis)reaction, can accelerate the drain age velocity of foam, reduce Film strength, thus facilitate bubble burst, improve and easily float performance.Ethoxylated alkyl sulfate has soil-removing action; Fatty alcohol-polyoxyethylene ether has infiltration and soil-removing action; Lauroyl amido CAB has the effect of decontamination and adjusting viscosity; Alkyl glycoside has decontamination, softening, also can reduce the pungency of other tensio-active agents, have the performance of good thickening property and stabilising system.By the synergy of above-mentioned 4 kinds of tensio-active agents and mixed fatty acid soap, the consumption of other tensio-active agents beyond fatty acid soaps can be reduced, while enhancing detersive power, facilitated lather collapse during water, without the need to additionally adding defoamer, reach the effect that a rinsing gets final product basic rinse.Thickening material is used for regulation system viscosity.Phenylethylene ethylene/propenoic acid ester copolymer, for regulating pH and system rheologic behavio(u)r, makes target product stable in viscosity and phase globality.Sequestrant can sequester heavy metal ions, reduces water hardness.
The combination of said components and the above-mentioned percentage range of each component are that contriver is determined by lot of experiments, and aforesaid combination and percentage range make laundry soap lye provided by the invention have excellent detersive power and easily float performance.
Preferably, described mixed fatty acid soap is obtained through alkali neutralization by mixed fatty acid, and described mixed fatty acid is made up of with the mass ratio of 3 ~ 8:1 saturated fatty acid and unsaturated fatty acids, and described alkali is selected from alkali-metal oxyhydroxide.In order to ensure the complete of mixed fatty acid saponification, the add-on of alkali is excessive a little, and therefore, in laundry soap lye provided by the invention, not containing free fatty acids, pH is between 7.5 ~ 8.5.
Preferably, described saturated fatty acid by lauric acid and stearic acid with (1 ~ 2): the mass ratio of (2 ~ 1) forms, and described unsaturated fatty acids is oleic acid.
Preferably, described basic metal is selected from sodium and/or potassium, and described sequestrant is selected from tetrasodium ethylenediamine tetraacetate and/or disodium ethylene diamine tetraacetate, and described thickening material is sodium-chlor.
Preferably, laundry soap lye provided by the invention comprises following component and mass percent thereof: potassium laurate 1 ~ 4%, potassium stearate 1 ~ 4%, potassium oleate 0.5 ~ 2 %, ethoxylated alkyl sulfate 3 ~ 6%, fatty alcohol-polyoxyethylene ether 1 ~ 3%, lauroyl amido CAB 1 ~ 3%, alkyl glycoside 1 ~ 3%, Tripotassium Citrate 0.2 ~ 1%, tetrasodium ethylenediamine tetraacetate 0.1 ~ 0.5%, sodium-chlor 1 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 1%, sanitas 0.1 ~ 1%, essence 0 ~ 0.5%, water 70 ~ 90%.
Preferably, laundry soap lye provided by the invention comprises following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl glycoside 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, essence 0.15%, water 81.8%.
Preferably, the alkyl carbon chain lengths of described alkyl glycoside is C
8~ C
12.
Preferably, described fatty alcohol-polyoxyethylene ether is selected from AEO
7and/or AEO
9.
Preferably, described sanitas by Bronopol and methylisothiazolinone with (6 ~ 9): the mass ratio of 1 forms.
Described essence, can adopt the industry to commonly use essence, also can select not add essence.Whether the interpolation of essence, can not have an impact to the major function of laundry soap lye provided by the invention.Obviously, in addition to the above components, on basis of the present invention, other components such as applicable pigment can also be added.
Correspondingly, the present invention also provides the preparation method of laundry soap lye, comprise the steps: by thickening material and alkali soluble in water, be warming up to 60 ~ 80 DEG C, under agitation condition, add lauric acid, stearic acid and oleic acid, after reaction 0.1 ~ 1h, cooling, under agitation condition, add ethoxylated alkyl sulfate, fatty alcohol-polyoxyethylene ether, lauroyl amido CAB, alkyl glycoside, citric acid, tetrasodium ethylenediamine tetraacetate, sanitas and essence, obtain mixed solution; Under agitation condition, the phenylethylene ethylene/propenoic acid ester copolymer with water-dispersion, sanitas and essence are added in described mixed solution, stir and obtain laundry soap lye.Add citric acid and return acid, suitably can reduce pH, and the Citrate trianion obtained can offset polyvalent cation such as calcium and the magnesium negative effect to washing.In addition, Citrate trianion can improve detersive efficiency and the effect of tensio-active agent.
Compared with prior art, the invention has the beneficial effects as follows: laundry soap lye provided by the invention, easy to use, steady quality, preparation method is simple, cost is low, without soapy feeling during hand washing, by the synergy of mixed fatty acid soap and other tensio-active agents, while enhancing detersive power, facilitate lather collapse during washed water, without the need to additionally adding defoamer, reach easy rinsing, a rinsing gets final product the effect of basic rinse, applied widely, be applicable to the washing under high-hardness water condition.The preparation method of laundry soap lye provided by the invention is simple, and obtained laundry soap lye steady quality, washing effect is good, easy rinsing.
Embodiment
Below by specific embodiment, the present invention is described in further detail.
Each component in the present invention is conventional commercial product, such as, the alkyl glycoside in embodiment purchased from Shanghai Fakai Chemical Co., Ltd., article No. APG0814; Phenylethylene ethylene/propenoic acid ester copolymer purchased from Luomen Hars China Co., article No. Acusol op301.
embodiment one is done washing soap lye
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl glycoside 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
Preparation method: by weight, every part of 1kg, take 80 parts of water, add 1.5 parts of sodium-chlor and 1.2 parts of potassium hydroxide, stir, be warming up to 70 DEG C, under agitation condition, add 2 parts of lauric acid, 2 parts of stearic acid and 1 part of oleic acid, after reaction 0.5h, be cooled to 50 DEG C, under agitation condition, add 5 parts of ethoxylated alkyl sulfates, 2 parts of fatty alcohol-polyoxyethylene ether, 2 parts of lauroyl amido CAB, 2 parts of alkyl glycoside, 0.25 part of citric acid and 0.1 part of tetrasodium ethylenediamine tetraacetate, be cooled to 30 DEG C, under agitation condition, add 0.1 part of styrene acrylic copolymer (with 1.95 parts of water-dispersions), 0.1 portion of sanitas and 0 part of essence, stir and get final product.
embodiment two is done washing soap lye
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 4%, potassium stearate 3%, potassium oleate 2%, ethoxylated alkyl sulfate 3%, fatty alcohol-polyoxyethylene ether 1%, lauroyl amido CAB 1%, alkyl glycoside 2%, Tripotassium Citrate 0.5%, tetrasodium ethylenediamine tetraacetate 0.2%, sodium-chlor 2%, phenylethylene ethylene/propenoic acid ester copolymer 0.5%, sanitas 0.2%, essence 0.15%, water 80.45%.
Preparation method: similar with the preparation method in embodiment one.
embodiment three is done washing soap lye
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 3%, potassium stearate 4%, potassium oleate 2%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 3%, alkyl glycoside 1%, Tripotassium Citrate 1%, tetrasodium ethylenediamine tetraacetate 0.4%, sodium-chlor 2%, phenylethylene ethylene/propenoic acid ester copolymer 1%, Bronopol 0.18%, methylisothiazolinone 0.02%, essence 0.5%, water 74.9%.
Preparation method: similar with the preparation method in embodiment one.
comparative example 1
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 4%, lauroyl amido CAB 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
The difference of the present embodiment and embodiment one is: the mass percent of alkyl glycoside is become 0 from 2%, and the mass percent of fatty alcohol-polyoxyethylene ether is become 4% from 2%.
Preparation method: similar with the preparation method in embodiment one.
comparative example 2
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, lauroyl amido CAB 2%, alkyl glycoside 4%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
The difference of the present embodiment and embodiment one is: the mass percent of alkyl glycoside is become 4% from 2%, and the mass percent of fatty alcohol-polyoxyethylene ether is become 0% from 2%.
Preparation method: similar with the preparation method in embodiment one.
comparative example 3
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 7%, lauroyl amido CAB 4%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
The difference of the present embodiment and embodiment one is: the mass percent of alkyl glycoside is become 0 from 2%, the mass percent of fatty alcohol-polyoxyethylene ether is become 0% from 2%, the mass percent of ethoxylated alkyl sulfate becomes 7% from 5%, and the mass percent of lauroyl amido CAB becomes 4% from 2%.
Preparation method: similar with the preparation method in embodiment one.
comparative example 4
Laundry soap lye comprises following component and mass percent thereof: potassium laurate 4%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl glycoside 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
The difference of the present embodiment and embodiment one is: the mass percent of potassium laurate is become 4% from 2%, and the mass percent of potassium stearate becomes 0 from 2%.
Preparation method: similar with the preparation method in embodiment one.
comparative example 5
Laundry soap lye comprises following component and mass percent thereof: potassium stearate 4%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl glycoside 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
The difference of the present embodiment and embodiment one is: the mass percent of potassium laurate is become 0 from 2%, and the mass percent of potassium stearate becomes 4% from 2%.
Preparation method: similar with the preparation method in embodiment one.
comparative example 6
Laundry soap lye comprises following component and mass percent thereof: potassium palmitate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl glycoside 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, water 81.95%.
The difference of the present embodiment and embodiment one is: change potassium laurate into potassium palmitate, and mass percent is 2%.
Preparation method: similar with the preparation method in embodiment one.
detersive power effect example
By the method for GB/T 13174-2008, the laundry soap lye of different embodiment is carried out to the test of detersive power, result is as shown in table 1.As known from Table 1, embodiment one, embodiment two and embodiment three show stronger detersive power, especially very excellent clean effect is shown to carbon black class and sebum class, and be significantly better than the clean effect of comparative example one, comparative example two and comparative example three, illustrate that the composite of ethoxylated alkyl sulfate, fatty alcohol-polyoxyethylene ether, lauroyl amido CAB and alkyl glycoside serves obvious synergy.Although fatty alcohol-polyoxyethylene ether and alkyl glycoside are all conventional nonionogenic tensides, surprisingly, for washing soap liquid system provided by the invention, fatty alcohol-polyoxyethylene ether and alkyl glycoside are all indispensable.
。
wash effect embodiment
By the method for GB/T 15818-2006, the laundry soap lye of different embodiment is carried out to the test of foam height after rinsing, result is as shown in table 2.As known from Table 2, embodiment one, embodiment two and embodiment three show stronger easy drift performance, namely rinse is can be considered through a rinsing, and be significantly better than the wash effect of comparative example one, comparative example two and comparative example three, illustrate that the mixed fatty acid soap that lauric acid, stearic acid and oleic acid generate through neutralization serves obvious synergy.Although lauric acid and stearic acid are all conventional saturated fatty acids, surprisingly, for washing soap liquid system provided by the invention, lauric acid soap and stearate soap are all indispensable.
。
Above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to protection scope of the present invention.
Claims (10)
1. a laundry soap lye, is characterized in that: comprise following component and mass percent thereof: mixed fatty acid soap 2 ~ 15%, ethoxylated alkyl sulfate 2 ~ 10%, fatty alcohol-polyoxyethylene ether 1 ~ 5%, lauroyl amido CAB 0.2 ~ 5%, alkyl glycoside 0.2 ~ 5%, Citrate trianion 0.1 ~ 3%, sequestrant 0.1 ~ 1.0%, thickening material 0.5 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 2%, sanitas 0.1 ~ 2%, essence 0 ~ 1%, water 50 ~ 90%.
2. laundry soap lye according to claim 1, it is characterized in that: described mixed fatty acid soap is obtained through alkali neutralization by mixed fatty acid, described mixed fatty acid by saturated fatty acid and unsaturated fatty acids with (3 ~ 8): the mass ratio of 1 forms, and described alkali is selected from alkali-metal oxyhydroxide.
3. laundry soap lye according to claim 2, is characterized in that: described saturated fatty acid by lauric acid and stearic acid with (1 ~ 2): the mass ratio of (2 ~ 1) forms, and described unsaturated fatty acids is oleic acid.
4. laundry soap lye according to claim 3, it is characterized in that: described basic metal is selected from sodium and/or potassium, described sequestrant is selected from tetrasodium ethylenediamine tetraacetate and/or disodium ethylene diamine tetraacetate, and described thickening material is sodium-chlor.
5. laundry soap lye according to claim 4, it is characterized in that: comprise following component and mass percent thereof: potassium laurate 1 ~ 4%, potassium stearate 1 ~ 4%, potassium oleate 0.5 ~ 2%, ethoxylated alkyl sulfate 3 ~ 6%, fatty alcohol-polyoxyethylene ether 1 ~ 3%, lauroyl amido CAB 1 ~ 3%, alkyl glycoside 1 ~ 3%, Tripotassium Citrate 0.2 ~ 1%, tetrasodium ethylenediamine tetraacetate 0.1 ~ 0.5%, sodium-chlor 1 ~ 3%, phenylethylene ethylene/propenoic acid ester copolymer 0.1 ~ 1%, sanitas 0.1 ~ 1%, essence 0 ~ 0.5%, water 70 ~ 90%.
6. laundry soap lye according to claim 5, is characterized in that: comprise following component and mass percent thereof: potassium laurate 2%, potassium stearate 2%, potassium oleate 1%, ethoxylated alkyl sulfate 5%, fatty alcohol-polyoxyethylene ether 2%, lauroyl amido CAB 2%, alkyl glycoside 2%, Tripotassium Citrate 0.25%, tetrasodium ethylenediamine tetraacetate 0.1%, sodium-chlor 1.5%, phenylethylene ethylene/propenoic acid ester copolymer 0.1%, sanitas 0.1%, essence 0.15%, water 81.8%.
7. laundry soap lye according to any one of claim 1 to 6, is characterized in that: the alkyl carbon chain lengths of described alkyl glycoside is C
8~ C
12.
8. laundry soap lye according to any one of claim 1 to 6, is characterized in that: described fatty alcohol-polyoxyethylene ether is selected from AEO
7and/or AEO
9.
9. laundry soap lye according to any one of claim 1 to 6, is characterized in that: described sanitas by Bronopol and methylisothiazolinone with (6 ~ 9): the mass ratio of 1 forms.
10. the preparation method of laundry soap lye according to any one of claim 1 to 9, is characterized in that: comprise the steps: thickening material and alkali to be added to the water, be warming up to 60 ~ 80 DEG C, under agitation condition, add lauric acid, stearic acid and oleic acid; After reaction 0.1 ~ 1h, cooling, under agitation condition, adds ethoxylated alkyl sulfate, fatty alcohol-polyoxyethylene ether, lauroyl amido CAB, alkyl glycoside, citric acid, tetrasodium ethylenediamine tetraacetate, sanitas and essence, stir, obtain mixed solution; Under agitation condition, phenylethylene ethylene/propenoic acid ester copolymer, sanitas and essence are added in described mixed solution, stir and obtain laundry soap lye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510206598.4A CN104818168B (en) | 2015-04-28 | 2015-04-28 | A kind of laundry soap lye and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510206598.4A CN104818168B (en) | 2015-04-28 | 2015-04-28 | A kind of laundry soap lye and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104818168A true CN104818168A (en) | 2015-08-05 |
| CN104818168B CN104818168B (en) | 2016-07-06 |
Family
ID=53728651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510206598.4A Active CN104818168B (en) | 2015-04-28 | 2015-04-28 | A kind of laundry soap lye and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104818168B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255598A (en) * | 2015-11-17 | 2016-01-20 | 孙铭岐 | Detergent |
| CN105596231A (en) * | 2015-12-16 | 2016-05-25 | 无锡吉进环保科技有限公司 | Life oil stain cleaner |
| CN105985870A (en) * | 2016-07-13 | 2016-10-05 | 西南大学 | Quick-drying antimicrobial mildewproof multifunctional laundry detergent and preparation method thereof |
| CN107057888A (en) * | 2017-06-17 | 2017-08-18 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of feather products cleaning agent |
| CN107418796A (en) * | 2017-07-06 | 2017-12-01 | 广西顺帆投资有限公司 | One kind removes acarid soap lye |
| CN107418772A (en) * | 2017-06-17 | 2017-12-01 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of the cleaning agent of down products |
| CN108219993A (en) * | 2018-01-09 | 2018-06-29 | 广州市加茜亚化妆品有限公司 | A kind of micro-perfume capsule liquid detergent and preparation method thereof |
| CN108823012A (en) * | 2018-05-22 | 2018-11-16 | 吕树平 | A kind of sterilizing laundry soap lye of natural green environmental protection and preparation method thereof |
| CN109135954A (en) * | 2018-09-30 | 2019-01-04 | 北京洛娃日化有限公司 | A kind of environment-friendly high-efficiency liquid detergent |
| CN111085142A (en) * | 2019-12-16 | 2020-05-01 | 东莞波顿香料有限公司 | Orange oil nano dispersion, preparation method thereof, transparent beverage and detergent |
| CN112745995A (en) * | 2019-10-31 | 2021-05-04 | 陆卫 | Perfume type natural soap liquid and preparation method thereof |
| CN113528256A (en) * | 2020-04-14 | 2021-10-22 | 刘含勤 | Strong detergent for natural vegetable oil conversion |
| CN115247108A (en) * | 2021-04-26 | 2022-10-28 | 塞买提江 | Method for preparing soil soap liquid |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107699401A (en) * | 2017-08-24 | 2018-02-16 | 林福运 | A kind of children's laundry soap lye |
| CN109181914B (en) * | 2018-08-04 | 2020-09-29 | 中山市妙洁精细化工有限公司 | Long-acting antibacterial laundry soap solution and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101166815A (en) * | 2005-04-29 | 2008-04-23 | 克劳罗克斯公司 | Oxidizing compositions and methods thereof |
| CN103013723A (en) * | 2012-12-21 | 2013-04-03 | 纳爱斯集团有限公司 | Low-foam laundry detergent composite facilitating rinsing |
-
2015
- 2015-04-28 CN CN201510206598.4A patent/CN104818168B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101166815A (en) * | 2005-04-29 | 2008-04-23 | 克劳罗克斯公司 | Oxidizing compositions and methods thereof |
| CN103013723A (en) * | 2012-12-21 | 2013-04-03 | 纳爱斯集团有限公司 | Low-foam laundry detergent composite facilitating rinsing |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255598A (en) * | 2015-11-17 | 2016-01-20 | 孙铭岐 | Detergent |
| CN105596231A (en) * | 2015-12-16 | 2016-05-25 | 无锡吉进环保科技有限公司 | Life oil stain cleaner |
| CN105985870A (en) * | 2016-07-13 | 2016-10-05 | 西南大学 | Quick-drying antimicrobial mildewproof multifunctional laundry detergent and preparation method thereof |
| CN107057888A (en) * | 2017-06-17 | 2017-08-18 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of feather products cleaning agent |
| CN107418772A (en) * | 2017-06-17 | 2017-12-01 | 安徽方翔羽绒制品有限公司 | A kind of preparation method of the cleaning agent of down products |
| CN107418796A (en) * | 2017-07-06 | 2017-12-01 | 广西顺帆投资有限公司 | One kind removes acarid soap lye |
| CN108219993A (en) * | 2018-01-09 | 2018-06-29 | 广州市加茜亚化妆品有限公司 | A kind of micro-perfume capsule liquid detergent and preparation method thereof |
| CN108823012A (en) * | 2018-05-22 | 2018-11-16 | 吕树平 | A kind of sterilizing laundry soap lye of natural green environmental protection and preparation method thereof |
| CN109135954A (en) * | 2018-09-30 | 2019-01-04 | 北京洛娃日化有限公司 | A kind of environment-friendly high-efficiency liquid detergent |
| CN112745995A (en) * | 2019-10-31 | 2021-05-04 | 陆卫 | Perfume type natural soap liquid and preparation method thereof |
| CN111085142A (en) * | 2019-12-16 | 2020-05-01 | 东莞波顿香料有限公司 | Orange oil nano dispersion, preparation method thereof, transparent beverage and detergent |
| CN113528256A (en) * | 2020-04-14 | 2021-10-22 | 刘含勤 | Strong detergent for natural vegetable oil conversion |
| CN115247108A (en) * | 2021-04-26 | 2022-10-28 | 塞买提江 | Method for preparing soil soap liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104818168B (en) | 2016-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104818168B (en) | A kind of laundry soap lye and preparation method thereof | |
| CN103013723B (en) | Low-foam laundry detergent composite facilitating rinsing | |
| CN101368147B (en) | Neat soap washing powder and preparing technique thereof | |
| SG193794A1 (en) | Ultra concentrated liquid laundry detergent | |
| CN105062703A (en) | Protease super-concentrated laundry detergent and preparation method thereof | |
| CN102618398A (en) | Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent | |
| CN104479899A (en) | Super-concentration fabric cleaning agent formula and preparing method thereof | |
| CN102864040B (en) | High-effect cleaning agent, preparation method thereof and special equipment | |
| EP0285436B1 (en) | Liquid detergent compositions | |
| CN103060140A (en) | Neutral low-foam liquid laundry detergent containing natural grease | |
| CN104031756A (en) | Concentrated laundry liquid suitable for machine washing, and preparation method thereof | |
| US20080064618A1 (en) | Low suds laundry detergents with enhanced whiteness retention | |
| CN102533465A (en) | Low foam fabric liquid detergent and preparation method thereof | |
| CN103966035A (en) | Environment-friendly water-saving super-concentrated cleaning agent and preparation method thereof | |
| CN103937620A (en) | Neutral detergent powder compound and preparation method thereof | |
| CN109135954A (en) | A kind of environment-friendly high-efficiency liquid detergent | |
| CN107603771A (en) | One kind concentration liquid detergent and preparation method | |
| CN103320236B (en) | Soap powder composition containing sodium fatty acid methyl ester sulfonate and preparation method thereof | |
| US6121227A (en) | Liquid detergent | |
| CN111534388A (en) | Low-foam easy-to-bleach sterilization laundry detergent and preparation method thereof | |
| CN108125848A (en) | A kind of shower cream and preparation method thereof | |
| CN106398903A (en) | Hand-wash laundry detergent capable of achieving rinsing easily and preparation method thereof | |
| KR20110019118A (en) | Liquid detergent composition | |
| CN106497712B (en) | A kind of easy rinsing underwear liquid detergent containing amino acid and preparation method thereof | |
| CN103820239A (en) | Mild safe laundry detergent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |